Synthesis of biodiesel from chicken’s skin waste by homogeneous transesterification

ABSTRACT

Poultry skin waste is considered to be a promising source of biodiesel. However, this source presents an environmental threat as it is being discharged into landfills without any treatment. We studied the feasibility of biodiesel production from poultry skin waste. Two-step extraction of lipids from chicken’s skin was developed and gave 97.5% yield using the optimum time and temperature. Esterification was then optimised to remove free fatty acids (FFA) where the ideal parameters were 65 °C during 30min with a molar ratio of methanol to oil of (1:3) and 1% of H₂SO₄. The third step was the transesterification which was performed using 60 °C and 300–600 rpm agitation for 1 h, with 1% basic catalyst and 1:3 (molar ratio) of methanol to oil. The biodiesel (FAME), was characterised using gas chromatography coupled with mass spectrometry (GC-MS) followed by chemical and physical analyses such as iodine number, acid number, flash point and cetane number. The total conversion was obtained using above conditions and most of the studied proprieties of produced biodiesel meet the EN14214 standard. This is an extremely encouraging result, offering a good source of biodiesel by valuing poultry skin waste.     

Environmental and economic benefit of recycling model of packaging waste:a case study on aluminum

In order to achieve sustainable utilization of natural resources, save energy and protect environment and ecosystem, it is important for a region or a nation to develop and implement a viable waste recycling model from both theoretical and practical point of view. Some packaging recycling models operated in developed countries are introduced in this article. Aluminium can recovery and recycling is emphasized. Cost effective, economic and environmental benefit of different models are compared and analyzed. The result shows that all recycling models have their characteristics due to the initial purpose of recovery and the situation of the implementing country. However, all the models contribute to the reduction of municipal solid waste disposal and resources conservation.     

Once there was a river: a benefit–cost analysis of rehabilitation of the Jordan River

The Jordan River is among the world’s most famous and culturally and historically significant waterways. The lower stretch of the river, however, has been a victim of development in a water scarce region, with current flows less than 5 % of historical levels. Furthermore, as it functions as an international border in a region of conflict, access to the river and its potential as a tourist attraction has been limited. Recently, there have been numerous calls for rehabilitation of the river. This study presents a first estimate of the economic benefits of such rehabilitation and compares them to the estimated costs. Identical contingent valuation method surveys were administered in Israel, Jordan, and the Palestinian Authority. Evidence from this study shows that, despite the large opportunity costs of increasing environmental flows, rehabilitation of the lower Jordan would produce positive net economic benefits. This is true even though the study estimated only the benefits to local populations, and not to international tourists or those outside the region. Net benefits are maximized when taking a regional, as opposed to strictly national, approach.     

Ecological and economical assessment of end‐of‐life waste recycling in the electrical and electronic recovery sector

Technological innovation and shorter product life cycles of electrical and electronic equipment coupled with their rapidly growing applications have resulted in the generation of an enormous amount of waste from electrical and electronic equipment (WEEE). To address the potential environmental problems that could stem from improper end‐of‐life management of WEEE, many countries have drafted national legislation to improve the reuse, remanufacture and material recycling from WEEE, and to reduce the amount of such waste going to landfills. With the introduction of such legislation comes an increased need for the recovery operators to evaluate the recycling costs and environmental benefits of reclaimed products and materials in order to select the most appropriate end‐of‐life options for individual products in WEEE. This paper presents a systematic methodology for ecological and economical assessment to provide a holistic understanding of the impacts associated with different end‐of‐life options for such waste. This assessment, in addition to providing decision‐support for the selection of the best possible end‐of‐life option for a particular product in WEEE, could also generate vital information to support the design and material selection processes during the initial product development activities. The assertion made is that the detailed considerations of the ecological and economical impacts associated with different end‐of‐life options will significantly improve the recovery and recycling of WEEE.     

The influence of resource strategies on childhood phthalate exposure—The role of REACH in a zero waste society

The present study aims to investigate how resource strategies, which intend to reduce waste and increase recycling, influence on human exposure to hazardous chemicals from material recycling. In order to examine the flows of hazardous chemicals in recycled material, a mass flow analysis of plastics and paper at European level, including the flow of phthalates, i.e. di(2-ethylhexyl) phthalate (DEHP), di-n-butyl phthalate (DBP), and benzyl-butyl phthalate (BBP), has been performed. The result for the year 2012 shows that 26% of plastic wastes and 60% of paper consumed in Europe were recycled. This corresponds to the finding that approximately 4% of DEHP and BBP and 18% of DBP annual demands in Europe as raw material re-enter the product cycle with recycled plastics and paper. To examine the potential contribution of the phthalate exposure through recycled plastics and paper, a case study assessing the childhood exposures to phthalates from foods packed in recycled paper and plastics has been performed for 2-year-old children in Denmark. The result verifies that an increase in recycled paperboard and PET bottles in food packaging material causes a significant increase in childhood exposure to DBP corresponding to an additional exposure of 0.116–0.355 μg/kg bw/day; up to 18% of the total DBP exposure in Danish 2-year-olds. While most of the DEHP exposure can be explained, more than 50% of DBP and 70% of BBP exposure sources still remain to be identified. Finally, a conceptual framework for a circular economy based on sustainable and clean resource flows is proposed in order to increase material recycling without increasing adverse health effects.     

Municipal solid waste management, source-separated waste and stakeholder’s attitude: a Contingent Valuation Study

Recognition of the social costs associated with traditional practices of urban waste management in India led to the formulation of Municipal Waste Management and Handling rules (2000). However, compliance with the proposed collection and disposal involves higher commitment in terms of both time and money on the part of the residents, local bodies as well as the state and central government. In this context, information about the value of the environmental improvements conferred upon the city dwellers would be important from the planner’s perspective. Given the non-market characteristic of waste disposal services, we infer about beneficiaries’ perceived demand for the proposed service by means of Double-Bounded Dichotomous Choice Contingent Valuation Survey conducted in the Bally Municipality in the district of Howrah, West Bengal. We estimate the average WTP by controlling for anchoring bias and use the annualized value of cost to examine the feasibility of the proposed system.     

Solid waste management in Bogotá: the role of recycling associations as investigated through SWOT analysis

In emerging economies, recycling provides an opportunity for cities to increase the lifespan of sanitary landfills, to reduce the costs of solid waste management, to decrease environmental problems from waste treatment by reincorporating waste into the productive cycle and to protect and develop the livelihoods of citizens who work as informal waste pickers. However, few studies have analysed the possibilities of and strategies for integrating the formal and informal sectors in solid waste management for the benefit of both. This integration is the key, especially in developing countries, to understanding how the recycling population can develop a business despite their social and economic limitations. The aim of this study was to perform a strength, weakness, opportunity and threat (SWOT) analysis of three recycling associations in Bogotá with the aim of examining and understanding the recycling situation from the perspective of members of the informal sector in their transition to becoming authorised waste providers. This issue has rarely been studied in the context of developing countries. The data used in the analysis are derived from multiple sources, including a literature review, Bogota’s recycling database, focus group meetings, governmental reports, national laws and regulations and interviews with key stakeholders. The results of this study show that as the primary stakeholders, the formal and informal waste management sectors can identify the internal and external conditions of recycling in Bogotá. Several strategies were designed based on the SWOT analysis. The participation of recycling associations is important in the design and application of waste policy, the consolidation of recycling through an effective business model, promotional programmes for social inclusion and the development of new transformation processes and technologies to valorise recycling materials. In conclusion, recycling associations can become authorised waste providers through a profitable business that increases recycling rates to create a productive process from waste during the generation of new materials and to decrease environmental problems while improving the welfare and living conditions of recyclers. These findings are important for Bogotá to advance and promote recycling as a key strategy for integrated sustainable waste management in the city.     

Carbon price impacts on sector cost: based on an input–output model of Beijing

Under the pressure of sustained growth in energy consumption in China, the implementation of a carbon pricing mechanism is an effective economic policy measure for promoting emission reduction, as well as a hotspot of research among scholars and policy makers. In this paper, the effects of carbon prices on Beijing’s economy are analyzed using input–output tables. The carbon price costs are levied in accordance with the products’ embodied carbon emission. By calculation, given the carbon price rate of 10 RMB/t-CO₂, the total carbon costs of Beijing account for approximately 0.22–0.40% of its gross revenue the same year. Among all industries, construction bears the largest carbon cost. Among export sectors, the coal mining and washing industry has much higher export carbon price intensity than other industries. Apart from traditional energy-intensive industries, tertiary industry, which accounts for more than 70% of Beijing’s economy, also bears a major carbon cost because of its large economic size. However, from 2007 to 2010, adjustment of the investment structure has reduced the emission intensity in investment sectors, contributing to the reduction of overall emissions and carbon price intensity.     

How much could a tanker spill cost British Columbians?

Ocean-based industries provide employment for nearly 30 % of the population in the North Coast region of British Columbia. Marine resource dependence has raised concerns about the possible economic impacts of a tanker spill along the proposed Enbridge Northern Gateway shipping route, which would export 525,000 barrels (bbls) per day of oil, bitumen, and condensate from Kitimat, British Columbia, to international markets. This study uses current and projected future values of four ocean-based industries and the Enbridge Northern Gateway project to estimate total (i.e., direct, indirect, and induced) economic effects on total output, employment, and gross domestic product (GDP) and impacts on the regional economy over a 50-year period under three potential spill scenarios: no impact (no spill), medium impact (a 63,000-bbl spill), and high impact (a 257,000-bbl spill). The proposed Enbridge Northern Gateway project could produce total positive economic effects of $600 million in output, 5,700–8,400 person years (PYs) of employment, and $300 million in GDP in the North Coast region. A medium impact tanker spill could cause losses of $40–$190 million in output, 400–1,500 PYs of employment, and $20–$100 million in GDP, and a high-impact spill could cause losses of $90–$300 million in output, 1,650–4,500 PYs of employment, and $70–$200 million in GDP.     

Analytical results and effective dose estimation of the operational Environmental Monitoring Program for the radioactive waste repository in Abadia de Goiás from 1998 to 2008

This paper presents the results of the Environmental Monitoring Program for the Radioactive waste repository of Abadia de Goiás, which was originated from the accident of Goiania, conducted by the Regional Center of Nuclear Sciences (CRCN-CO) of the National Commission on Nuclear Energy (CNEN), from 1998 to 2008.The results are related to the determination of ¹³⁷Cs activity per unit of mass or volume of samples from surface water, ground water, depth sediments of the river, soil and vegetation, and also the air-kerma rate estimation for gamma exposure in the monitored site.In the phase of operational Environmental Monitoring Program, the values of the geometric mean and standard deviation obtained for ¹³⁷Cs activity per unit of mass or volume in the analyzed samples were (0.08 ± 1.16) Bq.L⁻¹ for surface and underground water, (0.22 ± 2.79) Bq.kg⁻¹ for soil, and (0.19 ± 2.72) Bq.kg⁻¹ for sediment, and (0.19 ± 2.30) Bq.kg⁻¹ for vegetation. These results were similar to the values of the pre-operational Environmental Monitoring Program.With these data, estimations for effective dose were evaluated for public individuals in the neighborhood of the waste repository, considering the main possible way of exposure of this population group.The annual effective dose obtained from the analysis of these results were lower than 0.3 mSv.y⁻¹, which is the limit established by CNEN for environmental impact in the public individuals indicating that the facility is operating safely, without any radiological impact to the surrounding environment.     

Levellised electricity cost for wind and PV–diesel hybrid system in Oman at selected sites

Solar and wind energy data available for Oman indicate that these two resources are likely to play an important role in the future energy generation in this country. In this paper, a model is designed to assess wind and solar power cost per kWh of energy produced using different sizes of wind machines and photovoltaic (PV) panels at two sites in Oman, which then can be generalised for other locations in Oman. Hourly values of wind speed and solar radiation recorded for several years are used for these locations. The wind profiles from Thumrait and Masirah island are modelled using the Weibull distribution. The cost of wind-based energy is calculated for both locations using different sizes of turbines. Furthermore, this paper presents a study carried out to investigate the economics of using PV only and PV with battery as an energy fuel saver in two villages. The results show that the PV energy utilisation is an attractive option with an energy cost of the selected PV ranges between 0.128 and 0.144 $/kWh at 7.55% discount rate compared to an operating cost of 0.128–0.558 $\kWh for diesel generation, considering the capital cost of diesel units as sunk.     

Measuring individuals’ valuation distributions using a stochastic payment card approach: application to solid waste management in Nigeria

The objectives of this study are twofold. First it aims to establish empirical grounds for pricing the services of a new environmental management initiative in Enugu state, Nigeria. A joint initiative of the UK Department for International Development (DfID), Enugu State Environmental Protection Agency (ENSEPA) and the State and Local Government Programme (SLGP). The second is to test the empirical performance of a new approach to the contingent valuation method (CVM) i.e., the Stochastic Payment Card (SPC) design proposed by Wang (Contingent valuation of environmental resources: A stochastic perspective, 1997a, Journal of Environmental Economics & Management, 32:219–232, 1997b). The SPC design unlike many of the conventional CVM elicitation formats, takes into account the stochastic nature of individuals’ valuation decisions. The data for the analysis were obtained from a random sample survey of a district in Enugu metropolis. The results show that, on average, households in this city are willing to pay (WTP) 215 Naira ($1.6) monthly as against 200 Naira ($1.5) currently charged for the service by ENSEPA. Analysis of individual’s valuation distribution function indicates that this amount is positively and significantly related to the gender of the respondent, household income and the respondent’s perception of environmental quality.

The quest for environmental justice in China: citizen participation and the rural–urban network against Panguanying’s waste incinerator

Environmental distribution conflicts (EDCs) related to the construction and operation of waste incinerators have become commonplace in China. This article presents a detailed case study of citizen opposition to an incinerator in the village of Panguanying, Hebei Province. Drawing on in-depth fieldwork, we show how this case was notable, because it transcended the local arena to raise bigger questions about environmental justice, particularly in relation to public participation in siting decisions, after villagers exposed fraudulent public consultation in the environmental impact assessment. An informal network between villagers and urban environmental activists formed, enabling the Panguanying case to exert influence far beyond the village locality. This network was critical in creating wider public debate about uneven power and substandard public participation in siting disputes, a central feature in many Chinese EDCs. By transcending local specificities and exposing broader, systemic inadequacies, this case became instrumental in supporting “strong sustainability”.     

Analysis of the Capacity of Wellspring Conservation in Limestone Areas of Jinan

Spring water in the city of Jinan comes from the limestone areas. Understanding the capacity of wellspring conservation is a critical point to resume the perennial spewing of the spring water. The vegetation, soil, and other natural and human aspects related to the conservation are studied by using the methods of geographic information systems （GIS）, remote sensing （RS）, and field investigation. In the end, suggestions for administration and planning as well as countermeasures are put forward.     

‘We have a right to breathe clean air’: the emerging environmental justice movement against waste incineration in cement kilns in Spain

Waste is increasingly being used as an alternative to conventional fossil fuels in cement kilns worldwide. This has led to the emergence of socio-environmental conflicts in many countries in which local groups articulate a common struggle against the cement industry, a new target within the international anti-incineration movement. This case report aims at characterising this emerging movement against waste incineration in cement kilns in Spain and explores its main four discursive dimensions in relation to the concept of environmental justice. We argue that the movement against waste incineration in cement kilns is incipient and growing in Spain, and it uses a distinctive vocabulary to refer to the environmental justice dimension of the struggle.     

Citizens’ perception of the resilience of Australian cities

How well does the general public understand the concept of urban resilience? We address this question via an online survey of 500+ citizens living in three large Australian cities (Sydney, Melbourne and Perth). The majority of respondents claim not to know what urban resilience means. Of the remaining respondents, understanding ranges from poor to sophisticated. To circumvent this stated lack of understanding, we cast the concept of urban resilience into a more familiar framework consisting of risk and ability to cope with threats. This allows us to assess perceptions about what may challenge the resilience of Australian cities. Two concerns clearly emerge: (1) violence and social unrest and (2) environmental threats. Analysing a number of constructs from the social psychology literature reveals that these two concerns hold different cognitive signatures, whose understanding may facilitate discussion and communication within a public engagement process.     

Analysis of the Difference of the Basic Pension by Regions

Nowadays, the disparity of the basic pension in local regions of China can be described as follows: the low level of the unification of the basic pension systems, the large disparity of the level of the basic pension, and unfairness of the enterprises’ payment for the basic pension in different local regions in China. These have already brought many negative influences, which have greatly held back the development of the society and national economy. We should build the basic pension system in all local regions of China as a whole, which can cover all people and decrease the disparity in different local regions in China.     

Temporal-spatial Characteristics of the Urbanization of Rural Land in Xinjiang

Relying on remote sensor technology, GIS and Land-sat TM digital images, the authors use spatial and statistical analysis to examine the temporal-spatial characteristics of the change caused by urban Construction in Xinjiang＇s rural areas from the end of the 1980s to the end of the 1990s. The primary findings show the following： 1） The urban construction in rural areas has increased drastically. The expansion speed of urban land use has accelerated over the past decade. The sub-land use changes caused by the urbanization of rural are characterized by salient regional differentiation among the three main regions and among the 85 counties of Xinjiang. 2） The shift of land use is mostly characterized by cultivated land and grassland being used for urban and industrial projects. Moreover, this change of land use is characteristic of regional differences. 3） Factors of rural-urban construction land use changes in Xinjiang, are undoubtedly affected by natural environment, social, economic conditions, and to a larger degree by population growth, GDP development and industrial development.     

Degradation of 17α-ethinylestradiol by ozonation--identification of the by-products and assessment of their estrogenicity and toxicity

The presence of the synthetic estrogen 17α-ethinylestradiol (EE2) in waters at low levels is a concern due to its ability to act as an endocrine disruptor. Ozone (O₃) is commonly used in water treatment and reacts with EE2 to form by-products having characteristics that are mostly unknown. The aim of this study was to identify the by-products of E2 and EE2 ozonation and determine their estrogenicity and toxicity relative to the parent compound. Ozonation by-products were identified via LC-MS analysis. The estrogenicity was measured using the YES assay, and toxicity was determined by monitoring effects on histology of fetal rat testes and testosterone secretion by these tissues. Two EE2 by-products were identified with open phenolic ring structures (masses 302 and 344 u). The Yeast Estrogen Screening (YES) assay showed a decreased but incomplete removal of estrogenicity after ozonation of EE2. Histological analysis of fetal testes revealed that neither E2 nor EE2, with or without ozonation, had any effect on seminiferous cord formation; however, a remarkable negative effect on testosterone secretion was observed, with EE2 by-products after ozonation showing the most rapid and extensive inhibition. These results show that the removal of EE2 via reaction with O₃ resulted in the formation of by-products that are less estrogenic (as demonstrated by the YES assay), but have a greater negative impact on testosterone secretion. Thus, the disappearance of the parent compound is not a sufficient endpoint, as the by-products created may be more toxic. Care should be taken when implementing oxidation applications such as ozone during waste water treatment.