国内外石油公司甲烷排放差异性分析及启示

甲烷排放管控是国际石油公司推动低碳能源转型的一项重要举措,也是达成净零碳排放愿景的一个重要手段。研究发现,国内外石油公司的油气生产活动水平、甲烷排放控制水平、甲烷排放核算方法等3个方面均存在较大差异性。我国油井单井产量低,地面工程量大、工艺复杂,流程工艺中甲烷排放突出,油气系统甲烷排放水平较高,油气生产甲烷排放控制水平与国外石油公司相比尚有较大差距,与国外甲烷排放核算方法也存在较大差异性。着眼于甲烷排放管控,我国石油公司应充分衡量甲烷排放现状、生产活动水平、甲烷排放控制措施经济性和适用性等多重因素,严格控制潜在甲烷排放节点,并进一步做好甲烷排放检测、监测和数据统计工作,持续完善甲烷排放报告和核查体系。     

Methane fluxes from artificial wetlands: A global appraisal

Methane emissions make an important contribution to the enhanced greenhouse effect, emissions from rice growing being one of its major anthropogenic sources. The estimation of global fluxes of methane from rice and from coarse fiber production depends on extrapolating observed data across countries and agroclimatic zones: the estimates are therefore imprecise. We present a revised estimate of global emissions of 96 Tg CH₄/yr, given 1991 rice areas, and 1991 production data for those tropical coarse fibers that also produce methane under anaerobic conditions. This is higher than many previous studies, which systematically underestimated the fluxes from tropical countries. As the world's population increases, the demand for rice will rise. This demand can only be satisfied through greater rice production, either by bringing new areas into rice growing or by using the present area more intensively. Strategies based on improved water management and fertilizer use will allow increased rice production and yields and reduce the methane flux per unit or rice production.     

美国油气行业国家温室气体清单和报送体系

甲烷是由人类活动造成的仅次于二氧化碳的第二大温室气体,大幅度减少甲烷排放有助于降低近期温升,是实现巴黎协定目标的必要手段,也是中国实现“碳中和”目标的重要抓手。相比其他排放源,油气行业的甲烷减排最快、最有经济性。而有效的减排政策和监管必须建立在完整、准确的甲烷排放清单基础上。文章以甲烷为重点,概述了美国国家温室气体清单和油气行业的报送制度,介绍了两个报送体系的覆盖范围、要求等相关差异,说明了设施界定、排放因子和活动水平来源、监测方法以及有待改进之处,并针对中国油气行业甲烷排放数据的质量改善提出了建议。     

美国和中国油气系统甲烷排放状况

文章通过调研、分析美国和中国近年来油气系统中甲烷排放状况,对比分析美国与中国应用的主要甲烷计算方法,表明:美国油气系统中对甲烷排放量的计算方法可采用1996IPCC指南中提供的第一层次(Tier1)和第二层次(Tier2)法,计算结果相对比较准确,甲烷的排放呈逐年增加趋势;中国油气系统中甲烷排放量的计算方法目前只限于1996IPCC指南中提供的Tier1法,中国甲烷排放量相对于美国等发达国家较少,但整体呈增长趋势。     

Biomethanation of plant materials and agricultural residues using dung samples as wild population of microbes and also with isolated methanogens

Recycling of plant materials and agricultural residues for biomethanation was attempted in vials. The methanogenic activities of certain sewage samples have also been tested. Both sterilized and non-sterilized biomasses were used. Biomethanation was carried out with dung samples (cow, goat, buffalo, piggery wastes and poultry wash) as wild populations of microbes and in combination with other microbial isolates (isolated in the laboratory).Biomethanation had been observed to be good in most cases and particularly with the sterilized biomass. Mixed inoculum (dung samples and poultry wash) was found to be best for biomethanation. Of the microbe isolates, isolates from buffalo, pig and paper mill wastes appear to be most effective. Pretreated sawdust and rice straw were found to be good subtrates for biomethanation. Of the different plant biomass used Spirogyra (algae), Ipomea and water hyacinth were most effective whereas Jatropa gossypifolia and Parthenium sp. were the least effective. Biomethanation of Spirogyra was carried out both in anoxic and oxic conditions. Though methane production decreased enormously under oxic conditions, definite methane production continued indicating that the biomethanation process is not exclusively anoxic. Similarly, biomethanation of sewage samples from different sewage treatment plants were carried out with and without isolated methanogens and methane production was found to be moderate.     

Assessing alternatives for mitigating net greenhouse gas emissions and increasing yields from rice production in China over the next twenty years

Assessments of the efficacy of mitigation of greenhouse gas (GHG) emissions from paddy rice systems have typically been analyzed based on field studies. Extrapolation of the mitigation potential of alternative management practices from field studies to a national scale may be enhanced by spatially explicit process models, like the DeNitrification and DeComposition (DNDC) model. Our objective was to analyze the impacts of mitigation alternatives, management of water, fertilizer, and rice straw, on net GHG emissions (carbon dioxide, methane, and nitrous oxide fluxes), yields, and water use. After constructing a GIS database of soil, climate, rice cropping area and systems, and management practices, we ran DNDC with 21-yr alternative management schemes for each of the approximately 2500 counties in China. Results indicate that, despite large-scale adoption of midseason drainage, there is still large potential for additional methane reductions from Chinese rice paddies of 20 to 60% over 2000-2020. However, changes in management for reducing CH4 emissions simultaneously affect soil carbon dynamics as well as N2O emissions and can thereby reorder the ranking of technical mitigation effectiveness. The order of net GHG emissions reduction effectiveness found here is upland rice > shallow flooding > ammonium sulfate > midseason drainage > off-season straw > slow-release fertilizer > continuous flooding. Most of the management alternatives produced yields comparable to the baseline; however, continuous flooding and upland rice significantly reduced yields. Water management strategies appear to be the most technically promising GHG mitigation alternatives, with shallow flooding providing additional benefits of both water conservation and increased yields.     

Assessing energy efficiencies and greenhouse gas emissions under bioethanol-oriented paddy rice production in northern Japan

To establish energetically and environmentally viable paddy rice-based bioethanol production systems in northern Japan, it is important to implement appropriately selected agronomic practice options during the rice cultivation step. In this context, effects of rice variety (conventional vs. high-yielding) and rice straw management (return to vs. removal from the paddy field) on energy inputs from fuels and consumption of materials, greenhouse gas emissions (fuel and material consumption-derived CO(2) emissions as well as paddy soil CH(4) and N(2)O emissions) and ethanol yields were assessed. The estimated ethanol yield from the high-yielding rice variety, "Kita-aoba" was 2.94 kL ha(-1), a 32% increase from the conventional rice variety, "Kirara 397". Under conventional rice production in northern Japan (conventional rice variety and straw returned to the paddy), raising seedlings, mechanical field operations, transportation of harvested unhulled brown rice and consumption of materials (seeds, fertilizers, biocides and agricultural machinery) amounted to 28.5 GJ ha(-1) in energy inputs. The total energy input was increased by 14% by using the high-yielding variety and straw removal, owing to increased requirements for fuels in harvesting and transporting harvested rice as well as in collecting, loading and transporting rice straw. In terms of energy efficiency, the variation among rice variety and straw management scenarios regarding rice varieties and rice straw management was small (28.5-32.6 GJ ha(-1) or 10.1-14.0 MJ L(-1)). Meanwhile, CO(2)-equivalent greenhouse gas emissions varied considerably from scenario to scenario, as straw management had significant impacts on CH(4) emissions from paddy soils. When rice straw was incorporated into the soil, total CO(2)-equivalent greenhouse gas emissions for "Kirara 397" and "Kita-aoba" were 25.5 and 28.2 Mg CO(2) ha(-1), respectively; however, these emissions were reduced notably for the two varieties when rice straw was removed from the paddy fields in an effort to mitigate CH(4) emissions. Thus, rice straw removal avers itself a key practice with respect to lessening the impacts of greenhouse gas emissions in paddy rice-based ethanol production systems in northern Japan. More crucially, the rice straw removed is available for ethanol production and generation of heat energy with a biomass boiler, all elements required for biomass-to-ethanol transformation steps including saccharification, fermentation and distillation. This indicates opportunities for further improvement in energy efficiency and reductions in greenhouse gas emissions under whole rice plant-based bioethanol production systems.     

Transport and reaction processes affecting the attenuation of landfill gas in cover soils

Methane and trace organic gases produced in landfill waste are partly oxidized in the top 40 cm of landfill cover soils under aerobic conditions. The balance between the oxidation of landfill gases and the ingress of atmospheric oxygen into the soil cover determines the attenuation of emissions of methane, chlorofluorocarbons, and hydrochlorofluorocarbons to the atmosphere. This study was conducted to investigate the effect of oxidation reactions on the overall gas transport regime and to evaluate the contributions of various gas transport processes on methane attenuation in landfill cover soils. For this purpose, a reactive transport model that includes advection and the Dusty Gas Model for simulation of multicomponent gas diffusion was used. The simulations are constrained by data from a series of counter-gradient laboratory experiments. Diffusion typically accounts for over 99% of methane emission to the atmosphere. Oxygen supply into the soil column is driven exclusively by diffusion, whereas advection outward offsets part of the diffusive contribution. In the reaction zone, methane consumption reduces the pressure gradient, further decreasing the significance of advection near the top of the column. Simulations suggest that production of water or accumulation of exopolymeric substances due to microbially mediated methane oxidation can significantly reduce diffusive fluxes. Assuming a constant rate of methane production within a landfill, reduction of the diffusive transport properties, primarily due to exopolymeric substance production, may result in reduced methane attenuation due to limited O(2) -ingress.     

Anaerobic Digestion of Agricultural Solid Residues

Abstract

Agricultural residues can be converted to methane-rich gas mixture. Anaerobic biomethane production is an effective process for conversion of a broad variety of agricultural residues to methane to substitute natural gas and medium calorific value gases. Methane generating bacteria (methanogens) and other microbes that help digest dying plants in anaerobic conditions. Agricultural solid residues (ASR) represent a potential energy resource if they can be properly and biologically converted to methane.     

Methane oxidation in an intensively cropped tropical rice field soil under long-term application of organic and mineral fertilizers

Methane (CH4) oxidation is the only known biological sink process for mitigating atmospheric and terrestrial emissions of CH4, a major greenhouse gas. Methane oxidation in an alluvial soil planted to rice (Oryza sativa L.) under long-term application of organic (compost with a C/N ratio of 21.71), and mineral fertilizers was measured in a field-cum-laboratory incubation study. Oxidation rates were quantified in terms of decrease in the concentration of CH4 in the headspace of incubation vessels and expressed as half-life (t(1)2) values. Methane oxidation rates significantly differed among the treatments and growth stages of the rice crop. Methane oxidation rates were high at the maximum tillering and maturity stages, whereas they were low at grain-filling stage. Methane oxidation was low (t(1)2) = 15.76 d) when provided with low concentration of CH4. On the contrary, high concentration of CH4 resulted in faster oxidation (t(1)2) = 6.67 d), suggesting the predominance of "low affinity oxidation" in rice fields. Methane oxidation was stimulated following the application of mineral fertilizers or compost implicating nutrient limitation as one of the factors affecting the process. Combined application of compost and mineral fertilizer, however, inhibited CH4 oxidation probably due to N immobilization by the added compost. The positive effect of mineral fertilizer on CH4 oxidation rate was evident only at high CH4 concentration (t(1)2 = 4.80 d), while at low CH4 concentration their was considerable suppression (t(1) = 17.60 d). Further research may reveal that long-term application of fertilizers, organic or inorganic, may not inhibit CH4 oxidation.     

Application of strategies for sanitation management in wastewater treatment plants in order to control/reduce greenhouse gas emissions

Greenhouse gases (GHG), basically methane (CH(4)), carbon dioxide (CO(2)) and nitrous oxide (N(2)O), occur at atmospheric concentrations of ppbv to ppmv under natural conditions. GHG have long mean lifetimes and are an important factor for the mean temperature of the Earth. However, increasing anthropogenic emissions could produce a scenario of progressive and cumulative effects over time, causing a potential "global climate change". Biological degradation of the organic matter present in wastewater is considered one of the anthropogenic sources of GHG. In this study, GHG emissions for the period 1990-2027 were estimated considering the sanitation process and the official domestic wastewater treatment startup schedule approved for the Metropolitan Region (MR) of Santiago, Chile. The methodology considers selected models proposed by the Intergovernmental Panel on Climate Change (IPCC) and some others published by different authors; these were modified according to national conditions and different sanitation and temporal scenarios. For the end of the modeled period (2027), results show emissions of about 65Tg CO(2) equiv./year (as global warming potential), which represent around 50% of national emissions. These values could be reduced if certain sanitation management strategies were introduced in the environmental management by the sanitation company in charge of wastewater treatment.     

Methane emissions of rice increased by elevated carbon dioxide and temperature

Methane (CH4) effluxes by paddy-culture rice (Oryza sativa L.) contribute about 16% of the total anthropogenic emissions. Since radiative forcing of CH4 at current atmospheric concentrations is 21 times greater on a per mole basis than that of carbon dioxide (CO2), it is imperative that the impact of global change on rice CH4 emissions be evaluated. Rice (cv. IR72) was planted in sunlit, closed-circulation, controlled-environment chambers in which CH4 efflux densities were measured daily. The CO2 concentration was maintained at either 330 or 660 micromol mol(-1). Air temperatures were controlled to daily maxima and minima of 32/23, 35/26, and 38/29 degrees C at each CO2 treatment. Emissions of CH4 each day were determined during a 4-h period after venting and resealing the chambers at 0800 h. Diurnal CH4 effluxes on 77, 98, and 119 d after planting (DAP) were obtained similarly at 4-h intervals. Emissions over four-plant hills and over flooded bare soil were measured at 53, 63, and 100 DAP. Emissions were negligible before 40 DAP. Thereafter, emissions were observed first in high-CO2, high-temperature treatments and reached a sustained maximum efflux density of about 7 mg m(-2) h(-1) (0.17 g m(-2) d(-1)) near the end of the growing season. Total seasonal CH4 emission was fourfold greater for high-CO2, high-temperature treatments than for the low-CO2, low-temperature treatment, probably due to more root sloughing or exudates, since about sixfold more acetate was found in the soil at 71 DAP. Both rising CO2 and increasing temperatures could lead to a positive feedback on global warming by increasing the emissions of CH4 from rice.     

Application technique and slurry co-fermentation effects on ammonia,nitrous oxide,and methane emissions after spreading: II. Greenhouse gas emissions

The aim of this study was to investigate the effect of different application techniques on greenhouse gas emission from co-fermented slurry. Ammonia (NH3), nitrous oxide (N2O), and methane (CH4) emissions were measured in two field experiments with four different application techniques on arable and grassland sites. To gather information about fermentation effects, unfermented slurry was also tested, but with trail hose application only. Co-fermented slurry was applied in April at a rate of 30 m3 ha(-1). Measurements were made every 4 h on the first day after application and were continued for 6 wk with gradually decreasing sampling frequency. Methane emissions were <150 g C ha(-1) from co-fermentation products and seemed to result from dissolved CH4. Only in the grassland experiment were emissions from unfermented slurry significantly higher, with wetter weather conditions probably promoting CH4 production. Nitrous oxide emission was significantly increased by injection on arable and grassland sites two- and threefold, respectively. Ammonia emissions were smallest after injection or trail shoe application and are discussed in the preceding paper. We evaluated the climatic relevance of the measured gas emissions from the different application techniques based on the comparison of CO2 equivalents. It was evident that NH3 emission reduction, which can be achieved by injection, is at least compensated by increased N2O emissions. Our results indicate that on arable land, trail hose application with immediate shallow incorporation, and on grassland, trail shoe application, bear the smallest risks of high greenhouse gas emissions when fertilizing with co-fermented slurry.     

Emissions of ammonia, methane, carbon dioxide, and nitrous oxide from dairy cattle housing and manure management systems

Concentrated animal feeding operations emit trace gases such as ammonia (NH?), methane (CH?), carbon dioxide (CO?), and nitrous oxide (N?O). The implementation of air quality regulations in livestock-producing states increases the need for accurate on-farm determination of emission rates. The objective of this study was to determine the emission rates of NH?, CH?, CO?, and N?O from three source areas (open lots, wastewater pond, compost) on a commercial dairy located in southern Idaho. Gas concentrations and wind statistics were measured each month and used with an inverse dispersion model to calculate emission rates. Average emissions per cow per day from the open lots were 0.13 kg NH?, 0.49 kg CH?, 28.1 kg CO?, and 0.01 kg N?O. Average emissions from the wastewater pond (g m(-2) d(-1)) were 2.0 g NH?, 103 g CH?, 637 g CO?, and 0.49 g N?O. Average emissions from the compost facility (g m(-2) d(-1)) were 1.6 g NH?, 13.5 g CH?, 516 g CO?, and 0.90 g N?O. The combined emissions of NH?, CH?, CO?, and N?O from the lots, wastewater pond and compost averaged 0.15, 1.4, 30.0, and 0.02 kg cow(-1) d(-1), respectively. The open lot areas generated the greatest emissions of NH?, CO?, and N?O, contributing 78, 80, and 57%, respectively, to total farm emissions. Methane emissions were greatest from the lots in the spring (74% of total), after which the wastewater pond became the largest source of emissions (55% of total) for the remainder of the year. Data from this study can be used to develop trace gas emissions factors from open-lot dairies in southern Idaho and potentially other open-lot production systems in similar climatic regions.     

Biological degradation and greenhouse gas emissions during pre-storage of liquid animal manure

Storage of manure makes a significant contribution to global methane (CH4) emissions. Anaerobic digestion of pig and cattle manure in biogas reactors before outside storage might reduce the potential for CH4 emissions. However, manure pre-stored at 15 to 20 degrees C in buildings before anaerobic digestion may be a significant source of CH4 and could reduce the potential CH4 production in the biogas reactor. Degradation of energy-rich organic components in slurry and emissions of CH4 and carbon dioxide (CO2) from aerobic and anaerobic degradation processes during pre-storage were examined in the laboratory. Newly mixed slurry was added to vessels and stored at 15 and 20 degrees C for 100 to 220 d. During storage, CH4 and CO2 emissions were measured with a dynamic chamber technique. The ratio of decomposition in the subsurface to that at the surface indicated that the aerobic surface processes contributed significantly to CO2 emission. The measured CH4 emission was used to calculate the methane conversion factor (MCF) in relation to storage time and temperature, and the total carbon-C emission was used to calculate the decrease in potential CH4 production by anaerobic digestion following pre-storage. The results show substantial methane and carbon dioxide production from animal manure in an open fed-batch system kept at 15 to 20 degrees C, even for short storage times, but the influence of temperature was not significant at storage times of <30 d. During long-term storage (90 d), a strong influence of temperature on the MCF value, especially for pig manure, was observed.     

Controlling greenhouse gas emissions through landfill in situ aeration

Landfills and old waste deposits are some of the major anthropogenic sources of methane (CH₄) emissions worldwide. Despite the fact that during the last 15 years the amount of carbon dioxide equivalent (CO₂-eq.) emitted from German landfills was reduced by approximately two thirds, estimates show that currently more than 10 Mtonnes are still being emitted annually. As a case study, the in situ aerated former Kuhstedt Landfill (District of Rotenburg (Wümme), Germany) was assessed regarding the possibility of reducing the emitted amounts of greenhouse gases (GHG; here methane). The assessment was based on both a model calculation of the landfill gas emissions that should occur under anaerobic conditions (reference scenario) as well as using monitoring data plus extrapolations to determine the actual emissions from the landfill. It was demonstrated that more than 72% of the total GHG emissions occurring under anaerobic conditions could be avoided by altering the ambient aerobic/oxidizing conditions. By means of subsequent thermal treatment (regenerative thermal oxidation, RTO) of the extracted off-gases during the aeration process, the amount of CO₂-eq. savings, as calculated from the amount of emitted methane taking into account secondary emissions for energy production, could be further increased to 96%.     

Effect of co-culturing of methanogens with sulphur-reducing bacteria on biomethanation

Biomethanation as a result of co-culturing methanogenic bacteria with sulphate-reducing bacteria was studied under anoxic conditions. Toxic sulphur compounds are known not to inhibit methanogenesis. Hence varying experimental conditions can lead to the optimum conditions for biomethanation. Under controlled experimental conditions, the interacting behaviour of both isolated methanogens and sulphate reducers show interesting features, viz. allelopathy.     

Efficiency of energy delivery systems: III. Assessing potential energy savings of a comprehensive insulation program

It is possible to develop large quantities of energy by installing a comprehensive regional insulation program. This paper develops a computer model for examining the quantity of energy that may be saved in a region if such a program is undertaken. The program requires data on: number of houses, type of houses and present degree of insulation. The results indicate that in the region under consideration it is possible to make available more energy, far cheaper, through insulation than by the alternative of constructing a large power plant.     

Natural and Anthropogenic Methane Emission from Coastal Wetlands of South India

For the first time, the methane emissions from diverse coastal wetlands of South India have been measured. Annual emission rates varied widely, ranging from 3.10 mg/m²/hr (Bay of Bengal) to 21.56 mg/m²/hr (Adyar River), based on nature of the perturbance to each of the ecosystems studied. Distinct seasonality in methane emission was noticed in an unpolluted ecosystem (mangrove: 7.38 mg/m²/hr) and over a twofold increase was evident in the ecosystem that was disturbed by human activities (21.56 mg/m²/hr). The wide ranges in estimate suggest that methanogenesis occurs by both natural and anthropogenic activities in these coastal wetlands. Several physical and chemical factors such as salinity, sulfate, oxygen, and organic matter content influenced methanogenesis to a large degree in each of these ecosystems in addition to individual responses to human-induced stress. For example, there was a clear negative correlation between oxygen availability (0.99), sulfate (0.98), and salinity (0.98) with CH₄ emission in the Adyar river ecosystem. Although similar results were obtained for the other wetland ecosystems, CH₄ emission was largely influenced by tidal fluctuations, resulting in a concomitant increase in methanogenesis with high sulfate concentrations. This study demonstrates that coastal wetlands are potentially significant sources of atmospheric methane and could be a greater source if anthropogenic perturbations continue at the current rate. RID=" ID=" &ast;Author to whom correspondence should be addressed.     

Radiative Forcing Due to Anthropogenic Greenhouse Gas Emissions from Finland: Methods for Estimating Forcing of a Country or an Activity

The objective of this study was to assess the radiative forcing due to Finnish anthropogenic greenhouse gas emissions in three scenarios. All the Kyoto Protocol gases, i.e., CO₂, CH₄, N₂O, and fluorinated gases, were included. The calculations showed that forcing due to Finnish emissions will increase in the case of all gases except methane by the year 2100. In 1990, radiative forcing due to Finland's emission history of all Kyoto Protocol gases was 3.2 mW/m², of which 71% was due to carbon dioxide, 17% to methane, and the rest to nitrous oxide. In 1990 the share of fluorinated gases was negligible. The share of methane in radiative forcing is decreasing, whereas the shares of carbon dioxide and of fluorinated gases are increasing and that of nitrous oxide remains nearly constant. The nonlinear features concerning additional concentrations in the atmosphere and radiative forcing due to emissions caused by a single country or activity are also considered. Radiative forcing due to Finnish emissions was assessed with two different approaches, the marginal forcing approach and the averaged forcing approach. The impact of the so-called background scenario, i.e., the scenario for concentration caused by global emissions, was also estimated. The difference between different forcing models at its highest was 40%, and the averaged forcing approach appeared to be the more recommendable. The effect of background concentrations in the studied cases was up to 11%. Hence, the choice of forcing model and background scenario should be given particular attention.