基于BP神经网络的齐齐哈尔地区地下水水质评价

阐述了人工神经网络基本原理,介绍了BP网络的地下水水质评价模型.在传统的评价方法基础上,根据各评价因子对环境和人类影响程度不同,给水质监测指标分组,从实用角度对水质进行评价.与传统评价方法相比,该评价模型在某评价因子数值极大的情况下,也能准确反映地下水的污染情况,并且通过GIS技术利用评价结果得到地下水水质分布图,从空间反映地下水水质变化规律.     

Time Series Analysis to Monitor and Assess Water Resources: A Moving Average Approach

An understanding of the behavior of the groundwater body and its long-term trends are essential for making any management decision in a given watershed. Geostatistical methods can effectively be used to derive the long-term trends of the groundwater body. Here an attempt has been made to find out the long-term trends of the water table fluctuations of a river basin through a time series approach. The method was found to be useful for demarcating the zones of discharge and of recharge of an aquifer. The recharge of the aquifer is attributed to the return flow from applied irrigation. In the study area, farmers mainly depend on borewells for water and water is pumped from the deep aquifer indiscriminately. The recharge of the shallow aquifer implies excessive pumping of the deep aquifer. Necessary steps have to be taken immediately at appropriate levels to control the irrational pumping of deep aquifer groundwater, which is needed as a future water source. The study emphasizes the use of geostatistics for the better management of water resources and sustainable development of the area.     

Hydrogeochemistry and Groundwater Quality Assessment of Lower Part of the Ponnaiyar River Basin, Cuddalore District, South India

The Lower Ponnaiyar River Basin forms an important groundwater province in South India constituted by Tertiary formations dominated by sandstones and overlain by alluvium. The region enjoyed artesian conditions 50 years back but at present frequent failure of monsoon and over exploitation is threatening the aquifer. Further, extensive agricultural and industrial activities and urbanization has resulted in the increase in demand and contamination of the aquifer. To identify the sources and quality of groundwater, water samples from 47 bore wells were collected in an area of 154 km² and were analysed for major ions and trace metals. The results reveal that the groundwater in many places is contaminated by higher concentrations of NO₃, Cl, PO₄ and Fe. Four major hydrochemical facies Ca–Mg–Cl, Na–Cl, Ca–HCO₃ and Na–HCO₃ were identified using Piper trilinear diagram. Salinity, sodium adsorption ratio, and sodium percentage indicate that most of the groundwater samples are not suitable for irrigation as well as for domestic purposes and far from drinking water standards. The most serious pollution threat to groundwater is from nitrate ions, which are associated with sewage and fertilizers application. The present state of the quality of the lower part of Ponnaiyar River Basin is of great concern and the higher concentration of toxic metals (Fe and Ni) may entail various health hazards.     

Assessment of groundwater vulnerability in the Yinchuan Plain,Northwest China using OREADIC

Groundwater vulnerability assessments provide a measure of the sensitivity of groundwater quality to an imposed contaminant load and are globally recognized as an essential element of all aquifer management and protection plans. In this paper, the vulnerability of groundwaters underlying the Yinchuan Plain of Northwest China is determined using OREADIC, a GIS-based assessment tool that incorporates the key characteristics of the universally popular DRASTIC approach to vulnerability assessment but has been modified to consider important additional hydrogeological factors that are specific to the region. The results show that areas of high vulnerability are distributed mainly around Qingtongxia City, Wuzhong City, Lingwu City, and Yongning County and are associated with high rates of aquifer recharge, shallow depths to the water table, and highly permeable aquifer materials. The presence of elevated NO₃⁻ in the high vulnerability areas endorses the OREADIC approach. The vulnerability maps developed in this study have become valuable tools for environmental planning in the region and will be used for predictive management of the groundwater resource.     

A novel high-frequency groundwater quality monitoring system

High-frequency, long-term monitoring of water quality has revolutionized the study of surface waters in recent years. However, application of these techniques to groundwater has been limited by the ability to remotely pump and analyze groundwater. This paper describes a novel autonomous groundwater quality monitoring system which samples multiple wells to evaluate temporal changes and identify trends in groundwater chemistry. The system, deployed near Fresno, California, USA, collects and transmits high-frequency data, including water temperature, specific conductance, pH, dissolved oxygen, and nitrate, from supply and monitoring wells, in real-time. The system consists of a water quality sonde and optical nitrate sensor, manifold, submersible three-phase pump, variable frequency drive, data collection platform, solar panels, and rechargeable battery bank. The manifold directs water from three wells to a single set of sensors, thereby reducing setup and operation costs associated with multi-sensor networks. Sampling multiple wells at high frequency for several years provided a means of monitoring the vertical distribution and transport of solutes in the aquifer. Initial results show short period variability of nitrate, specific conductivity, and dissolved oxygen in the shallow aquifer, while the deeper portion of the aquifer remains unchanged—observations that may be missed with traditional discrete sampling approaches. In this aquifer system, nitrate and specific conductance are increasing in the shallow aquifer, while invariant changes in deep groundwater chemistry likely reflect relatively slow groundwater flow. In contrast, systems with high groundwater velocity, such as karst aquifers, have been shown to exhibit higher-frequency groundwater chemistry changes. The stability of the deeper aquifer over the monitoring period was leveraged to develop estimates of measurement system uncertainty, which were typically lower than the manufacturer’s stated specifications, enabling the identification of subtle variability in water chemistry that may have otherwise been missed.     

A probabilistic methodology to assess the risk of groundwater quality degradation

An approach to assess the risk of groundwater quality degradation with regard to fixed standards, based on DisjunctiveKriging (DK) is presented. The DK allows one to evaluate the Conditional Probability (CP) of overriding a given threshold of concentration of a pollutant at a given time, and at a generic point in a consideredgroundwater system. The result of such investigation over the considered area can be plotted in form of maps of spatial risk. By repeating this analysis at different times, severalspatial riskmaps will be produced, one for each consideredtime. By means of non-parametric statistics, the temporal trendof the CPs can be evaluated at every point of the considered area. The trend index, assessed by means of a sort of classification of the trend values obtained as described above,can be superimposed on the most recent values of the spatialrisk (i.e.: the most recent values of probability). Consequentlya classification of the risk of groundwater quality degradationresults with which to weigh both the spatial distribution and thetemporal behaviour of the probability to exceed a given standardthreshold. The methodology has been applied to values of nitrateconcentration sampled in the monitoring well network of theModena plain, northern Italy. This area is characterised by intensive agricultural exploitation and hog breeding along withindustrial and civil developments. The influence of agriculture on groundwater results in a high nitrate pollution that limitsits use for potable purposes.     

A groundwater flow model for water resources management in the Ismarida plain,North Greece

This paper presents the development of a regional flow simulation model of the stream–aquifer system of Ismarida plain, northeastern Greece. It quantifies the water budget for this aquifer system and describes the components of groundwater and the characteristics of this system on the basis of results of a 3-year field study. The semiconfined aquifer system of Ismarida Lake plain consists of unconsolidated deltaic clastic sediments, is hydraulically connected with Vosvozis River, and covers an area of 46.75 km². The annual precipitation ranges in the study area from 270 to 876 mm. Eighty-seven irrigation wells are densely located and have been widely used for agricultural development. Groundwater flow in this aquifer was simulated with MODFLOW. Model calibration was done with observed water levels, and match was excellent. To evaluate the impacts of the current pumping schedule and propose solutions, four management scenarios were formulated and tested with the model. Based on model results, the simulated groundwater budget indicates that there must be approximately 33% decrease of withdrawals to stop the dramatic decline of groundwater levels. The application of these scenarios shows that aquifer discharge to the nearby river would be very low after a 20-year period.     

Major ion chemistry of shallow groundwater of a fast growing city of Central India

Nagpur City located in semiarid area of central India is a fast-growing industrial centre. In recent years, rapid development has created an increased demand for drinking water, which is increasingly being fulfilled by groundwater abstraction. The present study was undertaken to assess major ion chemistry of shallow groundwater to understand geochemical evolution of groundwater and water quality for promoting sustainable development and effective management of groundwater resources. A total of 47 water samples were collected from shallow aquifer of selected parts of the city and the water chemistry of various ions viz. Ca^2 +, Mg^2 +, Na⁺, K⁺, CO₃  ^2-_{3}^{\ \, 2-}, HCO₃  ^-_{3}^{\ \, -}, Cl⁻, SO₄  ^2-_{4}^{\ \,2-} and NO₃  ^-_{3}^{\ \,-} are carried out. The chemical relationships in Piper diagram identify Ca–HCO₃–Cl and mixed Ca–Na–HCO₃–Cl as most prevalent water types. Alkaline earth exceeds alkalis and weak acids exceed strong acids. Ionic ratios and Gibb’s diagram suggest that silicate rock weathering and anthropogenic activities are the main processes that determine the ionic composition in the study area. The nitrate appeared as a major problem of safe drinking water in this region. We recorded highest nitrate concentration, i.e., 411 mg/l in one of the dug well. A comparison of groundwater quality in relation to drinking water quality standards revealed that about half of the shallow aquifer samples are not suitable for drinking.     

南宁市城市内河黑臭分级综合评价研究

为有效避免南宁市城市内河水质出现仅透明度超标导致黑臭等级误判的情况,通过相关性分析、方差分析和多重对应分析确定评价指标和临界值,建立基于综合水质指数法的城市内河黑臭分级评价方法。结果表明:以溶解氧、氨氮、总磷和化学需氧量为黑臭分级评价指标,水体轻度黑臭和重度黑臭综合水质指数临界值分别为6.3和8.5。该评价方法结果符合实际情况,且能反映水质的时空变化情况。     

Speciative determination of Cr (III) and Cr (VI) in dyeing waste water of Dil Creek discharge to Izmit Gulf (Izmit-Kocaeli, Turkey) by ICP-AES

Wastewater pollution in industrial areas is one of the most important environmental problems. Heavy metal pollution, especially chromium pollution in wastewater sources from dyeing and tannery has affected the life on earth. This pollution can affect all ecosystems and human health directly or by food chain. Therefore, the determination of chromium in this study is of great importance. Dil Creek is located in the eastern Marmara region and discharges into the Izmit Gulf. This water source is used for irrigation in agriculture and as drinking water for animals. In this study, a rapid, sensitive and selective method for the speciative direct determination of Cr (III) and Cr (VI) in dyeing waste water samples collected from the nearest station to Izmit Gulf of Dil Creek in May 2006 by inductively coupled plasma-atomic emission spectrometry (ICP-AES) has been developed. An analysis of a given sample is completed in about 15 min for ICP-AES the method. As the result of the chromium analysis, the limit of quantification (LOQ) for the Cr (III), Cr (VI) and total Cr were founded as 0.0111 ± 0.0002 mg/l (RSD, 1.80%), 0.0592 ± 0.0010 mg/l (RSD, 1.70%) and 0.0703 ± 0.0020 mg/l (RSD, 2.84%) respectively. In addition, the general mathematical formula has been developed to calculate the concentration of Cr(III), which can be applied to any other metal species. The result of Cr (VI) analysis indicated that water quality of Creek was IV. class quality according to the inland water classification. In order to validate the applied method, recovery studies were performed.     

Hydro-chemical Survey of Groundwater of Hisar City and Assessment of Defluoridation Methods Used in India

Ground water quality of Hisar city was assessed for its suitability for drinking purposes. Samples collected from the Bore-wells (forms a part of municipal water supply) and handpumps (direct consumption) were analyzed for the various physico-chemical parameters including pH, electrical conductivity, total dissolved salts, total hardness, total alkalinity, sodium, potassium, calcium, magnesium, carbonate, bicarbonate, chloride and sulfate. The concentrations of magnesium, sodium, potassium, sulfate and especially of chloride were found moderately higher than the WHO standards for the drinking water. Further a comparison of fluoride (F⁻) levels in groundwater of various cities and towns of Haryana state was performed. The relatively higher concentrations of F⁻ in groundwater of Haryana raise the risk of fluorosis and hence groundwater must be used with proper treatment. Promising defluoridation methods using locally available materials and technologies are discussed for the prevention and control of fluorosis. Data were assessed statistically to find the suitable markers of ground water quality as an aid to monitoring groundwater quality.     

Response of groundwater to climate variation: fluctuations of groundwater level and well yields in the Halacli aquifer (Cankiri, Turkey)

The aim of this study was to investigate the response of groundwater level and well yields in the Halacli aquifer to climate variations in Central Anatolia, Turkey. The Halacli aquifer is a typical aquifer due to its vulnerability to the climate variations. The aquifer is shallow and its recharge area is small. The waters from rains and snow melts can rapidly infiltrate down to the groundwater body because the vadose zone is thin and formed from coarse material. Therefore, the groundwater system responds to the short-term recharges by raising its level. Although any exploitation did not occur, the groundwater levels have declined from 1989 to 1997. However, the groundwater levels began rising when the exploitation started in the summer of 1998. After the year 2000, although the amount and duration of yearly exploitation was constant, fluctuations of water level continued. Fluctuation of groundwater levels and well yields bewilders the water users and imperils the sustainable water management in the study area and also in arid and semi-arid regions of Turkey. In order to overcome this problem, behavior of groundwater level and discharges of the wells must be recorded and the water users must be informed about the current conditions and the possible trend in the future of the system.     

Quantity and quality management of groundwater: An application to irrigated agriculture in Iraklion,Crete

A quantity-quality problem in which pollution generates production externalities is analyzed empirically. Water is pumped by farmers from a common access aquifer, and deep percolation resulting from the irrigation causes accumulation of pollutants in the aquifer. Pollution negatively affects the production of the agricultural output through the deterioration of the groundwater quality. By comparing the cooperative with the noncooperative solution, an optimal policy scheme in the form of water taxes is determined. The scheme induces farmers acting noncooperatively to follow policies that correspond to the regulator's optimum. The model is applied to the case of groundwater management in the Iraklio prefecture of Crete. Agricultural production functions are estimated using an externality variable as explanatory variable. An optimal control model that corresponds to the cooperative solution is solved using multiple shooting methods. Paths for water stock, salinity stock, and water use at the regulator's optimum are derived. The optimal water tax is calculated in the final stage.     

Leachate Characterization and Assessment of Groundwater Pollution Near Municipal Solid Waste Landfill Site

Leachate and groundwater samples were collected from Gazipur landfill-site and its adjacent area to study the possible impact of leachate percolation on groundwater quality. Concentration of various physico-chemical parameters including heavy metal (Cd, Cr, Cu, Fe, Ni, Pb and Zn) and microbiological parameters (total coliform (TC) and faecal coliform (FC)) were determined in groundwater and leachate samples. The moderately high concentrations of Cl⁻, NO⁻ ₃, SO²⁻ ₄, NH⁺ ₄, Phenol, Fe, Zn and COD in groundwater, likely indicate that groundwater quality is being significantly affected by leachate percolation. Further they proved to be as tracers for groundwater contamination. The effect of depth and distance of the well from the pollution source was also investigated. The presence of TC and FC in groundwater warns for the groundwater quality and thus renders the associated aquifer unreliable for domestic water supply and other uses. Although some remedial measures are suggested to reduce further groundwater contamination via leachate percolation, the present study demand for the proper management of waste in Delhi.     

Quality of Shallow Groundwater and Drainage Water in Irrigated Agricultural Lands in A Mediterranean Coastal Region of Turkey

Spatial and seasonal differences in water quality of drainage water and unconfined shallow groundwater were related to irrigation in Samandağ, a Mediterranean coastal region. Eighteen wells, seven drainage points and Orontes River were monitored bimonthly for one year for analyses of electrical conductivity (EC), total dissolved solids (TDS), sodium adsorption ratio (SAR), cations (Na, K, Ca + Mg) and anions (CO₃, HCO₃, Cl and SO₄). Agricultural irrigation using saline groundwater decreased water quality of Orontes River during the irrigation season (May to September) more than during the non-irrigation season (October to April). Seasonal fluctuations in water quality of shallow groundwater were greater during the irrigation season than the non-irrigation season in the study area. Excessive use of groundwater resulted in a decline in the water table levels in the irrigation season. Water table level rose up to the soil surface in areas where there was a lack of drainage or poor drainage, due to the impact of precipitation in the winter. SAR and pH values of drainage water increased in the irrigation season, while the other properties of drainage water decreased. Irrigation water quality of Orontes River was classified as C₃S₁ in both seasons. Irrigation water quality of shallow groundwater and drainage water varied from C₂S₁ to C₄S₂ in one year. Drainage and well waters were found to be different on yearly basis in terms of Na, SAR (p<0.01) and Ca + Mg concentrations (p<0.001). Ca + Mg concentrations for both sources were different for all sampling dates (p<0.001).     

Groundwater quality assessment in semi-arid regions using integrated approaches: the case of Grombalia aquifer (NE Tunisia)

As many arid and semi-arid regions in the Mediterranean Basin, the Grombalia coastal aquifer (NE Tunisia) is affected by severe groundwater exploitation and contamination. Therefore, quality assessments are becoming increasingly important as the long-term protection of water resources is at stake. Multidisciplinary investigations, like the one presented in this paper, are particularly effective in identifying the different origins of mineralization within an aquifer and investigating the impact of anthropogenic activities on groundwater quality. An integrated assessment, focused on the combined use of geostatistical, geochemical and isotopic (δ¹⁸O, δ²H and ³H) tools, was performed in the Grombalia aquifer between February and March 2014. The overall goal was to study the main processes controlling aquifer salinization, with special focus to nitrate contamination. Results indicate a persisting deterioration of water quality over the whole basin except the south-eastern zone juxtaposing the recharge area of the aquifer. Nitrate contents exceed the drinking water standard (50 mg/l) in 70% of groundwater samples, mainly due to the excessive use of fertilizers and urban activities. Stable isotope measurements showed the contribution of modern rainwater to aquifer recharge and proved the presence of evaporation contributing to the salinity increase. Tritium values of groundwater samples suggested two hypotheses: the existence of mixture between old and recent water or/and the existence of two recharge periods of the aquifer, pre- and post-nuclear weapons test. Principal component analysis confirmed the geochemical interpretation, highlighting that water-rock interaction evaporation effect and intensive anthropogenic activities constitute the main processes controlling the regional groundwater mineralization.     

丹江口水库湖北库区水质分区及长期变化趋势

丹江口水库是南水北调中线工程水源地,准确地掌握丹江口水库水环境质量状况变化情况,对保障调水工程顺利进行有着极其重要的意义。基于水质理化指标将丹江口水库湖北库区水域划分为4个区,各分区的主要物理指标存在显著差异,化学指标较为均一;近10年水质历史监测数据显示,湖北库区除总氮指标外,其余监测指标水质类别均达到或优于Ⅱ类,总体水质保持优良;氨氮、总磷、总氮3项指标年均浓度从2007年起呈增加趋势,在2011年后均有所降低并趋于稳定。农业面源污染对丹江口水库水质影响较大。目前采取的各项环保措施对丹江口水库的水质产生了积极的影响,需继续加大各项治理措施的实施力度,完善水质监测系统,保障丹江口水库水质安全。     

MONITORING OF SPATIAL AND TEMPORAL HYDROCHEMICAL CHANGES IN GROUNDWATER UNDER THE CONTAMINATING EFFECTS OF ANTHROPOGENIC ACTIVITIES IN MERSIN REGION, TURKEY

The development of groundwater resources for water supply is a favored way in Turkey. The Berdan alluvial aquifer in Mersin is particularly productive, but little is known about the natural phenomena that govern the groundwater quality and the contamination sources in this region. During 2001 and 2002, water samples for chemical analysis were obtained from 27 wells and from two points of Berdan River and analyzed by ICP. Main chemical characteristics of sampled groundwater define two aquifers, which were also determined by hydrogeological investigations. The groundwater produced from some of the wells was affected by anthropogenic activities temporally and spatially by seawater intrusion. Berdan River is polluted with the wastewater discharges and river water also influences the groundwater quality.     

Integrating geospatial and ground geophysical information as guidelines for groundwater potential zones in hard rock terrains of south India

The increasing demand of water has brought tremendous pressure on groundwater resources in the regions were groundwater is prime source of water. The objective of this study was to explore groundwater potential zones in Maheshwaram watershed of Andhra Pradesh, India with semi-arid climatic condition and hard rock granitic terrain. GIS-based modelling was used to integrate remote sensing and geophysical data to delineate groundwater potential zones. In the present study, Indian Remote Sensing RESOURCESAT-1, Linear Imaging Self-Scanner (LISS-4) digital data, ASTER digital elevation model and vertical electrical sounding data along with other data sets were analysed to generate various thematic maps, viz., geomorphology, land use/land cover, geology, lineament density, soil, drainage density, slope, aquifer resistivity and aquifer thickness. Based on this integrated approach, the groundwater availability in the watershed was classified into four categories, viz. very good, good, moderate and poor. The results reveal that the modelling assessment method proposed in this study is an effective tool for deciphering groundwater potential zones for proper planning and management of groundwater resources in diverse hydrogeological terrains.     

Fluoride in groundwater, Varaha River Basin, Visakhapatnam District, Andhra Pradesh, India

Excess intake of fluoride through drinking water causes fluorosis on human beings in many States of the country (India), including Andhra Pradesh. Groundwater quality in the Varaha River Basin located in the Visakhapatnam District of Andhra Pradesh has been studied, with reference to fluoride content, for its possible sources for implementing appropriate management measures, according to the controlling mechanism of fluoride concentration in the groundwater. The area occupied by the river basin is underlain by the Precambrian Eastern Ghats, over which the Recent sediments occur. Results of the chemical data of the groundwater suggest that the considerable number of groundwater samples show fluoride content greater than that of the safe limit prescribed for drinking purpose. Statistical analysis shows that the fluoride has a good positive relation, with pH and bicarbonate. This indicates an alkaline environment, as a dominant controlling mechanism for leaching of fluoride from the source material. Other supplementary factors responsible for the occurrence of fluoride in the groundwater are evapotranspiration, long contact time of water with the aquifer material, and agricultural fertilizers. A lack of correlation between fluoride and chloride, and a high positive correlation between fluoride and bicarbonate indicate recharge of the aquifer by the river water. However, the higher concentration of fluoride observed in the groundwater in some locations indicates insufficient dilution by the river water. That means the natural dilution did not perform more effectively. Hence, the study emphasizes the need for surface water management structures, with people's participation, for getting more effective results.