Effects of Land Use and Sample Location on Nitrate‐Stream Flow Hysteresis Descriptors during Storm Events

The U.S. Geological Survey's New Jersey and Iowa Water Science Centers deployed ultraviolet‐visible spectrophotometric sensors at water‐quality monitoring sites on the Passaic and Pompton Rivers at Two Bridges, New Jersey, on Toms River at Toms River, New Jersey, and on the North Raccoon River near Jefferson, Iowa to continuously measure in‐stream nitrate plus nitrite as nitrogen (NO₃ + NO₂) concentrations in conjunction with continuous stream flow measurements. Statistical analysis of NO₃ + NO₂ vs. stream discharge during storm events found statistically significant links between land use types and sampling site with the normalized area and rotational direction of NO₃ + NO₂‐stream discharge (N‐Q) hysteresis patterns. Statistically significant relations were also found between the normalized area of a hysteresis pattern and several flow parameters as well as the normalized area adjusted for rotational direction and minimum NO₃ + NO₂ concentrations. The mean normalized hysteresis area for forested land use was smaller than that of urban and agricultural land uses. The hysteresis rotational direction of the agricultural land use was opposite of that of the urban and undeveloped land uses. An r² of 0.81 for the relation between the minimum normalized NO₃ + NO₂ concentration during a storm vs. the normalized NO₃ + NO₂ concentration at peak flow suggested that dilution was the dominant process controlling NO₃ + NO₂ concentrations over the course of most storm events.     

Spatial Variability of Nitrate Concentrations Under Diverse Conditions in Tributaries to a Lake Watershed1

Abstract: Nitrate‐nitrogen (NO₃‐N) concentrations in stream water often respond uniquely to changes in inter‐annual conditions (e.g., biological N uptake and precipitation) in individual catchments. In this paper, we assess (1) how the spatial distribution of NO₃‐N concentrations varies across a dense network of nonnested catchments and (2) how relationships between multiple landscape factors [within whole catchments and hydrologically sensitive areas (HSAs) of the catchments] and stream NO₃‐N are expressed under a variety of annual conditions. Stream NO₃‐N data were collected during two synoptic sampling events across >55 tributaries and two synoptic sampling periods with >11 tributaries during summer low flow periods. Sample tributaries drain mixed land cover watersheds ranging in size from 0.150 to 312 km² and outlet directly to Cayuga Lake, New York. Changes in NO₃‐N concentration ratios between each sampling event suggest a high degree of spatial heterogeneity in catchment response across the Cayuga Lake Watershed, ranging from 0.230 to 61.4. Variations in NO₃‐N concentrations within each of the large synoptic sampling events were also high, ranging from 0.040 to 8.7 mg NO₃‐N/l (March) and 0.090 to 15.5 mg NO₃‐N/l (October). Although Pearson correlation coefficients suggest that this variability is related to multiple landscape factors during all four sampling events, partial correlations suggest percentage of row crops in the catchments as the only similar factor in March and October and catchment area as the only factor during summer low flows. Further, the strength of the relationships is typically lower in the HSAs of catchment. Advancing current understanding of such variations and relationships to landscape factors across multiple catchments – and under a variety of biogeochemical and hydrological conditions – is important, as (1) nitrate continues to be employed as an indicator of regional aquatic ecosystem health and services and (2) a unified framework approach for understanding individual catchment processes is a rapidly evolving focus for catchment‐based science and management.     

Field Testing the Riparian Ecosystem Management Model on a Riparian Buffer in the North Carolina Upper Coastal Plain

The riparian ecosystem management model (REMM) was field tested using five years (2005‐2009) of measured hydrologic and water quality data on a riparian buffer located in the Tar‐Pamlico River Basin, North Carolina. The buffer site received NO₃‐N loading from an agricultural field that was fertilized with inorganic fertilizer. Field results showed the buffer reduced groundwater NO₃‐N concentration moving to the stream over a five‐year period. REMM was calibrated hydrologically using daily field‐measured water table depths (WTDs), and with monthly NO₃‐N concentrations in groundwater wells. Results showed simulated WTDs and NO₃‐N concentrations in good agreement with measured values. The mean absolute error and Willmott's index of agreement for WTDs varied from 13‐45 cm and 0.72‐0.92, respectively, while the root mean square error and Willmott's index of agreement for NO₃‐N concentrations ranged from 1.04‐5.92 mg/l and 0.1‐0.86, respectively, over the five‐year period. REMM predicted plant nitrogen (N) uptake and denitrification were within ranges reported in other riparian buffer field studies. The calibrated and validated REMM was used to simulate 33 years of buffer performance at the site. Results showed that on average the buffer reduced NO₃‐N concentrations from 12 mg/l at the field edge to 0.7 mg/l at the stream edge over the simulation period, while the total N and NO₃‐N load reductions from the field edge to the stream were 77 and 82%, respectively.     

Hydrologic Controls on Nitrogen and Phosphorous Dynamics in Relict Oxbow Wetlands Adjacent to an Urban Restored Stream

Although wetlands are known to be sinks for nitrogen (N) and phosphorus (P), their function in urban watersheds remains unclear. We analyzed water and nitrate (NO₃^?) and phosphate (PO₄^3?) dynamics during precipitation events in two oxbow wetlands that were created during geomorphic stream restoration in Baltimore County, Maryland that varied in the nature and extent of connectivity to the adjacent stream. Oxbow 1 (Ox1) received 1.6‐4.2% and Oxbow 2 (Ox2) received 4.2‐7.4% of cumulative streamflow during storm events from subsurface seepage (Ox1) and surface flow (Ox2). The retention time of incoming stormwater ranged from 0.2 to 6.7 days in Ox1 and 1.8 to 4.3 days in Ox2. Retention rates in the wetlands ranged from 0.25 to 2.74 g N/m²/day in Ox1 and 0.29 to 1.94 g N/m²/day in Ox2. Percent retention of the NO₃^?‐N load that entered the wetlands during the storm events ranged from 64 to 87% and 23 to 26%, in Ox1 and Ox2, respectively. During all four storm events, Ox1 and Ox2 were a small net source of dissolved PO₄^3? to the adjacent stream (i.e., more P exited than entered the wetland), releasing P at a rate of 0.23‐20.83 mg P/m²/day and 3.43‐24.84 mg P/m²/day, respectively. N and P removal efficiency of the oxbows were regulated by hydrologic connectivity, hydraulic loading, and retention time. Incidental oxbow wetlands have potential to receive urban stream and storm flow and to be significant N sinks, but they may be sources of P in urban watersheds.     

The Role of Headwater Wetlands in Altering Streamflow and Chemistry in a Maine,USA Catchment1

Morley, Terry R., Andrew S. Reeve, and Aram J.K. Calhoun, 2011. The Role of Headwater Wetlands in Altering Streamflow and Chemistry in a Maine, USA Catchment. Journal of the American Water Resources Association (JAWRA) 1‐13. DOI: 10.1111/j.1752‐1688.2011.00519.x Abstract: Headwater wetlands, including hillside seeps, may contribute to downstream systems disproportionately to their relatively small size. We quantified the hydrology and chemistry of headwater wetlands in a central Maine, USA, catchment from 2003 to 2005 to determine their role in maintaining headwater streamflow and in affecting stream chemistry. A few of these headwater wetlands, commonly referred to as “seeps,” were characterized by relatively high groundwater discharge. During summer base flow, seeps were the primary source of surface water to the stream, contributing between 40 and 80% of stream water. Comparisons of groundwater and surface water dominant ion chemistry revealed only slight differences at the bedrock interface; however, significant changes occurred at the shallow groundwater‐surface water interface where we found decreases in total and individual cation concentrations with decreasing depth. Seep outflows significantly increased total cation and calcium concentrations in streams. Outflows at two seeps produced relatively high nitrate concentrations (88 ± 15 and 93 ± 15 μg/l respectively), yet did not correspond to higher nitrate in stream water below seep outflows (2 ± 1 μg/l). We demonstrate that small wetlands (< 1,335 m²) can contribute to headwater stream processes by linking groundwater and surface‐water systems, increasing the duration and magnitude of stream discharge, and by affecting stream chemistry, particularly during periods of base flow.     

IMPACT OF A TURFGRASS SYSTEM ON NUTRIENT LOADINGS TO SURFACE WATER1

ABSTRACT: Turfgrass systems are one of the most intensively managed land uses in the United States. Establishment and maintenance of high quality turfgrass usually implies substantial inputs of water, nutrients, and pesticides. The focus of this work was to quantify the concentration and loading of a typically maintained municipal turfgrass environment on surface water. Water quantity and quality data were collected from a golf course in Austin, Texas, and analyzed for a 13‐month period from March 20, 1998, to April 30, 1999. Twenty‐two precipitation events totaling 722 mm, produced an estimated 98 mm of runoff. Nutrient analysis of surface runoff exiting the course exhibited a statistically significant (p < 0.05) increase in median nitrate plus nitrite nitrogen (NO₃+NO₂‐N) concentration compared to runoff entering the course, a statistically significant decrease in ammonia nitrogen (NH₄‐N), but no difference in orthophosphate (PO₄‐P). During the 13‐month period, storm runoff contributed an estimated 2.3 kg/ha of NO₃+NO₂‐N and 0.33 kg/ha of PO₄‐P to the stream. Storm flow accounted for the attenuation of 0.12 kg/ha of NH₄‐N. Baseflow nutrient analysis showed a statistically significant increase in median NO₃+NO₂‐N, a significant reduction in NH₄‐N, and no change in PO₄‐P. Estimated NO₃+NO₂‐N mass in the baseflow was calculated as 4.7 kg/ha. PO₄‐P losses were estimated at 0.06 kg/ha, while 0.8 kg/ha of NH₄‐N were attenuated in baseflow over the study period. Even though nutrient concentrations exiting the system rarely exceeded nutrient screening levels, this turfgrass environment did contribute increased NO₃+NO₂‐N and PO₄‐P loads to the stream. This emphasizes the need for parallel studies where management intensity, soil, and climate differ from this study and for golf course managers to utilize an integrated management program to protect water quality while maintaining healthy turfgrass systems.     

Impact of an Invasive Exotic Species on Stream Nitrogen Levels in Southern Illinois1

Abstract: Autumn‐olive (Elaeagnus umbellata Thunb.) is an invasive, exotic shrub that has become naturalized in the eastern United States. Autumn‐olive fixes nitrogen (N) via a symbiotic relationship with the actinomycete Frankia. At the plot scale, the presence of autumn‐olive has been related to elevated soil water nitrate‐N (NO₃^?‐N) concentrations. This study examined the relationship between autumn‐olive cover in a watershed and stream water quality. Stream water nitrate‐N (NO₃^?‐N) and ammonium‐N (NH₄⁺‐N) concentrations were measured in 12 first order ephemeral streams draining watersheds with mixed forest cover and a range of 0‐35% autumn‐olive cover. Percent autumn‐olive cover was positively correlated with mean stream NO₃^?‐N concentrations, but was not correlated with mean stream NH₄⁺‐N concentrations. While other studies have demonstrated a significant relationship between native N‐fixers and stream NO₃^?‐N, this is the first study to document a relationship for an invasive, exotic N‐fixing species. Results suggest that this exotic species can be an additional source of NO₃^? in local and regional water bodies and demonstrates an additional negative ecosystem consequence of invasion beyond losses in biodiversity.     

Stormwater Runoff Quality and Quantity From Traditional and Low Impact Development Watersheds1

Abstract: The quality and quantity of residential stormwater runoff from a control, traditional, and low impact development (LID) watershed were compared in a paired watershed study. A traditional neighborhood was built using typical subdivision standards while a LID design was constructed with best management practices including grass swales, cluster housing, shared driveways, rain gardens, and a narrower pervious concrete‐paver road. Weekly, flow‐weighted, composite samples of stormwater were analyzed for nitrate + nitrite‐nitrogen (NO₃ + NO₂‐N), ammonia‐nitrogen (NH₃‐N), total Kjeldahl nitrogen (TKN), total phosphorus (TP), and total suspended solids (TSS). Monthly composite samples were analyzed for total copper (Cu), lead (Pb), and zinc (Zn). Mean weekly storm flow increased (600x) from the traditional watershed in the postconstruction period. Increased exports of TKN, NO₃ + NO₂‐N, NH₃‐N, TP, Cu, Zn, and TSS in runoff were associated with the increased storm flow. Postconstruction storm flow in the LID watershed was reduced by 42% while peak discharge did not change from preconstruction conditions. Exports were reduced from the LID watershed for NH₃‐N, TKN, Pb, and Zn, while TSS and TP exports increased.     

WATERSHED SCALING EFFECT ON BASE FLOW NITRATE,VALLEY AND RIDGE PHYSIOGRAPHIC PROVINCE1

ABSTRACT: A study of stream base flow and NO₃‐N concentration was conducted simultaneously in 51 subwatersheds within the 116‐square‐kilometer watershed of East Mahantango Creek near Klingerstown, Pennsylvania. The study was designed to test whether measurable results of processes and observations within the smaller watersheds were similar to or transferable to a larger scale. Ancillary data on land use were available for the small and large watersheds. Although the source of land‐use data was different for the small and large watersheds, comparisons showed that the differences in the two land‐use data sources were minimal. A land use‐based water‐quality model developed for the small‐scale 7.3‐square‐kilometer watershed for a previous study accurately predicted NO₃‐N concentrations from sampling in the same watershed. The water‐quality model was modified and, using the imagery‐based land use, was found to accurately predict NO₃‐N concentrations in the subwatersheds of the large‐scale 116‐square‐kilometer watershed as well. Because the model accurately predicts NO₃‐N concentrations at small and large scales, it is likely that in second‐order streams and higher, discharge of water and NO₃‐N is dominated by flow from smaller first‐order streams, and the contribution of ground‐water discharge to higher order streams is minimal at the large scale.     

Constructed Wetland Treatment of Nitrates: Removal Effectiveness and Cost Efficiency

A constructed wetland (CW) was strategically placed to treat nitrates in groundwater as part of a watershed‐based farmer engagement process. Using stream water quality data collected before and after installation, this CW was found to reduce stream concentrations of nitrogen from nitrate (NO₃‐N) during the growing season by about 0.14 mg/l at mean streamflow, a 17% reduction. Based upon realistic ecological and economic assumptions, about 80 kg of NO₃‐N were removed annually by the CW at a cost of around US$30/kg. This per unit cost is at the low range of small wastewater treatment plant costs for nitrates, but higher than the costs of reduced fertilizer application.     

Nutrients and suspended solids in dry weather and storm flows from a tropical catchment with various proportions of rural and urban land use

The results of an investigation characterizing the nutrients and suspended solids contained in stormwater from Kranji Catchment in Singapore are reported in this paper. Stormwater samples were collected from 4 locations and analyzed for the following eleven analytes: TOC, DOC, TN, TDN, NH₄⁺, NO₂⁻ + NO₃⁻ (NO_x), TP, TDP, OP, SiO₂ and TSS. Stormwater was sampled from catchments with various proportions of rural and urban land use, including forested areas, grassed areas, agricultural and residential and commercial areas. The event mean concentrations (EMCs) of nutrients and TSS from sampling stations which have agricultural land use activities upstream were found to be higher. Comparison of site EMCs (SMCs) with published data showed that the SMCs of the nutrients and TSS are generally higher than SMCs reported for forested areas but lower than published SMCs for urban areas. Positive correlations (p < 5%) were found between loading and peak flow at locations most impacted by ubanisation or agricultural activities. Correlation between loading and rainfall variables was less distinct. EMC was found to correlate less with rainfall and flow variables compared to pollutant loading. Unlike loading, no consistent pattern exists linking EMC to any particular storm or flow variable in any of the catchments. Lastly, positive correlations were obtained between the particulate forms of nitrogen and phosphorus and TSS.     

Characterizing Storm Hydrograph Rise and Fall Dynamics With Stream Stage Data1

Abstract: Storm‐flow transients (i.e., hydrograph rise and fall dynamics) may represent an important aspect of understanding streamflow dynamics. However, little is known about how temporal resolution of transient data and climate variability may color these potential indicators of hydrologic pattern or condition. Warm‐season stream stage and rainfall were monitored continuously (5 min) during the 2002 water year in eight tributaries of the Little Miami River (Ohio), which drain 17‐58 km² catchments. Rise rates generated using 5‐min data were different than those generated with mean daily data [calculated with the Indicators of Hydrologic Alteration (IHA) software], though fall rates were similar for fine and coarse temporal data. This result suggests that data with low temporal resolution may not be adequate to fully represent the dynamics of storm rise rates. Conversely, fall rates based on daily stage data (via IHA) were similar to those based on the 5‐min data, and so daily mean data may be appropriate for characterizing fall rates. We next analyzed the possible correlations between rainfall variability and storm‐flow stage dynamics. We derived rise and recession rates from storm stage hydrographs by assuming exponential rise and decay of a runoff peak. We found that raw rise rates (R_raw) were correlated with both the maximum rainfall rate and the time to the centroid of a rain event. We subsequently removed the trend based on these rainfall characteristics, which yielded new representations of rise rates abbreviated as R_rate and R_tcent, respectively, and that had lower variability than the uncorrected (raw) data. Fall rates were found to be independent of rainfall characteristics. Due to the predominant influence of stream hydrology upon aquatic biota and nutrient fluxes, our work suggests that these stage data analysis protocols can refine or otherwise reduce variability in these indices by accounting for relevant factors such as rainfall forcing. These protocols for derivation of transient indices should be tested for their potential to improve correlations between stream hydrology and temporally aligned biotic data and dissolved nutrient fluxes in streams.     

Winter Hydrology and NO3− Concentrations in a Forested Watershed: A Detailed Field Study in the Adirondack Mountains of New York1

Abstract: More than 85% of NO₃^? losses from watersheds in the northeastern United States are exported during winter months (October 1 to May 30). Interannual variability in NO₃^? loads to individual streams is closely related to interannual climatic variations, particularly during the winter. The objective of our study was to understand how climatic and hydrogeological factors influence NO₃^? dynamics in small watersheds during the winter. Physical parameters including snow depth, soil temperature, stream discharge, and water table elevation were monitored during the 2007‐2008 winter in two small catchments in the Adirondack Mountains, New York State. Snowpack persisted from mid‐December to mid‐April, insulating soils such that only two isolated instances of soil frost were observed during the study period. NO₃^? export during a mid‐winter rain‐on‐snowmelt event comprised between 8 and 16% of the total stream NO₃^? load for the four‐month winter study period. This can be compared with the NO₃^? exported during the final spring melt, which comprised between 38 and 45% of the total four‐month winter NO₃^? load. Our findings indicate that minor melt events were detectable with changes in soil temperature, streamflow, groundwater level, and snow depth. But, based on loading, these events were relatively minor contributors to winter NO₃^? loss. A warmer climate and fluctuating snowpack may result in more major mid‐winter melt events and greater NO₃^? export to surface waters.     

Boosted Regression Tree Models to Explain Watershed Nutrient Concentrations and Biological Condition

Boosted regression tree (BRT) models were developed to quantify the nonlinear relationships between landscape variables and nutrient concentrations in a mesoscale mixed land cover watershed during base‐flow conditions. Factors that affect instream biological components, based on the Index of Biotic Integrity (IBI), were also analyzed. Seasonal BRT models at two spatial scales (watershed and riparian buffered area [RBA]) for nitrite‐nitrate (NO₂‐NO₃), total Kjeldahl nitrogen, and total phosphorus (TP) and annual models for the IBI score were developed. Two primary factors — location within the watershed (i.e., geographic position, stream order, and distance to a downstream confluence) and percentage of urban land cover (both scales) — emerged as important predictor variables. Latitude and longitude interacted with other factors to explain the variability in summer NO₂‐NO₃ concentrations and IBI scores. BRT results also suggested that location might be associated with indicators of sources (e.g., land cover), runoff potential (e.g., soil and topographic factors), and processes not easily represented by spatial data indicators. Runoff indicators (e.g., Hydrological Soil Group D and Topographic Wetness Indices) explained a substantial portion of the variability in nutrient concentrations as did point sources for TP in the summer months. The results from our BRT approach can help prioritize areas for nutrient management in mixed‐use and heavily impacted watersheds.     

Groundwater Nutrient Concentrations and Mass Loading Rates at Iowa Golf Courses

Golf courses are often considered by the public to be significant nitrogen (N) and phosphorus (P) nonpoint sources but only limited information exists on nutrient concentrations and loads in golf course groundwater. In this study, we measured N and P concentrations in groundwater and available surface water at six randomly selected Iowa golf courses to assess the loading risk posed by these facilities to groundwater and local rivers. At each course, three shallow monitoring wells were installed, one each on representative tee, fairway, and rough locations. Wells and available surface water were sampled on eight occasions during 2015 and 2016. NO₃‐N concentrations were not detected above 1 mg/L at three of the six courses monitored in this study and the overall mean NO₃‐N concentration in Iowa golf courses was 2.2 mg/L. The mass of NO₃‐N recharged to groundwater averaged 3.3 kg/ha at the six courses, which represents approximately one‐tenth of the NO₃‐N load exported by the watershed that contains the course and represented approximately 0.1 to 8% of the fertilizer N applied. Groundwater orthophosphorus concentrations averaged 0.13 mg/L and were similar to those measured in a variety of settings across Iowa. Study results should prove useful in evaluating nutrient contributions from golf courses in Midwestern states where nutrient reduction strategies are being pursued.     

Simulation of Daily Flow Pathways,Tile‐Drain Nitrate Concentrations,and Soil‐Nitrogen Dynamics Using SWAT

Tile drainage significantly alters flow and nutrient pathways and reliable simulation at this scale is needed for effective planning of nutrient reduction strategies. The Soil and Water Assessment Tool (SWAT) has been widely utilized for prediction of flow and nutrient loads, but few applications have evaluated the model's ability to simulate pathway‐specific flow components or nitrate‐nitrogen (NO₃‐N) concentrations in tile‐drained watersheds at the daily time step. The objectives of this study were to develop and calibrate SWAT models for small, tile‐drained watersheds, evaluate model performance for simulation of flow components and NO₃‐N concentration at daily intervals, and evaluate simulated soil‐nitrogen dynamics. Model evaluation revealed that it is possible to meet accepted performance criteria for simulation of monthly total flow, subsurface flow (SSF), and NO₃‐N loads while obtaining daily surface runoff (SURQ), SSF, and NO₃‐N concentrations that are not satisfactory. This limits model utility for simulating best management practices (BMPs) and compliance with water quality standards. Although SWAT simulates the soil N‐cycle and most predicted fluxes were within ranges reported in agronomic studies, improvements to algorithms for soil‐N processes are needed. Variability in N fluxes is extreme and better parameterization and constraint, through use of more detailed agronomic data, would also improve NO₃‐N simulation in SWAT. Editor's note : This paper is part of the featured series on SWAT Applications for Emerging Hydrologic and Water Quality Challenges. See the February 2017 issue for the introduction and background to the series.     

Two‐Stage Ditch Floodplains Enhance N‐Removal Capacity and Reduce Turbidity and Dissolved P in Agricultural Streams

Two‐stage ditches represent an emerging management strategy in artificially drained agricultural landscapes that mimics natural floodplains and has the potential to improve water quality. We assessed the potential for the two‐stage ditch to reduce sediment and nutrient export by measuring water column turbidity, nitrate (NO₃^?), ammonium (NH₄⁺), and soluble reactive phosphorus (SRP) concentrations, and denitrification rates. During 2009‐2010, we compared reaches with two‐stage floodplains to upstream reaches with conventional trapezoid design in six agricultural streams. At base flow, these short two‐stage reaches (<600 m) reduced SRP concentrations by 3‐53%, but did not significantly reduce NO₃^? concentrations due to very high NO₃^? loads. The two‐stage also decreased turbidity by 15‐82%, suggesting reduced suspended sediment export during floodplain inundation. Reach‐scale N‐removal increased 3‐24 fold during inundation due to increased bioreactive surface area with high floodplain denitrification rates. Inundation frequency varied with bench height, with lower benches being flooded more frequently, resulting in higher annual N‐removal. We also found both soil organic matter and denitrification rates were higher on older floodplains. Finally, influence of the two‐stage varied among streams and years due to variation in stream discharge, nutrient loads, and denitrification rates, which should be considered during implementation to optimize potential water quality benefits.     

NITROGEN AND PHOSPHORUS CONCENTRATIONS IN FOREST STREAMS OF THE UNITED STATES1

ABSTRACT: Seventy to eighty percent of the water flowing in rivers in the United States originates as precipitation in forests. This project developed a synoptic picture of the patterns in water chemistry for over 300 streams in small, forested watersheds across the United States. Nitrate (NO₃^?) concentrations averaged 0.31 mg N/L, with some streams averaging ten times this level. Nitrate concentrations tended to be higher in the northeastern United States in watersheds dominated by hardwood forests (especially hardwoods other than oaks) and in recently harvested watersheds. Concentrations of dissolved organic N (mean 0.32 mg N/L) were similar to those of NO₃～, whereas ammonium (NH₄⁺) concentrations were much lower (mean 0.05 mg N/L). Nitrate dominated the N loads of streams draining hardwood forests, whereas dissolved organic N dominated the streams in coniferous forests. Concentrations of inorganic phosphate were typically much lower (mean 12 mg P/L) than dissolved organic phosphate (mean 84 mg P/L). The frequencies of chemical concentrations in streams in small, forested watersheds showed more streams with higher NO₃^? concentrations than the streams used in national monitoring programs of larger, mostly forested watersheds. At a local scale, no trend in nitrate concentration with stream order or basin size was consistent across studies.     

EFFECT OF A POINT SOURCE INPUT ON STREAM NUTRIENT RETENTION1

ABSTRACT: We examined the effect of a point source (PS) input on water chemistry and nutrient retention in Spavinaw Creek, Arkansas, during summer baseflows in 1998 and 1999. The nutrient uptake length (S_w) concept was used to quantify the impact of nutrient inputs in the receiving stream. We used an artificial injection upstream of the PS inputs to estimate background S and used the natural decline in nutrient concentrations below the PS to estimate the net nutrient uptake length (S_net). S_w for soluble reactive phosphorus (SRP) in the upstream reference section was O.75 km, but S_net ranged from 9.0 to 31 km for SRP and 3.1 to 12 km for NO₃‐N in the reach below the PS. S_net‐SRP was significantly correlated with discharge whereas S_net‐NO₃‐N was correlated with the amount of NO₃‐N enrichment from the PS. In order to examine specific mechanisms of P retention, loosely exchangeable P and P Sorption Index (PSI) of stream sediments were measured. Sediments exhibited little natural P buffering capacity (low PSI) above the PS, but P loading from the PS further reduced PSI. Loosely exchangeable P in the sediments also increased three fold below the PS, indicating sediments removed some water column P. The physical process of flow and sediment sorption apparently regulated P retention in Spavinaw Creek, whereas the level of N enrichment and possibly biotic uptake and denitrification influenced N retention. Regardless of the mechanism, Spavinaw Creek demonstrated little ability to retain PS‐added nutrients because net nutrient uptake lengths were in the km range.     

Simulation of Nitrogen Transport in Soil Under Municipal Wastewater Application Using LEACHN1

Abstract: To reduce the risk of surface and ground water pollution from nitrate, and in so doing improve the quality of receiving waters, better management options for land application of wastewater must be explored. In order to determine proper and environmentally safe wastewater land application methods, different application scenarios were simulated in this study to determine the fate and transport of nitrogen in sand‐filled field lysimeters. The Leaching Estimation and CHemistry Model for Nutrients (LEACHN) model was used to assess alternative wastewater land application scenarios: applications of low‐, medium‐, or high‐N concentration wastewaters, at different rates (0.06, 0.19, 0.31, or 0.6 m³/m²/day), under continuous or intermittent application. In the simulations, the NO₃^?‐N levels decreased in the leachate with an increase in wastewater application rates, due to enhanced denitrification in the upper anoxic zone of the soil generated under high flow rates. With low‐N concentrated wastewater, under all tested flow rates, the NO₃^?‐N levels in the leachate were below the permissible limit. When medium‐N wastewater was applied, the NO₃^?‐N level in leachate from the highest flow rate was below the permissible limit. Therefore, wastewater with low‐N concentrations, about 10 and 0.5 mg/l NO₃^?‐N and NH₄⁺‐N, may be continuously applied to soil at all tested flow rates, with minimal nitrate pollution problems. Medium and high‐N concentrated wastewaters increased nitrate levels in the leachate, as compared to their levels in the low‐N concentrated wastewater. It appears that while low‐N wastewater can be safely applied to land without much nitrate leaching problems, the application of medium and high‐N wastewater could pose nitrate pollution problems. The simulation with intermittent application of low‐, medium‐, and high‐N concentrated wastewater at different rates showed a 51‐89% greater reduction in NO₃^?‐N levels in the leachate, than for continuous application under all tested wastewater N‐levels and flow rates. Also, the levels of NO₃^?‐N in their leachates were below the permissible limit. Therefore, wastewater with high levels of nitrogenous compounds (up to 54 NO₃‐N mg/l) could be treated through an intermittent application to land.