上海河流氮负荷的年际变化及其水体富营养化的原因探讨

利用1990-2002年水质监测数据,分析了上海河流水体中氮负荷(总氮和氨氮)的年际变化特征：从整体上来看,上海河流水体氮负荷较大,氮污染严重:苏州河、黄浦江下游河段氮负荷明显高于上游河段,市区河流氮负荷明显高于郊区河流;从年际变化上看,苏州河、黄浦江、市区河流(除龙华港)水体历年氮含量有降低趋势,郊区河流水体历年氮含量有增长趋势。在此基础上,从六个方面讨论了造成上海河流水体富营养化的原因,以期为上海市河流综合整治的规划决策提供重要的科学依据。     

基于北京清河流域水质提升的入河排污口排放要求确定策略研究

为探究基于流域水质目标的入河排污口排放标准与排污许可的实施路径,以北京清河为例,通过入河排污口实地摸排,确定了22个入河排污口和5个河道断面,并于2019年3—10月对27个采样点进行12次水样采集,对水样COD、氨氮、TN和TP进行检测。基于研究河段实测数据,应用MIKE11模型构建流域水动力水质模型,分析3种情景组合的截污纳管方案(方案1)、截污减排方案(方案2)对河段水质的改善效果,以及减排方案在雨期、非雨期对河段水质的污染影响。结果表明:(1)与方案1相比,方案2下研究河段水质状况明显改善,下游出水断面(Q5断面)的COD、氨氮、TN和TP模拟值分别降低49.08%、61.27%、65.80%、63.86%;COD、氨氮、TN和TP排放总量分别削减了541.95、46.13、216.79、8.30t/a。(2)雨期雨水汇入河段后,各污染物达标情况反而恶化,因此应做好入河排污口的污染管控,科学控制入河排污口雨期污染。     

着生藻类在苏州河黄浦江水质监测中的应用

对苏州河和黄浦江两条河流7个样点着生藻类进行了1年的动态研究,比较分析了2条河流着生藻类种类、数量、密度、多样性指数和优势种的变化情况,并且采用Palmer提出的20属耐受污染藻类的污染指数值求出水体的总污染指数。分析结果表明,苏州河和黄浦江的着生藻类主要为硅藻,各月各样点藻类的总污染指数分别为29、32,水质状况均是重度有机污染。     

上海城市水环境质量改善历程与面临的挑战

上海市排污总量大,污染负荷重.历史上,黄浦江曾经黑臭,苏州河则在20世纪70～90年代终年黑臭,地表水污染一度成为困扰上海环境的一个主要问题.20世纪80年代以来,上海加大了对城市受污染河流的治理力度,开展了一系列工作,其中苏州河修复是最具代表性的一项.苏州河治理耗资157亿元,历时20年.在实施了苏州河污水合流一期、苏州河环境综合整治一、二、三期项目后,苏州河黑臭现象消失,水质持续改善,滨河风貌明显改观,受到各方面高度评价.与此同时,上海城市水环境质量总体趋好,而要进一步稳定和持续改善全市水环境质量,深化整治势在必行,水环境工作者面临新的挑战.     

黄浦江水质的模糊数学综合评价研究

在黄浦江的水质综合评价中,采用基于加权平均模型的模糊数学综合评价法进行评价,取得了良好的效果。研究结果表明,黄浦江水质基本属于Ⅲ～Ⅳ类水,偏Ⅳ类。并尝试采用SPSS统计软件进行多元统计分析,深入探讨各污染指标之间的相互关系,更好地了解黄浦江水质的污染特性。通过SPSS统计软件的相关分析结果表明,所选择的7项污染指标是有代表性的。     

城市污水处理的水环境效应预测和分析

城市污水处理是城市环境综合整治的一项重要措施，从佛山市城市污水和地表水环境的实际情况出发，建立了可行的水量方程的一维扩散方程，预测佛山市场城市污水处理对佛山水道质改变情况，结果表明建设污水处理厂可以大大减缓军桥涌河段的有机污染态势，但对以工业污染为主的横溶附近河段水质改善程度较小。并讨论了污水口设置位置差异对水质改善的影响，提出排污口的最佳位置。     

微生物在苏州河生态系统中的地位及作用

苏州河是上海的母亲河 ,但近年来随着上海经济的发展 ,苏州河的污染越来越严重。这不仅损害了上海市民的生活质量和身体健康 ,而且与上海国际大都市的形象格格不入。 2 0世纪 80年代 ,上海市政府开始治理苏州河 ,但从未从生态学的角度治理过苏州河。微生物作为生态系统重要组成部分———分解者 ,对维持苏州河生态系统的平衡起着极其重要的作用。微生物不仅能降解苏州河水体和底泥中的有机物 ,而且可作为水体污染程度及受污后治理恢复状况的指示指标。本文主要选取有代表性的指示微生物 ,通过对苏州河上海市区段 8个采样段面处底泥 (主要是表层底泥 )中微生物指标的定量测试及代表性河段的耗氧速率测定 ,来了解目前苏州河的污染状况及微生物在整个生态系统中的地位和作用 ,从而为苏州河的综合治理提供依据。     

微生物在苏州河生态系统中的地位及作用

苏州河是上海的母亲河，但近年来随着上海经济的发展，苏州河的污染越来越严重。这不仅损害了上海市民的生活质量和身体健康。而且与上海国际大都市的形象格格不入。20世纪80年代，上海市政府开始治理苏州河，但从未从生态学的角度治理过苏州河。微生物作为生态系统重要组成部分－分解者，对维持苏州河生态系统的平衡起着极其重要的作用。微生物不仅能降解苏州河水体和底泥中的有机物，而且可作为水体污染程度及受污后治理恢复状况的指示指标。本文主要选取有代表性的指示微生物，通过对苏州河上海市区段8个采样段面处底泥（主要是表层底泥）中微生物指标的定量测试及代表性河段的耗氧速率测定，来了解目前苏州河的污染状况及微生物在整个生态系统中的地位和作用，从而为苏州河的综合治理提供依据。     

一种兼顾水质目标和成本投入的流域减排措施优化方法

综合考虑断面水质及治污成本,构建流域治污减排措施优化模型,分析单位污染物去除成本与断面水质改善间的关系,并以承德市武烈河流域治污减排优化为例,绘制治污减排措施优化曲线,提出优化方案。结果表明,在达到流域水质要求的情况下,优化后,治污减排项目由34项缩减到22项,平均单位COD去除成本由1.44万元/t下降到0.65万元/t,同时实现了流域水质达标和降低投入成本的要求。     

黄浦江上游来水与黄浦江水源水质内在关联研究

使用有机污染综合指数评价和数理统计方法,对1986—2000年黄浦江水源地及黄浦江上游来水的水质监测数据进行分析。结果表明,黄浦江水源近15a水质变化可分为缓慢恶化、加速恶化和逐渐改善3个阶段;黄浦江松浦大桥取水口水质与园泄泾相近,且均劣于淀峰和太浦河,优于大泖港;大泖港与松浦大桥水质密切相关,对松浦大桥取水口水质恶化贡献很大。基于这一机理建立的回归方程能够较好地拟合出取水口水质的演变趋势。     

Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments of rivers and an estuary in Shanghai, China

Concentrations, spatial distribution and sources of 17 polycyclic aromatic hydrocarbons (PAHs) and methylnaphthalene were investigated in surface sediments of rivers and an estuary in Shanghai, China. Total PAH concentrations, excluding perylene, ranged from 107 to 1707 ng/g-dw. Sedimentary PAH concentrations of the Huangpu River were higher than those of the Yangtze Estuary. The concentration of the Suzhou River was close to the average concentration of the Huangpu River. PAHs source analysis suggested that, in the Yangtze Estuary, PAHs at locations far away from cities were mainly from petrogenic sources. At other locations, both petrogenic and pyrogenic inputs were significant. In the Huangpu and Suzhou Rivers, pyrogenic input outweighed other sources. The pyrogenic PAHs in the upper reaches of the Huangpu River were mainly from the incomplete combustion of grass, wood and coal, and those in the middle and lower reaches were from vehicle and vessel exhaust.     

可视化黄浦江水环境数学模型系统设计与开发

随着信息技术的高速发展,传统的水环境数学模型与数据库技术、GIS技术、可视化编程工具紧密结合,水环境数学模型的可视化是其发展的一个重要趋势,也是开发水环境决策支持系统和水环境数学模型商业软件的重要基础。对可视化水环境数学模型的设计框架进行了初步探讨,并结合自主开发的可视化黄浦江二维水环境数学模型系统,介绍可视化水环境数学模型的设计与开发。     

底泥对河流的二次污染浅析

根据底冲中污染物质累积和释放过程和底泥对河流二次污染的机理,运用适用的模式和苏州河的实测资料,可得到二次污染ＢＯＤ和ＣＯＤ的年释放量,以及增加上覆河上的ＢＯＤ和ＣＯＤ浓度。由此认为,对于底泥污染严重的河流,疏浚是必不可少的,其目的在于清除或隔绝黑富集层上覆河上的二次污染。     

多水源供水管网中铁释放规律

针对水源切换而引起的水质超标现象,开展了多水源联合供水条件下管网中铁释放规律的研究。分析了北方某城市2种水源(滦河水和长江水)的水质特点,利用实验模拟反应器分别研究了水源完全置换和供水分界线处水源混合区域的铁释放规律。结果表明,多水源供水管网的铁释放速率与水源水质密切相关,特别是水中含高浓度SO2-4和氯化物时会加快铁的释放。不同水源之间的频繁切换会破坏管垢表面的钝化层,使铁释放速率迅速变化,随后会有所缓解,但新的平衡的形成需要较长时间。供水分界线处的水源混合区域,由于水质的不断变化造成管垢表面很难形成稳定的钝化层,铁释放速率持续偏高,只有当长江水所占比例高达75%以上时才能得到抑制。     

Trace metal and metalloid levels in surface water of Marcal River before and after the Ajka red mud spill, Hungary

The aim of this study was to compare and assess the dissolved concentrations of trace elements (As, Zn, Hg, Cd, Cr, Ni, Pb and Cu) in surface water of Marcal River before and after the red mud spill that occurred in Ajka, western Hungary, in October 2010. The caustic sludge flooded the surrounding settlements and polluted the nearby Torna Creek, which flows through the Marcal and Raba rivers into the Danube. A total of 92 surface water samples were collected from the Marcal River in the period of 2007–2012 and analysed for dissolved trace metal(loid)s by atomic absorption spectroscopy method. After the spill, the water management authority initially focused on acid dosing of surface waters to lower pH and was effective in lowering both pH and metal(loid) concentrations. Among the dissolved trace metal(loid)s, arsenic and nickel levels were moderately higher in the Marcal River 2 years since the spill compared to that observed in the pre-disaster period. The concentrations of dissolved trace metal(loid)s did not exceed the European water quality standards and the US Environmental Protection Agency aquatic life criteria values (excluding one sample for cadmium).     

Occurrence and risk assessment of antidepressants in Huangpu River of Shanghai,China

Antidepressants are gaining public attention because of increasing reports of their occurrence in environment and their potential impact on ecosystems and human health. Continuous input of pharmaceuticals into rivers, through psychiatric hospital or wastewater treatment plant (WWTPs) effluent, may cause adverse effects on the aquatic ecosystems of the receiving water bodies. This work investigates the occurrence and sources of 8 antidepressants in main stream and tributaries of Huangpu River in Shanghai. The detected concentrations of the selected antidepressants ranged from low nanogram per liter to 42.9 ng L^?1 (fluoxetine) in main stream and ranged from low nanogram per liter to 33.7 ng L^?1 (fluoxetine) in tributaries. To study the effect of hospital or wastewater treatment plants (WWTPs) on environment, the upstream and downstream samples were analyzed. Generally, antidepressants had greater concentrations in downstream than that in upstream of the WWTPs or hospitals. It is suggesting that WWTPs and hospitals may introduce pollution into water environment. A preliminary risk assessment was conducted: none of the eight target compounds yielded risk quotient (RQ) values more than 0.1, thus indicating that no adverse effect is expected in water environment. These results will provide background data for future antidepressants pollution control and management in Shanghai, China.     

Water mass interaction in the confluence zone of the Daning River and the Yangtze River—a driving force for algal growth in the Three Gorges Reservoir

Increasing eutrophication and algal bloom events in the Yangtze River Three Gorges Reservoir, China, are widely discussed with regard to changed hydrodynamics and nutrient transport and distribution processes. Insights into water exchange and interaction processes between water masses related to large-scale water level fluctuations in the reservoir are crucial to understand water quality and eutrophication dynamics. Therefore, confluence zones of tributaries with the Yangtze River main stream are dedicated key interfaces. In this study, water quality data were recorded in situ and on-line in varying depths with the MINIBAT towed underwater multi-sensor system in the confluence zone of the Daning River and the Yangtze River close to Wushan City during 1 week in August 2011. Geostatistical evaluation of the water quality data was performed, and results were compared to phosphorus contents of selective water samples. The strongly rising water level throughout the measurement period caused Yangtze River water masses to flow upstream into the tributary and supply their higher nutrient and particulate loads into the tributary water body. Rapid algal growth and sedimentation occurred immediately when hydrodynamic conditions in the confluence zone became more serene again. Consequently, water from the Yangtze River main stream can play a key role in providing nutrients to the algal bloom stricken water bodies of its tributaries.     

Synthetic musks in the aquatic environment and personal care products in Shanghai, China

The concentrations and distributions of six polycyclic musks and two nitro musks in Suzhou Creek, influent/effluent of a sewage treatment plant (STP), and household commodities were investigated and discussed in this study. The levels of 1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexa-methylcyclopenta(g)-2-benzopyran (HHCB) and 7-acetyl-1,1,3,4,4,6-hexamethyl-1,2,3,4-tetrahydronaphthalene (AHTN) in Suzhou Creek were 3-78 ng g(-1) (dry weight) and 2-31 ng g(-1) (dry weight) in sediments, while 20-93 ng l(-1) and 8-20 ng l(-1) in surface waters. The results indicated a low proportion of wastewater burden in this river. The concentrations of HHCB and AHTN in the effluent of the STP were 5- to 6-fold higher than those in Suzhou Creek. The amounts discharged into the aquatic environment from sewage in Shanghai are 1.26 t (HHCB) and 0.38 t (AHTN) in 2007, and the input into the STPs is estimated to be HHCB 0.2 g y(-1) and AHTN 0.06 g y(-1) per inhabitant, respectively. A broad concentration range of HHCB and AHTN could be observed in household commodities. The distributions are in accordance with the profiles of musks in aquatic environment, with HHCB and AHTN being the major components.