厌氧酸化水解-SBR工艺试验研究

针对化工废水难于处理的情况，文中简要介绍了厌氧酸化水解-SBR工艺和用高效复合微生物技术处理化工废水的厌氧酸化水解-SBR工艺。     

纺织印染废水的处理技术

印染废水的色度大，有机物含量高，可生化性差．针对上述特点，采用了厌氧水解酸化一生物接触氧化、气浮等工艺处理印染废水．结果表明，该工艺对印染废水有很好的处理效果，最终出水基本达到无色，达到纺织染整工业水污染物排放一级标准（GB4287-1992），处理成本较低．     

生物絮凝剂在啤酒废水处理中的应用实验

本文用生物絮凝剂处理可生化性的啤酒废水，对生物絮凝剂投加量、生物絮凝剂处理的适宜pH值、温度、金属离子影响等条件进行较系统的研究，绘制出单一因素对生物絮凝剂处理效果影响的曲线，确定生物絮凝剂处理啤酒废水的最适条件．经过5d处理，啤酒废水中COD去除率可达90．53％；污水中氨氮的去除率可达84．08％；絮凝率可达87．56％．     

投菌水解（酸化）—生物接触氧化—混凝法处理酵母生产废水

研究了采用投菌水解（酸化）－生物接触氧化－浊凝化处理酵母生产废水。试验结果表明，进水浓度控制在ＣＯＤＣｒ值５０００ｍｇ／Ｌ左右，生化系统可取得较高的处理效率；生经处理出水再以碱式 化铝为混凝剂，聚丙烯酰胺为助凝剂进行混凝处理，其出水ＣＯＤＣｒ值可控制在２００ｍｇ／Ｌ以下，并且可部分回流使用。     

造纸废水中硫化物的测定

我国造纸行业和一些环保部门,多年来一直采用醋酸锌—过滤—碘量法测定造纸废水中的硫化物。但测定值严重偏高。近年来一些环境监测部门以酸化吹气前处理代替沉淀—过滤前处理大大减小测定误差。但当废水中含有酸性条件下可挥发的还原物质如SO_2、R—SH、R—S—R等仍干扰碘量分析。SO_2浓度高于1毫克/升时将干扰比色分析。     

气浮-水解-SBR工艺处理高浓度香料废水的试验研究

试验研究了气浮-水解-SBR工艺对高浓度香料废水的处理效果以及生活污水投加方法对生化处理效果的改善，讨论了高浓度香料废水生物处理中的重要因素。     

水解酸化+CASS工艺处理半夏泡制废水工程应用

采用水解酸化+CASS工艺处理半夏泡制废水,工程运行结果表明,在进水COD、NH3-N、SS的质量浓度分别为1800～2200mg/L、60～80mg/L、500～800mg/L时,经该工艺处理后,废水中的COD、NH3-N和SS总去除率可分别达到97.7%、96.3%和95%以上,出水达到《污水综合排放标准》(GB8978-1996)表4一级标准限值。该工艺运行稳定、处理效果好,运行费用低。     

吹气—吸收法测定废水中硫化物

对吹气－吸收法测定废水中硫化物进行了吸收试验，提出了用去离子除氧水配制硫化物标液，可增加其稳定性；用ＩＳＯ硫化物吹脱器取代普通气吸收装置，可提高硫化物回收率。试验结果表明，改进后方法的精密度，准确度及适用怀强垃令人满意。     

松香废水处理技术及机理研究

为了解决松香废水对环境的污染问题，采用内电解-生物法-混凝沉淀法处理松香废水。结果表明，在内电解反应时间为10h、生物法停留时间为24h、混凝沉淀法选用混凝剂为聚合硫酸铁、最佳投药量为200mg／L时，出水COD〈70mg／L，达到污水综合排放标准的一级排放标准。废水经过内电解处理后可生化性明显提高，对其机理进行研究发现，除特别难处理的高分子物质外，其他物质均能得到很好的处理。     

GC/FTIR-FID测定石化废水中挥发性有机物

所述石化废水中挥发性有机物分析方法 ,以 GC分离 ,FTIR定性 ,FID定量。水样前处理采用大吹脱体积 ,两级捕集的吹脱捕集技术。为解决剖析分析无标样定量问题 ,成功地实现了 GC/FTIR-FID匹配联机 ,使得未知组分定性定量一次完成。方法变异系数低于 5% ,回收率高于 90 % ,最低检出浓度可达 0 .0 0 5mg/L     

An investigation on biological stability of product water generated by lab-scale and pilot-scale distillation systems

Material Disposal Area G is the primary low-levelradioactive waste disposal site at Los Alamos NationalLaboratory, New Mexico, and is adjacent to Pueblo of SanIldefonso lands. Pueblo residents and Los Alamos scientists areconcerned about radiological doses resulting from uptake of AreaG radionuclides by mule deer (Odocoileus hemionus) andRocky Mountain elk (Cervus elaphus), then consumption ofdeer and elk meat by humans. Tissue samples were collected fromdeer and elk accidentally killed near Area G and were analyzedfor ³H, ⁹⁰Sr, total U, ²³⁸Pu, ^{239, 240}Pu,²⁴¹Am, and ¹³⁷Cs. These data were used to estimatehuman doses based on meat consumption of 23 kg y^-1. Humandoses were also modeled using RESRAD, and dose rates to deer andelk were estimated with a screening model. Dose estimates tohumans from tissue consumption were 2.9 × 10^-3 mSv y^-1and 1.6 × 10^-3 mSv y^-1 from deer and elk, respectively,and RESRAD dose estimates were of the same order of magnitude. Estimated dose rates to deer and elk were 2.1 × 10^-4 mGyd^-1 and 4.7 × 10^-4 mGy d^-1, respectively. Allestimated doses were significantly less than established exposurelimits or guidelines.     

Metal concentrations in deciduous tree leaves from urban areas in Poland

Accumulation of metals in deciduous tree foliage fromurban areas in western-south Poland was monitored duringthe vegetation season of 2000 year. Concentrations of Al,Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Sr, Ti and Znwere measured in birch, willow, linden and maple leavesusing the ICP-AES method. Seasonal variations of metalconcentrations and their relations with sampling sitewere investigated. The most dynamic accumulation of Al,Cd, Cr, Ni and Pb was observed for examined species. Thehighest differences in element concentrations forinvestigated sites were found for Ba, Cd, Mn and Ni.Interelement correlations were investigated. In allfoliar samples synergistic relationships between Al–Crand Ca-Sr were found. Statistically significant negativecorrelations were observed only for Cd and Ti in birch leaves.     

Varying Stable Nitrogen Isotope Ratios of Different Coastal Marsh Plants and Their Relationships with Wastewater Nitrogen and Land Use in New England, USA

The stable nitrogen isotope ratios of some biota have been used as indicators of sources of anthropogenic nitrogen. In this study the relationships of the stable nitrogen isotope ratios of marsh plants, Iva frutescens (L.), Phragmites australis (Cav.) Trin ex Steud, Spartina patens (Ait.) Muhl, Spartina alterniflora Loisel, Ulva lactuca (L.), and Enteromorpha intestinalis (L.) with wastewater nitrogen and land development in New England are described. Five of the six plant species (all but U. lactuca) showed significant relationships of increasing δ ¹⁵N values with increasing wastewater nitrogen. There was a significant (P < 0.0001) downward shift in the δ ¹⁵N of S. patens (6.0 ± 0.48‰) which is mycorrhizal compared with S. alterniflora (8.5 ± 0.41‰). The downward shift in δ ¹⁵N may be caused by the assimilation of fixed nitrogen in the roots of S. patens. P. australis within sites had wide ranges of δ ¹⁵N values, evidently influenced by the type of shoreline development or buffer at the upland border. In residential areas, the presence of a vegetated buffer (n = 24 locations) significantly (P < 0.001) reduced the δ ¹⁵N (mean = 7.4 ± 0.43‰) of the P. australis compared to stands where there was no buffer (mean = 10.9 ± 1.0‰; n = 15). Among the plant species, I. frutescens located near the upland border showed the most significant (R ² = 0.64; P = 0.006) inverse relationship with the percent agricultural land in the watershed. The δ ¹⁵N of P. australis and I. frustescens is apparently an indicator of local inputs near the upland border, while the δ ¹⁵N of Spartina relates with the integrated, watershed-sea nitrogen inputs.     

Effect of heavy metal contaminated shooting range soils on mycorrhizal colonization of roots and metal uptake by leek

We grew leek (Allium porrum) in soils of two shooting ranges heavily contaminated with heavy metals in the towns of Zuchwil and Oberuzwil in Switzerland as a bioassay to test theactivity of arbuscular mycorrhizal (AM) fungi in these soils.Soil samples were taken from (1) front of the shooting house(HOUSE), (2) the area between house and target (FIELD) and (3) the berm (BACKSTOP). Samples of Ribwort plantain (Plantagolanceolata) growing naturally within the shooting ranges werealso collected and the colonization of its roots by mycorrhizalfungi was measured. The number of AM spores in the soils wassignificantly reduced concomitant with the increase in thedegree of soil contamination with metals. In Zuchwil,mycorrhizal fungi equally colonized roots of Ribwort plantainsampled from BACKSTOP and HOUSE. In Oberuzwil, however, plantsfrom BACKSTOP had lower colonization when compared with thosesampled from HOUSE. Colonization of leek was strongly reducedin the BACKSTOP soil of Zuchwil and slightly reduced in theBACKSTOP soil of Oberuzwil when compared with plants grown inrespective HOUSE soil. Concentrations of Cd, Cr, Cu, Ni, Pb andZn in the leaves of leek grown in the BACKSTOP soil was withinthe range considered toxic for human consumption. This pointsto the high degree of bio-availability of these metal in thesesoils. Significant decrease in the number of mycorrhizal sporesin the BACKSTOP soils in Zuchwil and the low colonization ofleek roots grown in these soils point to possible changes inthe species diversity of mycorrhizal fungi in these soils.     

Radionuclide Concentrations in Benthic Invertebrates from Amchitka and Kiska Islands in the Aleutian Chain, Alaska

Concentrations of 13 radionuclides (¹³⁷Cs, ¹²⁹I, ⁶⁰Co, ¹⁵²Eu, ⁹⁰Sr, ⁹⁹Tc, ²⁴¹Am, ²³⁸Pu, ^239,249Pu, ²³⁴U, ²³⁵U, ²³⁶U, ²³⁸U were examined in seven species of invertebrates from Amchitka and Kiska Islands, in the Aleutian Chain of Alaska, using gamma spectroscopy, inductively coupled plasma mass spectroscopy, and alpha spectroscopy. Amchitka Island was the site of three underground nuclear test (1965–1971), and we tested the null hypotheses that there were no differences in radionuclide concentrations between Amchitka and the reference site (Kiska) and there were no differences among species. The only radionuclides where composite samples were above the Minimum Detectable Activity (MDA) were ¹³⁷Cs, ²⁴¹Am, ^239,249Pu, ²³⁴U, ²³⁵U, ²³⁶U, and ²³⁸U. Green sea urchin (Strongylocentrotus polyacanthus), giant chiton (Cryptochiton stelleri), plate limpets (Tectura scutum) and giant Pacific octopus (Enteroctopus dofleini) were only tested for ¹³⁷Cs; octopus was the only species with detectable levels of ¹³⁷Cs (0.262 ± 0.029 Bq/kg, wet weight). Only rock jingle (Pododesmus macroschisma), blue mussel (Mytilus trossulus) and horse mussel (Modiolus modiolus) were analyzed for the actinides. There were no interspecific differences in ²⁴¹Am and ^239,240Pu, and almost no samples above the MDA for ²³⁸Pu and ²³⁶U. Horse mussels had significantly higher concentrations of ²³⁴U (0.844 ± 0.804 Bq/kg) and ²³⁸U (0.730 ± 0.646) than the other species (both isotopes are naturally occurring). There were no differences in actinide concentrations between Amchitka and Kiska. In general, radionuclides in invertebrates from Amchitka were similar to those from uncontaminated sites in the Northern Hemisphere, and below those from the contaminated Irish Sea. There is a clear research need for authors to report the concentrations of radionuclides by species, rather than simply as ‘shellfish’, for comparative purposes in determining geographical patterns, understanding possible effects, and for estimating risk to humans from consuming different biota.     

Kelp as a Bioindicator: Does it Matter Which Part of 5 M Long Plant is Used for Metal Analysis?

Kelp may be useful as a bioindicator because they are primary producers that are eaten by higher trophic level organisms, including people and livestock. Often when kelp or other algae species are used as bioindicators, the whole organism is homogenized. However, some kelp can be over 25 m long from their holdfast to the tip of the blade, making it important to understand how contaminant levels vary throughout the plant. We compared the levels of arsenic, cadmium, chromium, lead, manganese, mercury and selenium in five different parts of the kelp Alaria nana to examine the variability of metal distribution. To be useful as a bioindicator, it is critical to know whether levels are constant throughout the kelp, or which part is the highest accumulator. Kelp were collected on Adak Island in the Aleutian Chain of Alaska from the Adak Harbor and Clam Cove, which opens onto the Bering Sea. In addition to determining if the levels differ in different parts of the kelp, we wanted to determine whether there were locational or size-related differences. Regression models indicated that between 14% and 43% of the variation in the levels of arsenic, cadmium, chromium, manganese, mercury, and selenium was explained by total length, part of the plant, and location (but not for lead). The main contributors to variability were length (for arsenic and selenium), location (mercury), and part of the plant (for arsenic, cadmium, chromium and manganese). The higher levels of selenium occurred at Clam Cove, while mercury was higher at the harbor. Where there was a significant difference among parts, the holdfast had the highest levels, although the differences were not great. These data indicate that consistency should be applied in selecting the part of kelp (and the length) to be used as a bioindicator. While any part of Alaria could be collected for some metals, for arsenic, cadmium, chromium, and manganese a conversion should be made among parts. In the Aleutians the holdfast can be perennial while the blade, whipped to pieces by winter wave action, is regrown each year. Thus the holdfast may be used for longer-term exposure for arsenic, cadmium, chromium and manganese, while the blade can be used for short-term exposure for all metals. Cadmium, lead and selenium were at levels that suggest that predators, including people, may be at risk from consuming Alaria. More attention should be devoted to heavy metal levels in kelp and other algae from Adak, particularly where they may play a role in a subsistence diets.     

Assessing Potential for Recovery of Biotic Richness and Indicator Species due to Changes in Acidic Deposition and Lake ph in Five Areas of Southeastern Canada

Biological damage to sensitive aquatic ecosystems is among the most recognisable, deleterious effects of acidic deposition. We compiled a large spatial database of over 2000 waterbodies across southeastern Canada from various federal, provincial and academic sources. Data for zooplankton, fish, macroinvertebrate (benthos) and loon species richness and occurrence were used to construct statistical models for lakes with varying pH, dissolved organic carbon content and lake size. pH changes, as described and predicted using the Integrated Assessment Model (Lam et al., 1998; Jeffries et al., 2000), were based on the range of emission reductions set forth in the Canada/US Air Quality Agreement (AQA). The scenarios tested include 1983, 1990, 1994 and 2010 sulphate deposition levels. Biotic models were developed for five regions in southeastern Canada (Algoma, Muskoka, and Sudbury, Ontario, southcentral Québec, and Kejimkujik, Nova Scotia) using regression tree, multiple linear regression and logistic regression analyses to make predictions about recovery after emission reductions. The analyses produced different indicator species in different regions, although some species showed consistent trends across regions. Generally, the greatest predicted recovery occurred during the final phase of emission reductions between 1994 and 2010 across all taxonomic groups and regions. The Ontario regions, on average, were predicted to recover to a greater extent than either southcentral Québec or the Kejimkujik area of Nova Scotia. Our results reconfirm that pH 5.5–6.0 is an important threshold below which damage to aquatic biota will remain a major local and regional environmental problem. This damage to biodiversity across trophic levels will persist well into the future if no further reductions in sulphate deposition are implemented.     

Nitrogen Content of Letharia vulpina Tissue from Forests of the Sierra Nevada, California: Geographic Patterns and Relationships to Ammonia Estimates and Climate

Nitrogen (N) pollution is a growing concern in forests of the greater Sierra Nevada, which lie downwind of the highly populated and agricultural Central Valley. Nitrogen content of Letharia vulpina tissue was analyzed from 38 sites using total Kjeldahl analysis to provide a preliminary assessment of N deposition patterns. Collections were co-located with plots where epiphytic macrolichen communities are used for estimating ammonia (NH₃) deposition. Tissue N ranged from 0.6% to 2.11% with the highest values occurring in the southwestern Sierra Nevada (range: 1.38 to 2.11). Tissue N at 17 plots was elevated, as defined by a threshold concentration of 1.03%. Stepwise regression was used to determine the best predictors of tissue N from among a variety of environmental variables. The best model consisted only of longitude (r ² = 0.64), which was reflected in the geographic distribution of tissue values: the southwestern Sierra Nevada, the high Sierras near the Tahoe Basin, and the Modoc Plateau, are three apparent N hotspots arranged along the tilted north–south axis of the study area. Withholding longitude and latitude, the best regression model suggested that NH₃ estimates and annual number of wetdays interactively affect N accumulation (r ² = 0.61; % N ∼ NH₃ + wetdays + (NH₃ × wetdays)). We did not expect perfect correspondence between tissue values and NH₃ estimates since other N pollutants also accumulate in the lichen thallus. Additionally, other factors potentially affecting N content, such as growth rate and leaching, were not given full account.     

Spatial Relationships Between Water Quality and Pesticide Application Rates in Agricultural Watersheds

Pesticide applications to agricultural lands in California, USA, are reported to a central data base, while data on water and sediment quality are collected by a number of monitoring programs. Data from both sources are geo-referenced, allowing spatial analysis of relationships between pesticide application rates and the chemical and biological condition of water bodies. This study collected data from 12 watersheds, selected to represent a range of pesticide usage. Water quality parameters were measured during six surveys of stream sites receiving runoff from the selected watershed areas. This study had three objectives: to evaluate the usefulness of pesticide application data in selecting regional monitoring sites, to provide information for generating and testing hypotheses about pesticide fate and effects, and to determine whether in-stream nitrate concentration was a useful surrogate indicator for regional monitoring of toxic substances. Significant correlations were observed between pesticide application rates and in-stream pesticide concentrations (p < 0.05) and toxicity (p < 0.10). In-stream nitrate concentrations were not significantly correlated with either the amount of pesticides applied, in-stream pesticide concentrations, or in-stream toxicity (all p > 0.30). Neither total watershed area nor the area in which pesticide usage was reported correlated significantly with the amount of pesticides applied, in-stream pesticide concentrations, or in-stream toxicity (all p > 0.14). In-stream pesticide concentrations and effects were more closely related to the intensity of pesticide use than to the area under cultivation.     

Heavy Metals and Selenium in Herring Gulls (LARUS ARGENTATUS) NESTING IN COLONIES FROM EASTERN LONG ISLAND TO VIRGINIA

With increasing interest in assessing the health or well-being ofcommunities and ecosystems, birds are being used asbioindicators. Coloniallynesting species breed mainly in coastal areas that are alsopreferred for humandevelopment, exposing the birds to various pollutants. Inthis paper concentrations of heavy metal and selenium in the feathers ofHerring Gulls(Larus argentatus) nesting in several colonies fromMassachusetts toDelaware are reported. There were significant differencesamong colonies forall metals, with metal concentrations being two to nearly fivetimes higher atsome colonies than others. Selenium showed the leastdifference, and cadmium showed the greatest difference among sites. Concentrations of lead werehighest at Pralls Island; mercury was highest at Shinnecock,Huckleberry andHarvey, and manganese was highest at Captree.