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1.
The major and trace element component of 48 recent sediment samples in three distinct intervals (0–10, 10–20, and 20–30 cm) from Lake Ac?göl is described to present the current contamination levels and grift structure of detrital and evaporate mineral patterns of these sediments in this extreme saline environment. The spatial and vertical concentrations of major oxides were not uniform in the each subsurface interval. However, similar spatial distribution patterns were observed for some major element couples, due mainly to the detrital and evaporate origin of these elements. A sequential extraction procedure including five distinct steps was also performed to determine the different bonds of trace elements in the <?60-μ particulate size of recent sediments. Eleven trace elements (Ni, Fe, Cd, Pb, Cu, Zn, As, Co, Cr, Al and Mn) in nine surface and subsurface sediment samples were analyzed with chemical partitioning procedures to determine the trace element percentage loads in these different sequential extraction phases. The obtained accuracy values via comparison of the bulk trace metal loads with the total loads of five extraction steps were satisfying for the Ni, Fe, Cd, Zn, and Co. While, bulk analysis results of the Cu, Ni, and V elements have good correlation with total organic matter, organic fraction of sequential extraction characterized by Cu, As, Cd, and Pb. Shallow Lake Ac?göl sediment is characteristic with two different redox layer a) oxic upper level sediments, where trace metals are mobilized, b) reduced subsurface level, where the trace metals are precipitated.  相似文献   

2.
The concentrations of heavy metals and metals (Zn, Pb, Bi, Cd, Ni, Co, Fe, Mn, Mg, Cu, Cr, Ca, Sr, Na, Li, K) were measured in muscle of five species Cyprinus carpio (from I??kl? dam), Scardinius erythrophthalmus (from I??kl? dam), Tinca tinca (from I??kl? dam), C. carpio (from Karaca?ren dam), Carassius carassius (from Karaca?ren dam) caught from I??kl? and Karaca?ren. The highest metal was Na (466.95 μg/g) in C. carassius, while the lowest levels were Fe (0.37 μg/g) and Cu (0.37 μg/g) in C. carpio from I??kl? dam. The mean concentrations μg/g d.w. some of heavy metals in muscle of C. carpio (from I??kl? dam), S. erythrophthalmus (from I??kl? dam), T. tinca (from I??kl? dam), C. carpio (from Karaca?ren dam), C. carassius (from Karaca?ren dam) were as follows: Cd 2.00-2.10-1.95-2.06-2.27, Zn 4.36-2.64-13.13-13.33-24.47, Pb 1.65-1.24-1.90-2.37-2.41, Co 2.46-2.37-2.48-2.58-2.80, Mg 138.51-154.35-218.59-204.58-202.16, Fe 0.37-2.62-3.17-3.01-12.33, respectively.  相似文献   

3.
The accumulation of heavy metals such as Pb, Hg, Co, Cr, Cu, Zn, and Br were determined in water, sediment, muscle, and gill of three fish species (Leuciscus cephalus, Capoeta tinca, Capoeta capoeta) which were collected in K?z?l?rmak River Basin (Delice River). The metal concentration showed a general trend of Br>Zn> Pb>Cr>Cu>Hg>Co in water and Cr>Zn>Pb> Cu>Co>Hg>Br in sediment samples while Zn> Cu>Pb>Br>Cr>Hg>Co were in muscle and Zn>Pb>Cu>Cr>Br>Hg>Co were in the gill tissue.  相似文献   

4.
Achanthobrama marmid (thorn-bream) (n:24), Chondrostoma regium (nose-carp) (n:33) and Silurus glanis (wels) (n:21), and Cyprinus carpio (carp) (n:30) were collected from Sır Dam Lake in Kahramanmaraş Province. The iron (Fe), manganese (Mn), cobalt (Co), nickel (Ni), and lead (Pb) levels were determined in the total of 108 fish samples by Atomic Absorption Spectrophotometer. The concentrations of heavy metals were expressed as mg kg−1 wet weight of tissue. The mean Fe and Mn levels of muscle and gill of C. carpio were 0.8–5.71 and 0.30–1.96, respectively. The mean of the Fe and Mn levels of muscle and gill of A. marmid were 1.22, 5.07 and 0.38, 0.85 mg kg−1, respectively. The ranges of mean concentrations of Fe and Mn levels in muscle and gill of C. regium were 0.91, 5.61 and 0.27, 3.42 mg kg−1, respectively. The mean value of Fe in S. glanis gill was 1.03, which of Mn was 0.17 mg kg−1. Fe, Mn, Co, Ni, and Pb were not detected in the muscle of S. glanis. The mean values for Co in muscle of thorn-bream, carp, and nose-carp were 0.005, 0.01, 0.0 mg kg−1, respectively. Nickel values in the muscle were ranged between 0.38 and 1.93 in thorn-bream, 0.06 and 1.34 in carp, 0.14 and 1.89 in nose-carp, in that order. The mean Pb levels of muscle and gill of A. marmid were 0.14 and 0.29 mg kg−1, respectively. The mean values of Pb concentration of muscle and gill for C. carpio were 0.13 and 0.50 mg kg−1, respectively. In C. regium mean values for Pb in muscle and gill were 0.06 and 0.06 mg kg−1, respectively. The mean value of Pb in S. glanis gill was 0.42, ranged between 0.0–0.92 mg kg−1.  相似文献   

5.
Research on the influence of the activities of Pechenganickel Mining and Metallurgical Company on sediment heavy-metal geochemistry of the subarctic Lake Kuetsj?rvi (north-western Russia) are described. It is estimated that during 60 years of mining/refining activity, 310 t of Ni, 120 t of Cu, 14 t of Co, 19 t of Zn, 0.087 t of Cd, 0.78 t of Pb and 0.053 t of Hg have accumulated in the lake sediments. The latter can be a source of secondary pollution and represent a danger for the lake ecosystem. The sedimentation rate in the lake is estimated to be within the range of 1.5-3 mm year(-1). The average concentrations of Ni, Cu, Hg and Co in superficial sediments have increased 25, 14, 11 and 5 times, respectively in the last century.  相似文献   

6.
In this study which was carried out between March 2003 and February 2005 Fe, Cu, Zn, Mn, Cr, Pb and Cd contents were determined in muscle, liver and gill of carp (Cyprinus carpio L., 1758) caught from Beyşehir Lake. Among the heavy metals analyzed Cr, Pb and Cd were below the detection limit (<0.03). Heavy metal concentrations varied significantly depending on the type of the tissue and season. The highest metal concentrations were found in the liver, followed by gill and muscle. Heavy metal levels in tissues of carp were increased in summer and winter, while were decreased in autumn and spring. The present study shows that precautions need to be taken in Beyşehir Lake in order to prevent heavy metal pollution that can occur in the future.  相似文献   

7.
Concentrations of heavy metals were determined in the water column (including the sea-surface microlayer, subsurface, mid-depth and bottom water) and sediments from Singapore’s coastal environment. The concentration ranges for As, Cd, Cr, Cu, Ni, Pb and Zn in the seawater dissolved phase (DP) were 0.34–2.04, 0.013–0.109, 0.07–0.35, 0.23–1.16, 0.28–0.78, 0.009–0.062 and 0.97–3.66 μg L−1 respectively. The ranges for Cd, Cr, Cu, Ni, Pb and Zn in the suspended particulate matter (SPM) were 0.16–0.73, 6.72–53.93, 12.87–118.29, 4.34–60.71, 1.10–6.08 and 43.09–370.49 μg g−1, respectively. Heavy metal concentrations in sediments ranged between 0.054–0.217, 37.48–50.52, 6.30–21.01, 13.27–26.59, 24.14–37.28 and 48.20–62.36 μg g−1 for Cd, Cr, Cu, Ni, Pb and Zn, respectively. The lowest concentrations of metals in the DP and SPM were most frequently found in the subsurface water while the highest concentrations were mostly observed in the SML and bottom water. Overall, heavy metals in both the dissolved and particulate fractions have depth profiles that show a decreasing trend of concentrations from the subsurface to the bottom water, indicating that the prevalence of metals is linked to the marine biological cycle. In comparison to data from Greece, Malaysia and USA, the levels of metals in the DP are considered to be low in Singapore. Higher concentrations of particulate metals were reported for the Northern Adriatic Sea and the Rhine/Meuse estuary in the Netherlands compared to values reported in this study. The marine sediments in Singapore are not heavily contaminated when compared to metal levels in marine sediments from other countries such as Thailand, Japan, Korea, Spain and China.  相似文献   

8.
A total of 11 sediment samples were collected from the sites along Haihe River?CBohai Bay, with site 1 at the beginning of Haihe River and site 11 in Bohai Bay, about 150 km away from site 1. Quinone profiles were used for the analysis of microbial community as influenced by pollutants in water and sediments, such as heavy metals, and other environmental factors. Nineteen species of quinones were found at site 1 while only six species at sites 10 and 11. Both the diversity of quinone species (DQ) and the number of quinones were higher in the sediments from Haihe River and the near-sea area of Bohai Bay than in those from the deep-sea area. The ?? diversity values were significantly higher, while Jaccard indexes of similarity were much lower among non-contiguous pairs of sites as compared with the contiguous ones. Cluster analysis indicated that quinone profiles may be grouped into two main clusters (sites 1?C7 and sites 8?C11), and there were higher similarities within the groups than between groups. Quinone species composition varied at different sites. Ubiquinones such as UQ-8, UQ-9, and UQ-10 and menaquinones such as MK-6, MK-7, MK-8 were isolated from all the sites and accounted for the largest proportions. Pearson correlation analysis revealed that both the number of quinone species and DQ correlated positively with total organic carbon contents in water and sediments, but negatively correlated with salinity and electroconductivity and did not correlate significantly with heavy metal contents in water.  相似文献   

9.
Bottom sediments from Nakaumi Lagoon and the Honjo Area in southwest Japan were analyzed to determine their geochemical compositions and to assess potential impacts by comparison with sediment quality guidelines. Present-day water quality was also assessed. Results showed that the water quality of Nakaumi Lagoon and the Honjo area contrasts between their upper and lower parts. Average abundances of As, Pb, Zn, Cu, Ni, and Cr in the Nakaumi sediments were 12, 25, 135, 32, 21, and 46 ppm, respectively, compared to 10, 24, 110, 26, 20, and 38 ppm in the Honjo area. All averages are greater than those of the upper continental crust. The elevated metal concentrations are probably related to the fine-grained nature of the sediments, reducing bottom conditions produced by abundant organic matter and possibly minor non-point anthropogenic sources. Trace metal contents are strongly correlated with Fe2O3, suggesting that Fe oxides play a role in controlling abundances. Metal concentrations exceed the NYSDEC lowest effect level and CCME interim sediment quality guidelines that indicate moderate impact on aquatic organisms. Average abundances of As and Zn are comparable to the Coastal Ocean Sediment Database threshold, whereas maximum concentrations exceed that value, indicating that the concentrations of these metals are potentially toxic. These enrichments suggest that regular monitoring may be desirable even where no point sources of metal pollution exist.  相似文献   

10.
The metal accumulation levels for muscle, skin, gill, liver and intestine tissues of some Cyprinidae species (Carassius carassius, Condrostoma nasus, Leuciscus cephalus and Alburnus alburnus) in Enne Dame Lake (Kütahya/Turkey), which is mostly fed by hot spring waters, were investigated. Analyses were performed for copper (Cu), zinc (Zn), manganese (Mn), iron (Fe), cobalt (Co), magnesium (Mg), nickel (Ni), chrome (Cr) and boron (B) using inductively coupled plasma-optic emission spectroscopy (ICP-OES), and cadmium (Cd) using atomic absorption spectrophotometer (AAS) utilizing microwave digestion techniques. The concentrations of the heavy metals found in the fish varied in the follow ing ranges: Cu: < DL-7.04, Zn: 6.96-357.25, Mn: < DL-20.70, Ni: < DL-6.21, Fe: 9.62-2500.33, Cr: < DL-1.74, Co: < DL-0.54, Cd: 0.01-0.27 and Mg: 197.44-904.90 mg/kg wet weight. While B had the second highest concentration in the water of the lake, it was not encountered in any tissue of the investigated species. In all tissues and the species, While the bioaccumulation factors (BAFs) of Mn, Zn, Fe and Cu were remarkably high, the BAFs of Mg, Cr, Co, and B were also fairly low or none. Although the heavy metal accumulation levels for the muscle were generally lower than other tissues, there were some exceptions. Cd level in the muscle of C. carassius was higher than the permissible limit stated by Turkish legislation, FAO and WHO. The mean metal amounts for all the investigated tissues and species are statistically compared and discussed in this study.  相似文献   

11.
Surface soil samples collected from a Pb and Zn mining area in India were subjected to multi-elemental analysis by using inductively coupled plasma-atomic emission spectrometry. Multivariate statistical methods such as principal component analysis and cluster analysis, coupled with correlation coefficient analysis, were used to analyze the data and to apportion the possible sources of elements in soils of a metal mining area. Soils in this area have elevated heavy metal concentrations especially Pb, Zn, Mn, Cu, As, and Tl. Using principal component (PC) analysis, six components were extracted, out of which two PCs explaining 50.12% of total variance are more important. The first principal component with a high contribution of Ag, As, Be, Cd, Co, Cu, Mg, Mn, Ni, Pb, and Zn was deemed to be technogenic/anthropogenic component, and the second principal component, with high loadings for the five discerning variables (Al, Be, Cr, K, Li), was considered as lithogenic component. The third component having strong loadings of Ba, Ca, K, and Na is supposed to have a mixed origin (lithogenic as well as technogenic). Electrical conductivity and total organic matter were not correlated with any element and also have a strong loading in the fifth component which is probably the biomass and ions present in these soils. The findings of the principal component analysis were also substantiated by the cluster analysis. The present study would not only enhance our knowledge regarding the soil pollution status in the study area but would also provide us information to manage the sources of these elements in the study area.  相似文献   

12.
13.
In the present study, some heavy metals (Cu, Fe, Zn and Mn) were seasonally determined in water, sediment and some tissues of fish Tinca tinca from Bey?ehir Lake, which is an important bird nesting and visiting area, a water source for irrigation and drinking. In the water, Fe has the highest concentrations among the studied metals. Generally, the metal concentrations increased in the hottest period decreased in warm seasons. Results for levels in water were compared with national and international water quality guidelines, as well as literature data reported for the lakes. Fe was the highest in sediment samples, also Cu and Zn were the highest in spring, while Fe and Mn were in autumn. Among the heavy metals studied, Cu and Mn were below the detection limits in some tissues. Generally, higher concentrations of the tested metals were found in the summer and winter, compared with those during the autumn and spring seasons. High levels of heavy metals were found in liver of T. tinca, while low levels in muscle samples. Metal concentrations in the muscle of examined fish were within the safety permissible levels for human consumption. The present study shows that precautions need to be taken in order to prevent further heavy metal pollution.  相似文献   

14.
Coastal and estuarine areas are often polluted by heavy metals that result from industrial production and agricultural activities. In this study, we investigated the concentration trait and vertical pattern of trace elements, such as As, Cd, Ni, Zn, Pb, Cu, and Cr, and the relationship between those trace elements and the soil properties in coastal wetlands using 28 profiles that were surveyed across the Diaokouhe Nature Reserve (DKHNR). The goal of this study is to investigate profile distribution characteristics of heavy metals in different wetland types and their variations with the soil depth to assess heavy metal pollution using pollution indices and to identify the pollution sources using multivariate analysis and sediment quality guidelines. Principal component analysis, cluster analysis, and pollution level indices were applied to evaluate the contamination conditions due to wetland degradation. The findings indicated that the concentration of trace elements decreased with the soil depth, while Cd increases with soil depth. The As concentrations in reed swamps and Suaeda heteroptera surface layers were slightly higher than those in other land use types. All six heavy metals, i.e., Ni, Cu, As, Zn, Cr, and Pb, were strongly associated with PC1 (positive loading) and could reflect the contribution of natural geological sources of metals into the coastal sediments. PC2 is highly associated with Cd and could represent anthropogenic sources of metal pollution. Most of the heavy metals exhibited significant positive correlations with total concentrations; however, no significant correlations were observed between them and the soil salt and soil organic carbon. Soil organic carbon exhibited a positive linear relationship with Cu, Pb, and Zn in the first soil layer (0–20 cm); As, Cr, Cu, Ni, Pb, and Zn in the second layer (20–40 cm); and As, Cr, Cu, Ni, Pb, and Zn in the third layer (40–60 cm). Soil organic carbon exhibited only a negative correlation with Cd (P?I geo values), which averaged less than 0 in the three soil layers, this finding indicates that the soils have remained unpolluted by these heavy metals. The mean concentrations of these trace elements were lower than Class I criteria. The degradation wetland restoration suggestions have also been provided in such a way as to restore the reserved flow path of the Yellow River. The results that are associated with trace element contamination would be helpful in providing scientific directions to restore wetlands across the world.  相似文献   

15.
Concentration of the some heavy metals (Co, Cu, Fe, Ni, Pb and Zn) Mediterranean mussel Mytilus galloprovincialis from Yalova (Marmara Sea) were investigated seasonally. The mean concentrations of Co, Cu, Fe, Ni, Pb and Zn in the soft tissues were 4.08 ± 0.67, 5.54 ± 0.59, 156.72 ± 20.18, 3.71 ± 1.14, 2.92 ± 0.51 and 106.23 ± 5.66 mg kg(?-1) dry weights, respectively. There were no significant differences between the metal concentrations among the seasons (P > 0.05). The mean Pb and Zn concentrations were higher than the acceptable limit proposed by International Turkish standards.  相似文献   

16.
The paper presents the results of heavy metals determination in samples of sedimentary rocks from the Mosina-Krajkowo water well field (Poland). The concentration of heavy metals was analysed by type of rock (sand, gravel, warp, silt, till, and clay). Variation of heavy metal concentrations with depth was studied taking into account the age series of the rocks (fluvial sediments of the modern Warta River valley, sediments of the Baltic Glaciation, tills of the Middle-Polish Glaciation, sediments of the Masovian Interglacial (Holstein), tills of the Poznań series) and granulometric fractions. The grain sizes considered included: >2.0, 2.0-1.0, 1.0-0.5, 0.5-0.25, 0.25-0.1, 0.1-0.063, and <0.063 mm. The concentrations of the heavy metals studied were found to change with the type of rock, age series, and granulometric fraction. The levels of the metals were determined by the technique of atomic absorption spectrometry with flame atomisation (F-AAS) and inductively coupled plasma-atomic emission spectrometry (ICP-AES).  相似文献   

17.
Understanding spatial variability of dynamic soil attributes provides information for suitably using land and avoiding environmental degradation. In this paper, we examined five neighboring land use types in Indagi Mountain Pass - Cankiri, Turkey to spatially predict variability of the soil organic carbon (SOC), bulk density (BD), textural composition, and soil reaction (pH) as affected by land use changes. Plantation, recreational land, and cropland were the lands converted from the woodland and grassland which were original lands in the study area. Total of 578 disturbed and undisturbed soil samples were taken with irregular intervals from five sites and represented the depths of 0-10 and 10-20 cm. Soil pH and BD had the lower coefficient of variations (CV) while SOC had the highest value for topsoil. Clay content showed greater CV than silt and sand contents. The geostatistics indicated that the soil properties examined were spatially dependent to the different degrees and interpolations using kriging showed the dynamic relationships between soil properties and land use types. The topsoil spatial distribution of SOC highly reflected the changes in the land use types, and kriging anticipated significant decreases of SOC in the recreational land and cropland. Accordingly, BD varied depending on the land use types, and also, the topsoil spatial distribution of BD differed significantly from that of the subsoil. Generally, BD greatly decreased in places where the SOC was relatively higher except in the grassland where overgrazing was the more important factor than SOC to determine BD. The topsoil spatial distributions of clay, silt, and sand contents were rather similar to those of the subsoil. The cropland and grassland were located on the very fine textured soils whereas the woodland and plantation were on the coarse textured soils. Although it was observed a clear pattern for the spatial distributions of the clay and sand changing with land uses, this was not the case for the silt content, which was attributed to the differences of dynamic erosional processes in the area. The spatial distribution of the soil pH agreed with that of the clay content. Soils of the cropland and grassland with higher amounts of clay characteristically binding more cations and having higher buffering capacities had the greater pH values when compared to the soils of other land uses with higher amounts of sand naturally inclined to be washed from the base cations by the rainwater.  相似文献   

18.
Temporal variations in sediment phosphorus (P) composition and mobility were estimated in surface sediments of accumulation (core PS509 44?cm) and erosion (core PS2009 30?cm) areas of the shallow, large Lake Peipsi sensu stricto (s.s.; 2611?km(2), unregulated water level). The P pool in sediments including buried and mobile P is evaluated for the first time, which will provide baseline data for the future modelling of internal loading in L. Peipsi. Five sedimentary P fractions (including inorganic and nonreactive P) were separately quantified: loosely adsorbed and pore-water P (NaCl-P); redox-sensitive fraction P (NaBD-P); P bound to oxides of non-reducible Fe and Al (NaOH-P); calcium-bound P, mainly from apatite minerals (HCl-P) and refractory, mainly organic P (Res-P). Concentrations of P fractions varied during the 100?years with the highest values around 2007-2008 and 1923-1935. The P in "active" layers that are available for bacteria and algae or those undergoing changes and diagenetic transformations in the sediment could follow sediments with the water content of ~88%. Potentially mobile P is not decreased in the sediments deposited 50-100?years ago and makes up ca 63?mg?m(-2)?y(-1) (with range 8.3-23.7% of the total P (TP)) in the accumulation area, and ca 0.047?mg?cm(-3) (with range 1.3-22.4% of TP) in the erosion area. The result shows that 13-60% of TP contained in the surface sediment (from 34 to 398?mg P m(-2) y(-1)) has been remobilised during accumulation and could be exported to the overlying water.  相似文献   

19.
Urban pesticide use has a direct impact on surface water quality. To determine the extent of pesticide contamination, the California Department of Pesticide Regulation initiated a multi-area urban monitoring program in 2008. Water and sediment samples were collected at sites unaffected by agricultural inputs in three areas: Sacramento (SAC), San Francisco Bay (SFB), and Orange County (OC). Samples were analyzed for up to 64 pesticides or degradates. Multiple detections were common; 50 % of the water samples contained five or more pesticides. Statewide, the most frequently detected insecticides in water were bifenthrin, imidacloprid, fipronil, fipronil sulfone, fipronil desulfinyl, carbaryl, and malathion. Bifenthrin was the most common contaminant in sediment samples. Key differences by area: OC had more pesticides detected than SAC or SFB with higher concentrations of fipronil, whereas SAC had higher concentrations of bifenthrin. The most frequently detected herbicides were 2,4-D, triclopyr, dicamba, diuron, and pendimethalin. Key differences by area: OC and SFB had higher concentrations of triclopyr, whereas SAC had higher concentrations of 2,4-D and dicamba. Detection frequency, number of pesticides per sample, and pesticide concentration increased during rainstorm events. In water samples, all of the bifenthrin, malathion, fipronil, permethrin, and λ-cyhalothrin detections, and most of the fipronil sulfone and cyfluthrin detections were above their lowest US EPA aquatic benchmark. Diuron was the only herbicide that was detected above its lowest benchmark. Based on the number of pesticides and exceedances of aquatic benchmarks or the high number of sediment toxicity units, pesticides are abundant in California surface waters.  相似文献   

20.
The Henry's law constant (H) is an important parameter in predicting the transport, behavior and fate of organic compounds in environment. H is also required to model the air-water exchange of chemicals. Henry's law constant of formaldehyde (HCHO) was determined at six temperatures (50, 40, 30, 20, 10, and 5 degrees C) using a bubble-column technique. The apparent Henrys law constant (H*) values were strongly correlated to inverse of temperature (1/T, K) and the following relationship was obtained: In H* = (-1,641.3/T)-3.089. Seven concurrent ambient air and aqueous samples were also collected between October 11-17, 2005 at a sampling site located on the shoreline of Tahtali dam Lake in Izmir, Turkey to determine the magnitude and direction (deposition or gas-out) of HCHO flux. In all cases, the modeled gas-phase flux was positive (average +/- SD, 3,181 +/- 408 microg m(-2) day(-1)) indicating that atmospheric HCHO deposited to the Tahtali Lake.  相似文献   

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