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1.
A study was carried out in Pettavaithalai area to evaluate the current status of physico-chemical contaminants and their sources in groundwater. Groundwater samples collected from pettavaithalai area in 15 different stations were analyzed every alternative months over a period of two years from August 2000 to June 2002. A sugar mill is situated at the heart of the study area. Three profiles (profile A, B and C) were selected based on the direction in which the sugar mill effluent flows. In each profile five samples were collected from five different station at a regular distance of about 1 Km. The physico-chemical parameters such as pH, EC TDS, TH, NO3, SO4, PO4, Na, K, Ca, Mg, DO, BOD and COD have been analyzed. The results showed that among the three profiles, many of the estimated physico-chemical parameters of profile C were very high when compared to profile B and A which indicates the poor quality of the groundwater around this area.  相似文献   

2.
The present study has been carried out to assess groundwater quality in parts of Hindon–Yamuna interfluve region of western Uttar Pradesh. Fifty-five groundwater samples were collected from hand pumps in post-monsoon 2005 and pre-monsoon 2006 period, respectively, covering an area of about 1,345 km2. Physical and chemical parameters of groundwater such as electrical conductivity, pH, total dissolved solid, Na, K, Ca, Mg, HCO3, Cl, and SO4 were determined. Concentration of the chemical constituents in groundwater of the study area varies spatially and temporarily. Interpretation of analytical data of major ion chemistry helps to identify three chemical types of groundwater i.e. ‘mixed’, ‘mixed bicarbonate’ and ‘alkali bicarbonate’ types. The species likely to occur in groundwater of the study area are Ca-HCO3, Mg-HCO3, Ca-SO4, Na-Cl, Na-SO4, Na-HCO3, K-Cl, and some other possible species of K, depending on its abundance. The groundwater of the study area comes under the category of moderately hard to very hard, mildly acidic to slightly alkaline in nature. There is anomalously high concentration of major ions, particularly, Na, K, SO4, and Cl. High SO4 and K values may be related to anthropogenic influences, rather than through some natural process. Sodium along with Cl may be added to the system through sewage pollution and leachate percolation.  相似文献   

3.
The level of arsenic (As) contamination and the geochemical composition of groundwater in Shuklaganj area located on the banks of the Ganges Delta of Kanpur-Unnao district were elucidated. Samples (n?=?59) were collected from both India Mark II hand pumps (depth, 30-33 m) and domestic hand pump tube wells (10-12 m) located within 5 km from the banks of Ganges. Samples were analyzed for various parameters, including total inorganic As, sulfate, nitrate, alkalinity, ammonia, and iron. Hydrochemistry of the groundwater aquifer was studied through the trilinear plots between monovalent and divalent cations and anions. In Indian mark II hand pumps, arsenic concentration ranged from below detection limit to 448 μg/L. Most of the samples contained both As(III) and As(V). The pH of the samples ranged from 7.1 to 8.2. Except for a few, most of the samples were reducing in nature as evident by their negative oxidation reduction potentials. A positive correlation for arsenic with iron, ammonia, and dissolved organic carbon shows the probability of biodegradation of organic matter and reductive dissolution of Fe oxyhydroxide processes to leach As in aquifers. For confirmation of the suggested arsenic mobilization mechanism, the presence and absence of sulfate-reducing bacteria and iron-reducing bacteria were also tested.  相似文献   

4.
The present study aims at identifying the groundwater contamination problems in Bangalore city in India. Groundwater samples from 30 different locations of the industrial area were collected. Analytical techniques as described in the Standard methods for the examination of water and wastewater were adopted for physico-chemical analysis of these samples and the results compared with the Bureau of Indian Standards (BIS) guideline values for potable water in the light of possible health hazards. The investigations reveal that most of the study area is highly contaminated due to the excessive concentrations of one or more water quality parameters such as Nitrates, Total Hardness, Calcium, Magnesium, Total dissolved solids, Sulphates and Fluorides, which have rendered nearly 77% of the water samples tested, non- potable. Discussions held by the authors with the local public as well as the Primary health centre authorities of the area revealed that a lot of people in the area are suffering from severe health problems on using this water. The findings show that there is a clear correlation between the ill health faced by the public and contamination of the said groundwaters.  相似文献   

5.
Atmospheric particulate and gaseous polycyclic aromatic hydrocarbons (PAHs) samples were collected from an urban area in Dokki (Giza) during the summer of 2007 and the winter of 2007–2008. The average concentrations of PAHs were 1,429.74 ng/m3 in the particulate phase, 2,912.56 ng/m3 in the gaseous phase, and 4,342.30 ng/m3 in the particulate + gaseous phases during the period of study. Dokki has high level concentrations of PAH compounds compared with many polluted cities in the world. The concentrations of PAH compounds in the particulate and gaseous phases were higher in the winter and lower in the summer. Total concentrations of PAHs in the particulate phase and gaseous phase were 22.58% and 77.42% in summer and 36.97% and 63.03% in winter of the total (particulate + gaseous) concentrations of PAHs, respectively. The gaseous/particulate ratios of PAHs concentration were 3.43 in summer and 1.71 in winter. Significant negative correlation coefficients were found between the ambient temperature and concentrations of the total PAHs in the particulate and gaseous phases. The distribution of individual PAHs and different categories of PAHs based on aromatic ring number in the particulate and gaseous phases during the summer and winter were nearly similar, indicating similar emission sources of PAHs in both two seasons. Benzo(b)fluoranthene in the particulate phase and naphthalene in the gaseous phase were the most abundant compounds. Diagnostic concentration ratios of PAH compounds indicate that these compounds are emitted mainly from pyrogenic sources, mainly local vehicular exhaust emissions. Health risks associated with the inhalation of individual PAHs in particulate and gaseous phases were assessed on the basis of its benzo(a)pyrene equivalent concentration. Dibenzo(a,h)anthracene and benzo(a)pyrene in the particulate phase and benzo(a)pyrene and benzo(a)anthracene in the gaseous phase were the greatest contributors to the total health risks. The relative mean contributions of the total carcinogenic activity (concentrations) of all PAHs to the total concentrations of PAHs were 29.37% and 25.15% in the particulate phase and 0.76% and 0.92% in the gaseous phase during the summer and winter, respectively. These results suggest that PAHs in the particulate phase in the ambient air of Dokki may pose a potential health risk.  相似文献   

6.
Hydrogeochemical data of groundwater from the semi-confined aquifer of a coastal two-tier aquifer in Amol–Ghaemshahr plain, Mazandaran Province, Northern Iran reveal salinization of the fresh groundwater (FGW). The saline groundwater zone is oriented at an angle to both Caspian Sea coastline and groundwater flow direction and extends inland from the coastline for more than 40 km. Spearman’s rank correlation coefficient matrices, factor analysis data, and values of C ratio, chloro-alkaline indices, and Na+/Cl? molar ratio indicate that the ionic load in the FGW is derived essentially from carbonic acid-aided weathering of carbonates and aluminosilicate minerals, relict connate saline water, and ion exchange reactions. Saline groundwater samples (SGWS) (n?=?20) can be classified into two groups. SGWS of group 1 (n?=?17) represent the saline groundwater zone below the Caspian Sea level, and salinization is attributed essentially to (1) lateral intrusion of Caspian seawater as a consequence of (a) excessive withdrawal of groundwater from closely spaced bore wells located in the eastern part of the coastal zone and (b) imbalance between recharge and discharge of the two-tier aquifer and (2) upconing of paleobrine (interfaced with FGW) along deep wells. SGWS of this group contain, on average, 7.9 % of saltwater, the composition of which is similar to that of Caspian seawater. SGWS of group 2 (n?=?3) belong to the saline groundwater zone encountered above the Caspian Sea level, and salinization of the groundwater representing these samples is attributed to irrigation return flow (n?=?2) and inflow of saline river water (n?=?1).  相似文献   

7.
Surface sediment samples collected from the Salina Cruz Bay in the last twenty years, were analyzed for the total available trace elements (Cr, Cu, Fe, Pb, Ni, V, and Zn) to evaluate metal contamination due to possible anthropogenic inputs. Normalization of metals to iron and fine-grained fraction (< 63 μm) indicated relatively high enrichment factors for lead during the last two decades. Sediment Quality Guidelines suggest that lead must be considered as a chemical of potential concern in the marine and estuarine ecosystem. Concentration levels of lead ranged from 5–124 μg/g, while Ni and V below 70 and 30 μg/g, respectively. Geoaccumulation and enrichment factors for the rest of elements show comparable values to those reported for sites with similar activities in the world. Spatial distribution suggests that in addition to harbor activities, a transboundary source for Pb must account for the observed trends.  相似文献   

8.
Wind erosion is a phenomenon that is reasonably common in regions where dry winds blow. For the most part, these regions correspond to the dry lands; areas where the soil, generally, is dry and shifting and lacks vegetation for most of the year. The winds are sufficiently strong to lift and move sands and soil particles. The repeated removal of superficial layers by the action of winds can modify the texture of the topsoil, by removing the fine particles and leaving the larger particles. Dust and sandstorm (DSS) is the generic term for a serious environmental phenomenon that involves strong winds that blow a large quantity of dust and fine sand particles away from the ground and carry them over a long distance with significant environmental impacts along the way. In the realm of DSS in Iran country, the people who live in Yazd and Sistan–Baluchestan provinces form a single ecological community due to their geographic proximity and climatic contiguity. The major sources of DSS in the region are believed to be the desert and semidesert areas of the Yazd–Ardakan plain in Yazd province. Both Sistan and Baluchestan are the recipients of this dust. To address the long-range transboundary environmental problem of DSS, a regional cooperation mechanism must be established among the provinces in the region. Yazd–Ardakan plain, with area of about 650,000 ha, is located in the center of Iran, between Yazd and Ardakan cities. The mean annual rainfall is less than 65 mm. Rainfall distribution is a simple modal and more than 70% of it occurs in winter. Plant density varies from 0% to 25%, and Artemisia sieberi is the dominant plant species. The major part of Yazd–Ardakan plain is bare land. According to the recent investigation, more than 20,000-m3 dust with less than 100-μm diameter falls down annually on Yazd city with an area of 7,000 ha. Horizontal visibility is reduced to less than 6 m in stormy days in some parts of Yazd–Ardakan plain. This phenomenon causes car accidents on the main roads of Yazd–Ardakan and can cancel the airplane flights in the stormy days. At present, it is estimated that wind erosion causes more than $6.8 million damages to socioeconomic resources in Yazd plain each year. This paper describes the pattern of occurrence of wind erosion and major contributing factors, summarizes measured rates of wind erosion, outlines the techniques used to mitigate wind erosion hazard, and suggests research priorities. Also, damages of DSS have been estimated and methods for prevention and control are suggested.  相似文献   

9.
Most wastewater from the city of Chetumal is discharged into the adjoining bay without treatment through a pluvial sewer system. The bay also receives a high volume of vegetal organic material from the River Río Hondo. The average of biochemical oxygen demand (BOD) was 32.26 mg l-1, it was low compared with other reports and should be indicative of self-depuration processes in Chetumal Bay. In the area most used by the public for recreational and fishing activities, concentrations of fecal coliforms above the limit established by Mexican Legislation were shown. The border between Mexico and Belize is Chetumal Bay, which recently was declared a protected area for manatees.  相似文献   

10.
The Department of Energy’s Savannah River Site is a former nuclear weapon material production and current research facility located in South Carolina, USA. Wastewater discharges from a fuel and nuclear reactor target manufacturing facility released depleted and natural U, as well as other metals into the Tims Branch-Steed Pond water system. We investigated the current dynamics of this system for the purposes of environmental monitoring and assessment by examining metal concentrations, bioavailability, and trophic transfer of contaminants in seven ponds. Biofilm, detritus, and Anuran and Anisopteran larvae were collected and analyzed for stable isotopes (δ 15N, δ 13C) and contaminants of potential concern (COPC) with a focus on Ni, U, and Hg, to examine metal mobility. Highest levels of Ni and U were found in biofilms U (147 and 332 mg kg?1 DW, respectively), while highest Hg levels were found in tadpoles (1.1 mg kg?1 DW). We found intraspecific biomagnification of COPCs as expressed through stable isotope analysis. Biofilms were the best indicators for contamination and Anuran larvae with the digestive tract removed were the best indicators of the specific bioavailability of the focal metals. Monitoring data showed that baseline δ 15N values differed between ponds, but within a pond, values were stable throughout tadpole Gosner stage, strengthening the case to use this species for monitoring purposes. It is likely that there still is risk to ecosystem integrity as COPC metals are being assimilated into lower trophic organisms and even low levels of this mixture has shown to produce deleterious effects to some wildlife species.  相似文献   

11.
Ashtamudi estuary, situated on the southwest coast of India, is enormously affected by anthropogenic interventions. Physicochemical quality of water and sedimentological features of the estuary are evaluated during monsoon and nonmonsoon seasons to elucidate its quality variations and to link the same with existing environmental scenario. The whole data has been factorized using principal component analysis for extracting the total variability and linear relationships existing among a set of different physicochemical parameters of the backwater system. In PCA, high loadings were obtained for conductivity, salinity, fluoride, calcium, magnesium, sulfate, boron, and pH. The results were revealed that all the physicochemical processes depend upon seasonal fluctuation of freshwater input and seawater intrusion. Wide spatial concentration fluctuations of organic carbon and iron in bottom sediment have been noticed and both constituents reveal good correlation with sediment texture. The results showed high deterioration of the physicochemical quality of water during nonmonsoon season with respect to monsoon season.  相似文献   

12.
The large demand for drinking, irrigation and industrial water in the region of Torbali (Izmir, Turkey) is supplied from groundwater sources. Almost every factory and farm has private wells that are drilled without permission. These cause the depletion of groundwater and limiting the usage of groundwater. This study investigates spatial and temporal change in groundwater quality, relationships between quality parameters, and sources of contamination in Torbali region. For this purpose, samples were collected from 10 different sampling points chosen according to their geological and hydrogeological properties and location relative to factories, between October 2001 and July 2002. Various physical (pH, temperature, EC), chemical (calcium, magnesium, potassium, sodium, chloride, alkalinity, copper, chromium, cadmium, lead, zinc) and organic (nitrate, nitrite, ammonia, COD and cyanide) parameters were monitored. It was observed that the groundwater has bicarbonate alkalinity. Agricultural contamination was determined in the region, especially during the summer. Nitrite and ammonia concentrations were found to be above drinking water standard. Organic matter contamination was also investigated in the study area. COD concentrations were higher than the permissible limits during the summer months of the monitoring period.  相似文献   

13.
The seasonal effects of untreated and treated municipal sewage on the nutrients-nitrate (NO(3)), phosphate (PO(4)), sulphate (SO(4)), and the biochemical oxygen demand (BOD), chemical oxygen demand (COD) and dissolved oxygen (DO) of the receiving urban canal, the Buckingham canal at Kalpakkam (Tamil Nadu, India) was monitored monthly during pre- monsoon-2005 to post-monsoon-2006. The NO(3), PO(4) and SO(4) contents were higher in the downstream than that of the upstream of the outfall points of treated as well as untreated sewage, of the canal. The NO(3) and PO(4) contents were higher during summer than that of monsoon; however the SO(4) was higher during winter and lower during summer in the canal water. The BOD and COD were lower and DO was higher at the upstream than that of downstream of the canal. The concentrations of BOD and COD were higher during summer season, which decreased during monsoon season, while the DO decreased during the summer season and increased in monsoon season in the canal water. Cluster analysis applied to the six sampling points of the canal, has grouped them based on the water quality similarities.  相似文献   

14.
Data from the Environmental Protection Agency's (EPA) Environmental Monitoring and Assessment Program (EMAP) from 1990 to 1993 were used to assess the condition of the Long Island Sound (LIS) estuary. Ambient water, sediment and biota were collected during the summer months from 53 LIS stations using an unbiased sampling design. The design consists of two LIS subunits, LIS proper, and small estuaries (<2.6 km2) at the margins of the Sound. Selected indicators of condition included: benthic species composition, abundance and biomass; fish species composition and gross external pathology; sediment physical and chemical characterization and sediment toxicity; and water clarity and quality. Results of the four-year sampling indicated that 28(±11)% of the areal extent of LIS proper had a benthic index < zero (impacted) and 51(±12)% of the area of small estuaries was impacted. Analysis of the results of other indicators also shows that small estuaries were particularly affected. For example, 42(±10)% of the areal extent of small estuaries exhibited sediment toxicity, and significant chemical contamination was evident in 22% of the area of small estuaries. Low dissolved oxygen (D.O.) concentrations (<5 ppm), however, appeared to affect only the deeper open waters of western LIS. Approximately 48(±12)% of the areal extent of LIS proper documented exposure to at least moderate D.O. stress (<5 ppm). The overall results of this monitoring study indicate that significant anthropogenic impacts have occurred in LIS and that if remediation was to take place, specific localized sediment problems would need attention. Point source and non-point source nutrient inputs to the Sound, which are believed to be the primary causative factor for the observed hypoxic conditions, would also need attention.  相似文献   

15.
Surface soil (0–20 cm) samples (n?=?143) were collected from vegetable, maize, and paddy farmland used for commercial crops in Liaoning, China. Sixteen priority polycyclic aromatic hydrocarbons (PAHs) listed in US Environmental Protection Agency were analyzed by high-performance liquid chromatography using a fluorescence detector. The soil concentrations of the 16 PAH ranged from 50 to 3,309 ng/g with a mean of 388 ng/g. The highest concentration of total PAHs found in soil of the vegetable farmland was 448 ng/g in average, followed by maize and paddy with total PAHs of 391 and 331 ng/g, respectively. Generally, the low molecular weight PAHs were more predominant than the high molecular weight PAHs in most of the soils. The evaluation of soil PAH contamination based on the Canadian criterion indicated that only naphthalene, phenanthrene, and pyrene were over the target values in several sampling sites. Isomer pair ratios and principal component analysis indicated that biomass and coal combustion were the main sources of PAHs in this area. And the average value of total B[a]Peq concentration in vegetable soils was higher than paddy and maize soils. We suggest that biomass burning should be abolished and commercial farming should be carried out far from the highways to ensure the safety of food products derived from commercial farming.  相似文献   

16.
This study is an analysis of the concentrations and components of heavy metals in PM2.5 and the total suspended particulate (TSP) collected at a mechanical industrial complex (IC) site in Changwon and at a residential site in Masan, Korea. Particulate was collected during two sampling periods, from the late summer to the early fall and from the middle to late fall, at the IC site and one sampling period, from the middle fall to the early winter, at the residential site. PM2.5 and TSP samples were taken by an annular denuder system and a hi-volume air sampler, respectively. The authors also identified the concentrations and components of heavy metals extracted from the PM2.5 and TSP filters, the acidic components extracted from the PM2.5 filters, and the polycyclic aromatic hydrocarbons (PAHs) extracted from polyurethane foam (PUF) plug. The average concentrations of the PM2.5 collected at the IC and residential sites were very similar. Major sources of PM2.5 at the study sites, however, were air emissions from vehicles and industry as well as emissions from residential heating and soil origins, respectively. The higher concentrations of the TSP at the IC site, as compared to those at the residential site, were due to either increased suspended dust from vehicle emissions or re-suspended road dust because of increased vehicle speeds near the IC site. Heavy metal concentrations in the TSPs were higher than those in the PM2.5. The heavy metal concentrations in the PM2.5 and TSP at the IC site with heavy traffic were substantially greater than those at the residential site. The concentrations of TSP and heavy metals and PAHs in PM during the period of the middle to late fall was much higher than those during the period of the late summer to early fall at the IC site. This is because of the difference in meteorological characteristics and energy uses between two periods. The residential site also showed higher concentrations of acidic anions while the IC site showed higher concentrations of acidic cation. Secondary aerosols or particulates, such as ammonium nitrate or ammonium nitrite, might have been important constituents of the PM2.5 at the residential site. The PAHs in the TSP collected at the IC site was greatly affected by traffic and industry emissions consisting mostly of high molecular weight PAHs with two to four rings. PAHs in the TSP at the site, however, were affected by residential heating and air emissions from small chemical plants having higher concentrations of low molecular weight PAHs with five to six rings.  相似文献   

17.
Trichoderma harzianum was isolated from local dumpsites of Shivamogga District for use in the biodegradation of polyethylene. Soil sample of that dumpsite was used for isolation of T. harzianum. Degradation was carried out using autoclaved, UV-treated, and surface-sterilized polyethylene. Degradation was monitored by observing weight loss and changes in physical structure by scanning electron microscopy, Fourier transform infrared spectroscopy, and nuclear magnetic resonance spectroscopy. T. harzianum was able to degrade treated polyethylene (40 %) more efficiently than autoclaved (23 %) and surface-sterilized polyethylene (13 %). Enzymes responsible for polyethylene degradation were screened from T. harzianum and were identified as laccase and manganese peroxidase. These enzymes were produced in large amount, and their activity was calculated using spectrophotometric method and crude extraction of enzymes was carried out. Molecular weight of laccase was determined as 88 kDa and that of manganese peroxidase was 55 kDa. The capacity of crude enzymes to degrade polyethylene was also determined. By observing these results, we can conclude that this organism may act as solution for the problem caused by polyethylene in nature.  相似文献   

18.
Bottom sediments from Nakaumi Lagoon and the Honjo Area in southwest Japan were analyzed to determine their geochemical compositions and to assess potential impacts by comparison with sediment quality guidelines. Present-day water quality was also assessed. Results showed that the water quality of Nakaumi Lagoon and the Honjo area contrasts between their upper and lower parts. Average abundances of As, Pb, Zn, Cu, Ni, and Cr in the Nakaumi sediments were 12, 25, 135, 32, 21, and 46 ppm, respectively, compared to 10, 24, 110, 26, 20, and 38 ppm in the Honjo area. All averages are greater than those of the upper continental crust. The elevated metal concentrations are probably related to the fine-grained nature of the sediments, reducing bottom conditions produced by abundant organic matter and possibly minor non-point anthropogenic sources. Trace metal contents are strongly correlated with Fe2O3, suggesting that Fe oxides play a role in controlling abundances. Metal concentrations exceed the NYSDEC lowest effect level and CCME interim sediment quality guidelines that indicate moderate impact on aquatic organisms. Average abundances of As and Zn are comparable to the Coastal Ocean Sediment Database threshold, whereas maximum concentrations exceed that value, indicating that the concentrations of these metals are potentially toxic. These enrichments suggest that regular monitoring may be desirable even where no point sources of metal pollution exist.  相似文献   

19.
Two methods were used to calculate the meteorologically adjusted ground level ozone trends in southern Taiwan. The first method utilized is a robust linear regression method. The second approach uses a multilayer perceptron (MLP) artificial neural network (ANN) method. The observations obtained from 16 monitoring stations were analyzed and divided into six groups by hierarchical divisive clustering procedure. The daily maximum 1 and 8 h ozone concentrations for each group are then calculated. The meteorologically adjusted trends obtained by linear regression and MLP methods are smaller than the unadjusted trends for all groups and average time. It indicts that the meteorological conditions in Taiwan tend to increase ambient ozone concentrations in recent years.  相似文献   

20.
Using the membrane filtration technique to count total coliform (TC), fecal coliform (FC) and fecal streptococci (FS), the microbiological water quality of the Mfoundi River and four of its representative tributaries at Yaoundé, Cameroon, was assessed for human use and contact. Sampling was conducted so as to examine the potential origin of fecal contamination and how rainfall affects the measured concentrations of indicators organisms. Our results revealed that waters were not safe for human use or primary contact according to the standards for water quality established by the Word Health Organization (WHO). Indeed, these waters exhibited high concentrations of TC (Mean ± SD=5.6 × 108 ± 2.5 × 106 CFU/100 ml), FC (Mean ± SD=6.8 × 105 ± 2.4 × 103 CFU/100 ml) and FS (Mean ± SD=7.3 × 105 ± 2.1 × 103 CFU/100 ml) that varied with the sampling sites and points. FC/FS ratio suggested that this contamination was more from warm-blooded animals than humans and correlation analysis points to the role of rainfall as a contributing factor, which enhanced the bacterial numbers detected. We conclude that there is a great potential risk of infection for users of waters from the Mfoundi River and its tributaries at Yaoundé.  相似文献   

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