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1.
The present report describes some effects of industrial and municipal effluents on the waters of San Vicente Bay. Analyses ofthe main substances contained in the fishing industry effluentsuggest rating criteria based on the oxygen saturation of thewater as an assessment of organic pollution. Six cruises were carried out throughout the Bay, from June to December 1996. Watersamples were analyzed for dissolved oxygen, oil and grease content, and sediment samples for organic matter content. Waterparameters (salinity, temperature) were used to characterize theBay's hydrography, and to calculate values for oxygen saturation. The measurements demonstrated a local broad range of oxygen deficit, with a maximum of 45% in the winter to 95% in the spring. In November more than 65% of the Bay's area showed oxygendeficits greater than 40%. Organic matter was unusually high insediments along the northern sector of the Bay. The results suggest that the oxygen depletion was a representative parameterfor establishing a relative scale of water quality in this Bay.  相似文献   

2.
San Vicente Bay is a coastal shallow embayment in Central Chile with multiple uses, one of which is receiving wastewater from industrial fisheries, steel mill effluents, and domestic sewage. A simulation model was developed and applied to dissolved oxygen consumption by organic residues released into this embayment. Three compartments were established as function of: depth, circulation and outfall location. The model compartments had different volumes, and their oxygen saturation value was used as baseline. The parameters: (a) BOD5 of the industrial and urban effluents, (b) oxygen demand by organic sediments, (c) respiration, (d) photosynthesis and (e) re-aeration were included in the model. Iteration results of the model showed severe alterations in Compartment 1, with a decrease of 65% in the oxygen below saturation. Compartment 2 showed a small decline (10%) and compartment 3 did not show apparent changes in oxygen values. Measures recommended for remediation were to decrease the BOD5 loading by 30% in the affected sector. Iteration of the model for 200 h following recommendations derived from the preceding results produced an increase in saturation of 60% (5 ml O2 L−1), which suggested an improvement of the environmental conditions.  相似文献   

3.
Since Delaware's coastal bays have been highly eutrophied for at least twenty years and Maryland's coastal bays are not nutrient stressed, dominance of the fish community in Delaware's coastal bays by Fundulus sp. may be an indicator of nutrient stress. Maryland's coastal bays are menhaden, spot, and anchovy dominated. The dominance of Fundulus sp. in a nutrient-stressed system relates to the hardy nature of these fishes, especially in low-oxygen conditions. Submerged aquatic vegetation as seagrasses (SAV) has been absent from the highly nutrient-stressed Delaware coastal bays for about twenty-five years. In contrast, SAV is still found in Maryland's coastal bays. The loss of SAV as a habitat for young fish may also be contributing to the apparent species shift in Delaware's coastal bays.Indian River Bay is less hospitable to macroalgae (seaweeds) than Rehoboth Bay. Dominance of Ulva in Indian River Bay reflects its tolerance to varying salinities, higher nutrient levels, and increased turbidities, and indicates a stressed system. The total volume of macroalgae, especially in Rehoboth Bay, tends to follow the seasonal cycle for phosphorus.Based on an assessment of the ecological condition of the Delaware and Maryland coastal bays conducted by EMAP in 1993 and other related studies, the author offers a conceptual framework for Delaware's inland bays environmental classification, considering the water quality parameters of turbidity, TSS, Chla, DIN, DIP, and O2 as they relate to presence of SAV, seaweed abundance and diversity, benthic invertebrate diversity, and fish sensitivity to low oxygen.  相似文献   

4.
We measured the concentration of 12 metals in coastal waters of seven sites of San Jorge Bay in Antofagasta (northern Chile), in order to relate the presence of metals with the different uses of San Jorge Bay coastal border, and to evaluate the quality of the bay's bodies of water according to the proposed current Chilean Quality Guide for trace elements in seawater (CONAMA 2003). The results suggest that the coastal water of San Jorge Bay has very good quality according to the proposed regulation mentioned above. However, the distribution of metals such as Cu and Pb along the bay's coast line evidences a notorious effect of the industrial activity, which would involve different behavior patterns for some trace elements in some bodies of water, suggesting that the levels indicated in the environmental guideline of the Chilean legislation do not represent pollution-free environments.  相似文献   

5.
Wastewater discharge from shrimp farming is one of the main causes of eutrophication in mangrove ecosystems. We investigated the phosphorus (P) geochemistry in mangrove soils affected by shrimp farming effluents by carrying out a seasonal study of two mangrove forests (a control site (CS); a site affected by shrimp farm effluents (SF)). We determined the soil pH, redox potential (Eh), total organic carbon (TOC), total phosphorus (TP), and dissolved P. We also carried out sequential extraction of the P-solid phases. In SF, the effluents affected the soil physicochemical conditions, resulting in lower Eh and higher pH, as well as lower TOC and higher TP than in CS. Organic P forms were dominant in both sites and seasons, although to a lesser extent in SF. The lower TOC in SF was related to the increased microbial activity and organic matter decomposition caused by fertilization. The higher amounts of P oxides in SF suggest that the effluents alter the dominance of iron and sulfate reduction in mangrove soils, generating more reactive Fe that is available for bonding to phosphates. Strong TP losses were recorded in both sites during the dry season, in association with increased amounts of exchangeable and dissolved P. The higher bioavailability of P during the dry season may be attributed to increased mineralization of organic matter and dissolution of Ca-P in response to more oxidizing and acidic conditions. The P loss has significant environmental implications regarding eutrophication and marine productivity.  相似文献   

6.
A coupled three-dimensional hydrodynamic–ecological model was used for the assessment of water quality in Narva Bay during one biologically active season. Narva Bay is located in the south-eastern Gulf of Finland. Narva River with a catchment’s area covering part of Russia and Estonia discharges water and nutrients to Narva Bay. The ecological model includes phytoplankton carbon, nitrogen and phosphorus, chlorophyll a, zooplankton, detritus carbon, nitrogen and phosphorus, inorganic nitrogen, inorganic phosphorus and dissolved oxygen as state variables. Both the hydrodynamic and ecosystem models were validated using a limited number of measurements. The hydrodynamic model validation included comparison of time series of currents and temperature and salinity profiles. The ecological model results were compared with the monitoring data of phytoplankton biomass, total nitrogen and phosphorus and dissolved oxygen. The comparison of hydrodynamic parameters, phytoplankton biomass, surface layer total phosphorus and dissolved oxygen and near-bottom layer total nitrogen was reasonable. Time series of spatially mean values and standard deviations of selected parameters were calculated for the whole Narva Bay. Combining model results and monitoring data, the characteristic concentrations of phytoplankton biomass, total nitrogen and phosphorus and near-bottom dissolved oxygen were estimated. Phytoplankton biomass and total phosphorus showed seasonal variations, of 0.6–1.1 and 0.022–0.032 mg/l, respectively, during spring bloom, 0.1–0.3 and 0.015–0.025 mg/l in summer and 0.2–0.6 and 0.017–0.035 mg/l during autumn bloom. Total nitrogen and near-bottom oxygen concentrations were rather steady, being 0.25–0.35 and 2–6 mg/l, respectively. The total nitrogen and phosphorus concentrations show that according to the classification of Estonian coastal waters, Narva Bay water belongs to a good water quality class.  相似文献   

7.
This study presents an integrated k-means clustering and gravity model (IKCGM) for investigating the spatiotemporal patterns of nutrient and associated dissolved oxygen levels in Tampa Bay, Florida. By using a k-means clustering analysis to first partition the nutrient data into a user-specified number of subsets, it is possible to discover the spatiotemporal patterns of nutrient distribution in the bay and capture the inherent linkages of hydrodynamic and biogeochemical features. Such patterns may then be combined with a gravity model to link the nutrient source contribution from each coastal watershed to the generated clusters in the bay to aid in the source proportion analysis for environmental management. The clustering analysis was carried out based on 1 year (2008) water quality data composed of 55 sample stations throughout Tampa Bay collected by the Environmental Protection Commission of Hillsborough County. In addition, hydrological and river water quality data of the same year were acquired from the United States Geological Survey's National Water Information System to support the gravity modeling analysis. The results show that the k-means model with 8 clusters is the optimal choice, in which cluster 2 at Lower Tampa Bay had the minimum values of total nitrogen (TN) concentrations, chlorophyll a (Chl-a) concentrations, and ocean color values in every season as well as the minimum concentration of total phosphorus (TP) in three consecutive seasons in 2008. The datasets indicate that Lower Tampa Bay is an area with limited nutrient input throughout the year. Cluster 5, located in Middle Tampa Bay, displayed elevated TN concentrations, ocean color values, and Chl-a concentrations, suggesting that high values of colored dissolved organic matter are linked with some nutrient sources. The data presented by the gravity modeling analysis indicate that the Alafia River Basin is the major contributor of nutrients in terms of both TP and TN values in all seasons. With this new integration, improvements for environmental monitoring and assessment were achieved to advance our understanding of sea-land interactions and nutrient cycling in a critical coastal bay, the Gulf of Mexico.  相似文献   

8.
The present study investigated the impacts of treated effluent discharge on physicochemical and biological properties of coastal waters from three pharmaceuticals situated along the coast of Visakhapatnam (SW Bay of Bengal). Seawater samples were collected (during the months of December 2013, March 2014 and April 2014) from different sampling locations (Chippada (CHP), Tikkavanipalem (TKP) and Nakkapalli (NKP)) at 0- and 30-m depths within 2-km radius (0.5 km = inner, 1 km = middle and 2 km?=?outer sampling circles) from the marine outfall points. Physicochemical and biological parameters, which differed significantly within the stations, were likely to be influenced by strong seasonality rather than local discharge. Dissolved oxygen variability was tightly coupled with both physical and biological processes. Phytoplankton cell density and total chlorophyll (TChla) concentrations were significantly correlated with dissolved inorganic nutrient concentrations. CHP (December) represented a diatom bloom condition where the highest concentrations of diatom cells, total chlorophyll (TChla), dissolved oxygen coupled with lower zooplankton abundance and low nutrient levels were noticed. The centric diatom, Chaetoceros sp. (>?50%) dominated the phytoplankton community. TKP (March) represented a post-diatom bloom phase with the dominance of Pseudo-nitzschia seriata; zooplankton abundance and nutrient concentrations were minimum. Conversely, NKP (April) represented a warm well-stratified heterotrophic period with maximum zooplankton and minimum phytoplankton density. Dinoflagellate abundance increased at this station. Relatively higher water temperature, salinity, inorganic nutrients coupled with very low concentrations of dissolved oxygen, TChla and pH were observed at this station. Copepods dominated the zooplankton communities in all stations and showed their highest abundance in the innermost sampling circles. Treated effluent discharge did not seem to have any significant impact at these discharge points.  相似文献   

9.
Five crude oil flow stations saver pit effluents were sampledduring the months of May, June, July and August to determinesome of their physico-chemical qualities and microbiologicaldensities before their discharge into the environment. Standardanalytical techniques were employed in the investigation. A highmicrobial density in the range of 106 cfu mL-1 was observed in the samples. The high coliform count obtained poses apotential threat to the local inhabitants of the area. Thephysico-chemical qualities of the effluents appear to falloutside acceptable standards. The pH of the effluent fell belowthe desirable range of 7.0 to 8.5 in May and August inflowstations 3, 4 and 5. Total dissolved solids were above thehighest desirable levels for most months from June to August inall flowstations. Dissolved oxygen levels fell below minimumdesirable level of 2.0 mg L-1 in August for flowstations 1, 2, and4. Adequate treatment of the effluent is required especiallyduring the month of August before discharge into the environment.  相似文献   

10.
The Bothnian Bay, which is the northernmost part of the Gulf of Bothnia in Northern Finland, is affected by effluents discharged from point sources such as the pulp and paper mills of Stora Enso Oyj Veitsiluoto Mill and Oy Metsä-Botnia Ab Kemi Mill at Kemi, and the Kemi municipal sewage plant, as well as the River Kemijoki. In this paper we discuss, how modernisation of the wastewater treatment plant at the mills, and process investments in the Best Available Techniques (BAT) for effluent treatment, have decreased the effluent discharges of biological oxygen demand (BOD), chemical oxygen demand (COD), total phosphorus (Tot-P), total nitrogen (TOT-N), total suspended solids (TSS) and adsorbable organically bound halogens (AOX) from the mills since 1988. One specific aim of the study was to determine the EOX (Extractable Organically Bound Halogens) concentrations in bottom sediment of the Bothnian Bay in order to assess whether the EOX concentrations reflect the reduction in discharges of chlorinated compounds. According to the monitoring program carried out every third year between 1997–2006, the decreasing trend in EOX concentrations in the top 2 cm of the bottom sediment reflect the decrease in organochlorine discharges (AOX) from the mills. In 1997 the EOX concentrations in bottom sediment varied between 3–70 μg of Cl g?1 (dry weight), and in 2006 between 3.3–32 μg of Cl g?1 (dry weight).  相似文献   

11.
Capture-based aquaculture of Atlantic bluefin tuna in the Mediterranean has been expanding rapidly but little is known about its environmental impact. In order to understand the consequences of this new sector, long-term monitoring is needed. For this purpose, we investigated the impact of a capture-based tuna farm located in the Gerence Bay (Aegean Sea) on the water column on a seasonal basis from 2005 to 2008, where in the water column, temperature, salinity, pH, dissolved oxygen, nutrients (nitrite, nitrate, ammonium, and phosphate), and chlorophyll a, in the sediment organic carbon variables were measured. Although highest nutrient concentrations were observed at the cage station as compared to the two controls in the production period, differences were not statistically significant between stations. Monitoring of physico-chemical parameters, nutrients, and chlorophyll a in water column together with organic carbon in sediment did not show detectable impact of fattening of Atlantic bluefin tuna. This was probably caused by strong currents present in the area, location of the cages away from the coast, hence high water depth, controlled feeding, and periodic presence of tuna farming activity in the study area.  相似文献   

12.
A set of geographically isolated differential nitrogen (N) and phosphorus (P) load model scenarios from major Chesapeake basins provides information on the relative impact of nutrient loads on primary production and dissolved oxygen in the Chesapeake Bay. Model results show the relationships of deep water dissolved oxygen with nutrient limitation-related algal blooms, organic carbon loads from the watershed, estuarine circulation, nutrient cycling, and nutrient diagenesis. The combined effect of changes in load from multiple basins is additive for changes in both chlorophyll-a and deep water dissolved oxygen concentrations. Management of both N and P are required in the Chesapeake watershed and tidal waters to achieve water quality standards, but overall efficiencies could be gained with strategies that place greater emphasis on P control in the upper Bay and greater emphasis on N control in the lower Bay. The areas of the Bay with the highest degree of dissolved oxygen degradation that generally drive management decisions are mostly P-limited and are significantly influenced by the load from the upper Bay’s basins. Reducing P from the upper Bay’s basins will intensify P limitation and would allow an increase in N of about six times the weight of P reduction. Combining the relative nutrient reduction effectiveness with the relative control cost information could improve management efficiency and provide benefits at a lower cost. This article describes initial steps that can be taken to examine the benefits from N-P exchanges.  相似文献   

13.
Perdido Bay is a shallow estuarine system of approximately 130 km2 with three major freshwater inputs. On a seasonal basis the productivity and chlorophyll a concentration of phytoplankton in Perdido Bay are controlled by temperature. One input, Eleven Mile Creek, is influenced by a paper mill discharge. Eleven Mile Creek exhibits high levels of light attenuation, high concentrations of dissolved nutrients, and low rates of carbon fixation that are significantly different from the other inputs or areas of Perdido Bay and productivity in Eleven Mile Creek is light limited. Upper Perdido Bay had slightly elevated concentrations of dissolved nutrients which correlate with significantly higher rates of carbon fixation and phytoplankton biomass. Nutrients and color from Eleven Mile Creck are diluted by the Perdido River inflow, restricting nutrient and light limitations to the area at the mouth of Eleven Mile Creek.  相似文献   

14.
Coastal aquaculture is faced with extreme variation in water quality. The Deeba Triangle on Lake Manzala is the largest marine coastal aquaculture-producing area on the Egyptian Mediterranean. Samples from 16 ponds were taken during four seasons (2014–2015), to investigate the variation of 12 water quality parameters at that region. We tested the hypothesis that there is no spatial or temporal variation in water quality of the fish ponds. Fish ponds were statistically clustered into three groups (p?=?0.0005) coincident with their geographical location. Hypersaline and transparent waters characterized the western ponds; higher dissolved oxygen and higher nutrients characterized the central region. These spatial differences were principally due to variations in salinity and nutrients of the water sources used for irrigation of the ponds and to differences in the aeration management styles. Strong seasonality was seen in water temperature (following air temperature), nutrients, and turbidity (following the seasonal cycles of various water sources from the Lake Manzala and the seasonality of the petrochemical plants effluents close to these ponds). We conclude that municipal effluents significantly affected, spatially and temporally, the quality of the irrigation water used for coastal aquaculture purposes, which consequently might affect fish yield.  相似文献   

15.
Cu, Pb, and Hg concentrations were determined in surface sediment samples collected at three sites in San Jorge Bay, northern Chile. This study aims to evaluate differences in their spatial distribution and temporal variability. The highest metal concentrations were found at the site “Puerto”, where minerals (Cu and Pb) have been loaded for more than 60 years. On the other hand, Hg does not pose a contamination problem in this bay. Cu and Pb concentrations showed significant variations from 1 year to another. These variations seem to be a consequence of the combination of several factors, including changes in the loading and/or storage of minerals in San Jorge Bay, the dredging of bottom sediments (especially at Puerto), and seasonal changes in physical–chemical properties of the water column that modify the exchange of metals at the sediment–water interface. Differences in the contamination factor and geoaccumulation index suggest that pre-industrial concentrations measured in marine sediments of this geographical zone, were better than geological values (average shale, continental crust average) for evaluating the degree of contamination in this coastal system. Based on these last two indexes, San Jorge Bay has a serious problem of Cu and Pb pollution at the three sampling locations. However, only Cu exceeds the national maximum values used to evaluate ecological risk and the health of marine environments. It is suggested that Chilean environmental legislation for marine sediment quality—presently under technical discussion—is not an efficient tool for protecting the marine ecosystem.  相似文献   

16.
Waste stabilization pond is an artificial ecosystem; its performance is governed by the nature of the biological communities it supports. These are primarily used as secondary effluent treatment plants to polish the effluents. However, they are also used to treat the raw sewage and industrial effluents. In the present study, the functioning of a waste stabilization pond system from an industrial complex located in Goa was taken up. The raw waste released by the industrial complex and the final effluent released from the stabilization ponds were analyzed for pH, dissolved oxygen (DO), biological oxygen demand, phosphate content, chlorophyll content, and algal diversity and density. Also, the activities of the enzymes catalase and phosphatase were measured. The study was carried out for a period of 1 year and the data covering pre-monsoon, monsoon, and post-monsoon seasons are tabulated. The study revealed that DO, chlorophyll content, and algal count were maximum during pre-monsoon when compared to monsoon and post-monsoon. Similarly, maximum enzymatic activity was recorded during pre-monsoon and also maximum removal of biological oxygen demand and phosphate was recorded during this period than in monsoon and post-monsoon.  相似文献   

17.
The long-term water quality monitoring program implemented by the Massachusetts Water Resources Authority in 1992 is extensive and has provide substantial understanding of the seasonality of the waters in both Boston Harbor and Massachusetts Bay and the response to improvements in effluent quality and offshore transfer of the effluent in September 2000. The monitoring program was designed with limited knowledge of spatial and temporal variability and long-term trends within the system. This led to an extensive spatial and temporal sampling program. The data through 2003 showed high correlation within physical parameters measured (e.g., salinity, dissolved oxygen) and in biological measures such as chlorophyll fluorescence. To address the potential sampling redundancies in the measurement program, an assessment of the impact of reduced levels of monitoring on the ability to make water quality decisions was completed. The optimization was conducted by applying statistical models that took into account whether there was evidence of a seasonal pattern in the data. The optimization used model survey average readings to identify temporal fixed effects, model survey-average-corrected individual station readings to identify spatial fixed effects, corrected the individual station readings for temporal and spatial fixed effects and derived a correlation model for the corrected data, and applied the correlation model to characterize the correlation of annual average readings from reduced monitoring programs with true parameter levels. Reductions in the number of sampling stations were found less detrimental to the quality of the data for annual decision-making than reductions in the number of surveys per year, although there is less of a difference in this regard for dissolved oxygen than there is for chlorophyll. The analysis led to recommendations for a substantially lower monitoring effort with minimal loss of information. The recommendation supported an annual budget savings of approximately $183,000. Most of the savings was from fewer surveys as approximately $21,000 came from the reduction in the number of stations monitored from 21 to 7 and associated laboratory analytical costs.  相似文献   

18.
The impact of liquid wastes from a paper mill on the benthic diatoms in flowing waters has been studied for a period of two years. Water and algal samples were analysed at monthly intervals at three sites along the course of the river, along with raw effluents. The water before the confluence of effluents was well oxygenated with an alkaline pH. Organic matter, NH3 and nutrients were recorded at low concentrations. At the entry of effluents, the water showed considerable decline in dissolved oxygen content, increase in organic matter, hardness, Cl, HCO3 and total dissolved solids. Diatoms constituted 61% by numerical abundance and were reduced to 25% of total algae at the entry of effluents. Multiple regression analysis was employed to discover the relative importance of various physicochemical variables on the abundance and distribution of diatoms at various sampling stations. Mathematical equations were derived involving the physicochemical variables for better prediction of algal number.  相似文献   

19.
The extraction of coal and coal seam gas (CSG) will generate produced water that, if not adequately treated, will pollute surface and groundwater systems. In Australia, the discharge of produced water from coal mining and related activities is regulated by the state environment agency through a pollution licence. This licence sets the discharge limits for a range of analytes to protect the environment into which the produced water is discharged. This study reports on the impact of produced water from coal mine activities located within or discharging into high conservation environments, such as National Parks, in the outer region of Sydney, Australia. The water samples upstream and downstream from the discharge points from six mines were taken, and 110 parameters were tested. The results were assessed against a water quality index (WQI) which accounts for pH, turbidity, dissolved oxygen, biochemical oxygen demand, total dissolved solids, total phosphorus, nitrate nitrogen and E .coli. The water quality assessment based on the trace metal contents against various national maximum admissible concentration (MAC) and their corresponding environmental impacts was also included in the study which also established a base value of water quality for further study. The study revealed that impacted water downstream of the mine discharge points contained higher metal content than the upstream reference locations. In many cases, the downstream water was above the Australia and New Zealand Environment Conservation Council and international water quality guidelines for freshwater stream. The major outliers to the guidelines were aluminium (Al), iron (Fe), manganese (Mn), nickel (Ni) and zinc (Zn). The WQI of surface water at and downstream of the discharge point was lower when compared to upstream or reference conditions in the majority of cases. Toxicology indices of metals present in industrial discharges were used as an additional tool to assess water quality, and the newly proposed environmental water quality index (EWQI) lead to better trend in the impact of coal and coal seam gas mining activities on surface water quality when compared to the upstream reference water samples. Metal content limits were based on the impact points assigned by the Agency for Toxic Substances and Disease Registry, USA. For environmental and health impact assessment, the approach used in this study can be applied as a model to provide a basis to assess the anthropogenic contribution from the industrial and mining activities on the environment.  相似文献   

20.
Field surveys were carried out from January 2007 to December 2008 to investigate seasonal variations of dissolved inorganic nitrogen (DIN) and phosphorus (DIP) transported to the Linjiang Bay of the Three Gorges Reservoir, China. The results revealed that both DIN and DIP exhibited large seasonal variability. DIN (dominated by NH4?CN) concentrations were drastically higher in the dry season than those in the rainy season, and the same seasonal patterns of DIP concentrations and DIN and DIP fluxes were observed but inverse to that of DIN concentrations. The interannual variation in DIN fluxes descended by 28.2% from 2007 to 2008, while DIP fluxes increased by 40.9%, which were closely constant with interannual changes in DIN and DIP concentrations, respectively. The study indicated that nutrient fluxes (DIN and DIP) were strongly correlated with both nutrient concentrations and river discharge, and the Linjiang Bay received approximately 3,416 × 103 kg DIN and 324 × 103 kg DIP every year. In addition, DIN mainly originated from point sources, but DIP originated from non-point sources. It is shown that to control point source pollution is the most effective step for water quality improvement and reducing nutrient loading inputs in the Linjiang Bay.  相似文献   

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