Experiment-based investigations on the effect of ignition energy on dust explosion behaviors

Explosion behaviors of typical light metal and carbonaceous dusts induced by different ignition energies were investigated based on systematic experiments in a Siwek 20 L vessel. Comparative analysis reveals that the explosion mechanism of carbonaceous dust is the volatile combustion, whereas the mechanism for light metal dust mainly features the surface heterogeneous oxidation. Influences of ignition energy on severity and flammability limit are much more significant for carbonaceous dust than light metal, especially for the powder with less volatile. An innovative approach was introduced to derive flame thickness from the pressure–time trace. The relation between explosion induction time and combustion duration of ignitor was also analyzed. Results show inappropriate ignition energy will cause under-/over-driving in the thermodynamic/kinetic characteristic measurements. In this way, a dimensionless parameter pressure ratio was introduced to evaluate the under-driving, while two methods by using flame thickness and induction time respectively, were proposed to evaluate over-driving. To improve the accuracy of dust explosion tests, authors advocate that explosion severity determination should be conducted at the critical ignition energy. Moreover, a comparison between the European and Chinese flammability limit determination procedures was also conducted, indicating that EN 14034-3 is suitable for light metal but not for carbonaceous, while GB/T 16425 appears to be slightly conservative for both carbonaceous and light metal dusts.     

Modeling of n-butane ignition, combustion, and preflame oxidation in the 20-l vessel

The objective of the study reported herein is to simulate various physical and chemical phenomena accompanying fuel-rich n-butane–oxygen mixture preparation, ignition, preflame oxidation, and combustion in the standard 20-l explosion vessel, by applying mathematical models. Based on the computational fluid dynamics (CFD) simulations of the mixing process and natural convection of the ignition kernel, as well as on the analysis of the detailed reaction mechanism of n-butane oxidation, laminar flame propagation, and self-ignition, possible explanations for the phenomena observed experimentally have been suggested. The results of the study indicate that seemingly inflammable mixtures can become hazardous depending on the mixture preparation procedure and forced ignition timing.     

几种地板燃烧性能的实验研究

地板的燃烧性能对室内火灾的发展蔓延及火灾危害都有重要的影响,本文使用锥形量热仪对市场上常见几种地板(实木地板、竹制地板和复合地板)的燃烧性能进行试验研究。实验结果表明,地板的热释放速率具有两个峰,相同辐射功率下,竹地板和实木地板的比消光面积分别比复合地板高29．3％、42．5％,竹制地板点燃时间较小,复合地板火灾危险性要小于竹制地板和实木地板。     

Vapor flammability above aqueous solutions of flammable liquids

The flammability of vapors above aqueous solutions of ethanol and acetonitrile was studied experimentally in a 20-L combustion apparatus. No liquid was present in the apparatus, but the vapor concentrations were adjusted to correspond to the vapor in equilibrium with a specified aqueous solution. The experimental results for these two systems show that

• As water is added to the vapor, the lower boundary of the flammability zone decreases. For ethanol, the lower flammability limits (LFL) decreases from 3.7% for pure vapor to 3.2% with saturated water vapor. For acetonitrile, the decrease is from 4.2% to 3.8%. Thus, to a good approximation, the water vapor can be treated as an inert, enabling the data to be displayed on a single flammability triangle diagram. This provides a very simplified method for estimating the flammable behavior for aqueous solutions.

• The upper boundary of the flammability zone is unchanged with the addition of water.

• The limiting oxygen concentration (LOC) is essentially constant for all concentrations of aqueous solutions. The LOC for the pure solvent may be used as a universal LOC for all solvent concentrations.

• The vapor mixture above the aqueous solution is not flammable below a certain liquid mol fraction of flammable. The flammable concentration at which this occurs can be called the maximum safe solvent concentration (MSSC). A method is presented to determine the MSSC from experimental flammability data.

• The oxygen concentration defining the flammable boundary for the vapor decreases rapidly from the MSSC and then increases as the liquid solvent concentration increases.

The calculated adiabatic flame temperature (CAFT) method qualitatively predicts the same behavior as the experimental data.     

Methodology for case studies of accidental gas explosions

This paper discusses a procedure for case studies of accidental gas explosions. The procedure for each case study can be subdivided into four steps, i.e., collection of proofs, analyses, confirmation, and inference about the processes of the accident, and the issues in each step are pointed out. Making a guess on the sequence of the accident to be investigated should be avoided during collection of proofs. Misunderstanding of the phenomena in analyses and confirmation is likely caused by inappropriate knowledge on the phenomena and/or use of unsuitable models. The sequence of the accidental gas explosion should be inferred on the basis of confirmed processes. If there are other possibilities, those should be described in the report. The reasonableness of the results of a case study depends on the rationality of the procedure and the quality or plausibility of knowledge to infer the probable sequence.     

Detailed and reduced chemistry for hydrogen autoignition

Reaction-rate parameters are given for the detailed chemistry of gas-phase hydrogen combustion, involving 21 reversible elementary steps. It is indicated that, when attention is restricted to specific combustion processes and particular conditions of interest, fewer elementary steps are needed. In particular, for calculating autoignition times over a wide range of pressures for temperatures between about 1000 and 2000 K, five irreversible elementary steps suffice, yielding a remarkable reduction in complexity. It is explained that, from a mathematical viewpoint, in terms of global reaction-kinetic mechanisms, the hydrogen–oxygen system in principle comprises only six overall steps. Rational reduced chemical mechanisms for hydrogen combustion therefore necessarily must have fewer than six overall steps. For autoignition over the range of conditions specified above, ignition times can be determined accurately by considering, in addition to an elementary initiation step and an elementary termination step, at most three overall steps for reaction intermediaries, which reduce to two for very fuel-lean conditions and to one for stoichiometric or fuel-rich conditions. The resulting reductions can simplify computations that need to be performed in risk analyses for hydrogen storage and utilization.     

Effect of self-inhibition at a flame propagation in rich gaseous mixtures of combustible–air–diluent

An analysis of published experimental data characterizing the influence of diluents of various chemical nature (both halogenated and chemically inert) on upper flammability limits of flammable gases in air (methane and hydrogen have been considered as examples) has been done. Dependences of critical oxygen concentration and critical fuel equivalence ratio _cr for mixtures combustible–air–diluent at upper flammability limits on diluent concentration were determined. The obtained data were interpreted on the basis of the concept of self-inhibition at combustion of rich mixtures of organic combustibles in air. A method for evaluation of relative effectiveness of various inhibitors and for determination of availability of self-inhibitive properties of a combustible gas has been proposed.     

An experimental investigation of an inertization effectiveness of fluorinated hydrocarbons in relation to premixed H2–N2O and CH4–N2O flames

An experimental investigation of an influence of trifluoromethane CHF_3, pentafluoroethane C₂HF₅ and perfluorobutane C₄F₁₀ on near-limit hydrogen-nitrous oxide and methane-nitrous oxide premixed flames was performed. Flammability limits, a maximum explosion pressure ΔP_max, maximum rate of pressure rise (dP/dt)_max, and a laminar burning velocity S_u were determined. The flammability area in the case of N₂O as an oxidizer is substantially wider than for the case of the oxidizer which is the mixture of oxygen and nitrogen with the O₂ content 25% (vol.). The dependences of S_u, ΔP_max and (dP/dt)_max on concentration of the fluorinated hydrocarbons are characterizing by an availability of maxima which positions are close to the peak concentrations of the flammability regions. A qualitative interpretation of the results obtained is given.     

A review of the past,present and future of the European loss prevention and safety promotion in the process industries

In 2013, the European Federation of Chemical Engineering (EFCE) celebrates its 60th anniversary. EFCE has continually promoted scientific collaboration and supported the work of engineers and scientists in thirty European countries. As for its mission statement, EFCE helps European Society to meet its needs through highlighting the role of Chemical Engineering in delivering sustainable processes and products. Within this organizational framework the Loss Prevention Symposium series, organized throughout Europe on behalf of the Loss Prevention Working Party of the EFCE, represents a fruitful tradition covering a time span of forty years. The tri-annual symposium gathers experts and scientists to seek technical improvements and scientific support for a growingly safer industry and quality of life. Following the loss prevention history in this paper, a time perspective on loss prevention and its future is presented.     

I2SI: A comprehensive quantitative tool for inherent safety and cost evaluation

This paper presents details of an integrated inherent safety index (I2SI). The conceptual framework of this index was presented at the 37th Annual Loss Prevention Symposium of the AIChE (2003) and published in Process Safety Progress (volume 23(2), 136–148, 2004). In addition to the framework, the current paper discusses additional features of the index such as the cost model and system design model, which were not presented or discussed earlier. I2SI is called an integrated index because the procedure considers the life cycle of the process with economic evaluation and hazard potential identification for each option. I2SI is comprised of sub-indices which account for hazard potential, inherent safety potential, and add-on control requirements. In addition to evaluating these respective characteristics, there are also indices that measure the economic potential of the option. To demonstrate the applicability and efficacy of I2SI, an application of the index to three acrylic acid production options is also discussed in the paper.