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针对2-萘酚生产废水p H值低、色泽深,亚硫酸盐和萘磺酸盐高、COD浓度高的特点,采用酸化脱硫-两级络合萃取-氧化絮凝工艺处理,介绍了专利工艺的流程设计,给出了主要工艺设计参数及投资运行成本。工程运行结果表明,该工艺设计合理、技术成熟、处理效果稳定,2-萘酚生产废水经处理后达到GB 8978—1996《污水综合排放标准》一级排放标准要求;回收的萘磺酸钠固体可返回2-萘酚生产系统套用;反萃取黑液经蒸发浓缩,合成的减水剂产品各项指标达到或超过GB 8076—2008《混凝土外加剂》高效减水剂指标要求。 相似文献
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采用物化法与生化法相结合的工艺处理含油废水,工程运行实践表明,该工艺处理效果好、运行稳定,各项指标均可达到GB8978-1996<污水综合排放标准>中的一级排放标准. 相似文献
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大型针织印染废水处理工程的设计与运行 总被引:5,自引:0,他引:5
阐述了运用缺氧水解 -好氧 -混凝工艺处理大型针织印染废水的工程实例。运行结果表明 ,该工艺切实可行 ,处理出水水质达到了污水综合排放一级标准 相似文献
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在生产油漆的过程中,产生的污水腐蚀性强,有机物浓度高,研究了用碱液蒸馏吸附工艺处理酯化工业污水,其工艺流程简单,经吸附后,排出的水质清澈,可达到国家排放标准。 相似文献
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厌氧—好氧法治理酒糟废液的实例 总被引:5,自引:0,他引:5
罐式套氧接触发酵工艺处理全糟(半糟)生产沼气,推流式活性污泥曝气好氧工艺处理消化液,薯干酒糟废液经综合治理达到国标GB8978-88污水综合排放行业新扩改二级标准。本文介绍了该工艺在博兴酒厂的应用。 相似文献
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臭氧氧化作为水处理工艺中预处理或深度处理的手段之一,在饮用水厂、污水处理厂等已被广泛应用。文章以研究有机物急、慢性毒性的模式生物——斑马鱼胚胎为模型,对2-萘酚及其臭氧氧化溶液的急性毒性进行了研究。结果表明,2-萘酚对斑马鱼胚胎具有明显的致畸和孵化抑制作用,胚胎的死亡率随暴露溶液浓度的升高而升高,24、48、72 h的LC50值分别为(7.39±0.65)mg/L、(6.49±0.48)mg/L、(6.27±0.52)mg/L。臭氧氧化可以有效去除2-萘酚,并降低其急性毒性,急性毒性随着反应时间的增加而降低,有利于后续的生物处理和污水达标排放。初始浓度为25 mg/L的2-萘酚溶液在实验条件下,经臭氧氧化12 min后去除率达100%,反应35 min后,溶液对斑马鱼胚胎的急性毒性消失。结合胚胎急性毒性实验结果和液相色谱/质谱、离子色谱的中间产物分析表明,2-萘酚臭氧氧化产物对斑马鱼胚胎的急性毒性作用大大低于2-萘酚,臭氧处理能有效降低2-萘酚的生态风险。 相似文献
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To explore biodegradation of 2-naphthol and its metabolites accumulated in wastewater treatment, a series of bio-degradation
experiments were conducted. Two main metabolites of 2-naphthol, 1,2-naphthalene-diol and 1,2-naphthoquinone, were identified by
high-performance liquid chromatography with standards. Combining fungus Aspergillus niger with bacterium Bacillus subtilis in the
treatment enhanced 2-naphthol degradation e ciency, lowered the accumulation of the two toxic metabolites. There were two main
phases during the degradation process by the kinetic analysis: 2-naphthol was first partly degraded by the fungus, producing labile
and easily accumulated metabolites, and then the metabolites were mainly degraded by the bacterium, attested by the degradation
processes of 1,2-naphthalene-diol and 1,2-naphthoquinone as sole source of carbon and energy. Sodium succinate, as a co-metabolic
substrate, was the most suitable compound for the continuous degradation. The optimum concentration of 2-naphthol was 50 mg/L.
The overall 2-naphthol degradation rate was 92%, and the CODCr removal rate was 80% on day 10. These results indicated that
high degradation rate of 2-naphthol should not be considered as the sole desirable criterion for the bioremediation of 2-naphtholcontaminated
soils/wastewater. 相似文献
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Effects of the surface chemistry of macroreticular adsorbents on the adsorption of 1-naphthol/1-naphthylamine mixtures from water 总被引:1,自引:0,他引:1
ZHANG Wei-ming CHEN Jin-long CHEN Qun HE Min-yang PAN Bing-cai ZHANG Quan-xing 《环境科学学报(英文版)》2005,17(5):782-785
The adsorption behaviors of 1-naphthol, 1-naphthylamine and l-naphthol/l-naphthylamine mixtures in water over two macroreticular adsorbents were investigated in single or binary batch systems at 293 K, 303 K and 313 K respectively. All the adsorption isotherms in the studied systems can be adequately fitted by Langmuir model. In the case of aminated macroreticular adsorbent NDA103, 1-naphthol is adsorbed to a larger extent than 1-naphthylamine; while, the opposite trend is found for nonpolar macroreticular adsorbent NDA100. It is noteworthy that at higher temperature(303 K and 313 K), the total uptake amounts of 1-naphthol and 1-naphthylamine in all binary-component systems are obvious larger than the pure uptake amounts in single-component systems, which is presumably due to the cooperative effect primarily arisen from the hydrogen-bonding interaction between the loaded 1-naphthol and 1-naphthylamine molecules. The simultaneous adsorption systems were confirmed to be helpful to the selective adsorption towards 1-naphthol according to the larger selective index. 相似文献
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1-萘酚是多环芳烃降解过程中极易积累的典型含氧多环芳烃,其难降解、毒性大,直接影响多环芳烃污染环境的修复效果.为探究微生物联合代谢1-萘酚的特性,以前期从含氧多环芳烃污染土壤中分离出的两种共生菌株——成晶节杆菌NT16和芽孢杆菌NG16为受试菌株,结合HPLC、TOC、GC-MS等测定方法进行降解特性的测定.结果表明,NT16菌和NG16菌均能以1-萘酚为唯一碳源和能源生长,两种菌株联合代谢比NT16菌、NG16菌单独降解1-萘酚的生长量分别高2.758×10~9 cfu·mL~(-1)和1.4×10~9 cfu·mL~(-1),对1-萘酚的降解率可提高20%,使体系中TOC值加速降低.NT16菌和NG16菌联合代谢1-萘酚可按照两个途径进行,其一,1-萘酚羟化后开环,进入邻苯二甲酸代谢途径.NT16菌更易进入该途径,而NG16菌则不易通过该途径降解1-萘酚;其二,1-萘酚羟化后开环,进入苯丙酸代谢途径.NG16菌迅速将1-萘酚降解为对羟基苯乙酸,其在降解体系中积累,NT16菌无法高效降解1-萘酚却能够降解对羟基苯乙酸至较短烷基链的小分子化合物.该研究结果将为含氧多环芳烃污染环境实际修复中微生物群落协同作用降解污染物奠定基础. 相似文献
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2-naphthylamine was incubated with induced rat liver microsome S9 preparation and the metabolites were separated through HPLC. The following products were identified: 2-amino-5-naphthol, 2-amino-6-naphthol, 2-amino-7-naphthol and 2-amino-8-naphthol. The yields of these four metabolites are varying in quantity, and the relative contents of 2-amino-8-, -5-, -6- and -7-naphthol are 52.6%, 28.5%, 14.0% and 4.9% respectively. These results are consistent with the quantitative HMO calculation and inference based upon Di-region theory, i.e., the metabolisms of aryl amines on extra-ring (assigned the ring without the substituent of amino group) are through the epoxidation and then NIH shift, but are not the direct hydroxylation in the formation of phenols. It is shown that both the amino group and the carbon atoms on the extra-ring play duality roles of activation and detoxification in metabolism. 相似文献
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The kinetics of the recombinant Coprinus cinereus peroxidase-catalyzed 2-naphthol oxidation was investigated in the presence of rhamnolipid biosurfactant JBR425 and synthetic surfactant Surfynol465 at pH 5.5 and 25℃, with concentrations of (bio)surfactants both less than critical micelle concentrations (CMC) and larger than CMC. It was shown that monomers of JBR425 as well as monomers of Surfynol465 had an enhancing effect on the conversion of 2-naphthol in dose response manner and did not influence the initial rate of 2-naphthol oxidation. The results were accounted by a scheme, which contains a stadium of enzyme inhibition by oligomeric 2-naphthol oxidation products. The action of the biosurfactant's (or synthetic surfactant's) monomers was explained by avoidance of the enzyme active center clothing with oligomers. Similar results have demonstrated the potential of rhamnolipid biosurfactant JBR425 due to its biodegradability. When biosurfactants' concentrations are larger than CMC, (bio)surfactants have an opposite effect on the oxidation of 2-naphthol by peroxidase. 相似文献
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Trace copper (II) in water can be preconcentrated using silica gel modified with 1-(2-pyridylazo)-2-naphthol (PAN) and be determined spectrophotometri-cally. The conditions for the preconcentration were studied. The method was applied to both artificial and natural water samples and the results suggest that copper (II) of ppb level in water can be measured accurately after the preconcentration. 相似文献
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《Journal of Cleaner Production》2008,16(10):1081-1089
Treatment systems consisting of physico-chemical treatment, biological treatment, ozonation, reverse osmosis system, nanofiltration system, multiple effect evaporator, crystalliser and solar evaporation pans set up by three dyeing units in Tirupur, India, were assessed in the present study. The composite samples were analysed for colour, pH, TSS, TDS, chlorides, sulphates, COD, total iron, silica, SDI, LSI and total hardness. The results indicated that the physico-chemical treatment alone is inadequate to achieve the feed water quality norms for spiral wound RO membranes. It is recommended that the primary treatment may incorporate biological treatment and ultrafiltration to reduce COD and SDI in the feed water. Water recovery by reverse osmosis and salt recovery using nanofilter were 87% and 71%, respectively.It was also found that there is substantial direct profit in recovering water using reverse osmosis and sodium chloride in solution using nanofiltration as compared to the recovery of Na2SO4. The study also revealed that high quality water could be produced by treatment system incorporating membrane technology at affordable costs and recycled back into the process in the textile dyeing industry. 相似文献