三峡库区柑橘对土壤重金属吸收富集特征研究

研究区域柑橘果实重金属含量符合NY/T 426-2000<绿色食品柑橘>标准,果实品质达到一级产品.土壤中重金属的含量越高,柑橘叶片、果皮、果肉的重金属含量也越高.柑橘叶片对土壤重金属铜、锌、铅、镉、镍、汞、砷、铬的吸收富集能力显著大于果皮与果肉,果皮对土壤重金属铜、锌、铅、镉、汞的吸收富集能力显著大于果肉,果肉对土壤重金属铬的吸收富集能力显著大于果皮.柑橘同一部位对土壤中不同重金属元素的吸收富集能力也存在很大的差异,柑橘叶片对土壤中不同重金属元素的富集系数大小顺序为Hg＞Pb＞Cd＞Cu＞Zn＞Cr＞As＞Ni,柑橘果皮对土壤中不同重金属元素的富集系数大小顺序为Cd＞Hg＞Cu＞Zn＞Pb＞Cr＞Ni＞As,柑橘果肉对土壤中不同重金属元素的富集系数大小顺序为Hg＞Cu＞Cr＞Zn＞Cd＞Ni＞Pb＞As.     

太原市大气颗粒物中重金属的污染特征及来源解析

为了解太原市采暖期大气颗粒物不同粒径中重金属的污染特征及其来源,于2012年10月—2013年2月对环境空气中颗粒物采样,用原子吸收分光光度法测定样品中Fe、Pb、Cu、Ni、Cr、Cd、Mn、Zn等8种元素的含量。结果表明,太原市采暖期重金属浓度从高到低依次为FePbMnZnCrCuNiCd。重金属Pb、Mn、Zn、Ni、Cd主要富集在PM2.5中;Cr主要富集在PM10中;Cu主要富集在PM5中;Fe主要在粒径大于2.5μm的粗粒子中富集。除Zn外,其他7种元素浓度均表现为灰霾期采暖期采暖前。通过主因子分析表明,太原市大气颗粒物中重金属主要来源于冶金、有机合成工业、燃煤、汽车尾气、土壤尘等。     

真藓对碳酸盐型锰矿区重金属污染的指示意义

锰矿开采产生重金属污染,对周围环境造成影响,有必要对矿区重金属进行监测。研究以典型碳酸盐型锰矿——南茶锰矿(按职能划分为4个功能区:矿井区、废石区、选矿区、蓄矿区)为对象,以区域内真藓Bryum argenteum为材料,结合相关分析、聚类分析、主成分分析、变异系数等方法考察了真藓和土壤中重金属的含量及其可能的来源。结果表明:各功能区均受到不同程度的人为干扰,人为干扰越强,区域污染越严重。在不同污染梯度的功能区内,真藓的重金属(Fe、Mn、Zn、Cr、Ni、Ba、Co、Mo、Hg、Pb、Cd、Cu、Tl、As、Sb)含量与土壤重金属含量显著正相关(P<0.05),说明真藓是监测碳酸盐型锰矿重金属污染的有效指标。真藓指示南茶锰矿除了可能受到采矿活动的强烈影响外(Mn、Cu、Fe、Zn、Cr、Ni、Mo、Ba),还受到来自运输车辆的机械磨损、排放及采矿活动的复合污染(Tl、Cd、Pb、As、Sb),识别结果与区域重金属分布情况吻合,表明真藓具有识别重金属污染的能力。在今后碳酸盐型锰矿污染防治工作中,可将真藓作为重金属污染监测的生物材料。     

罗布泊“大耳朵”地区L07-10剖面沉积物重金属赋存形态研究

本研究以罗布泊"大耳朵"地区L07-10剖面沉积物中重金属Cu、Ni、Mn为研究对象,研究了重金属Cu、Ni、Mn的赋存形态,结果显示:Cu以残渣态和有机物结合态为主,可交换态和碳酸盐结合态较少;Ni以残渣态存在的比例较高,可交换态和有机物结合态含量较小;Mn以铁锰氧化物结合态和残渣态为主,可交换态和有机物结合态含量较少。重金属Cu、Ni和Mn的赋存形态在该剖面垂直方向上大部分呈波折多峰分布,其赋存形态与有机质也存在一定的相关性,但相关性有所不同。研究结果揭示了这3种重金属在罗布泊"大耳朵"地区L07-10剖面沉积物中赋存形态的分布规律,研究结果可为罗布泊干盐湖区重金属相关研究补充基础数据。     

蔬菜与土壤环境中铅镉含量相关性调查

通过调查5种蔬菜对铅、镉绝对吸收量以及富集系数不同,分析了蔬菜与土壤中重金属含量相关性.结果表明,各种蔬菜对镉的吸收绝对量差异明显,同类型蔬菜对铅、镉的吸收量接近.各种蔬菜对铅的富集能力排序为白菜>黄瓜>番茄>青菜>辣椒,对镉的富集能力排序为青菜>白菜>辣椒>番茄>黄瓜.蔬菜对土壤中镉的吸收能力明显大于铅.     

洪泽湖鱼体内重金属含量调查

对洪泽湖鱼体中的Pb、Cd、Cu、Cr、Zn等5种重金属进行了测定,分析了不同重金属在鱼的组织器官中的含量分布情况,并重点探讨了重金属在鱼体内的富集规律。结果显示：同一类组织器官中重金属的含量、同一金属在不同组织器官中的分布、不同鱼类对同种金属元素的吸收积累存在显著差异,5种重金属的含量以肌肉中的含量最低;均值型指数法显示,鱼样中肌肉组织残毒污染较小,属于微污染到轻污染级别;污染负荷比说明洪泽湖鱼体残毒的主要污染因子是铅、镉。     

基于多源大数据可视化的城市居民区绿地土壤环境监测点位布设及采样研究

为科学合理的监测城市居民区绿地土壤环境状况,对居民区绿地土壤监测点位布设和采样的方法进行研究,包括代表性居民区的选取、监测点采样位置的确定、点位数量的确定等。通过多源大数据可视化手段选取某城市代表性的居民区,对其居民区内绿地土壤重金属(镉、汞、砷、铅、铜、铬、锌和镍)进行监测。结果表明:多源大数据的应用对城市土壤监测布点具有积极作用和优势;不同建筑年代的居民区土壤中重金属含量存在一定差异,为全面监测居民区土壤环境状况应选取不同建筑年代的居民区作为监测对象;不同采样位置对居民区土壤样品中重金属含量无明显影响,优先于居民区内面积占比较大的绿地采样;同一居民区内不同监测点位样品存在差异性,每个居民区内至少布设3~4个监测点位可代表该居民区土壤环境状况。     

上海市黄浦江表层沉积物重金属污染评价

用沉积物富集系数法和Hakanson潜在生态风险评估法对上海市黄浦江表层沉积物重金属含量进行了评价。结果显示,沉积物中Cd、As和Pb含量富集程度较低,Hg和Cu含量富集程度较高;其分布特征为上游段含量相对较轻,到中游段有所上升,至下游段含量又有所下降,整体呈钟型分布,重金属含量分布规律可能与苏州河对黄浦江下游沉积物的影响和黄浦江中游段有工业污染排放输入有关;河口与内陆河流沉积物中重金属含量存在差异性,河口重金属含量明显下降;调查区37.5%的断面Hg含量潜在生态危害为中等;沉积物富集系数法可用来评价重金属累积程度,而潜在生态风险指数则突出对生物有很强毒性的重金属作用。     

洪泽湖溧河洼水生植物体内重金属调查

对洪泽湖溧河洼区域的水生植物进行了Cu、Zn、Pb、Cr和Cd等重金属元素的污染调查与监测分析,结果表明:水生植物对重金属元素的吸收与积累反映了环境中的重金属污染水平,不同水生植物对各种重金属元素的吸收富集状况具有相对一致性,即Zn>Cu>Cr>Pb>Cd。水生植物对各种重金属元素的平均富集系数大小顺序为:Cd>Cu>Zn>Cr>Pb,这与各元素迁移性强弱的顺序也是相一致的,Cd、Cu、Zn等各元素较易为植物所吸收,而Pb的移动性较差。大部分水生植物根部的重金属含量比茎叶部分高。研究表明:可以从中筛选出具有高富集作用的植物,作为修复水体或土壤重金属污染的实验植物,为植物修复作用的研究提供参考。     

白马湖甲壳动物体内重金属含量调查

对白马湖3种甲壳动物体内的Pb、Cd、Cu、Cr、Zn的含量进行了调查。结果表明，Cu、Zn含量较高；同种重金属元素在不同种类的软体动物体内含量差异较大，富集能力的次序是克氏原敖虾＞日本青沼＞秀丽白虾；Cd 和 Pb 在克氏原螯虾体内的不同器官和组织中富集程度不同，其中以肌肉中含量最低，鳃中的含量居中，虾壳中的含量为最高。     

河流沉积物中有机污染物的分析研究进展

总结了近年来河流沉积物中有机污染物的研究进展 ,集中评述了国内有关沉积物中多环芳烃、有机氯农药和多氯联苯的分析研究现状 ,包括样品采集、样品前处理和样品分析 ,并对今后河流、湖泊及水库沉积物中污染物的分析工作作了展望     

Challenges in meeting international standards in undertaking social impact assessment in Russia

Implementing good practice social impact assessment (SIA) that meets international standards in countries in transition is problematic. We reflect on the challenges faced when undertaking SIA in the Russian Federation. These challenges restrict meaningful SIA processes from being undertaken and limit public participation and the effective community engagement of project-affected local people. Based on the self-reflexive professional experience of two Russian-based social practitioners, and their discursive interactions with two leading academics in environmental and social impact assessment, as well as on in-depth interviews with prominent Russian and international experts, we identified the key challenges that prevent effective SIA from being implemented in Russia: a lack of understanding of the international standards; discrepancy in the determination of the social area of influence between the national requirements and international standards; difficulties in combining national and international impact assessment processes; and a tendency by companies to restrict stakeholder engagement to the minimum. We hope that by having an awareness of these limitations, improvements to SIA practice in Russia and elsewhere will be made.     

Changes in the trade in native medicinal plants in Brazilian public markets

Plants continue to be an important source of new bioactive substances. Brazil is one of the world’s mega-diverse countries, with 20 % of the world’s flora. However, the accelerated destruction of botanically rich ecosystems has contributed to a gradual loss of native medicinal species. In previous study, we have observed a fast and intensive change in trade of medicinal plants in an area of Amazon, where human occupation took place. In this study, we surveyed 15 public markets in different parts of Brazil in search of samples of 40 plants used in traditional medicine and present in first edition of Brazilian Official Pharmacopoeia (FBRAS), published in 1926. Samples of plants commercialized as the same vernacular name as in Pharmacopoeia were acquired and submitted to analysis for authentication. A total of 252 plant samples were purchased, but the laboratory analyses showed that only one-half of the samples (126, 50.2 %) were confirmed as the same plant species so named in FBRAS. The high number of unauthenticated samples demonstrates a loss of knowledge of the original native species. The proximity of the market from areas in which the plant occurs does not guarantee that trade of false samples occurs. The impact of the commerce of the substitute species on their conservation and in public health is worrying. Strategies are necessary to promote the better use and conservation of this rich heritage offered by Brazilian biodiversity.     

西藏典型城市公园繁殖鸟类中的外来鸟种

选取位于西藏拉萨的罗布林卡、龙王潭公园、布达拉宫广场,位于林芝的福建公园,以及位于昌都的天津广场等5个城市公园,于2017年5—6月采取样线法对其中的鸟类群落组成和外来鸟种情况进行调查。调查共记录到鸟类9目20科36种,其中属于古北界的有12种,东洋界和广布种也均为12种。36种鸟类中,留鸟24种,夏候鸟6种,冬候鸟2种,旅鸟4种。统计到外来鸟种4种,包括山噪鹛(Garrulax davidi)、八哥(Acridotheres cristatellus)、红嘴相思鸟(Leiothrix lutea)及大紫胸鹦鹉(Psittacula derbiana),占调查鸟种种类的11.1%,外来物种的入侵风险在高原不容忽视。     

Quantifying nickel in soils and plants in an ultramafic area in Philippines

In this study, concentrations of nickel (Ni) were quantified in the soils and plants in the agricultural areas of Salcedo watershed in Eastern Samar Island, Philippines. The quantity of total Ni in soils (TS-Ni) was significantly high with a mean of 1,409 mg kg^?1, while the soil available Ni (SA-Ni) was low with a mean of 8.66 mg kg^?1. As the levels of TS-Ni in the Salcedo watershed greatly exceeded the maximum allowable concentrations for agricultural soils, the site is not suitable for agricultural purposes. Despite significant TS-Ni levels, SA-Ni levels were very low due to tight binding between Ni and soil components. Consequently, all plants investigated did not meet the criterion for a Ni hyperaccumulator plant with low Ni contents (mean TP-Ni of 14.7 mg kg^?1). Comparison of Ni levels between food plants and its recommended daily intake (RDI) suggests that consumption of food-plants grown in the study area is unlikely to pose health risks. However, caution must be taken against combined consumption of food plants with high Ni levels or their prolonged consumption, as it can induce accumulation of Ni above RDI.     

Trends in Nitrogen Transport in Swedish Rivers

Concern about nitrogen loads in marine environments has drawn attention to the existence and possible causes of long-term trends in nitrogen transport in rivers. The present study was based on data from the Swedish environmental monitoring programme for surface water quality; the continuity of these data is internationally unique. A recently developed semiparametric method was employed to study the development of relationships between runoff and river transport of nitrogen since 1971; the observed relationships were then used to produce time series of flow-normalised transports for 66 sites in 39 river basins. Subsequent statistical analyses of flow-normalised data revealed only few significant downward trends (p 0.05) during the time period 1971–1994, and the most pronounced of these downward trends were caused by reduced point emissions of nitrogen. The number of significant upward trends was substantially larger (15 for total-N and 18 for NO₃-N). Closer examination of obtained results revealed the following: (i) the most pronounced upward trends were present downstream of lakes, and (ii) observed increases in nitrogen transport coincided in time and space with reduced point emissions of phosphorus or organic matter. This indicated that changes in the retention of nitrogen in lakes were responsible for the upward nitrogen trends. The hypothesis that nitrogen saturation of forest soils has caused a general increase in the riverine export of nitrogen from forested catchments in Sweden was not confirmed. Neither did the results indicate that improved agricultural practices have reduced the export of nitrogen from agricultural catchments.     

Variations in the level of some trace elements in hair of participants in the Italian expeditions in Antarctica

As a part the Italian National Programme of Research in Antarctica (PNRA) a monitoring study has been undertaken to quantify the concentrations of some selected trace elements in human hair of participants in the Antarctic expeditions. Such concentrations may vary as a consequence of the extreme environmental conditions and changes in lifestyle experienced by participants in the expeditions, as some evidence in previous investigations seems to suggest. The present study regards samples collected on the occasion of the 2002-2003 expedition to the Italian Base of Terra Nova Bay (now Mario Zucchelli Base), i.e., just before the expedition and about one month later. Seven essential elements were taken into account, namely, Ca, Cu, Cr, Fe, Mg, Mn and Mo. Determinations were performed by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) and Dynamic Reaction Cell Inductively Coupled Plasma Mass Spectrometry (DRC-ICP-MS). Data obtained were statistically treated by using the non-parametric Friedman test. The concentrations of Ca, Cu and Mg were found to decrease (P < 0.05). The stress caused by the severe environmental conditions might well play a role in the observed decrease.     

HPLC法测定饲料中维生素A、维生素D 3 和维生素E

建立了以w(C2H5OH)=95 %乙醇直接提取,高效液相色谱仪在波长280 nm和254 nm处连续测定饲料中维生素A、维生素D3和维生素E的方法.色谱柱为大连依利特Hypersil ODS C18(25 cm×4.6 mm×5 μm),流动相为甲醇-水,流速为1.2 mL/min.维生素A、维生素D3、维生素E的质量浓度分别在1.0 mg/L～20.0 mg/L、0.5 mg/L～15.0 mg/L 、2.5 mg/L～50.0 mg/L范围内与峰面积呈良好的线性关系,检测限分别为0.3×10-6 μg、0.04×10-6 μg、5.0×10-6 μg,相对标准偏差分别为1.6 %、2.7 %、2.4 %,平均回收率分别为99 %、102 %、98 %.     

丽水市空气中Pb污染调查

为调查丽水市空气中Pb污染现状，在机动车相对集中的市区布设5个测点，测点高度1．2m；监测周期为1a，每星期采样1d或2d，每天采集1个样，每次采样6h；监测项目为TSP、Pb；评价标准采用GB3095—1996《环境空气质量标准》。结果表明，丽水市各测点空气中Pb最大的季均值、年均值均未超标；常规测点和交通路口测点之间TSP、Pb质量浓度值均存在显著的差异性。     

Nitrous acid concentrations in homes and offices in residential areas in Greater Cairo

Indoor and outdoor measurements of nitrous acid and nitrogen dioxide were conducted at four homes and two offices in residential areas in Greater Cairo during winter (2000-2001) and summer (2001) seasons. Indoor nitrogen dioxide concentrations were higher than outdoor levels at the four homes, whereas indoor concentrations of nitrogen dioxide were lower than outdoor levels at the two offices, during both seasons. Indoor nitrous acid concentrations were higher than outdoor levels at all homes and offices during the period of study. The mean indoor nitrous acid concentrations were 6.8 ppb and 3.67 ppb in the four homes, whereas they were 1.42 ppb and 1.24 ppb in the two offices, during the winter and summer seasons, respectively. Indoor/outdoor ratios of nitrous acid concentration were 6.94 in the winter and 5.03 in the summer for all of the homes. However, the ratios were 1.31 and 1.61 during the winter and summer seasons, respectively, for the two offices. Insignificant positive correlation coefficients were found between indoor and outdoor concentrations of nitrous acid at homes and offices. The maximum outdoor nitrous acid concentrations were recorded during the winter season. Significant positive correlation coefficients were found between nitrous acid and nitrogen dioxide and relative humidity in homes and offices. The ratios of nitrous acid to nitrogen dioxide concentrations ranged from 0.045 to 0.16, with a mean of 0.1, in the four homes, whereas the ratios ranged from 0.026 to 0.09, with a mean of 0.059, in the two offices.