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1.
Residues and ecological risks of organochlorine pesticides in Lake Small Baiyangdian, North China 总被引:3,自引:0,他引:3
Yan Wang Wen-Jing Wu Wei He Ning Qin Qi-Shuang He Fu-Liu Xu 《Environmental monitoring and assessment》2013,185(1):917-929
The levels of hexachlorocyclohexane (HCH) and dichloro-diphenyl-trichloroethane (DDT) in the water, suspended particulate matter (SPM), and sediments from Lake Small Baiyangdian were measured by gas chromatograph with a 63Ni microelectron capture detector. The residual levels of the total HCHs in the water, SPM, and sediments were 1.59?±?2.24 ng L?1, 25.42?±?1.72 ng g?1 dw (dry weight), and 0.86?±?1.44 ng g?1 dw, respectively. DDTs were not detected in the water samples. The concentrations of total DDTs were 158.79?±?1.67 ng g?1 dw in SPM and 0.46?±?1.97 ng g?1 dw in the sediments. Compared to other areas in China and abroad, the levels of residual HCH and DDT were relatively low in the water and sediments, but they were moderate to high in the SPM. Organic carbon partition coefficient values for HCH in this study were higher than previously published values and may reflect new input in this area. The residual HCHs in this area could be derived from a mixture of technical HCH and lindane because ongoing lindane use may be occurring. DDT in the majority of the study area was primarily attributed to historical discharge, but some regions may be receiving new input. The ecological risks of γ-HCH in the water were very low according to species sensitivity distribution models. The concentrations of HCH and DDT in the sediments from the study area did not exceed the sediment quality guidelines, which indicate little risk for benthic organisms. 相似文献
2.
Yan Wang Wei He Ning Qin Qi-Shuang He Xiang-Zhen Kong Shu Tao Fu-Liu Xu 《Environmental monitoring and assessment》2013,185(2):1777-1790
The residual levels of dichlorodiphenyltrichloroethane (DDT) and its metabolites (DDXs, including p,p′-DDT, DDD, and DDE) in water, suspended particulate matter (SPM), and sediments from major rivers, lakes, and reservoirs in Haihe Plain were measured with a gas chromatograph equipped with a 63Ni microelectron capture detector. In the fall of 2004, the contents of the total DDXs in the water and SPM were 0.29?±?0.69 ng L?1 and 423.13?±?577.85 ng g?1 dry wt., respectively. In the spring of 2005, the total DDXs were 0.36?±?0.91 ng L?1 for water and 35.93?±?62.65 ng g?1 dry wt. for SPM. The average concentration of DDXs for sediments was 7.10?±?7.57 ng g?1 dry wt. during the two seasons. The Eastern-Hebei-Province Coastland River System was the most polluted, which was mainly attributable to the extensive use of DDT pesticide and dicofol in that system. Recent DDT inputs still occur in some regions, as indicated by DDT/(DDD + DDE) > 1 at 29–36 % of the sites for water and 55–61 % of the sites for SPM. The potential ecological risks of DDT in the water were assessed using a species sensitivity distribution model. Only shrimp and crabs were found to have potentially affected fraction values of 1.63?×?10?3 to 2.27?×?10?4, with probabilities beyond the hazardous concentration for 5 % of species (HC5) values of 1.90–2.56 %, suggesting only slight risks. DDXs in the sediments of some sites were also of potential risk to benthic organism based on consensus-based sediment quality guidelines. 相似文献
3.
The presented results include decade of monitoring of the Vistula Lagoon waters and have been supplemented by the determination of chlorinated compounds, as well as on concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in the sedimentation zone. Monitoring of river waters entering the Polish part of the lagoon and the lagoon waters confirmed the presence of plant protection chemical; the largest contributors has lindane (34%) and DDTtotal (21%); the same as for sediments were dominate lindane (19%) and DDTtotal (14%) within pp-DDT isomer dominate (13%). In the lagoon water, PCDD/Fs were determined within a range of 1.5–5.6 ng dm?3, leading to average toxicity of 0.18?±?0.13 ng TEQ·dm?3. In sediments, their concentrations fell within a range of 22.7–405.7 ng kg?1 dw and the average toxicity of the lagoon sediments was set at 5.00?±?1.98 ng TEQ·kg?1 dw. Both in water and sediments, the greatest share among PCDD/Fs has octa-chlorodibenzodioxin. Due to the hydromorphological conditions of the lagoon, the waters are mixed to the bottom causing the surface layer of sediment to become remobilized—this is suggested as the key factor when it comes to water recontamination and increased access of POPs to marine organisms. 相似文献
4.
Badreddine Barhoumi Karyn LeMenach Marie-Hélène Devier Walid Ben Ameur Henry Etcheber Hélène Budzinski Jérôme Cachot Mohamed Ridha Driss 《Environmental monitoring and assessment》2014,186(5):2653-2669
To assess the status of polycyclic aromatic hydrocarbon (PAH) contamination in sediments from the Bizerte Lagoon (northern Tunisia), 18 surface sediment samples were collected in March 2011 and analyzed for 14 US Environmental Protection Agency priority PAHs by high-performance liquid chromatography. The total concentrations of the 14 PAHs (ΣPAHs) ranged from 16.9 to 394.1 ng g?1 dry weight (dw) with a mean concentration of 85.5 ng g?1 dw. Compared with other lagoons, coasts, and bays in the world, the concentrations of PAHs in surface sediments of the Bizerte Lagoon are low to moderate. The PAHs’ composition pattern was dominated by the presence of four-ring PAHs (45.8 %) followed by five-ring (26.8 %) and three-ring PAHs (12.7 %). The PAH source analysis suggested that the main origin of PAHs in the sediments of the lagoon was mainly from pyrolytic sources. According to the numerical effect-based sediment quality guidelines of the USA, the levels of PAHs in the Bizerte Lagoon should not exert adverse biological effects. The total benzo[a]pyrene toxicity equivalent values calculated for the samples varied from 3.1 to 53.7 ng g?1 dw with an average of 10.6 ng g?1 dw. 相似文献
5.
Bin Men Haozheng Wang Mengchang He Chunye Lin Xiangchun Quan 《Environmental monitoring and assessment》2011,177(1-4):515-526
Nitroaromatic compounds are known to be hazardous to ecological and human health. To assess the status of nitroaromatic compounds contamination in the main rivers in the important industrial bases of the northeastern China, we collected water, suspended particulate matter (SPM) and sediment samples from 28 sites in the Daliao River watershed and analysed them for eight nitroaromatic compounds by gas chromatography. The total concentrations of eight nitrobenzenes in the water column including aqueous and SPM phases ranged from 740 to 15,828 ng L???1, with a mean concentration of 3,460 ng L???1. The total concentrations of eight nitrobenzenes in the sediment were 7.47 to 8,185.76 ng g???1, with a mean concentration of 921.98 ng g???1, and several times higher than those found from the Yellow River in China. 4-Nitrotoluene was the predominant contaminant in the water and sediment of the three rivers of the Daliao River watershed. 2,6-Dichloro-4-nitroaniline was generally dominant in the SPM. The levels of nitroaromatic compounds were different among different sites in the Daliao River watershed, mainly caused by the distribution of pollution sources. No obvious correlation was found between the total concentrations of eight nitrobenzenes concentrations and TOC or the slit-clay content of the sediments. 相似文献
6.
Distribution and sources of polycyclic aromatic hydrocarbons in the surface water of Taizi River, Northeast of China 总被引:2,自引:0,他引:2
Xueying Song Xiaojun Hu Miaomiao He Rujing Liang Yushuang Li Fengmei Li 《Environmental monitoring and assessment》2013,185(10):8375-8382
Spatial and seasonal distribution and sources of 16 polycyclic aromatic hydrocarbons (PAHs), identified as priority pollutants by the US Environmental Protection Agency, were investigated in the surface water of the Taizi River in Liaoning Province, northeast of China. Samples were collected from the mainstream, and tributaries of the Taizi River in dry, wet, and normal seasons. Five important industrial point sources were also monitored. The total PAH concentrations ranged from 454.5 to 1,379.7 ng l?1 in the dry season, 1,801.6 to 5,868.9 ng l?1 in the wet season, and 367.0 to 5,794.5 ng l?1 in the normal season. The total PAH concentrations were significantly increased in the order of wet season > normal season > dry season. The profile of PAHs in the surface water samples was dominated by low molecular weight PAHs particularly with two- and three-ring components in the three seasons, suggesting that the PAHs were from a relatively recent local source. Source identification inferred that the PAHs in the surface water of the Taizi River came from both petrogenic inputs and pyrogenic sources. 相似文献
7.
A complex investigation of the extent of pollution in sediments of the Sava River: part 2: persistent organic pollutants 总被引:1,自引:0,他引:1
Ester Heath Janez Ščančar Tea Zuliani Radmila Milačič 《Environmental monitoring and assessment》2010,163(1-4):277-293
Sediment pollution of the biggest Danube tributary, the Sava River, was investigated within the sixth framework European Union project “Sava River Basin: Sustainable Use, Management and Protection of Resources” (SARIB). The extent of pollution was estimated by determining the amount of inorganic and persistent organic pollutants in sediment samples at 20 selected sampling sites along the Sava River. For the purpose of clarity, the findings are presented and published separately (part I: selected elements and part II: persistent organic pollutants). This study presents an investigation into the presence of organic pollutants in the Sava River sediment. According to the Water Framework Directive, the following persistent organic pollutants were investigated: polycyclic aromatic hydrocarbons (PAH), polychlorinated biphenyls (PCB), selected chlorinated pesticides and organotin compounds. The results reveal that PAHs were present in moderate concentrations (sum of 16 PAHs: up to 4,000 ng g???1) and their concentrations increased downstream. Concen trations of PCB were low (sum of seven indicator PCBs: below 4 ng g???1) and among the pesticides analyzed only p,p-dichlorodiphenyltrichloroethane was found in moderate concentrations at two sampling sites in Croatia (up to 3 ng g???1) and hexachlorobenzene was found in a high concentration in the city of Belgrade (91 ng g???1), although the use of these persistent pesticides has been banned for decades. Repeated sampling at the same location revealed point pollution near Belgrade. Among the organic pollutants surveyed, organotin compounds were not detected. Overall results reveal the presence of persistent organic pollutants in 20 of the Sava River sediments tested that is, in general, comparable or lower than the levels in the Danube River and other moderately polluted European rivers. 相似文献
8.
The temporal changes in road stormwater runoff quality and the implications to first flush control in Chongqing, China 总被引:1,自引:0,他引:1
Qianqian Zhang Xiaoke Wang Peiqiang Hou Wuxing Wan Yufen Ren Zhiyun Ouyang Le Yang 《Environmental monitoring and assessment》2013,185(12):9763-9775
This study investigates the quality of stormwater runoff from a driveway in the southwest mountainous urban area of Chongqing, China, from 2010 to 2011. The results showed that the mean concentrations of chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) were 4.1, 2.4, and 2.2 times the grade V levels of the national surface water standard of China. The pollutant concentration peak preceded or synchronized with the rainfall intensity peak and occurred 10 min after the runoff started. The significant high pollutant concentration in the initial stage of the rainfall suggested that first flush control is necessary, especially for the most polluted constitutes, such as total suspended solids, COD, and TN. Three potential pollution sources were identified: the atmospheric dry and wet deposition (TN, NO3 ?-N, NH4 +-N, and DCu), the road sediment and materials (total suspended solids, COD, and TP), and the vehicle emissions (DPb and DZn). Therefore, this study indicates that reductions in road sediments and material pollution and dry and wet deposition should be the priority factors for pollution control of road stormwater runoff in mountainous urban areas. 相似文献
9.
Tony R. Walker Devin MacAskill Theresa Rushton Andrew Thalheimer Peter Weaver 《Environmental monitoring and assessment》2013,185(10):8089-8107
Chemical contaminants were assessed in Sydney Harbour, Nova Scotia during pre-remediation (baseline) and 3 years of remediation of a former coking and steel facility after nearly a century of operation and historical pollution into the Sydney Tar Ponds (STP). Concentrations of polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls, metals, and inorganic parameters measured in sediments and total suspended solids in seawater indicate that the overall spatial distribution pattern of historical contaminants remains unchanged, although at much lower concentrations than previously reported due to natural sediment recovery, despite remediation activities. Measured sediment deposition rates in bottom-moored traps during baseline were low (0.4–0.8 cm?year?1), but during dredging operations required for construction of new port facilities in the inner Sydney Harbour, sedimentation rates were equivalent to 26–128 cm year?1. Measurements of sediment chemical contaminants confirmed that natural recovery rates of Sydney Harbour sediments were in broad agreement with predicted concentrations, or in some cases, lower than originally predicted despite remediation activities at the STP site. Overall, most measured contaminants in sediments showed little temporal variability (4 years), except for the detection of significant increases in total PAH concentrations during the onset of remediation monitoring compared to baseline. This slight increase represents only a short-term interruption in the overall natural recovery of sediments in Sydney Harbour, which were enhanced due to the positive impacts of large-scale dredging of less contaminated outer harbor sediments which were discharged into a confined disposal area located in the inner harbor. 相似文献
10.
Michelle M. Patterson Ginger B. Paige Katta J. Reddy 《Environmental monitoring and assessment》2010,171(1-4):267-280
High selenium (Se) concentrations have been found in surface waters in the Kendrick Reclamation Project, Wyoming. Precipitation and irrigation water moving over seleniferous soils are contributing causes, and drought may exacerbate this. This study surveyed Se concentrations and discharges in local surface streams, irrigation drains, and the delivery canal. Sites were sampled monthly and analyzed for Se and total suspended solids (TSS). A completely randomized design with two factors (soil parent material and location, inside or outside irrigation district) was used. Mean Se concentrations were 64 μg L???1 inside the irrigation district on shale soils, 17 μg L???1 inside the district off shale soils, 5 μg L???1 outside the district on shale soils, and 3 μg L???1 outside the district off shale soils. Correlations between discharge and Se concentrations were generally negative, while correlations between discharge and Se load were generally positive. There was little correlation between load and concentration, and little correlation between TSS and Se. A comparison of Se concentrations in streams and drains showed Se concentrations were significantly higher (p?<?0.001) in streams during the irrigation season, but not in the off-season (p?=?0.515). We conclude that higher discharges decrease Se concentration, but increase load. Conversion from flood to sprinkle irrigation may increase Se concentrations by reducing discharge, but decrease Se loads going into the N. Platte River, and will likely alter the timing and magnitude of flows. Both load and concentration should be considered when implementing Se regulations and standards. 相似文献