共查询到18条相似文献,搜索用时 250 毫秒
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采用便携式GC-MS法快速测定固定污染源废气中VOCs,32种VOCs在2×10~(-7)~1×10~(-6)范围内线性良好,方法检出限为2×10~(-9)~1×10~(-8),标准气体样品6次测定结果的RSD为1.9%~19.1%,环境空气样品的加标回收率为66.2%~116%。在实际现场监测固定污染源中VOCs时,使用速查(Survey)功能可初步判断样品浓度,确定稀释倍数。比对试验结果表明,气袋和玻璃注射器采样法对VOCs测定结果无显著性差异。 相似文献
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固相萃取-高效液相色谱法测地表水中11种酚类化合物 总被引:1,自引:1,他引:0
建立了固相萃取-高效液相色谱法同时测定地表水中11种酚类化合物的方法。水样经过全自动固相萃取仪富集,以HLB柱为萃取柱,乙腈(含1%乙酸)为洗脱剂,用高效液相色谱仪分析定量。该方法在0.5~5.0 mg/L范围内线性良好,相关系数为0.999 6~0.999 9,11种酚类化合物的纯水加标回收率为82.0%~111%,地表水加标回收率为98.5%~116%,精密度为3.58%~4.67%,检出限为1×10-4~5×10-4mg/L,该方法简单实用、准确可靠,可用于地表水中酚类化合物的同时测定。 相似文献
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NBS氧化流动注射化学发光法在土壤腐殖酸含量测定中的应用 总被引:1,自引:0,他引:1
在碱性条件下,NBS直接氧化腐殖酸产生强烈的化学发光信号,结合流动注射技术,建立了测定土壤腐殖酸含量的流动注射化学发光分析法并详细研究了影响化学发光信号强度的各种因素。方法的测定线性范围为1.0×10-7-1.0×10-3g/ml,检出限(3σ)为3×10-8g/ml。对5.0×10-5g/ml的腐殖酸进行11次平行测定,相对标准偏差为1.8%。将该法用于实际土壤样品分析,结果令人满意。 相似文献
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建立了过氧化聚吡咯(OPPy)和聚乙烯吡咯烷酮(PVP)修饰碳糊电极测定废水中苯酚的方法.优化了试验条件,苯酚的氧化峰电流在1.0×10-5 mol/L~1.0×10-3 mol/L之间线性关系良好,检出限为1.0×10-6 mol/L.该电极制作简单,选择性好,测定灵敏度高,精密度与准确度均符合要求. 相似文献
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曹爱丽 《环境监测管理与技术》2019,31(2):50-53
采用气袋采样-苏玛罐转移-GC/MS法测定废气中5种醛类恶臭物质,醛类同分异构体能够被完全分离、定性定量。保存时间验证试验表明,5种低浓度醛类在Tedler采样袋和PVDFs采样袋中能稳定存放12 h,高浓度醛类能较稳定地保存24 h,转移至苏玛罐中的样品能够稳定存放至少14 d。方法在4×10~(-10)~2×10~(-8)范围内线性良好,方法检出限为0.127μg/m~3~0.207μg/m~3,混合标气6次测定结果的RSD为3.4%~8.8%,加标回收率为103%~114%。 相似文献
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乌鲁木齐市2种主要温室气体浓度水平 总被引:3,自引:0,他引:3
利用2010年乌鲁木齐市近地面大气主要温室气体的自动监测数据,分析了CO2和CH4浓度的分布特征和时间变化规律.结果表明,乌鲁木齐市CO2小时浓度在(349.1~605.0)×10-6之间;采暖期浓度高,平均浓度为438.1 ×10-6,非采暖期浓度低,平均浓度为375.0×10-6.CH4浓度日变化明显,昼间低、夜间... 相似文献
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报道一种微量测定环境水样中痕量肼的新方法。该方法基于在氢氧化钠碱性介质中高锰酸钾直接氧化肼的化学发光现象,建立了微量肼的流动注射化学发光分析方法。该方法线性范围为1.0×10-9~8.0×10-5g/ml,检出限3.6×10-10g/ml,对1.0×10-8g/ml的肼连续11次测定的相对标准偏差为2.1%,该方法已成功用于环境水样中痕量肼的测定。 相似文献
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R. Sahraei A. Farmany S. S. Mortazavi H. Noorizadeh 《Environmental monitoring and assessment》2013,185(7):5817-5822
A new spectrophotometric method is reported for the determination of nanomolar level of malachite green in surface water samples. The method is based on the catalytic effect of silver nanoparticles on the oxidation of malachite green by hexacyanoferrate (III) in acetate–acetic acid medium. The absorbance is measured at 610 nm with the fixed-time method. Under the optimum conditions, the linear range was 8.0?×?10?9–2.0?×?10?7?mol?L?1 malachite green with a correlation coefficient of 0.996. The limit of detection (S/N?=?3) was 2.0?×?10?9?mol?L?1. Relative standard deviation for ten replicate determinations of 1.0?×?10?8?mol?L?1 malachite green was 1.86 %. The method is featured with good accuracy and reproducibility for malachite green determination in surface water samples without any pre-concentration and separation step. 相似文献
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A. Farmany A. Khosravi S. Abbasi J. Cheraghi R. Hushmandfar S. Sobhanardakani H. Noorizadeh S. S. Mortazavi 《Environmental monitoring and assessment》2013,185(1):553-558
A new kinetic method has been developed for the determination of iodine in water samples. The method is based on the catalytic effect of I? with the oxidation of Indigo Carmine (IC) by KBrO3 in the sulfuric acid medium. The optimum conditions obtained are 0.16 M sulfuric acid, 1?×?10?3 M of IC, 1?×?10?2 M KBrO3, reaction temperature of 35°C, and reaction time of 80 s at 612 nm. Under the optimized conditions, the method allowed the quantification of I? in a range of 12–375 ng/mL with a detection limit of 0.46 ng/mL. The method was applied to the determination of iodine in river and city water samples with the satisfactorily results. 相似文献
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贵州三水库冬季浮游生物分布及影响因子分析 总被引:3,自引:1,他引:2
为揭示喀斯特地区深水水库冬季的浮游生物群落结构及其影响因子,于2010年2月对贵州红枫湖、百花湖和阿哈水库进行采样分析。共鉴定出红枫湖、百花湖和阿哈水库的浮游植物分别为66、70、60种,浮游植物丰度范围分别为0.34×106~2.25×106、3.03×106~12.72×106、5.3×106~13.3×106 cells/L,后生浮游动物分别为22、16、24种,丰度变化范围分别为1.1~36.5、7.3~408、27~135 ind/L。Jaccard相似系数显示红枫湖/百花湖(0.381)>百花湖/阿哈水库(0.371)>红枫湖/阿哈水库(0.274)。典范对应分析(CCA)显示3个水库冬季的浮游植物的分布主要受透明度、温度、喜冷中镖水蚤、右突新镖水蚤、pH、舞跃无柄轮虫的影响,后生浮游动物的分布主要受透明度、温度、DO、沼泽颤藻、单角盘星藻具孔变种、TN和颗粒直连藻极狭变种螺旋变形的影响。 相似文献
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Saadat Rastegarzadeh Zeinab Barkat Rezaei 《Environmental monitoring and assessment》2013,185(11):9037-9042
A colorimetric assay method is described for the environmental detection of 2-mercaptobenzimidazole (MBI) using surface plasmon resonance of gold nanoparticles (AuNPs). Stable and dispersed AuNPs with intensified plasmon resonance were prepared in situ using a simple, rapid, and eco-friendly procedure by applying ascorbic acid as a reducer and cetyltrimethylammonium bromide as a stabilizer. The presence of MBI has a strong effect on the plasmon absorbance of AuNPs, which was employed for the detection of MBI. The calibration curve was linear in the range of 1.0?×?10?6–5.5?×?10?5 mol/L of MBI; the detection limit was 8.4?×?10?7 mol/L. The relative standard deviations for eight replicate measurements of 3.0?×?10?6 and 5?×?10?5 mol/L MBI were 3.9 and 1.4 %, respectively. The method was successfully applied to the determination of MBI in tap, river, sea, and heat exchanger cooling water samples. 相似文献
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P. Parameshwara Naik J. Karthikeyan A. Nityananda Shetty 《Environmental monitoring and assessment》2010,171(1-4):639-649
4-[N,N-(Diethyl)amino] benzaldehyde thiosemicarbazone (DEABT) is proposed as an analytical reagent for the spectrophotometric determination of platinum(IV). The DEABT forms 1:2 yellow complex with Pt(IV), which is sparingly soluble in water and completely soluble in water–ethanol–DMF medium. The Pt(IV)–DEABT complex shows maximum absorbance at 405 nm. Beer’s law is valid up to 7.80 μg cm???3, and optimum concentration range for the determination of platinum(IV) is 0.48–7.02 μg cm???3. The molar absorptivity and Sandell’s sensitivity of the method are found to be 1.755 × 104 dm3 mol???1 cm???1 and 0.0012 μg cm???2, respectively. The relative error and coefficient of variation (n?=?6) for the method does not exceed ±0.43% and 0.35%, respectively. Since the method tolerates a number of metal ions commonly associated with platinum, it can be employed for the determination of platinum in environmental samples, pharmaceutical samples, alloys, catalysts, and complexes. The method is rapid as the Pt(IV)–DEABT complex is soluble in water–ethanol–DMF medium and not requiring any time consuming extraction method for the complex. 相似文献
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Hossein Tavallali Fazlollah Boustani Mozhdeh Yazdandoust Mehdi Aalaei Mahboobeh Tabandeh 《Environmental monitoring and assessment》2013,185(5):4273-4279
A new complexing agent, 2-((2-((1H-benzo[d]imidazole-2yl)methoxy)phenoxy)methyl)-1H-benzo[d]imidazole (BIMPI), was used in cloud point extraction and applied for selective pre-concentration of trace amounts of cadmium in cigarette samples. Cadmium was complexed with BIMPI in a buffer solution (pH?=?10) using Triton X-114 as surfactant and quantitatively extracted into a small volume of the surfactant-rich phase after centrifugation. Under optimized conditions (pH?=?10.0, 0.8?×?10?4?mol?L?1 BIMPI and 0.08 % (w/v) Triton X-114), calibration graph was linear in the range of 34.0–1,670.0 μg?L?1. The proposed method was applied to the determination of Cd in various cigarette (tobacco) samples which gave satisfactory results. 相似文献