施用污泥堆肥对滩涂土壤理化性质的影响

污泥堆肥中富含有机质营养成分，可改良土壤，同时要防止重金属和病原菌等可能引起的污染。为评价污泥堆肥作为土壤改良基质的可能性，本试验系统进行了上海曲阳水质净化厂污泥堆肥／滩涂土混配土的理化性质分析。研究结果表明，污泥堆肥与滩涂土混配后，土壤pH、电导率、阳离子交换量等理化指标得到改善；营养得到补充，肥力提高明显；混配土中未见病原菌污染问题，污泥堆肥施加比例控制在30％（干重计）以内时，也不存在重金属污染风险，混配土可以满足农用要求。     

The effects of pulverized refuse fines (PRF) as a soil material on plant growth

Pulverized refuse fines (PRF) are the residual fine screenings from refuse-derived fuel plants after the removal of metals and oversize material from domestic refuse, and the extraction of the light fraction as fuel. It appears to be a potential soil amendment, but currently it is disposed of by landfilling. The glasshouse experiment described in this paper therefore evaluated its effectiveness as a soil amendment or soil material for plant growth.PRF had a slightly alkaline pH and was high in organic carbon and soluble salts. Unamended PRF supported significantly higher yields of ryegrass than PRF mixed with a sandy soil at 2 and 10% (w/w), and was comparable to that of sewage sludge and sludge-amended PRF. On the other hand, PRF supplemented with inorganic nitrogen or phosphorus resulted in better yields than PRF alone. Despite the high C/N ratio of PRF, nitrogen recovery in ryegrass suggested that mineralization was sufficiently high to allow adequate plant uptake and sustained plant growth, although there was initial inhibition. Tissue contents of zinc, copper and cadmium from pure PRF treatment were not excessive and were lower than those from sewage sludge.High rate applications of PRF, which are desirable from the viewpoint of disposal, should not cause environmental degradation. PRF is not as good as commercial fertilizers or potting media, but it can be an excellent soil substitute in horticulture and land reclamation.     

污泥农用对土壤环境的影响

土地利用是解决城市污泥处理处置的有效途径之一,本文从土壤理化性质、重金属污染风险以及有机污染风险3方面综述城市污泥农用对土壤环境的影响。城市污泥利用为植物提供营养元素,改良土壤结构,提高土壤肥力。污泥施用年限的长短与土壤中重金属的含量高低关系不明显,导致土壤重金属含量增加的主要因素是污泥施用量和污泥中重金属含量。在正常...     

Modeling organic carbon dynamics and cadmium fate in long-term sludge-amended soil

A model is described that may help to resolve uncertainty and controversy over the long-term consequences of sludge applications to arable land, especially with regard to the effects of sludge adsorption characteristics on trace metal solubility and bioavailability (e.g., the sludge "time bomb" or sludge "protection" hypotheses). Mass balances of organic and inorganic material derived from sludge and crop residues are simulated. Each pool has a potentially different adsorption affinity for trace metals, and this leads to changes in the adsorption capacity of sludge-amended soil that influence leaching and crop uptake. Model simulations were compared with measured changes in organic carbon and ethylenediaminetetraacetic acid (EDTA)-extractable cadmium contents in a clay loam soil following 41 years of sludge applications. The model adequately reproduced the data, although discrepancies in the vertical distribution of Cd were attributed to the effects of macropore transport and root-uptake driven recirculation. A Monte Carlo sensitivity analysis demonstrated that the most important parameters affecting leaching and crop uptake were the Cd loading and parameters controlling adsorption, especially the partition coefficient for sludge-derived inorganic material and the exponent regulating the effect of pH on sorption. Scenario simulations show that no general conclusions can be drawn with respect to the validity of the sludge "time bomb" and sludge "protection" hypotheses. Either may occur, or neither, depending on three key system parameters: the ratio of sludge adsorption capacity to the initial adsorption capacity of the soil, the proportion of the sludge adsorption capacity contributed by the inorganic fraction, and the sludge Cd loading.     

Nonconventional treatment of sewage sludge using cement kiln dust for reuse and catalytic conversion of hydrocarbons

Sewage sludge represents a critical environmental issue in Egypt. Large quantities of CKD are emitted from cement factories. It has negative impacts on humans, animals, plants, lands, water, and all remaining environment. It causes serious problems on the national level. Besides using CKD for sludge treatment and reuse as soil conditioner, a new scenario is to use it as catalytic convertor of some hydrocarbons. Results showed that CKD is used to separate the organic matters and suspended solids, reduce the organic micropollutants, scavenge heavy metals, and destruct viruses, parasites, and all pathogenic bacteria. The dehydrogenation of isopropanol to acetone and alcohol condensation of the produced acetone to give methyl isobutyl ketone over different catalyst samples was studied using a flow technique under normal pressure. Results revealed that treatment of raw sludge led to an increase in catalytic activity toward acetone formation by 50?% at 400?°C. A treatment system was proposed for continuous operation.     

Improvement of soil quality after "alperujo" compost application to two contaminated soils characterised by differing heavy metal solubility

Reclamation of trace element polluted soils often requires the improvement of the soil quality by using appropriate organic amendments. Low quality compost from municipal solid waste has been tested for reclamation of soils, but these materials can provide high amounts of heavy metals. Therefore, a high-quality compost, with low levels of heavy metals, produced from the main by-product of the Spanish olive oil extraction industry ("alperujo") was evaluated for remediation of soils affected by a pyritic mine sludge. Two contaminated soils were selected from the same area: they were characterised by differing pH values (4.6 and 7.3) and total metal concentrations, which greatly affected the fractionation of the metals. Compost was applied to soil at two rates (equivalent to 48 and 72 Tm ha(-1)) and compared with an inorganic fertiliser treatment. Compost acted as an available nutrient source (C, N and P) and showed a low mineralisation rate, suggesting a slow release of nutrients and thus favouring long term soil fertility. In addition, the liming effect of the compost led to a significant reduction of toxicity for soil microorganisms in the acidic soil and immobilisation of soil heavy metals (especially Mn and Zn), resulting in a clear increase in both soil microbial biomass and nitrification. Such positive effects were clearly greater than those provoked by the mineral fertiliser even at the lowest compost application rate, which indicates that this type of compost can be very useful for bioremediation programmes (reclamation and revegetation of polluted soils) based on phytostabilisation strategies.     

Trees' role in nitrogen leaching after organic, mineral fertilization: a greenhouse experiment

New sustainable agriculture techniques are arising in response to the environmental problems caused by intensive agriculture, such as nitrate leaching and surface water eutrophication. Organic fertilization (e.g., with sewage sludge) and agroforestry could be used to reduce nutrient leaching. We assessed the efficiency of establishing trees and pasture species in environmentally sensitive, irrigated Mediterranean grassland soils in controlling nitrate leaching. Four vegetation systems-bare soil, pasture species, cherry trees [ (L.) L.], and pasture-tree mixed plantings-and five fertilization treatments-control, two doses of mineral fertilizer, and two doses of organic fertilizer (sewage sludge)-were tested in a greenhouse experiment over 2 yr. In the experiment, the wet and warm climate characteristics of Mediterranean irrigated croplands and the plant-to-plant and soil-to-plant interactions that occur in open-field agroforestry plantations were simulated. Following a factorial design with six replicates, 120 pots (30-cm radius and 120 cm deep) were filled with a sandy, alluvial soil common in the cultivated fluvial plains of the region. The greatest pasture production and tree growth were obtained with sewage sludge application. Both pasture production and tree growth decreased significantly in the pasture-tree mixed planting. Nitrate leaching was negligible in this latter treatment, except under the highest dose of sewage sludge application. The rapid mineralization of sludge suggested that this organic fertilizer should be used very cautiously in warm, irrigated Mediterranean soils. Mixed planting of pasture species and trees, such as , could be a useful tool for mitigating nitrate leaching from irrigated Mediterranean pastures on sandy soils.     

Effects of grassland conversion to croplands on soil organic carbon in the temperate Inner Mongolia

This study investigated the effects of grassland conversion to croplands on soil organic carbon (SOC) in a typical grassland-dominated basin of the Inner Mongolia using direct field samplings. The results indicated that SOC contents decreased usually with increasing soil depth, with significant differences between the upper horizons (0-30cm) and the underlying horizons (30-100cm). Also, SOC densities decreased with an increase in the depth of soils. Average SOC densities in the upper horizons were 2.6-3.7 and 6.0-8.3kgCm(-2) for desert grassland-cropland sites (sites 1 and 2) and meadow-cropland sites (sites 3 and 4), respectively, with significant differences between grasslands and croplands (P<0.05). However, the SOC densities in the underlying horizons did not significantly differ between the land uses. The SOC densities up to 100cm depth were much higher in the meadow-cropland sites than in the desert grassland-cropland sites, reaching approximately 16 and 6kgCm(-2), respectively. The SOC: total nitrogen (TN) ratios were approximately 10, with no significant difference among the soil horizons of grasslands and croplands. The conversion of grasslands to croplands induced a slight loss of SOC, with a range of from -4% to 22% for the 0-100cm soil depth over about a 35-year period, in the temperate Inner Mongolia.     

Bioleaching of heavy metals from sewage sludge: A review

During the treatment of sewage, a huge volume of sludge is generated, which is disposed of on land as soil fertilizer/conditioner due to the presence of nitrogen, phosphorus, potassium and other nutrients. However, the presence of toxic heavy metals and other toxic compounds in the sludge restricts its use as a fertilizer. Over the years, bioleaching has been developed as an environmentally friendly and cost-effective technology for the removal of heavy metals from the sludge. The present paper gives an overview of the various bioleaching studies carried out in different modes of operation. The various important aspects such as pathogen destruction, odor reduction and metal recovery from acidic leachate also have been discussed. Further, a detailed discussion was made on the various technical problems associated with the bioleaching process, which need to be addressed while developing the process on a larger scale.     

Potential of the Conservation Reserve Program to control agricultural surface water pollution

The Conservation Reserve Program (CRP), initiated by the Conservation Title of the Food Security Act of 1985, is the primary federal program to control nonpointsource pollution in agricultural watersheds of the United States. However, the program is designed primarily to reduce soil erosion rather than to retire croplands in a manner optimal for controlling runoff of sediment and associated pollutants. This study estimates potential enrollment of streamside and floodplain croplands in this ten-year retirement program in order to gauge the potential of the CRP as a water-quality improvement policy. A contingent choice survey design was employed in Fayette County, Illinois, to demonstrate that there is substantial potential for retirement of streamside and floodplain croplands in the CRP. Enrollments in each program climb from less than 6% to over 83% of eligible croplands as the annual rental rate is increased from $20 to $200/acre. Potential retirement of streamside and floodplain croplands declines, however, if tree planting, drainage removal, or a 20-year contract are required. The potential of a CRP-based water-quality program to improve water quality and aquatic ecosystems in agricultural watersheds is thus substantial but constrained by the economic trade-offs that farmers make between crop production and conservation incentives in determining the use of their riparian lands.     

Effect of liming on the distribution of heavy metals in untreated industrial sewage sludge produced in Pakistan for the cultivation of <Emphasis Type="Italic">Sorghum bicolor</Emphasis> (L.)

The recycling of sewage sludge on agriculture land represents an alternative, advantageous, disposal of this waste material. The aim of the present study was to evaluate the feasibility of using industrial sewage sludge, produced in Pakistan, as a fertiliser. Agricultural soil amended with 25% (w/w) sewage sludge with or without lime treatment was used for growing a variety of sorghum (PARC-SS-1). The mobility of the heavy metals (HMs) (Cd, Cu, Cr, Ni, Pb and Zn) and metalloid (As) in the untreated industrial waste water sewage sludge (UIWS) samples were assessed by applying a modified BCR (Community Bureau of Reference) sequential extraction procedure. The single extraction procedure comprised of the application of mild extractant (CaCl₂) and water for the estimation of the proportion of easily soluble metal fractions. The precision and accuracy of BCR was evaluated by using a certified reference material of soil amended with sewage sludge BCR 483. The plant available metal contents, as extracted by the deionised water and 0.01 M CaCl₂ solution and exchangeable fraction of BCR sequential, decreased with lime application in the range of 10–44% for As, Cr, Ni, Pb and Zn, except in the cases of Cd and Cu, where their mobility was increased by 10% and 24%, respectively. Sludge amendment enhanced the dry weight yield of sorghum and the increase was more obvious after liming up to 25%. The uptake of HMs were lower in test samples (3.2–21.8%), except for Cu and Cd, which was higher (4%), while they were below the permissible limit of these metals. The present experiment demonstrates that liming was important in factors facilitating the growth of sorghum in sludge-amended soil.     

利用城市污水厂剩余污泥制备生物炭吸附镉

利用城市污水厂剩余污泥制备生物炭并用于吸附重金属离子Cd2＋，有利于城市污水厂污泥的处置，为污水中重金属的处理与处置和“碳减排”提供新的思路与方法。研究结果表明不同污水厂的污泥的最佳活化温度不同，昆明第一污水处理厂污泥最佳活化温度为300℃，第三、第五污水处理厂污泥为400℃；对于污水厂污泥制备的生物炭对镉的吸附量随着pH值的升高而增加；吸附模型拟和结果表明Freundllch模型在大部分温度下均具有比Iangrmuir模型有更好的相关性。     

Growth of alfalfa in sludge-amended soils and inoculated with rhizobia produced in sludge

The efficiency of rhizobial inoculants produced in wastewater sludge used as a growth medium and as a carrier was compared with that of inoculants produced in yeast mannitol broth (YMB) medium and by using peat as a carrier. Alfalfa (Medicago sativa L.) plants were inoculated with solid and liquid Sinorhizobium meliloti inoculants and grown in pots containing two soil types (Kamouraska clay soil and Saint-André sandy soil). The effect of various levels of sludge amendment (60 and 120 kg N/ha) and nitrogen fertilizer (60 kg N/ ha) was also studied. The sludge-based inoculants showed the same symbiotic efficiency (nodulation and plant yield) as YMB-based inoculants. The inoculation increased the nodulation indexes from 4-6 to 8-12, and the rhizobial number from 10(3) (uninoculated soils) to 10(6)-10(7) cells/g in inoculated soils. However, the shoot dry weights and the nitrogen contents were not increased significantly by the inoculation. Applying sludge as an amendment enhanced the rhizobial number in soils from 10(3) to 10(4) cells/g and improved significantly the plant growth (shoot dry weights and nitrogen contents). This improvement increased with sludge rate and with the cut (three cuts). Compared with sludge, N fertilizer gave lower plant yields. The nodulation was not affected by sludge and N-fertilizer application. The texture and physico-chemical properties of soil were found to affect the yield and nitrogen content of the plants. In this study, macroelements and heavy metals were at acceptable levels and were not considered to be negative factors.     

Plant growth and uptake of mineral elements at an oily sludge landfarming site in Kuwait

Oily sludge landfarmed in Kuwait soil contains higher concentrations of certain elements than that of the untreated of, soil, e.g. S, Cu, Cr, Zn, Pb, Ni, Mo and V. The growth and elemental content of three different plants grown on a sandy soil previously treated with different concentrations of oily sludge were studied. Tested plants differed in their response to landfarmed oily sludge; ryegrass was the least affected followed by oats, then barley. Uptake of elements differed both qualitatively and quantitatively between test plants. In barley, Zn increased in plants cultivated in soil treated with oily sludge, whereas other metal concentrations were reduced or not affected, namely, Cu, Pb, Ni, V. The uptake of P was greater in plants grown on treated soil compared with those on untreated soil, whereas Na, Ca, K, were either reduced or unaffected. In oats, Zn, Ni, Cu, Pb, V, were not significantly changed. Uptakes of K, Ca, P, and Na in plants from treated soil were higher than that of the control. In ryegrass, heavy metal concentrations were either reduced or remained the same as that of the control. In all cases, concentrations of essential heavy metals and other true elements under investigation were still lower than the levels considered to be sufficient for micronutrients. Thus, the oily sludge was a source of certain micro-nutrients which were deficient in the sandy soil. Further, it appears that uptake and distribution of elements in plant tissues were both highly variable according to the plant, species, and the soil characteristics.     

Nitrogen fertilization effects on stream water cadmium concentration

High transition metal concentrations were previously unexpectedly observed in soil water extracted by suction lysimeters following forest N fertilization. This observation called for additional measurements to investigate if the finding is a general phenomenon and, if so, whether stream water concentrations of transition metals could increase as a result of N fertilization. The measured levels of Cd in the preliminary findings were well above health limits for drinking water. Hence, the problem could be of major concern. Here we report on soil water and stream water concentrations at two partly fertilized watersheds. All sites were situated in the central part of Sweden. The N application (150 kg N ha(-1) in the form of calcium ammonium nitrate) resulted in increased concentrations of nitrate, and a pulse of acidity through the soil profile, which increased the solubility of transition metals (mainly Cd and Zn) and Al. Stream water concentrations of transition metals, on the other hand, were not affected during the studied period by the increased solubility of transition metals in the soil. The data imply that the solubilized transition metals probably insolubilize further down the soil profile, and that there is no risk from forest N fertilization (at normal soil pH levels) of transition metal levels increasing in nearby surface waters. To our knowledge, this is the first time this side effect of N fertilization has been considered.     

Land application of phosphorus-laden sludge: a feasibility analysis

An investigation was conducted to examine aerobic digestion of the phosphorus-laden sludge produced at the Regina Wastewater Treatment Plant and feasibility of land use of this sludge combined with the dewatered anaerobically digested primary sludge from this plant. Experimental studies showed that aerobic digestion can be employed for the stabilization of the chemical sludge. Results of the feasibility analysis showed that mixing the two digested sludges met the heavy metal criteria set by various guidelines for agricultural use, presented the advantage of an increased concentration of nutrients and a decreased concentration of heavy metals, and a longer useful life of the agricultural site compared to using dewatered anaerobically digested primary sludge alone. Land application of the mixed digested sludges would be a more appropriate method of sludge disposal compared to the present practice of landfilling the dewatered sludge and lagooning the chemical sludge.     

Cadmium: Simulation of environmental control strategies to reduce exposure

The effects of selected environmental control strategies on human dietary and respiratory exposure to environmental cadmium (Cd) have been simulated. For each control strategy, mean Cd dietary and respiratory exposures are presented for a twenty-year simulation period.Human exposures related to cadmium are associated with both process waste disposal and product disposal. Dietary exposure is by far the dominant mechanism for Cd intake. Dietary exposure related to aqueous discharges is primarily a result of municipal sludge landspreading, whereas that associated with emissions to the atmosphere derives mainly from the deposition on cropland of airborne particulates from product incineration. Only relatively small dietary exposure reductions are possible through restrictions on anysingle Cd use. Combinations of waste management and environmental control measures promise greater reductions in dietary and respiratory exposure than those achievable through use restrictions.Work supported by Office of Toxic Substances U.S. Environmental Protection Agency.     

Soil acidity and manganese in declining and nondeclining sugar maple stands in Pennsylvania

For decades, the hardwood forests of northern Pennsylvania have been subjected to chronic atmospheric loading of acidifying agents. On marginal, high-elevation, unglaciated sites, sugar maples (Acer saccharum Marsh.) have experienced severe decline symptoms and mortality. Accelerated soil acidification, base cation leaching, and increased availability of toxic metals have been suggested as predisposing factors contributing to this decline. Manganese, an essential micronutrient, is also a potentially phytotoxic metal that may be a factor associated with poor sugar maple health on soils vulnerable to acidification from anthropogenic sources. We measured Mn levels in four compartments of the soil-tree system (soil, foliage, xylem wood, and sap) on three sugar maple stands in northern Pennsylvania. Two stands were classified as declining and one was in good health. Negative correlations were found between soil pH and Mn levels in the soil, foliage, sap, and xylem wood. Levels of Mn in these pools were consistently higher on declining sites, which correspondingly exhibited lower levels of Ca and Mg. Species differences between red maple (Acer rubrum L.) and sugar maple at the two declining sites suggested different tolerances to excessive Mn. Molar ratios of Mg/Mn and Ca/Mn were different among sites and showed potential as indicators of soil acidification. Significant correlations among soil, sap, foliage, and xylem wood Mn were also noted. These results show clear Mn differences among sites and, when viewed with recent Mn toxicity experiments and other observational studies, suggest that excessive Mn may play a role in the observed decline and mortality of sugar maple.     

Distribution and movement of sludge-derived trace metals in selected Nigerian soils

Use of metal-rich sewage sludge as soil fertilizer may result in trace- metal contamination of soils. This study was conducted to evaluate the effects of long-term sludge application on trace-metal (Zn, Cu, Pb, and Ni) distribution and potential bioavailability in Nigerian soils under a tropical wet-dry climate. Total metal analyses, sequential chemical fractionation, and DTPA extractions were carried out on samples of control and sludge-amended pedons in Nigeria (a Rhodic Kandiustult and two Rhodic Kandiustalfs from Nigeria, respectively). The sewage sludge applied to the soils contained higher levels of Zn and Cu than Pb and Ni. The control pedon contained low levels of all four metals. Soil enrichment factors (EF) were calculated for each metal in the sludge-amended pedons. Compared with the control soil, the sludge-amended pedons showed elevated levels of Zn and Cu, reflecting the trace-metal composition of the sewage sludge. Zinc and Cu in the sludge-amended soils were strongly enriched at all depths in the profile, indicating that they had moved below the zone of sludge application. The sequential extraction and DTPA analyses indicated that the sludge-amended soils contained more readily extractable and bioavailable metal ions than the unamended soil.     

A value proposition: Resource recovery from faecal sludge—Can it be the driver for improved sanitation?

There is currently a lack of access to affordable sanitation in urban areas of Sub-Saharan Africa. This study evaluated the potential for resource recovery from innovative faecal sludge treatment processes to generate a profit that could help sustain the sanitation service chain. A total of 242 interviews were conducted in Accra, Ghana; Dakar, Senegal; and Kampala, Uganda to compare markets in different cultural and regional contexts. Products identified to have potential market value include dry sludge as a fuel for combustion, biogas from anaerobic digestion, protein derived from sludge processing as animal feed, sludge as a component in building materials, and sludge as a soil conditioner. The market demand and potential revenue varied from city to city based on factors such as sludge characteristics, existing markets, local and regional industrial sectors, subsidies, and locally available materials. Use as a soil conditioner, which has been the most common end use of treated sludge, was not as profitable as other end uses. These findings should help policy and decision makers of sanitation service provision to design financially viable management systems based on resource recovery options.