Evaluation of the levels and sources of trace elements in urban particulate matter

An assessment of air quality of Belgrade, Serbia, was performed by determining the trace element content in airborne daily PM₁₀ and PM_2.5 samples collected from a central urban area. The ambient concentrations of Zn were the highest in PM_2.5 (1,998.0 ng m⁻³). Multivariate receptor modelling (principal component analysis and cluster analysis) has been applied to determine the contribution of different sources of specific metallic components in airborne particles. The obtained results showed that vehicle traffic and fossil fuel combustion in stationary objects were the main sources of trace metals in Belgrade urban aerosols.     

Photocatalytic degradation of chlorophenols using Ru(bpy) 3 2+ /S2O 8 2−

Advanced oxidation processes, such as photocatalysed oxidation, provide an important route for degradation of wastes. In this study, the lowest excited state (³MLCT) of Ru(bpy)₃²⁺ is used to break down chlorophenol pollutant molecules to harmless products. This has the advantage of using visible light and a short-lived catalytically active species. Photolysis of deaerated aqueous solutions of a variety of mono- and poly-substituted chlorophenols has been followed in the presence of Ru(bpy)₃²⁺/S₂O₈²⁻ with near visible light (λ > 350 nm) by UV/visible absorption spectroscopy, luminescence, potentiometry, NMR and HPLC techniques. Upon irradiation, a decrease is observed in the chlorophenol concentration, accompanied by the formation of Cl⁻, H⁺ and SO₄²⁻ ions as the main inorganic products. Benzoquinone, phenol, dihydroxybenzenes and chlorinated compounds were the dominant organic products. As the ruthenium(II) complex is regenerated in the reaction, the scheme corresponds to an overall catalytic process. The kinetics of the rapid chlorophenol photodechlorination has been studied, and are described quite well by pseudo-first order behaviour. Further studies on this were made by following Cl⁻ release with respect to the initial Ru(bpy)₃²⁺ and S₂O₈²⁻ concentrations. A comparison is presented of the photodechlorination reactivity of the mono and polychlorophenols studied at acidic and alkaline pH.     

Effects of environmental hypercapnia on hemato-immunological parameters,carbonic anhydrase,and Na+, K+-ATPase enzyme activities in rainbow trout (Oncorhynchus mykiss) tissues

In this study, the effects of environmental hypercapnia on hemato-immunological parameters and the activities of respiratory enzymes such as carbonic anhydrase (CA) and Na⁺, K⁺-ATPase were investigated in rainbow trout (Oncorhynchus mykiss) tissues (gill, liver and kidney). Batches of 12 fish were exposed to 4.5 mg L^?1 (control) and 14 mg L^?1 CO₂. No mortalities occurred during the 14 days of the experimental period. Red blood cell (RBC), hemoglobin (Hb), and hematocrit (Ht) levels, and innate immune parameters such as nitro blue tetrazolium (NBT), lysozyme, and myeloperoxidase activities, and the melano-macrophage frequency were negatively affected by elevated CO₂ levels. Patterns of change in CA activity differed among the gill, liver, and kidney. Compared with the activities of CA in the control group, the CA enzyme was significantly stimulated at day 7 in the gill tissue, whereas it was stimulated at day 14 of the experiment in the liver tissue of fish exposed to 14 mg L^?1 CO₂ (P < 0.05). In contrast to the pattern of CA enzyme activities, the Na⁺, K⁺-ATPase enzymes were stimulated significantly in the liver after day 7 but inhibited in the kidney and gill (P < 0.05). These results suggest that a subchronic exposure to hypercapnia of rainbow trout tissues may lead to adaptive changes in the respiratory enzymes and negatively affects hemato-immunological parameters.     

Conversion of plant materials into hydroxymethylfurfural using ionic liquids

The use of fossil fuels now induces two major issues. First, fossil fuel burning is increasing atmospheric carbon dioxide (CO₂) concentrations and, in turn, global warming. Second, fossil fuel resources are limited and will thus decrease in the long run. As a potential solution, there is a need for ecological manufacturing processes that convert raw plant materials into chemical products. For instance, raw plants can be directly converted into hydroxymethylfurfural, which is a versatile intermediate for the synthesis of valuable biofuels such as dimethylfuran and 5-ethoxymethyl-2-furfural. This technology has two benefits for chemical sustainability. First, the pretreatment step is eliminated, thus contributing to reduction of CO₂ emissions. Second, plants are sustainable resources versus fossil fuels, which are limited. Here, we review current sustainable technologies for the production of biobased products and hydroxymethylfurfural from plants, using in particular ionic liquids. Plant sources include poplar, switchgrass, miscanthus, weed plants, and agave species.     

Recent advances in the photocatalytic reduction of carbon dioxide

Fossil fuels are currently the major energy source and are rapidly consumed to supply the increasing energy demands of mankind. CO₂, a product of fossil fuel combustion, leads to climate change and will have a serious impact on our environment. There is an increasing need to mitigate CO₂ emissions using carbon–neutral energy sources. Therefore, research activities are devoted to CO₂ capture, storage and utilization. For instance, photocatalytic reduction of CO₂ into hydrocarbon fuels is a promising avenue to recycle carbon dioxide. Here we review the present status of the emission and utilization of CO₂. Then we review the photocatalytic conversion of CO₂ by TiO₂, modified TiO₂ and non-titanium metal oxides. Finally, the challenges and prospects for further development of CO₂ photocatalytic reduction are presented.     

Estimating California ecosystem carbon change using process model and land cover disturbance data: 1951-2000

Land use change, natural disturbance, and climate change directly alter ecosystem productivity and carbon stock level. The estimation of ecosystem carbon dynamics depends on the quality of land cover change data and the effectiveness of the ecosystem models that represent the vegetation growth processes and disturbance effects. We used the Integrated Biosphere Simulator (IBIS) and a set of 30- to 60-m resolution fire and land cover change data to examine the carbon changes of California's forests, shrublands, and grasslands. Simulation results indicate that during 1951-2000, the net primary productivity (NPP) increased by 7%, from 72.2 to 77.1 Tg C yr⁻¹ (1 teragram = 10¹² g), mainly due to CO₂ fertilization, since the climate hardly changed during this period. Similarly, heterotrophic respiration increased by 5%, from 69.4 to 73.1 Tg C yr⁻¹, mainly due to increased forest soil carbon and temperature. Net ecosystem production (NEP) was highly variable in the 50-year period but on average equalled 3.0 Tg C yr⁻¹ (total of 149 Tg C). As with NEP, the net biome production (NBP) was also highly variable but averaged −0.55 Tg C yr⁻¹ (total of -27.3 Tg C) because NBP in the 1980s was very low (-5.34 Tg C yr⁻¹). During the study period, a total of 126 Tg carbon were removed by logging and land use change, and 50 Tg carbon were directly removed by wildland fires. For carbon pools, the estimated total living upper canopy (tree) biomass decreased from 928 to 834 Tg C, and the understory (including shrub and grass) biomass increased from 59 to 63 Tg C. Soil carbon and dead biomass carbon increased from 1136 to 1197 Tg C.Our analyses suggest that both natural and human processes have significant influence on the carbon change in California. During 1951-2000, climate interannual variability was the key driving force for the large interannual changes of ecosystem carbon source and sink at the state level, while logging and fire were the dominant driving forces for carbon balances in several specific ecoregions. From a long-term perspective, CO₂ fertilization plays a key role in maintaining higher NPP. However, our study shows that the increase in C sequestration by CO₂ fertilization is largely offset by logging/land use change and wildland fires.     

Carbon- and oxygen-isotope composition of the cuttlebone of Sepia officinalis: a tool for predicting ecological information?

Analysis of the isotope composition of calcareous structures of marine organisms has proved useful in providing biological data. The present study constitutes the first detailed work undertaken on the isotope composition of coleoid cephalopods. We analysed the carbon- and oxygen-isotope composition [δ¹³C (CO²⁻ ₃) and δ¹⁸O (CO²⁻ ₃), respectively] of the cuttlebone aragonite of wild and cultivated specimens of Sepia officinalis Linnaeus, 1758. δ¹³C (CO²⁻ ₃) ranged from −2.94 to 1.00‰, δ¹⁸O (CO²⁻ ₃) from −0.18 to 2.08‰. The carbon-isotope composition is not in equilibrium with the carbon species of the ambient seawater, and does not reflect the deposition of CaCO₃ in seawater. The potential influence of environmental factors and biological processes on the carbon-isotope composition of the cuttlebone is discussed. In contrast to δ¹³C, the oxygen-isotope composition of cuttlebone aragonite appears to be in isotopic equilibrium with the ambient seawater. Seasonal changes in isotopic temperature revealed by our analyses agreed with changes in the temperature of the ambient seawater. CaCO₃ was deposited all year round. A maximum life span of 2 yr, a year-round spawning season, and variable growth rates among and within individuals have been inferred from the isotopic temperatures. Received: 14 April 1998 / Accepted: 26 November 1998     

地质封存CO_2泄漏对蚯蚓的毒性效应

二氧化碳捕集与封存技术(CO_2 capture and storage, CCS)是当前国际上公认的CO_2减排的有效措施,但封存在地下的CO_2仍然因为各种不稳定因素存在泄漏风险,对土壤环境及土壤生态系统产生威胁。选择赤子爱胜蚓为研究对象,通过模拟高浓度CO_2对蚯蚓形态与生理变化的影响,探究CCS泄漏所产生的土壤高浓度CO_2对蚯蚓的毒性效应。研究表明,土壤高浓度CO_2使蚯蚓出现生殖环带肿大、尾部串珠以及断尾等外部形态变化,皮肤和刚毛受到损伤并且表皮发生褶皱等现象;随着CO_2浓度的增加以及暴露时间的延长,蚯蚓的死亡率不断增加,土壤高浓度CO_2对蚯蚓的7 d和14 d半致死浓度分别为26.39%和17.78%;蚯蚓体腔细胞溶酶体中性红保留时间(NRRT)减少。因此,蚯蚓有望作为监测CO_2泄漏的指示生物,NRRT可作为识别CO_2泄漏的敏感指标。     

Economic and environmental performance of electricity production in Finland: A multicriteria assessment framework

Meeting environmental, economic, and societal targets in energy policy is complex and requires a multicriteria assessment framework capable of exploring trade-offs among alternative energy options. In this study, we integrated economic analysis and biophysical accounting methods to investigate the performance of electricity production in Finland at plant and national level. Economic and environmental costs of electricity generation technologies were assessed by evaluating economic features (direct monetary production cost), direct and indirect use of fossil fuels (GER cost), environmental impact (CO₂ emissions), and global environmental support (emergy cost). Three scenarios for Finland's energy future in 2025 and 2050 were also drawn and compared with the reference year 2008. Accounting for an emission permit of 25 €/t CO₂, the production costs calculated for CHP, gas, coal, and peat power plants resulted in 42, 67, 68, and 74 €/MWh, respectively. For wind and nuclear power a production cost of 63 and 35 €/MWh were calculated. The sensitivity analysis confirmed wind power's competitiveness when the price of emission permits overcomes 20 €/t CO₂. Hydro, wind, and nuclear power were characterized by a minor dependence on fossil fuels, showing a GER cost of 0.04, 0.13, and 0.26 J/J_e, and a value of direct and indirect CO₂ emissions of 0.01, 0.04, and 0.07 t CO₂/MWh. Instead, peat, coal, gas, and CHP plants showed a GER cost of 4.18, 4.00, 2.78, and 2.33 J/J_e. At national level, a major economic and environmental load was given by CHP and nuclear power while hydro power showed a minor load in spite of its large production. The scenario analysis raised technological and environmental concerns due to the massive increase of nuclear power and wood biomass exploitation. In conclusion, we addressed the need to further develop an energy policy for Finland's energy future based on a diversified energy mix oriented to the sustainable exploitation of local, renewable, and environmentally friendly energy sources.     

Embodied energy and emergy evaluation of a typical biodiesel production chain in China

Biodiesel from non-grain feedstock has been considered as one of the proper substitutes for fossil fuels associated with a series of activities emerging in China in order to meet the resource shortage and develop the energy crops. This paper presents an ecological accounting framework based on embodied energy, emergy, and CO₂ emission for the whole production chain of biodiesel made from Jatropha curcas L. (JCL) oil. The energy and materials invested in and CO₂ emission from the whole process, including cropping, transportation, extraction, and production, are accounted and calculated. Also, E_mCO₂, the ratio of real CO₂ released to the emergy-based sustainability indicator per joule biodiesel, is proposed in this paper to present a new goal function for low-carbon system optimization. Finally, the results are compared with those of the bioethanol (wheat) production in Henan Province, China, and bioethanol (corn) production in Italy in view of the indices of embodied energy, emergy and CO₂ emissions and E_mCO₂.     

Effects of boreal forest management practices on the climate impact of CO2 emissions from bioenergy

In Life Cycle Assessment (LCA), carbon dioxide (CO₂) emissions from biomass combustion are traditionally assumed climate neutral if the bioenergy system is CO₂ flux neutral, i.e. the quantity of CO₂ released approximately equals the amount of CO₂ sequestered in biomass. This convention is a plausible assumption for fast growing biomass species, but is inappropriate for slower growing biomass, like forests. In this case, the climate impact from biomass combustion can be potentially underestimated if CO₂ emissions are ignored, or overestimated, if biogenic CO₂ is considered equal to anthropogenic CO₂. The estimation of the effective climate impact should take into account how the CO₂ fluxes are distributed over time: the emission of CO₂ from bioenergy approximately occurs at a single point in time, while the absorption by the new trees is spread over several decades. Our research target is to include this dynamic time dimension in unit-based impact analysis, using a boreal forest stand as case study. The boreal forest growth is modelled with an appropriate function, and is investigated under different forestry regimes (affecting the growth rate and the year of harvest). Specific atmospheric decay functions for biomass-derived CO₂ are then elaborated for selected combinations of forest management options. The contribution to global warming is finally quantified using the GWP_bio index as climate metric. Results estimates the effects of these practices on the characterization factor used for the global warming potential of CO₂ from bioenergy, and point out the key role played by the selected time horizon.     

A decomposition analysis of CO2 emissions: evidence from Malaysia’s tourism industry

The most important question raised from issues of environmental degradation is how economic activities bring about changes that will result in pollution. In the pursuit of tourism economy, contrary to popular interest, the travel and tourism (T&T) industry may cause environmental damages through the emissions of carbon dioxide (CO₂) from energy consumption in areas such as transportation and delivery of amenities. Given this major concern, this paper attempts to investigate the linkage between tourism and CO₂ emissions in Malaysia between 1981 and 2011. In particular, this study fills the knowledge gap by taking a closer look at the impact of international tourist arrivals on CO₂ emissions by sector – electricity and heat generation and transport. Results from the bound test method suggest that there exists a long-run relationship among the variables under consideration when CO₂ emissions become the dependent variable. The original result is similarly robust to alternatives, which are CO₂ emissions from sectors of electricity and heat generation and transport. Furthermore, the vector error correction model causality analysis indicates a causal relationship between tourism and CO₂ emissions by transport and electricity and heat generation. Subsequently, several tourism-related policies are drawn from these findings.     

Radiocarbon in food: a non-problem of health effects

Recently it has come to our attention that a paper was published in this journal entitled “recycling greenhouse gas fossil fuel emissions into low radiocarbon food products to reduce human genetic damage” (Williams in Environ Chem Lett 5:197–202, 2007). In this article, it is argued that food grown in a greenhouse is healthier for people, when the greenhouse is fertilised with CO₂ prepared from fossil fuels. In this comment, however, we argue that the effect on human health is completely negligible.     

Is there really a green paradox?

In the absence of a CO₂ tax, the anticipation of a cheaper renewable backstop increases current emissions of CO₂. Since the date at which renewables are phased in is brought forward and more generally future emissions of CO₂ will decrease, the effect on global warming is unclear. Green welfare falls if the backstop is relatively expensive and full exhaustion of fossil fuels is optimal, but may increase if the backstop is sufficiently cheap relative to the cost of extracting the last drop of fossil fuels plus marginal global warming damages as then it is attractive to leave more fossil fuels unexploited and thus limit CO₂ emissions. We establish these results by analyzing depletion of non-renewable fossil fuels followed by a switch to a clean renewable backstop, paying attention to timing of the switch and the amount of fossil fuels remaining unexploited. We also discuss the potential for limit pricing when the non-renewable resource is owned by a monopolist. Finally, we show that if backstops are already used and more backstops become economically viable as the price of fossil fuels rises, a lower cost of the backstop will either postpone fossil fuel exhaustion or leave more fossil fuel in situ, thus boosting green welfare. However, if a market economy does not internalize global warming externalities and renewables have not kicked in yet, full exhaustion of fossil fuel will occur in finite time and a backstop subsidy always curbs green welfare.     

Is there really a green paradox?

In the absence of a CO₂ tax, the anticipation of a cheaper renewable backstop increases current emissions of CO₂. Since the date at which renewables are phased in is brought forward and more generally future emissions of CO₂ will decrease, the effect on global warming is unclear. Green welfare falls if the backstop is relatively expensive and full exhaustion of fossil fuels is optimal, but may increase if the backstop is sufficiently cheap relative to the cost of extracting the last drop of fossil fuels plus marginal global warming damages as then it is attractive to leave more fossil fuels unexploited and thus limit CO₂ emissions. We establish these results by analyzing depletion of non-renewable fossil fuels followed by a switch to a clean renewable backstop, paying attention to timing of the switch and the amount of fossil fuels remaining unexploited. We also discuss the potential for limit pricing when the non-renewable resource is owned by a monopolist. Finally, we show that if backstops are already used and more backstops become economically viable as the price of fossil fuels rises, a lower cost of the backstop will either postpone fossil fuel exhaustion or leave more fossil fuel in situ, thus boosting green welfare. However, if a market economy does not internalize global warming externalities and renewables have not kicked in yet, full exhaustion of fossil fuel will occur in finite time and a backstop subsidy always curbs green welfare.     

Movements of tiger sharks (Galeocerdo cuvier) in coastal Hawaiian waters

The giant clam Tridacna crocea harbors in the mantle tissue symbiotic microalgae commonly called zooxanthellae. Isolated zooxanthellae release glycerol into the medium in the presence of mantle tissue homogenate (MH), but it is not clear whether the cells do so in situ. In order to determine the photosynthetic products released by zooxanthellae in the mantle of the giant clam we traced photosynthetic fixation products from ¹³C- and ¹⁴C-bicarbonate both in the clam and in isolated zooxanthellae (IZ) in the presence or absence of MH. After 15 min incubation in the absence of MH the IZ released less than 0.6% of the fixed labeled carbon, mainly as glucose. The major intracellular photosynthates were neutral lipids, which constituted 20 to 40% of the total extractable ¹⁴C. In the presence of MH, the IZ released up to 5.6% of the total fixed ¹⁴C, mostly as glycerol, and the major intracellular photosynthate was glucose. In an intact clam incubated in sea water containing ¹⁴C-bicarbonate, 46 to 80% of the fixed ¹⁴C was translocated from the zooxanthellae to the host tissues. Most of the ¹⁴C in the hemolymph, in the isolated zooxanthellae and in intact mantle tissue (containing zooxanthellae) was recovered as glucose. No ¹⁴C-glycerol was detected in the mantle after 1 to 30 min incubation, and, even after 60 min, far less ¹⁴C-glycerol was synthesized than by IZ in the presence of MH. The possibility that in clam tissue glycerol is converted to glucose was examined by tracing the labeled carbon from ¹⁴C-glycerol injected into the adductor muscle. After 5 min incubation, no labeled glucose was found in the hemolymph, but after 60 min, some 20% was found as glucose. Thin slices containing zooxanthellae, cut from the surface of the mantle, fixed inorganic carbon supplied as NaH¹⁴CO₃ in the medium and mainly released ¹⁴C-glucose. The addition of MH to the surrounding medium did not affect the release rate or form of release product. When the slices were cut into smaller pieces, however, the ratio of glycerol to glucose in the release product increased. These results indicate that in the presence of MH the metabolism of isolated zooxan- thellae was different from that of zooxanthellae in the mantle. In the presence of MH, isolated zooxanthellae release mostly glycerol, whereas in the mantle they release glucose. Received: 18 February 1998 / Accepted: 4 December 1998     

Does defoliation induce chemical and morphological defenses in the leaves of silver birch seedlings under changing climate?

Summary.  We examined the effects of defoliation con-currently with elevated temperature and CO₂ on some chemical and morphological characteristics in the leaves of silver birch seedlings (Betula pendula). We also analyzed the consequent changes in the palatability of leaves for adult blue alder leaf beetles (Agelastica alni). Under the different climatic treatments, the seedlings were subjected to three fertilizer treatments (0 kg, 130 kg and 270 kg N ha⁻¹) and defoliation treatments (0%, 25% and 50% of the total leaf area). In each climatic treatment, fertilization increased the nitrogen content in the leaves, but decreased total concentrations of soluble phenolics, detected by high-performance liquid chromatography (HPLC), and insoluble condensed tannins. Defoliation, both independently and in combination with elevated temperature and CO₂, decreased the concentrations of the phenolics. Compared to the intact controls, the leaves of the defoliated seedlings were smaller and tougher. Under elevated temperature, the beetles consumed a smaller amount of the leaves of plants subjected to the high fertilization, while under ambient climatic conditions, fertilization increased the feeding. The total leaf consumption was higher under the ambient climatic conditions than under elevated temperature, elevated CO₂ or the combination of elevated temperature and CO₂.     

Aspects and prospects of algal carbon capture and sequestration in ecosystems: a review

Long-term storage of carbon dioxide (CO₂) and other forms of carbon in non-atmospheric reservoirs is called carbon sequestration. Selective anthropogenic enrichment of the atmospheric carbon pool is causing dire environmental problems, thereby necessitating remediation by mitigation. Algae possess efficient carbon concentrating mechanisms and consequently high photosynthetic rates which make them suitable candidates for biosequestration of CO₂. Globally, nearly half of the atmospheric oxygen is generated by algal photosynthesis despite the fact that algae account for less than 1% of photosynthetic biomass. In water bodies, algae are responsible for creating the ‘biological pump’ that transports carbon from the upper sunlit waters to the depth below. A diverse array of photoautotrophs ranging from prokaryotic cyanobacteria to eukaryotic algae such as Chlorophytes, and even protists like euglenoids, contribute to this ‘biological pump’. It operates in a variety of aquatic ecosystems ranging from small freshwater ponds to the oceans where it has been most extensively studied. Two separate but intricately linked processes constitute this ‘biological pump’, viz. the ‘organic carbon pump’ and the ‘calcium carbonate pump’. The present review discusses the natural CO₂ sequestration processes carried out by algae and cyanobacteria in their native ecosystems.     

Recycling greenhouse gas fossil fuel emissions into low radiocarbon food products to reduce human genetic damage

Radiocarbon from nuclear fallout is a known health risk. However, corresponding risks from natural background radiocarbon incorporated directly into human genetic material have not been fully appreciated. Here we show that the average person will experience between 3.4 × 10¹⁰ and 3.4 × 10¹¹ lifetime chromosomal damage events from natural background radiocarbon incorporated into DNA and histones, potentially leading to cancer, birth defects, or accelerated aging. This human genetic damage can be significantly reduced using low radiocarbon foods produced by growing plants in CO₂ recycled from ordinary industrial greenhouse gas fossil fuel emissions, providing additional incentive for the carbon sequestration.