共查询到19条相似文献,搜索用时 718 毫秒
1.
用2种端氨基聚醚化合物Jeffamine-T403和Jeffamine-D230作原料分别合成了二硫代氨基甲酸盐型絮凝剂DTC-1和DTC-2,利用红外光谱分析,确认了产物分子的结构.以高岭土悬浊液为处理对象,通过考察DTC分子结构、投药量和Fe2+络离子浓度对絮凝的影响及Zeta电位的变化,讨论了DTC的作用规律和机理.结果表明,与DTC-2相比,DTC-1与Fe2+络合可形成网状超分子结构,故产生的絮体具有较好的网捕作用.金属离子为Fe3+时,絮凝性能较差.DTC-1除油能力强,在 Fe2+的配合下, 20mg/L的投加量可使油浓度从 93.9,404.3, 878.6mg/L分别降至1.1,3.2,6.4mg/L. 相似文献
2.
Performance of dithiocarbamate-type flocculant in treating simulated polymer
flooding produced water
Produced water from polymer flooding is di cult to treat due to its high polymer concentration, high viscosity, and emulsified
characteristics. The dithiocarbamate flocculant, DTC (T403), was prepared by the amine-terminated polyoxypropane-ether compound
known as Je amine-T403. The product was characterized by IR spectra and elemental analysis. The DTC agent chelating with Fe2+
produced a network polymer matrix, which captured and removed oil droplets e ciently. Oil removal by the flocculent on simulated
produced water with 0, 200, 500, 900 mg/L of partially hydrolyzed polyacrylamide (HPAM) was investigated for aspects of e ectiveness
of DTC (T403) dosage and concentrations of HPAM and Fe2+ ions in the wastewater. Results showed that HPAM had a negative
influence on oil removal e ciency when DTC (T403) dosage was lower than 20 mg/L. However, residual oil concentrations in
tested samples with di erent concentrations of HPAM all decreased below 10 mg/L when DTC (T403) dosage reached 30 mg/L.
The concentration of Fe2+ in the initial wastewater had a slight e ect on oil removal at the range of 2–12 mg/L. Results showed that
Fe3+ could not be used in place of Fe2+ as Fe3+ could not react with DTC under flocculated conditions. The e ects of mineral salts ions
were also investigated. 相似文献
3.
通过絮凝-沉淀法对采油废水进行深度处理,类比聚合氯化铝(PAC)、聚合氯化铝铁(PAFC)、聚合硫酸铝(PAS)、聚合硫酸铝铁(PAFS)、复合高分子絮凝剂(KD-11C)和生物絮凝剂6种絮凝剂对采油废水中含油量和悬浮固体(SS)含量的去除效果,通过单因素试验探究絮凝剂投加量、助凝剂投加量、温度、pH值和沉淀时间对絮凝效果的影响,并通过正交试验确定各因素影响程度的次序及最佳絮凝处理条件。结果表明:复合高分子絮凝剂絮凝效果最好;影响絮凝效果各因素的次序为温度pH值絮凝剂投加量助凝剂投加量沉淀时间;最佳絮凝处理条件是絮凝剂KD-11C投加量为50mg/L、助凝剂PAM投加量为3mg/L、温度为60℃、pH值为7.5、沉淀时间为30min。 相似文献
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采用Fenton法预处理干法腈纶聚合废水,考察H2O2投加量、Fe2+投加量及pH对Fenton反应过程中氧化和絮凝作用去除废水有机物的影响。结果表明,在H2O2投加量为90 mmolL,Fe2+投加量为30 mmolL,初始pH为3.0的条件下,反应120 min后调节pH至6.0进行絮凝,废水中TOC总去除率可达55.6%,Fenton氧化和絮凝作用可实现较好的有机物去除效果。Fenton氧化后将pH调至8.0,有利于絮体的沉降,在实际应用中更加合理。三维荧光光谱(EEM)和荧光区域积分(FRI)发现,Fenton反应能够去除废水中大部分类蛋白易降解有机物,氧化作用对废水中类富里酸有机物的去除作用较小,该类物质主要通过絮凝作用去除。 相似文献
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通过将Fenton法应用于印染废水的处理,研究pH值、温度、反应时间、Fe2+投加量以及H2O2投加量对Fenton试剂处理印染废水的影响,同时确定Fenton法处理印染废水的最适反应条件。实验结果表明:(1)最适反应条件,即pH值、温度、反应时间、Fe2+投加量、H2O2投加量分别为3,50℃,45 min,70 mg/L,2.5 mL/L,此时COD的去除率最高,为66.60%。(2)pH值为3时,下列因素对COD的去除率影响程度大小依次为H2O2投加量Fe2+投加量反应时间反应温度。 相似文献
7.
Fenton试剂+SBR法处理纤维素废水的研究 总被引:1,自引:0,他引:1
采用Fenton试剂+SBR法对COD很高的纤维素废水进行处理。首先用絮凝法预处理纤维素废水,然后加入Fenton试剂进行处理,得出在pH为3、Fe2+用量为1.5×10-2 mol/L即2.28 g/L、H2O2的投加量为0.858 g/L、H2O2和Fe2+的投加量比为6、反应时间为4 h时效果最佳,COD降到1 002.8 mg/L,去除效率为88.3%。然后进行SBR生物处理,厌氧处理8 h,好样处理10 h,此时COD处理效果最好为92.8 mg/L,去除效率为90.7%,BOD5为46.8 mg/L,去除效率为88.3%。 相似文献
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采用铁炭微电解-Fenton联合工艺处理制药废水生化出水,探讨了初始pH对微电解过程COD降解速率、出水中Fe2+和Fe3+变化规律以及后续Fenton氧化效果的影响,为优化联合工艺提出了微电解反应pH过程控制的理论。采用pH过程控制时,微电解对COD降解速率大大提高,降解过程基本符合零级反应动力学,同时可大大提高Fe2+和Fe3+浓度及总铁析出量。试验结果表明:当初始pH=2.5,以3.0L/h连续性投加稀硫酸100 min,曝气微电解反应2 h,出水再投加1.0mL/L的H2O2进行Fenton氧化2 h,出水COD总去除率可达85.6%;采用pH过程控制可将微电解出水ρ(Fe2+)浓度从48.6 mg/L提高至149 mg/L,COD降解速率从10.9 mg/(L·h)提高至23.8 mg/(L·h)。 相似文献
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以肼黄染料废水为模拟对象,在单因素试验的基础上通过响应面法优化Fenton氧化的脱色效果,研究了初始pH值、Fe2+投加量和H2O2投加量3个因素在该废水脱色过程中的显著性和交互性.结果表明,这3个因素对肼黄染料废水的脱色率的影响均具有显著性,且初始pH值与Fe2+投加量的交互影响、Fe2+投加量与H2O2投加量的交互影响也具有显著性.响应面法优化得到的最佳脱色工艺:初始pH值为3.19,Fe2+质量浓度为23.2 mg/L,H2O2质量浓度为345.4 mg/L,反应温度45℃,反应时间5 min;在此条件下的理论脱色率为90.85%,与3次实际平行试验的脱色率均值仅相差2.30%. 相似文献
10.
化学絮凝剂预处理马铃薯淀粉废水的比较研究 总被引:4,自引:1,他引:3
马铃薯淀粉废水产生的季节性使得常规生物处理应用起来存在很大困难,采用絮凝剂对废水进行预处理可减轻后续处理负担。文章使用常规化学絮凝剂AlCl3、Fe2(SO4)3、PAM以及有机和无机之间的相互复配对马铃薯淀粉废水进行絮凝预处理,研究了投药量、废水pH值、助凝剂CaCl2投加量以及沉降时间等因素对絮凝效果的影响,确定了各絮凝剂处理废水的较佳絮凝条件,并在较佳条件下处理废水,通过综合比较处理效率、处理成本、絮凝条件难易程度等方面,确定了马铃薯淀粉废水的较佳絮凝剂为AlCl3+PAM,其具有废水处理效果好(COD去除率为41.08%,浊度去除率为95.06%,色度去除率为90.63%)、投药量少(2mLAlCl3+0.3mLPAM)、助凝剂投加量少(1mLCaCl)2、较佳pH在废水初始pH范围内、处理成本低(11.05元/t废水)、产生污泥量少(649g/t废水)等优点。 相似文献
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Fe2+-H2O2法处理DSD酸生产氧化母液的研究 总被引:26,自引:1,他引:25
为改善DSD酸氧化母液的可生化降解性,将废液先用有机絮凝剂TS-1(一种季胺盐)处理,TS-1的投加量为3g/L,其后用Fe2+-H2O2法氧化,Fe2+和H2O2的量分别为150mg/L,7g/L,废液COD和色度的去除率分别可达64%和62%。经处理后的废水,其BOD5/COD≈0.3,可以认为已达到生化处理的要求。当H2O2的投量为2g/L,经Fe2+-H2O2氧化处理后的废液,再用FeCl3进行两级混凝处理(FeCl3的投加量分别为5g/L和2g/L),则COD和色度的去除率可达90%和95%。 相似文献
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均相Fenton法处理干法腈纶废水工艺优化与分析 总被引:2,自引:0,他引:2
采用均相Fenton法处理干法腈纶废水,并通过单因素试验和基于中心组合设计的响应面法考察了H2O2投加量、Fe2+投加量、初始pH值及反应时间的影响及其交互作用.同时,建立了以COD去除率为响应值的二次响应曲面模型,并采用方差分析对模型进行了验证.结果表明,影响COD去除效果的各因子显著性顺序依次为:Fe2+投加量>H2O2投加量>初始pH值>反应时间;Fe2+投加量与初始pH值的交互作用最为显著;反应最优组合条件为:H2O2投加量90.0mmol.L-1,Fe2+投加量30.0mmol.L-1、初始pH值3.1,反应时间113.6min,该条件下COD去除率为47.1%,与模型预测值48.5%基本一致. 相似文献
15.
添加原水改善SBR工艺处理猪场废水厌氧消化液性能 总被引:26,自引:7,他引:19
采用序批式反应器(SBR)工艺直接处理猪场废水厌氧消化液,处理系统的效率较低,COD去除率仅有10%左右,NH4+-N去除率70%左右;处理出水水质较差,出水COD高于1 000mg/L,出水NH4+-N在200mg/L左右;处理系统的工作不稳定,效能逐渐恶化.在猪场废水厌氧消化液中添加部分未经厌氧消化的猪场废水(原水),处理系统的处理效率明显提高,COD去除率高于80%,出水COD降到250~350mg/L;NH4+-N去除率高于99%,出水NH4+-N小于10mg/L;处理系统的稳定性也得到增强.添加原水后,猪场废水厌氧消化液的BOD5/COD比值从0.19上升到0.54,BOD5/TN比值从0.28上升到2.04,增加了微生物生长和反硝化所需的碳源,强化了反硝化作用,不仅提高了总氮去除效率,而且通过回补碱度,维持了处理系统的pH值稳定. 相似文献
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Commercial available zero valent aluminum under air-equilibrated acidic conditions (ZVAl/H+/air system) demonstrated an excellent capacity to remove aqueous organic compounds. Acetaminophen (ACTM), the active ingredient of the over-the-counter drug Tylenol®, is widely present in the aquatic environment and therefore the treatment of ACTM-contaminated water calls for further research. Herein we investigated the oxidative removal of ACTM by ZVAl/H+/air system and the reaction mechanism. In acidic solutions (pH < 3.5), ZVAl displayed an excellent capacity to remove ACTM. More than 99% of ACTM was eliminated within 16 hr in pH 1.5 reaction solutions initially containing 2.0 g/L aluminum and 2.0 mg/L ACTM at 25 ± 1\textcelsius. Higher temperature and lower pH facilitated ACTM removal. The addition of different iron species Fe0, Fe2+ and Fe3+ into ZVAl/H+/air system dramatically accelerated the reaction likely due to the enhancing transformation of H2O2 to HO. via Fenton's reaction. Furthermore, the primary intermediate hydroquinone and the anions formate, acetate and nitrate, were identified and a possible reaction scheme was proposed. This work suggested that ZVAl/H+/air system may be potentially employed to treat ACTM-contaminated water. 相似文献
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戊二醛交联酵母菌对Zn2+,Cd2+和Hg2+的吸附行为 总被引:5,自引:4,他引:1
用戊二醛作为交联剂,采用简单的方法制备机械强度高的交联酵母菌.考察菌体吸附Cd2 的影响因素,包括交联剂的用量,pH,金属离子初始质量浓度,吸附时间等,研究菌体对不同质量浓度的Zn2 ,Cd2 和Hg2 的吸附率.结果表明,戊二醛的最佳用量(体积分数)为1.0%,菌体对金属离子的吸附平衡时间为30 min,吸附过程符合准二级动力学方程.吸附为Langmuir单分子层吸附,相对于未交联菌,交联酵母菌对Cd2 的吸附容量提高2倍;pH实验表明,交联酵母菌对金属离子的吸附受酸度影响小.用于冶金厂废水的处理结果显示,0.050 0 g的交联酵母菌,对5.3 mg/L的Cd2 污水的去除率为80.6%,用0.1 mol/L的EDTA再生该吸附剂,Cd2 的解析率达92.1%. 相似文献
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Ferrous and manganese ions, as essential elements, significantly affect the synthesis of Haem-C, which participates in the energy metabolism and proliferation of anammox bacteria. In this study, two identical sequencing batch biofilm reactors were used to investigate the effects of ferrous and manganese ions on nitrogen removal efficiency and the potential of metal ions serving as electron donor/acceptors in the anammox process. Fluorescence in situ hybridization analysis was applied to investigate the microbial growth. Results showed that the nitrogen removal increased at high concentrations of Fe2+ and Mn2+ and the maximum removal efficiency was nearly 95% at Fe2+ 0.08 mmol/L and Mn2+ 0.05 mmol/L, which is nearly 15% and 8% higher than at the lowest Fe2+ and Mn2+ concentrations (0.04 and 0.0125 mmol/L). The stabilities of the anammox reactor and the anammox bacterial growth were also enhanced with the elevated Fe2+ and Mn2+ concentrations. The Fe2+ and Mn2+were consumed by anammox bacteria along with the removal of ammonia and nitrite. Stoichiometry analysis showed Fe2+ could serve as an electron donor for NO3-N in the anammox process. Nitrate could be reduced with Fe2+ serving as the electron donor in the anammox system, which causes the value of NO~-N/NH4-N to decrease with the increasing of N-removal efficiency. 相似文献