首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 500 毫秒
1.
The original Industrial Source Complex Model (ISCST, 90346) and its latest version, the ISCST2 (92090), are evaluated for the 1- and 24-hour averaging periods, using six statistical parameters. The confidence limits on two parameters were obtained using the bootstrap, jacknife, seductive, and robust resampling techniques. Evaluation is conducted in a multiple point source environment and in all the different stability categories, using a year of meteorological data, emission inventory of the Lucas County, in Toledo, Ohio, and monitoring data from two nearby stations for the year 1987. This was representative of a real time situation in which the ISCST is generally applied for regulatory work. The sensitivity analysis shows that the ISC is a poor performing model in the 1-h and 24-h averaging period, neutral and stable categories, and modifications to it are necessary in order to improve its performance. Its performance changes depending on the chosen paired values. A better relative performance is observed in the unstable category relative to the neutral and stable categories. Improved model performance may be achieved by applying modifications to the physics on which the model is based.  相似文献   

2.
The main purpose of the present work is to study the concentration of atmospheric particles in the Candiota region, in the state of Rio Grande do Sul, where the Presidente Médici coal power plant is located. Aerosol samples were collected at the studied locations between December 2000 and December 2001 during 24 h periods at 15 day intervals using HV PM10 and dichotomous samplers. Then, the values obtained with the ISCST (Industrial Source Complex Term) model, with the HV PM10 sampler at all studied stations, and with the dichotomous sampler at the 8 de Agosto station were compared with each other. The results show that the values for the model had been underestimated in relation to the HV PM10 data for the studied stations, but agreed with the values obtained with the dichotomous sampler.  相似文献   

3.
This paper presents monitoring results of daily brick kiln stack emission and the derived emission factors. Emission of individual air pollutant varied significantly during a firing batch (7 days) and between kilns. Average emission factors per 1,000 bricks were 6.35–12.3 kg of CO, 0.52–5.9 kg of SO2 and 0.64–1.4 kg of particulate matter (PM). PM emission size distribution in the stack plume was determined using a modified cascade impactor. Obtained emission factors and PM size distribution data were used in simulation study using the Industrial Source Complex Short-Term (ISCST3) dispersion model. The model performance was successfully evaluated for the local conditions using the simultaneous ambient monitoring data in 2006 and 2007. SO2 was the most critical pollutant, exceeding the hourly National Ambient Air Quality Standards over 63 km2 out of the 100-km2 modelled domain in the base case. Impacts of different emission scenarios on the ambient air quality (SO2, PM, CO, PM dry deposition flux) were assessed.  相似文献   

4.
Integrated pipe manufacturing industry is operation intensive and has significant air pollution potential especially when it is equipped with a captive power production facility. Emissions of SO2, NO x , and particulate matter (PM) were estimated from the stationary sources in a state-of-the-art pipe manufacturing plant in India. Major air polluting units like blast furnace, ductile iron spun pipe facility, and captive power production facility were selected for stack gas monitoring. Subsequently, ambient air quality modeling was undertaken to predict ground-level concentrations of the selected air pollutants using Industrial Source Complex (ISC 3) model. Emissions of SO2, NO x , and particulate matter from the stationary sources in selected facilities ranged from 0.02 to 16.5, 0.03 to 93.3, and 0.09 to 48.3 kg h???1, respectively. Concentration of SO2 and NO x in stack gas of 1,180-kVA (1 KW = 1.25 kVA) diesel generator exceeded the upper safe limits prescribed by the State Pollution Control Board, while concentrations of the same from all other units were within the prescribed limits. Particulate emission was highest from the barrel grinding operation, where grinding of the manufactured pipes is undertaken for giving the final shape. Particulate emission was also high from dedusting operation where coal dust is handled. Air quality modeling indicated that maximum possible ground-level concentration of PM, SO2, and NO x were to the tune of 13, 3, and 18 μg/m3, respectively, which are within the prescribed limits for ambient air given by the Central Pollution Control Board.  相似文献   

5.
In this contribution we show the integration of a mesoscale air quality model OPANA with the ISCST3 Gaussian model (EPA) in order to analyze the impact of different emission sources and particularly the traffic emission into the different gridboxes which define the OPANA Eulerian structure. The application is done over the Madrid (Spain) regional area with 80 × 100 km and gridboxes of about 5 km. Thousands of Gaussian runs over interested gridboxes are executed in order to simulate the traffic emissions from each gridbox. Each mobile unit is represented by a Gaussian point emitter. Input meteorological variables for the ISCST3 are taken from the OPANA mesoscale air quality model. Results shows that it is possible to model the impact of traffic emissions over each gridbox. A short comparison with air quality monitoring in each gridbox is also shown.  相似文献   

6.
The laboratory flux measurement system (LFMS) and dispersion models were used to investigate the kinetics of mercury emission flux (MEF) from contaminated soils. Representative soil samples with respect to total Hg concentration (26-9770 μg g(-1)) surrounding a decommissioned mercury-mining area (Las Cuevas Mine), and a former mercury smelter (Cerco Metalúrgico de Almadenejos), in the Almadén mercury mining district (South Central Spain), were collected. Altogether, 14 samples were analyzed to determine the variation in mercury emission flux (MEF) versus distance from the sources, regulating two major environmental parameters comprising soil temperature and solar radiation. In addition, the fraction of the water-soluble mercury in these samples was determined in order to assess how MEF from soil is related to the mercury in the aqueous soil phase. Measured MEFs ranged from less than 140 to over 10,000 ng m(-2) h(-1), with the highest emissions from contaminated soils adjacent to point sources. A significant decrease of MEF was then observed with increasing distance from these sites. Strong positive effects of both temperature and solar radiation on MEF was observed. Moreover, MEF was found to occur more easily in soils with higher proportions of soluble mercury compared to soils where cinnabar prevails. Based on the calculated Hg emission rates and with the support of geographical information system (GIS) tools and ISC AERMOD software, dispersion models for atmospheric mercury were implemented. In this way, the gaseous mercury plume generated by the soil-originated emissions at different seasons was modeled. Modeling efforts revealed that much higher emissions and larger mercury plumes are generated in dry and warm periods (summer), while the plume is smaller and associated with lower concentrations of atmospheric mercury during colder periods with higher wind activity (fall). Based on the calculated emissions and the model implementation, yearly emissions from the "Cerco Metalúrgico de Almadenejos" decommissioned metallurgical precinct were estimated at 16.4 kg Hg y(-1), with significant differences between seasons.  相似文献   

7.
2-Ethyl-1-hexanol is a possibly causative chemical in sick building symptoms, although 2-ethyl-1-hexanol has received little attention as a hazardous substance in studies on indoor air pollution. Airborne 2-ethyl-1-hexanol concentrations were measured from 2002 to 2004 in 99 rooms of 42 non-domestic buildings in Nagoya, Japan. The diffusive sampling method is effective for the measurement of a low level of 2-ethyl-1-hexanol in indoor air. The geometric mean (geometric standard deviation) of 2-ethyl-1-hexanol concentrations was 16.5 (5.4) microg m(-3) in indoor air and 1.9 (2.2) microg m(-3) in outdoor air. The maximum concentration of 2-ethyl-1-hexanol in indoor air and outdoor air was 2709 microg m(-3) and 12.4 microg m(-3), respectively. Fewer rooms in a small number of new buildings showed high concentrations of 2-ethyl-1-hexanol, while low concentrations were observed in many rooms of these buildings as well as the other new buildings. The room-to-room concentrations of 2-ethyl-1-hexanol in each building exhibited a wide variation. The geometric mean of the 2-ethyl-1-hexanol concentrations was significantly higher for indoor air than for outdoor air (p < 0.01). The correlation of the 2-ethyl-1-hexanol concentrations between indoor and outdoor air was not significant. Mechanical ventilation was effective in the temporary reduction of indoor 2-ethyl-1-hexanol level. These results suggest that the predominant source of 2-ethyl-1-hexanol was indoor areas.  相似文献   

8.
Multimedia environmental fate models are commonly-applied tools for assessing the fate and distribution of contaminants in the environment. Owing to the large number of chemicals in use and the paucity of monitoring data, such models are often adopted as part of decision-support systems for chemical risk assessment. The purpose of this study was to evaluate the performance of three multimedia environmental fate models (spatially- and non-spatially-explicit) at a European scale. The assessment was conducted for four polycyclic aromatic hydrocarbons (PAHs) and hexachlorobenzene (HCB) and compared predicted and median observed concentrations using monitoring data collected for air, water, sediments and soils. Model performance in the air compartment was reasonable for all models included in the evaluation exercise as predicted concentrations were typically within a factor of 3 of the median observed concentrations. Furthermore, there was good correspondence between predictions and observations in regions that had elevated median observed concentrations for both spatially-explicit models. On the other hand, all three models consistently underestimated median observed concentrations in sediment and soil by 1-3 orders of magnitude. Although regions with elevated median observed concentrations in these environmental media were broadly identified by the spatially-explicit models, the magnitude of the discrepancy between predicted and median observed concentrations is of concern in the context of chemical risk assessment. These results were discussed in terms of factors influencing model performance such as the steady-state assumption, inaccuracies in emission estimates and the representativeness of monitoring data.  相似文献   

9.
All major mining activity particularly opencast mining contributes to the problem of suspended particulate matter (SPM)directly or indirectly. Therefore, assessment and prediction are required to prevent and minimize the deterioration of SPM due tovarious opencast mining operations. Determination of emission rate of SPM for these activities and validation of air quality models are the first and foremost concern. In view of the above, the study was taken up for determination of emission rate for SPMto calculate emission rate of various opencast mining activitiesand validation of commonly used two air quality models for Indianmining conditions. To achieve the objectives, eight coal and three iron ore mining sites were selected to generate site specific emission data by considering type of mining, method of working, geographical location, accessibility and above all resource availability. The study covers various mining activitiesand locations including drilling, overburden loading and unloading, coal/mineral loading and unloading, coal handling orscreening plant, exposed overburden dump, stock yard, workshop, exposed pit surface, transport road and haul road. Validation of the study was carried out through Fugitive Dust Model (FDM) and Point, Area and Line sources model (PAL2) by assigning the measured emission rate for each mining activity, meteorologicaldata and other details of the respective mine as an input to the models. Both the models were run separately for the same set ofinput data for each mine to get the predicted SPM concentrationat three receptor locations for each mine. The receptor locationswere selected such a way that at the same places the actual filedmeasurement were carried out for SPM concentration. Statisticalanalysis was carried out to assess the performance of the modelsbased on a set measured and predicted SPM concentration data. The value of coefficient of correlation for PAL2 and FDM was calculated to be 0.990-0.994 and 0.966-0.997, respectively, which shows a fairly good agreement between measured and predicted values of SPM concentration. The average index of agreement values for PAL2 and FDM was found to be 0.665 and0.752, respectively, which represents that the prediction by PAL2 and FDM models are accurate by 66.5 and 75.2%, respectively. These indicate that FDM model is more suited for Indian mining conditions.  相似文献   

10.
根据江苏省72个国控点监测数据,采用了区域大气模式和多尺度空气质量模式系统(RAMS-CMAQ)模拟了2017年江苏省ρ(PM2.5)的时空分布,耦合综合源追踪算法(ISAM)分析了不同地区排放源对ρ(PM2.5)的贡献特征。结果表明,PM2.5模拟与观测值的相关系数(r)=0.76,标准平均偏差(NMB)=5.2%,均方根误差(RMSE)=23.4μg/m3,模拟结果落于观测结果0.5~2倍的比例(FAC2)=84.2%。源追踪模块结果显示,夏季主要受东南风控制,本地排放的贡献更大(省内贡献为52.34%),其他季节受偏北风输送影响,外源输送的影响较大(省外贡献为53.48%~56.84%);冬季苏北5市的排放贡献比沿江8市的更大,而春、夏季沿江8市排放贡献较大。  相似文献   

11.
The present study deals with the seasonal variations in the concentrations of heavy metals namely chromium, lead and mercury by using spectrophotometric methods. The water samples were collected at regular intervals from five selected sites of river Gomti in the pre-monsoon period (months of February-May) and the post monsoon period (months of October-January). The concentrations of chromium (VI) and mercury (II) were determined by using Genesys-10 UV-VIS Spectrophotometer while lead (II) concentrations were determined using Atomic Absorption Spectrophotometer, Perkin-Elmer 5000 model. The concentrations of all the three metals were found to be higher in the pre-monsoon period than in the post-monsoon period. The statistical analysis of the data was discussed in both the seasons in terms of mean, standard deviation and coefficient of variation.  相似文献   

12.
Michigan water quality standards for public bathing beaches require local health departments to collect and analyze a minimum of three water samples for Escherichia coli during each sampling event. The geometric mean number of E. coli colonies is then compared to the 300 colonies per 100 ml standard to determine compliance. This article compares the results of the currently mandated procedure to a composite sampling method, whereby the three samples are mixed in equal volumes and analyzed once. This effectively replaces the geometric mean of the individual sample results with an arithmetic mean. Although arithmetic means are more affected by outliers, this sensitivity to high concentrations is more health conservative than the geometric mean. During the 2007 sampling season, nine bathing beaches were monitored once each week. Three individual point samples and a composite sample were analyzed for each sampling event. No statistically significant differences in bacteria concentrations were found between composite sample analysis and the arithmetic mean of individual point sample analyses. No violations were detected in the 2007 sampling season, so using historical data, a retrospective analysis was performed on samples gathered at nine bathing beaches in Kalamazoo County, Michigan during the years 2001–2007. The arithmetic mean of the three samples taken at each site served as a surrogate composite sample. The benefits of compositing the three samples were investigated assuming a 2/3 reduction in analytical costs. In the traditional sampling method, three individual samples were obtained and analyzed once in every 3-week period during the summer season, whereas compositing was simulated by taking the arithmetic mean of each week’s results. The results of this retrospective cost analysis indicates that ten to 14 violations would have been missed using the less frequent traditional sampling and analysis methodology. Composite sampling is a cost-saving alternative to traditional sampling techniques that can be more protective of public health, particularly when the savings are applied to increased numbers of samples in time or space.  相似文献   

13.
A simple box model computing time-averaged concentrations in soil and water of contaminants such as pesticides, following a pulse emission under the assumption of constant removal rates, is presented and evaluated against a benchmark model and some lysimeter experiments representative of different soil and climate settings in Europe. The simple box model allows capturing to some extent the trends of contaminant releases observed from lysimeters or predicted by the benchmark model. This suggests that the correct order of magnitude of environmental concentrations and loads of contaminants can be described as a first approximation by a very simple back-of-the-envelope calculation. In the calculation, the time lag between contaminant application and the start of runoff or leaching should be considered. In the absence of more detailed information, repeating the calculation for the extreme cases of zero and one month lag yields a reasonably realistic range, and the geometric mean of the two is suggested as a first guess estimate. This configures a practical approach for the screening of contaminant losses especially suited for the mapping of predicted environmental concentrations (PECs) for assessment at broad scale (such as continental Europe, a country or a large catchment), where contingent determinants of contaminant fate tend to be averaged out and use of more detailed models usually promises to yield little improvement of PECs.  相似文献   

14.
Two and a half years of data of ambient concentrations of elemental mercury (Hg(0)), reactive gaseous mercury (RGM), and particle-bound mercury (Hg(p)) were collected at measurement sites at Elizabeth, New Jersey and New Brunswick, New Jersey with Tekran sampling units. The data were processed, summarized, and analyzed from a variety of perspectives. Data quality control and quality assurance procedures are described. Wind direction and wind speed data for each of the sites were also collected. Significant temporal variations in concentrations of all three species were observed. Some significant directional variations were also seen. The sporadic nature of many of the temporal variations is consistent with and could reflect highly variable emissions patterns from anthropogenic mercury sources. Overall mean concentrations of all species were determined. These were, for Hg(0), Hg(p), and RGM respectively; 2.25 +/- 0.04 nanograms per cubic meter (ng/m(3)), 8.21 +/- 0.39 picograms per cubic meter (pg/m(3)), and 8.93 +/- 0.31 pg/m(3) (arithmetic means and 95% confidence intervals) at Elizabeth, and 2.15 +/- 0.02 ng/m(3), 10.73 +/- 0.45 pg/m(3), and 6.04 +/- 0.30 pg/m(3) at New Brunswick. Mean concentrations were determined for 16 different sectors representing wind directions. The impact of one known large source is suggested by these data. Reasons for some directional variations are not apparent and suggest a need for further investigation.  相似文献   

15.
Modeling of non-point source pollution in a Mediterranean drainage basin   总被引:2,自引:0,他引:2  
SWAT ver. 2000 was used to predict hydrographs, and sediment, nitrate and total phosphorus loadings from a 1349 km2 mountainous/agricultural watershed in Northern Greece. The model was calibrated and verified using continuous meteorological data from eight stations within the drainage area, and runoff, sediment and nutrient concentrations measured at nine stations located within the main tributaries of the watershed, for the time period from May 1st, 1998 to January 31st, 2000. Model validation methodology and resulting input parameters appropriate for Mediterranean drainage basins are presented. Predicted by the model hydrographs, sedimentographs and pollutographs are plotted against observed values and show good agreement. Model performance is evaluated using the root mean square error computation and scattergrams of predicted versus observed data. The validated model is also used to test the effectiveness of three alternative cropping scenarios in reducing nutrient loadings from the agricultural part of the watershed. The study showed that this model, if properly validated, can be used effectively in testing management scenarios in Mediterranean drainage basins.  相似文献   

16.
The daily and seasonal atmospheric concentrations, deposition fluxes and emission sources of a few C3–C9 gaseous alkyl nitrates (ANs) at the Belgian coast (De Haan) on the Southern North Sea were determined. An adapted sampler design for low- and high-volume air-sampling, optimized sample extraction and clean-up, as well as identification and quantification of ANs in air samples by means of gas chromatography mass spectrometry, are reported. The total concentrations of ANs ranged from 0.03 to 85 pptv and consisted primarily of the nitro-butane and nitro-pentane isomers. Air mass backward trajectories were calculated by the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model to determine the influence of main air masses on AN levels in the air. The shorter chain ANs have been the most abundant in the Atlantic/Channel/UK air masses, while longer chain ANs prevailed in continental air. The overall mean N fluxes of the ANs were slightly higher for summer than those for winter-spring, although their contributions to the total nitrogen flux were low. High correlations between AN and HNO2 levels were observed during winter/spring. During summer, the shorter chain ANs correlated well with precipitation. Source apportionment by means of principal component analysis indicated that most of the gas phase ANs could be attributed to traffic/combustion, secondary photochemical formation and biomass burning, although marine sources may also have been present and a contributing factor.  相似文献   

17.
Reports on the occurrence and intake assessment of mercury for Korean seafood are currently not available. This is the first report to estimate the intake of methyl (Me-Hg) and total mercury (T-Hg) from seafood consumption in Korea. The concentrations of Me-Hg and T-Hg in seafood ranged from 1.02 to 780 (mean: 55.6) ng g(-1) wet weight and 4.89 to 1008 (mean: 100) ng g(-1) wet weight, respectively. The residue levels of Me-Hg and T-Hg in Korean seafood were moderate compared with those found in other countries. The methylation ratios of fish, cephalopods and crustaceans were similar, but shellfish had lower values compared with other species. The intakes of Me-Hg and T-Hg from seafood consumption for the general population were estimated to be 38.8 and 73.8 ng kg(-1) body weight per day, respectively. Mackerel, tuna and squid made the highest contributions to the total intake of these contaminants. Among eight age groups, 30-49 year and 3-6 year age groups had the highest exposure to Me-Hg and T-Hg. The concentrations and intakes of Me-Hg and T-Hg from Korean seafood were less than the allowable residue levels and threshold intake levels suggested by Korean and international authorities. The present study may be useful for risk management of mercury in Korean seafood.  相似文献   

18.
The emission estimation of nine volatile organic compounds (VOCs) from eight organic liquids storage tanks companies in Dar-es-Salaam City Tanzania has been done by using US EPA standard regulatory storage tanks emission model (TANKS 4.9b). Total VOCs atmospheric emission has been established to be 853.20 metric tones/yr. It has been established further that petrol storage tanks contribute about 87% of total VOCs emitted, while tanks for other refined products and crude oil were emitting 10% and 3% of VOCs respectively. Of the eight sources (companies), the highest emission value from a single source was 233,222.94 kg/yr and the lowest single source emission value was 6881.87 kg/yr. The total VOCs emissions estimated for each of the eight sources were found to be higher than the standard level of 40,000 kg/yr per source for minor source according to US EPA except for two sources, which were emitting VOCs below the standard level. The annual emissions per single source for each of the VOCs were found to be below the US EPA emissions standard which is 2,000~kg/yr in all companies except the emission of hexane from company F1 which was slightly higher than the standard. The type of tanks used seems to significantly influence the emission rate. Vertical fixed roof tanks (VFRT) emit a lot more than externally floating roof tanks (EFRT) and internally floating roof tanks (IFRT). The use of IFRT and EFRT should be encouraged especially for storage of petrol which had highest atmospheric emission contribution. Model predicted atmospheric emissions are less than annual losses measured by companies in all the eight sources. It is possible that there are other routes for losses beside atmospheric emissions. It is therefore important that waste reduction efforts in these companies are directed not only to reducing atmospheric emissions, but also prevention of the spillage and leakage of stored liquid and curbing of the frequently reported illegal siphoning of stored products. Emission rates for benzene, toluene, and xylene were used as input to CALPUFF air dispersion model for the calculation of spatial downwind concentrations from area sources. By using global positioning system (GPS) and geographical information system (GIS) the spatial benzene concentration contributed by organic liquid storage tanks has been mapped for Dar-es-Salaam City. Highest concentrations for all the three toxic pollutants were observed at Kigamboni area, possibly because the area is located at the wind prevailing direction from the locations of the storage tanks. The model predicted concentrations downwind from the sources were below tolerable concentrations by WHO and US-OSHA. The highest 24 hrs averaging time benzene concentration was used for risk assessment in order to determine maximum carcinogenic risk amongst the population exposed at downwind. Established risk for adult and children at 2.9×10-3 and 1.9×10-3 respectively, are higher than the acceptable US-EPA risk of 1×10-6. It is very likely that the actual VOCs concentrations in some urban areas in Tanzania including Dar-es-Salaam City are much higher than the levels reported in this study when other sources such as petrol stations and motor vehicles on the roads are considered. Tanzania Government therefore need to put in place: an air quality policy and legislation, establish air quality guidelines and acquire facilities which will enable the implementation of air quality monitoring and management programmes.  相似文献   

19.
The concentration of mercury was determined in samples of the lichen Hypogymnia physodes, the moss Pleurozium schreberi, and the soil humus collected in Polish and Czech Euroregions Praded and Glacensis. The sampling sites were located in Bory Stobrawskie, Bory Niemodlińskie and Kotlina K?odzka in Poland, and in Jeseniki and Gory Orlickie in the Czech Republic. The mean concentrations of mercury accumulated in the lichen (0.129?mg?g(-1)), in the moss (0.094?mg?g(-1)) and in soil (0.286?mg?g(-1)) were fairly close to the corresponding concentrations in other low-industrialized regions. The highest concentrations of mercury were observed in the lichen and the moss samples from Kotlina K?odzka. The primary deposition of mercury was evaluated using the comparison factor, defined as the ratio of a difference between the concentrations of a bioavailable analyte in lichens and in mosses, to the arithmetic mean of these concentrations.  相似文献   

20.
Gaussian-based dispersion models are widely used to estimate local pollution levels. The accuracy of such models depends on stability classification schemes as well as plume rise equations. A general plume dispersion model (GPDM) for a point source emission, based on Gaussian plume dispersion equation, was developed. The program complex was developed using Java and Visual basic tools. It has the flexibility of using five kinds of stability classification schemes, i.e., Lapse Rate, Pasquill–Gifford (PG), Turner, σ–θ and Richardson number. It also has the option of using two types of plume rise formulations – Briggs and Holland’s. The model, applicable for both rural and urban roughness conditions, uses meteorological and emission data as its input parameters, and calculates concentrations of pollutant at the center of each cell in a predefined grid area with respect to the given source location. Its performance was tested by comparing with 4-h average field data of continuous releases of SO2 from Dadri thermal power plant (Uttar Pradesh, India). Results showed that the Turner scheme used with Holland’s equation gives the best outcome having a degree of agreement (d) of 0.522.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号