Surface Water Seepage Effects on Shallow Ground‐Water Quality Along the Rio Grande in Northern New Mexico1

Abstract: Interactions between surface irrigation water, shallow ground water, and river water may have effects on water quality that are important for both drinking water supplies and the ecological function of rivers and floodplains. We investigated water quality in surface water and ground water, and how water quality is influenced by surface water inputs from an unlined irrigation system in the Alcalde Valley of the Rio Grande in northern New Mexico. From August 2005 to July 2006, we sampled ground water and surface water monthly and analyzed for concentrations of major cations and anions, specific conductance, pH, dissolved oxygen, and water levels. Results indicate that irrigation ditch seepage caused an increase in ground water levels and that the Rio Grande is a gaining stream in this region. Temporal and spatial differences were found in ion concentrations in shallow ground water as it flowed from under the ditch toward the river. Ground‐water ion concentrations were higher when the ditch was not flowing compared with periods during peak irrigation season when the ditch was flowing. Ditch inputs diluted ion concentrations in shallow ground water at well positions near the ditch. Specifically, lower ion concentrations were detected in ground water at well positions located near the ditch and river compared with well positions located in the middle of an agricultural field. Results from this project showed that ditch inputs influenced ion concentrations and were associated with ground‐water recharge. In arid region river valleys, careful consideration should be given to management scenarios that change seepage from irrigation systems, because in some situations reduced seepage could negatively affect ground‐water recharge and water quality.     

Specific Yield Functions for Estimating Evapotranspiration from Diurnal Surface Water Cycles

The White method has been routinely used to estimate evapotranspiration using diurnal variations in groundwater levels. Applications to surface water systems (e.g., wetlands) are less common. For applications to surface water systems, a stage‐dependent specific yield function must be defined. This is especially important for small wetlands formed in topographic depressions with bowl shaped bathymetries. Existing formulations of the specific yield function include weighting factors that impact the relative importance of the soil and open water specific yields on the composite value. Three formulations of the specific yield function from the literature were compared and found to produce varied results. Based on a comparison with empirical estimates of specific yield based on observed ratios of net precipitation to water level rise, one of the existing formulations is generalized and recommended for general use. The recommended function is dependent on wetland bathymetry, magnitude of the diurnal fluctuation, spatial extent of the equilibration area, and soil‐specific yield. A sensitivity analysis was conducted to examine the relative importance of these variables. The specific yield function is independent of wetland size and is strongly dependent on the basin profile coefficient (p), an indication of wetland shape. For most natural wetlands, bathymetry strongly influences specific yield.     

SIMULATING FLOW IN REGIONAL WETLANDS WITH THE MODFLOW WETLANDS PACKAGE1

ABSTRACT: As part of the Comprehensive Everglades Restoration Plan (CERP), various water supply projects have been proposed in a region located between the Miami metropolitan area and the extensive regional wetland systems that are part of the Everglades or remnant Everglades. A ground water flow model of the surficial aquifer within northern Miami‐Dade County was constructed using MODFLOW to evaluate the effects of these projects on water levels in the wetlands and the underlying surficial aquifer. The new Wetlands package was used to conjunctively simulate overland flow through these wetlands and the shallow ground water system. Comparisons of simulated to measured ground water levels and wetland stages were very satisfactory, where computed and measured water levels agreed within 0.5 ft over most of the period of record at nearly all of the monitoring sites. Temporal trends in water levels were also replicated. It was concluded that the assumptions and methodologies inherent to the Wetlands package were suitable for simulating regional wetland hydrology within the Everglades area.     

Riparian Ground‐Water Flow Patterns Using Flownet Analysis: Evapotranspiration‐Induced Upwelling and Implications for N Removal1

Abstract: Ground‐water flow paths constrain the extent of nitrogen (N) sinks in deep, stratified soils of riparian wetlands. We examined ground‐water flow paths at four forested riparian wetlands in deep, low gradient, stratified deposits subjected to Southern New England’s temperate, humid climate. Mid‐day piezometric heads were recorded during the high water table period in April/May and again in late November at one site. Coupling field data with a two‐dimensional steady‐state ground‐water flow model, flow paths and fluxes were derived to 3 m depths. April/May evapotranspiration (ET) dominated total outflux (44‐100%) while flux to the stream was <10% of total outflux. ET exerted upward ground‐water flux through shallow carbon‐rich soils, increasing opportunities for N transformations and diverting flow from the stream. Dormant season results showed a marked increase in flux to the stream (27% of the total flux). Riparian sites with deep water tables (naturally or because of increased urbanization or other hydrologic modifications) or shallow root zones may not generate ground‐water upwelling to meet evaporative demand, thereby increasing the risk of N movement to streams. As water managers balance issues of water quality with water quantity, they will be faced with decisions regarding riparian management. Further work towards refining our understanding of ET mediation of N and water flux at the catchment scale will serve to inform these decisions.     

GROUND WATER/SURFACE WATER RESPONSES TO GLOBAL CLIMATE SIMULATIONS,SANTA CLARA‐CALLEGUAS BASIN,VENTURA, CALIFORNIA1

ABSTRACT: Climate variations can play an important, if not always crucial, role in successful conjunctive management of ground water and surface water resources. This will require accurate accounting of the links between variations in climate, recharge, and withdrawal from the resource systems, accurate projection or predictions of the climate variations, and accurate simulation of the responses of the resource systems. To assess linkages and predictability of climate influences on conjunctive management, global climate model (GCM) simulated precipitation rates were used to estimate inflows and outflows from a regional ground water model (RGWM) of the coastal aquifers of the Santa Clara‐Calleguas Basin at Ventura, California, for 1950 to 1993. Interannual to interdecadal time scales of the El Niño Southern Oscillation (ENSO) and Pacific Decadal Oscillation (PDO) climate variations are imparted to simulated precipitation variations in the Southern California area and are realistically imparted to the simulated ground water level variations through the climate‐driven recharge (and discharge) variations. For example, the simulated average ground water level response at a key observation well in the basin to ENSO variations of tropical Pacific sea surface temperatures is 1.2 m/°C, compared to 0.9 m/°C in observations. This close agreement shows that the GCM‐RGWM combination can translate global scale climate variations into realistic local ground water responses. Probability distributions of simulated ground water level excursions above a local water level threshold for potential seawater intrusion compare well to the corresponding distributions from observations and historical RGWM simulations, demonstrating the combination's potential usefulness for water management and planning. Thus the GCM‐RGWM combination could be used for planning purposes and — when the GCM forecast skills are adequate — for near term predictions.     

Sensitivity and Uncertainty of Ground‐Water Discharge Estimates for Semiarid Shrublands1

Abstract: We proposed a step‐by‐step approach to quantify the sensitivity of ground‐water discharge by evapotranspiration (ET) to three categories of independent input variables. To illustrate the approach, we adopt a basic ground‐water discharge estimation model, in which the volume of ground water lost to ET was computed as the product of the ground‐water discharge rate and the associated area. The ground‐water discharge rate was assumed to equal the ET rate minus local precipitation. The objective of this study is to outline a step‐by‐step procedure to quantify the contributions from individual independent variable uncertainties to the uncertainty of total ground‐water discharge estimates; the independent variables include ET rates of individual ET units, areas associated with the ET units, and precipitation in each subbasin. The specific goal is to guide future characterization efforts by better targeting data collection for those variables most responsible for uncertainty in ground‐water discharge estimates. The influential independent variables to be included in the sensitivity analysis are first selected based on the physical characteristics and model structure. Both regression coefficients and standardized regression coefficients for the selected independent variables are calculated using the results from sampling‐based Monte Carlo simulations. Results illustrate that, while as many as 630 independent variables potentially contribute to the calculation of the total annual ground‐water discharge for the case study area, a selection of seven independent variables could be used to develop an accurate regression model, accounting for more than 96% of the total variance in ground‐water discharge. Results indicate that the variability of ET rate for moderately dense desert shrubland contributes to about 75% of the variance in the total ground‐water discharge estimates. These results point to a need to better quantify ET rates for moderately dense shrubland to reduce overall uncertainty in estimates of ground‐water discharge. While the approach proposed here uses a basic ground‐water discharge model taken from an earlier study, the procedure of quantifying uncertainty and sensitivity can be generalized to handle other types of environmental models involving large numbers of independent variables.     

USING REFERENCE SITES AND SIMPLE LINEAR REGRESSION TO ESTIMATE LONG‐TERM WATER LEVELS IN COASTAL PLAIN FORESTS1

ABSTRACT: The ability of regulators, resource managers, and consultants to assess accurately wetland hydrology is crucial when identifying and delineating wetlands. In this study, simple linear regression and long‐term (ten year) New Jersey Pinelands stream gaging and pitch pine lowland water‐level data sets were used to estimate long‐term hydroperiods at lowland test sites with short‐term (two year) records. Separate regression equations were developed for each test site using reference site data and stream gaging data, and two sets of equations for selected test sites were produced using two different short‐term periods of record. Test sites had long‐term records ranging from four to ten years, allowing validation of the regression models. Measured and predicted test site growing season water levels were similar regardless of which short‐term period of record was used. The results based on the stream gaging site data were similar, although the difference between measured and estimated growing season water levels was greater when this approach was used. Excellent agreement was found between measured and estimated frequencies of near‐surface saturation at test sites for each growing season month, and these relationships improved when cumulative, seasonal frequencies were considered. The reference wetland approach used in this study may have its greatest value in regions with both high development pressures and problem wetlands and may provide an effective way of resolving costly wetland delineation disputes.     

ISOTOPE HYDROLOGY DYNAMICS OF RIVERINE WETLANDS IN THE KANKAKEE WATERSHED,INDIANA1

ABSTRACT: Wetland restoration activities may disturb shallow ground‐water flow dynamics. There may be unintentional sources of water flowing into a constructed wetland that could compromise the long‐term viability of a wetland function. Measurement of naturally‐occurring isotopes in the hydrosphere can provide an indication of provenance, flow paths or components, and residence times or ages of wetland ground‐water flow systems. Hydraulic head measurements may not provide sufficient detail of shallow flow disturbances and can be complemented by analyzing isotopes in waters flowing through the wetland. Two north‐central Indiana wetlands in the Kankakee watershed are being studied to determine the adequacy of wetland restoration activities. The native LaSalle wetland and the restored Hog Marsh wetland have contrasting ground‐water flow regimes. The conservative water isotopes ¹⁸O, ²H, and ³H, and selected solute isotopes ¹³C, ¹⁴C, ¹⁵N, ³⁴S, ⁸⁷Sr, and 206–208Pb, demonstrate the complexity of ground‐water flow in Hog Marsh compared to the established flow regime at the LaSalle wetland.     

A conceptual framework for assessing cumulative impacts on the hydrology of nontidal wetlands

Wetlands occur in geologic and hydrologic settings that enhance the accumulation or retention of water. Regional slope, local relief, and permeability of the land surface are major controls on the formation of wetlands by surface-water sources. However, these landscape features also have significant control over groundwater flow systems, which commonly play a role in the formation of wetlands. Because the hydrologic system is a continuum, any modification of one component will have an effect on contiguous components. Disturbances commonly affecting the hydrologic system as it relates to wetlands include weather modification, alteration of plant communities, storage of surface water, road construction, drainage of surface water and soil water, alteration of groundwater recharge and discharge areas, and pumping of groundwater. Assessments of the cumulative effects of one or more of these disturbances on the hydrologic system as related to wetlands must take into account uncertainty in the measurements and in the assumptions that are made in hydrologic studies. For example, it may be appropriate to assume that regional groundwater flow systems are recharged in uplands and discharged in lowlands. However, a similar assumption commonly does not apply on a local scale, because of the spatial and temporal dynamics of groundwater recharge. Lack of appreciation of such hydrologic factors can lead to misunderstanding of the hydrologic function of wetlands within various parts of the landscape and mismanagement of wetland ecosystems.     

EVAPOTRANSPIRATION CONCEPTUALIZATION IN THE HSPF‐MODFLOW INTEGRATED MODELS1

In 1988, the Florida Institute of Phosphate Research (FIPR) funded project to develop an advanced hydrologic model for shallow water table systems. The FIPR hydrologic model (FHM) was developed to provide an improved predictive capability of the interactions of surface water and ground water using its component models, HSPF and MODFLOW. The Integrated Surface and Ground Water (ISGW) model was developed from an early version of FHM and the two models were developed relatively independently in the late 1990s. Hydrologic processes including precipitation, interception, evapotranspiration, runoff, recharge, streamflow, and base flow are explicitly accounted for in both models. Considerable review of FHM and ISGW and their applications occurred through a series of projects. One model evolved, known as the Integrated Hydrological Model IHM. This model more appropriately describes hydrologic processes, including evapotranspiration fluxes within small distributed land‐based discretization. There is a significant departure of many IHM algorithms from FHM and ISGW, especially for soil water and evapotranspiration (ET). In this paper, the ET concepts in FHM, ISGW, and IHM will be presented. The paper also identifies the advantages and data costs of the improved methods. In FHM and IHM, ground water ET algorithms of the MODFLOW ET package replace those of HSPF (ISGW used a different model for ground water ET). However, IHM builds on an improved understanding and characterization of ET partitioning between surface storages, vadose zone storage, and saturated ground water storage. The IHM considers evaporative flux from surface sources, proximity of the water table to land surface, relative moisture condition of the unsaturated zone, thickness of the capillary zone, thickness of the root zone, and relative plant cover density. The improvements provide a smooth transition to satisfy ET demand between the vadose zone and deeper saturated ground water. While the IHM approach provides a more sound representation of the actual soil profile than FHM, and has shown promise at reproducing soil moisture and water table fluctuations as well as field measured ET rates, more rigorous testing is necessary to understand the robustness and/or limitations of this methodology.     

Hydrologic Model Framework for Water Resources Planning in the Santa Cruz River,Southern Arizona1

Abstract: The authors develop a model framework that includes a set of hydrologic modules as a water resources management and planning tool for the upper Santa Cruz River near the Mexican border, Southern Arizona. The modules consist of: (1) stochastic generation of hourly precipitation scenarios that maintain the characteristics and variability of a 45‐year hourly precipitation record from a nearby rain gauge; (2) conceptual transformation of generated precipitation into daily streamflow using varied infiltration rates and estimates of the basin antecedent moisture conditions; and (3) surface‐water to ground‐water interaction for four downstream microbasins that accounts for alluvial ground‐water recharge, and ET and pumping losses. To maintain the large inter‐annual variability of streamflow as prevails in Southern Arizona, the model framework is constructed to produce three types of seasonal winter and summer categories of streamflow (i.e., wet, medium, or dry). Long‐term (i.e., 100 years) realizations (ensembles) are generated by the above described model framework that reflects two different regimes of inter annual variability. The first regime is that of the historic streamflow gauge record. The second regime is that of the tree ring reconstructed precipitation, which was derived for the study location. Generated flow ensembles for these two regimes are used to evaluate the risk that the regional four ground‐water microbasins decline below a preset storage threshold under different operational water utilization scenarios.     

STABLE ISOTOPE CHARACTERIZATION OF THE IMPACTS OF ARTIFICIAL GROUND WATER RECHARGE1

ABSTRACT: Stable isotopes of deuterium and oxygen-18 of surface and ground water, together with anion concentrations and hydraulic gradients, were used to interpret mixing and flow in ground water impacted by artificial recharge. The surface water fraction (SWF), the percentage of surface water in the aquifer impacted via recharge, was estimated at different locations and depths using measured deuterium/hydrogen (DIH) ratios during the 1992, 1993, and 1994 recharge seasons. Recharged surface water completely displaced the ground water beneath the recharge basins from the regional water table at 7.60 m to 12.16 m below the land surface. Mixing occurred beneath the recharge structures in the lower portions of the aquifer (>12.16 m). Approximately 12 m down-gradient from the recharge basin, the deeper zone (19.15 m depth) of the primary aquifer was displaced completely by recharged surface water within 193, 45, and 55 days in 1992, 1993, and 1994, respectively. At the end of the third recharge season, recharged surface water represented ～50 percent of the water in the deeper zone of the primary aquifer ～1000 m downgradient from the recharge basin. A classic asymmetrical distribution of recharged surface water resulted from the recharge induced horizontal and vertical hydraulic gradients. The distribution and breakthrough times of recharged surface water obtained with stable isotopes concurred with those of major anions and bromide in a tracer test conducted during the 1995 recharge season. This stable isotope procedure effectively quantified mixing between surface and ground water.     

WATER BUDGETS FOR SMALL DIKED MARSHES1

ABSTRACT: This paper reports an analysis of the water budgets of 10 small (5–6 ha) diked areas (cells) within the Delta Marsh in southcentral Manitoba, Canada. The important terms in the water budget equation in this study were precipitation (P), water pumped in (SWI), evapotranspiration (ET), seepage in (GWI) and out (GWO), and change in storage (ΔS). P, SWI, and S were measured directly, and the sum of ET and GWO determined by difference. Estimating ET as 0.7 pan evaporation gave a seepage loss of 2.9 mm/day from the most intensively studied cell. Other methods of estimating ET produced estimates of GWO ranging from 2.4 to 3.8 mm/day. Water budgets for less intensively studied cells indicated seepage loss increased as perimeter available for seepage increased, but not proportionately. Efforts to measure seepage directly or estimate it from measured hydraulic gradients and hydraulic conductivity produced estimates much lower than the estimates from the water budget equation. Hydraulic conductivities were very heterogeneous, reflecting the sorting of water deposited sediments. Comparison of the hydraulic conductivities with seepage estimates from the water budget strongly suggests water movement downward as well as laterally from these diked areas.     

Predicting Sustainable Ground Water to Constructed Riparian Wetlands: Shaker Trace,Ohio, USA

Water isotopy is introduced as a tool to design, locate, and select storm water best management practices for the prediction of sustained ground water inflows to prospective constructed wetlands. A primer and application of the stable isotopes, ¹⁸O and ²H, are discussed for riparian wetland restoration areas among an agricultural landscape in southwestern Ohio. Conventional piezometric measurements were ambiguous in identifying groundwater mounding across a transect which includes numerous agricultural tile drains. Instead evaporative potential data represented by δ¹⁸O values indicated a well delineated zone for prospective constructed wetlands. All successful constructed wetland areas thus far at Shaker Trace are represented by ground water with depleted δ¹⁸O values below −9.0‰ VSMOW. Such areas of sustainable ground water inflow could either be due to perched units at depth or simply the result of an increased flow gradient.     

SIMULATING THE EFFECTS OF REDUCED PRECIPITATION ON GROUND WATER AND STREAMFLOW IN THE NEBRASKA SAND HILLS1

ABSTRACT: The Nebraska Sand Hills have a unique hydrologic system with very little runoff and thick aquifers that constantly supply water to rivers, lakes, and wetlands. A ground water flow model was developed to determine the interactions between ground water and streamflow and to simulate the changes in ground water systems by reduced precipitation. The numerical modeling method includes a water balance model for the vadose zone and MOD‐FLOW for the saturated zone. The modeling results indicated that, between 1979 and 1990, 13 percent of the annual precipitation recharged to the aquifer and annual ground water loss by evapotranspiration (ET) was only about one‐fourth of this recharge. Ground water discharge to rivers accounts for about 96 percent of the streamflow in the Dismal and Middle Loup rivers. When precipitation decreased by half the average amount of the 1979 to 1990 period, the average decline of water table over the study area was 0.89 m, and the streamflow was about 87 percent of the present rate. This decline of the water table results in significant reductions in ET directly from ground water and so a significant portion of the streamflow is maintained by capture of the salvaged ET.     

EFFECTS OF TOPOGRAPHY AND SOIL PROPERTIES ON RECHARGE AT TWO SITES IN AN AGRICULTURAL FIELD1

ABSTRACT: Field experiments were conducted from 1992 to 1995 to estimate ground water recharge rates at two sites located within a 2.7‐hectare agricultural field. The field lies in a sand plain setting in central Minnesota and is cropped continuously in field corn. The sites are located at a topographically high (upland) site and a topographically low (lowland) site in an effort to quantify the effects of depression focusing of recharge. Three site‐specific methods were used to estimate recharge rates: well hydrograph analysis, chlorofluorocarbon age dating, and an unsaturated zone water balance. All three recharge methods indicated that recharge rates at the lowland site (annual average of all methods of 29 cm) exceeded those at the upland site (annual average of 18 cm). On an annual basis, estimates by the individual methods ranged from 12 to 44 percent of precipitation at the upland site and from 21 to 83 percent at the lowland site. The difference in recharge rates between the sites is primarily attributed to depression focusing of surface water runon at the lowland site. However, two other factors were also important: the presence of thin lamellae at the upland site, and coarser textured soils below a depth of 1.5 m at the lowland site.     

MODELING EFFECTS OF BRUSH MANAGEMENT ON THE RANGELAND WATER BUDGET: EDWARDS PLATEAU,TEXAS1

ABSTRACT: The Soil and Water Assessment Tool (SWAT) was used to evaluate the influence of woody plants on water budgets of semi‐arid rangelands in karst terrain. The model was configured for the hydrologic evaluation of the North Fork of the Upper Guadalupe River watershed and was calibrated and verified using measured flow data. Nash and Sutcliffe fit efficiencies for daily and monthly verification periods were 0.09 and 0.50, respectively. Streamflow, baseflow, and evapotranspiration (ET) rates were comparable to published field data. Simulated deep recharge was considerably higher than the published values for the Edwards Plateau. The model was then used to simulate conditions with existing brush cover and four different brush removal scenarios. Scenarios were created to represent existing brush and the removal of brush from only locations that were either covered by heavy brush, were on a moderate slope, or were in shallow soils. Resulting data was compared to previous studies of both field experiments and model simulations. Maximum brush removal resulted in a reduction in ET equal to 31.94 mm/yr depth over the entire basin, or 46.62 mm/yr depth over the treated area. Removal of heavy brush cover resulted in the greatest changes in evapotranspiration, surface runoff, base‐flow, and deep recharge. Slope was found to have the greatest effect on lateral subsurface flow.     

SIMULATION OF INTEGRATED SURFACE WATER AND GROUND WATER SYSTEMS - MODEL FORMULATION1

ABSTRACT: The unique characteristics of the hydrogeologic system of south Florida (flat topography, sandy soils, high water table, and highly developed canal system) cause significant interactions between ground water and surface water systems. Interaction processes involve infiltration, evapotranspiration (ET), runoff, and exchange of flow (seepage) between streams and aquifers. These interaction processes cannot be accurately simulated by either a surface water model or a ground water model alone because surface water models generally oversimplify ground water movement and ground water models generally oversimplify surface water movement. Estimates of the many components of flow between surface water and ground water (such as recharge and ET) made by the two types of models are often inconsistent. The inconsistencies are the result of differences in the calibration components and the model structures, and can affect the confidence level of the model application. In order to improve model results, a framework for developing a model which integrates a surface water model and a ground water model is presented. Dade County, Florida, is used as an example in developing the concepts of the integrated model. The conceptual model is based on the need to evaluate water supply management options involving the conjunctive use of surface water and groundwater, as well as the evaluation of the impacts of proposed wellfields. The mathematical structure of the integrated model is based on the South Florida Water Management Model (SFWMM) (MacVicar et al., 1984) and A Modular Three-Dimensional Finite-Difference Groundwater Flow Model (MODFLOW) (McDonald and Harbaugh, 1988).     

SUBSURFACE RETURN FLOW AND GROUND WATER RECHARGE OF TERRACE FIELDS IN NORTHERN TAIWAN1

ABSTRACT: This study estimates subsurface return flow and effective ground water recharge in terraced fields in northern Taiwan. Specifically, a three dimensional model, FEMWATER, was applied to simulate percolation and lateral seepage in the terraced fields under various conditions. In the terraced paddy fields, percolation mainly moves vertically downward in the central area, while lateral seepage is mainly focused around the bund. Although the simulated lateral seepage rate through the bund exceeded the percolation rate in the central area of the paddy field, annual subsurface return flow at Pei‐Chi and Shin‐Men was 0.17 × 10⁶ m³ and 0.37 × 10⁶ m³, representing only 0.17 percent and 0.21 percent of the total irrigation water required for rice growth at Pei‐Chi and Shin‐Men, respectively. For upland fields, the effective ground water recharge rate during the second crop period (July to November) exceeded that during the first crop period (January to May) because of the wet season in the second crop period. Terraced paddy fields have the most efficient ground water recharge, with 21.2 to 23.4 percent of irrigation water recharging to ground water, whereas upland fields with a plow layer have the least efficient ground water recharge, with only 4.8 to 6.6 percent of irrigation water recharging to ground water. The simulation results clearly revealed that a substantial amount of irrigation water recharges to ground water in the terraced paddy, while only a small amount of subsurface return flow seeps from the upstream to the downstream terraced paddy. The amounts of subsurface flow and ground water recharge determined in the study are useful for the irrigation water planning and management and provide a scientific basis to reevaluate water resources management in the terrace region under irrigated rice.     

GEOCHEMICAL CHARACTERIZATION OF SHALLOW GROUND WATER IN THE EUTAW AQUIFER,MONTGOMERY, ALABAMA1

ABSTRACT: Ground water samples were collected from 30 wells located in, or directly down gradient from, recharge areas of the Eutaw aquifer in Montgomery, Alabama. The major ion content of the water evolves from calcium‐sodium‐chloride‐dominated type in the recharge area to calcium‐bicarbonate‐dominated type in the confined portion of the aquifer. Ground water in the recharge area was under saturated with respect to aluminosilicate and carbonate minerals. Ground water in the confined portion of the aquifer was at equilibrium levels for calcite and potassium feldspar. Dissolved oxygen and nitrite‐plus‐nitrate concentrations decreased as ground water age increased; pH, iron, and sulfate concentrations increased as ground water age increased. Aluminum, copper, and zinc concentrations decreased as ground water age and pH increased. These relations indicate that nitrate, aluminum, copper, and zinc are removed from solution as water moves from recharge areas to the confined areas of the Eutaw aquifer. The natural evolution of ground water quality, which typically increases the pH and decreases the dissolved oxygen content, may be an important limiting factor to the migration of nitrogen based compounds and metals.