1986-2020年上海苏州河水质时空变化特征

以1986-2020年苏州河水质监测数据为依据,将水质变化过程划分成1986-1996年、1997-2006年和2007-2020年3个阶段,系统分析了苏州河水质状况及多年时空变化特征。结果表明,在第1阶段(1986-1996年),苏州河整体处于重度污染水平,从上游到下游水质显著恶化,市区段污染严重;在第2阶段(1997-2006年),苏州河市区段水质显著改善,有机污染指标消除劣Ⅴ类,氨氮和总磷仍处于较高污染水平,上下游水质逐渐趋同;在第3阶段(2007-2020年),苏州河水质持续改善,特别是2016年以来改善明显,2020年水质达到34年来的最好水平。苏州河水质改善与上海市实施的全市及苏州河多轮环境综合治理工程、上游来水水质改善等密切相关,反映了苏州河30多年环境综合治理的突出成效,并为城市黑臭水体治理提供经验。     

苏州河干流水质自动监测系统数据的可靠性分析

以苏州河干流水质自动监测系统为例,通过与实验室数据之间的统计分析,分析苏州河水质在线自动监测系统数据的可靠性。对比分析自动监测系统和实验室的温度、p H、DO、CODMn、NH3-N数据,自动监测系统数据合格,在0.01水平上两者不存在显著性差异,2种方法的结果高度相关,苏州河水质在线自动监测系统测定的数据真实可靠。在自动监测系统的维护中,要对系统关键部分进行不定期的清洗,特别是出现较可疑数据时,应及时寻找原因,解决问题。     

辽河水体主要污染指标时空异质性分析

利用1987～2009年辽河干流8个常规监测断面的历年监测数据,通过统计分析确定辽河水质的主要污染指标为化学需氧量(COD)和氨氮,2007年前辽河水质首要污染指标是COD,2008年和2009年氨氮超过COD成为辽河水质污染首要污染指标;分析干流两项指标的时间、水期、空间分布规律,明确给出水质污染重点治理时段和河段.     

小型岸边站技术在水质自动监测中稳定性和可靠性分析

以苏州河水质自动监测岸边站为例,根据近3年实际运行情况,从实样验收比对、连续运行比对等方面系统比较自动监测和实验室分析数据,深入探讨小型岸边站技术的稳定性和可靠性。结果表明:岸边站在线监测数据总体较为稳定,水温、溶解氧、p H、氨氮等监测结果和变化规律与实验室数据具有较好的相关性和一致性,其中,水温、p H、氨氮等指标均不存在明显差异,苏州河水质自动在线岸边站测定的数据真实可靠。加强自动站运维管理等可以进一步提高自动站数据质量。     

黄浦江水环境生物监测指标研究

对黄浦江进行了全面的生物监测及评价.通过相关性分析表明,底栖生物的Shnnon-Weaver指数和Coodnight指数与水质综合评价指数呈显著负相关;细菌总数和总大肠菌群数与水质综合评价指数呈显著正相关,R2值均＞0.9,能较敏感地反映水质变化的生态效应,构成了黄浦江水环境生物监测核心指标.     

水质自动监测与常规监测结果对比分析

为了系统研究水质自动监测数据与常规监测数据间差异问题,选取15个运行多年的国家地表水水质自动监测站,对p H、溶解氧(DO)、高锰酸盐指数(COD_(Mn))、氨氮(NH_3-N)及总磷(TP)5项监测指标开展了站房外常规监测、站房内常规监测与自动监测的对比实验研究。通过分析监测结果之间相对误差、相对偏差、水质类别变化发现,站房内常规监测、站房外常规监测与自动监测结果之间误差较小;同时通过误差统计分析及直方图分析发现,地表水水质自动监测系统监测结果与站房外常规监测结果之间误差整体属于随机误差(偶然误差)。研究得到了水质自动监测与常规监测数据一致可比的结论,为水质自动监测数据的应用提供了实验基础。     

水质自动监测参数的相关性分析及在水环境监测中的应用

通过水质自动监测数据与常规监测数据比较，表明了自动监测与常规监测数据的一致性；通过对自动监测数据分析，发现五参数可以更直接地反映水质变化，并且五参数之间以及五参数与其他监测指标之间都存在一定的相关性；典型污染事故预警监测案例的分析，更加凸显了五参数连续监测在预警监测中的重要性。     

袁河袁州区段溶解氧过饱和成因分析及防治

2020年8月15日袁河袁州区段(棚下-袁河水厂取水口)出现溶解氧过饱和现象,为了解该河段溶解氧的变化及提高河道流量前后对水生态环境的影响,将该段河道分为6个监测断面,于8月16—24日监测每个监测点的常规水质、浮游植物群落结构、溶解氧和实时流量.结果表明:自然状态下袁河袁州区段溶解氧沿水流方向从6.8 mg/L逐渐增...     

古泊善后河水质污染特征及污染来源调查

以2016—2020年古泊善后河国家和省级地表水监测网水质例行监测数据为依据,采用水质指数法(WQI)对古泊善后河水质污染状况进行综合评价;基于水质评价结果,选取影响最大的两项指标COD_Mn和TP,于2020年10月对古泊善后河开展加密监测,调查分析污染来源。结果表明,2016—2020年古泊善后河水质波动变化较大,汛期降雨对水质下降影响明显,COD_Mn、TP、COD_Cr、氟化物和BOD₅是影响古泊善后河水质的主要指标;加密监测期间,古泊善后河干流水质COD_Mn和TP指标浓度分别升高28.9%、38.3%,其中宿迁段升幅显著高于连云港段;支流水质超Ⅲ类比例为22.9%,劣Ⅴ比例为6.3%;部分乡镇生活污水直排和持续降雨将农田中高浓度污染物冲刷进河流支浜,是导致水质下降的主要原因。     

城市河道水质模拟研究

对玉绣河研究河段进行长期监测,确定玉绣河研究河段的主要水质问题是富营养化.选取叶绿素a作为富营养化的指示参数,并确定NH3-N为限制富营养化的控制性因子.以NH3-N为对象建立玉绣河水质模拟模型,利用监测数据在MATLAB环境中通过矩阵计算验证了所建模型的适用性.并利用MATLAB软件模拟了不同情况下的玉绣河水质变化趋势.进而分析了玉绣河目前存在的问题及需要采取的控制措施.     

苏州市水环境质量调查

简述了1990年—2000年苏州市区水系的变化及京杭运河苏州段沿岸主要工业污染源的变化，对苏州市区水环境质量的变化进行了分析。指出，苏州市区水环境质量的变化主要受水系的改变和污染源防治的共同影响。提出，除继续加强对工业污染源的防治外，还需对水系范围内的生活、农业等方面产生的污染进行防治；在规划水利建设工程时，应将水环境质量的改善与生态建设全面地比较与评价，按其结果再实施工程建设；已建成的环太湖闸在不影响其主要功能的情况下，应保持开启，让优质的太湖水补给运河，从根本上改善苏州市区水环境质量。     

关于河流纳污混合水质概率稀释模型及其应用研究

本文以淮河干流上游息县和维滨两个城关纳污河段为例，根据扩散理论和概率学理论，尝试建立了河流纳污混合水质浓度概率稀释模型。并研究确定了概率稀释模型在河流污染控制中的应用方法和技术路线。与实测结果比较，概率稀释模型方法计算更具有准确性和科学合理性．对水质评价和规划河流污染治理方案具有重要指导意义，对实现淮河水质返清目标有积极贡献。     

Water quality trends in the Delaware River Basin (USA) from 1980 to 2005

In 1940, the tidal Delaware River was ??one of the most grossly polluted areas in the United States.?? During the 1950s, water quality was so poor along the river at Philadelphia that zero oxygen levels prevented migration of American shad leading to near extirpation of the species. Since then, water quality in the Delaware Basin has improved with implementation of the 1961 Delaware River Basin Compact and 1970s Federal Clean Water Act Amendments. At 15 gages along the Delaware River and major tributaries between 1980 and 2005, water quality for dissolved oxygen, phosphorus, nitrogen, and sediment improved at 39%, remained constant at 51%, and degraded at 10% of the stations. Since 1980, improved water-quality stations outnumbered degraded stations by a 4 to 1 margin. Water quality remains good in the nontidal river above Trenton and, while improved, remains fair to poor for phosphorus and nitrogen in the tidal estuary near Philadelphia and in the Lehigh and Schuylkill tributaries. Water quality is good in heavily forested watersheds (>50%) and poor in highly cultivated watersheds. Water quality recovery in the Delaware Basin is coincident with implementation of environmental laws enacted in the 1960s and 1970s and is congruent with return of striped bass, shad, blue crab, and bald eagle populations.     

Seasonal variation in trace metals concentrations in the Ialomita River, Romania

Sampling streams for metals is an important aspect of water-quality monitoring. Using ICP-AES the concentration of some microelements in the Ialomi?a River (Romania) were determined. In order to grasp the different phases of the river regime, samples were collected from its water-sediment interface at seven locations along the river, during three campaigns: during snow melting periods in the mountain zones (April), the period of reduced flow and high water temperature (August) and the period of high precipitations (November). HNO3 was added to the samples for fixation. Cadmium and copper appear accidentally; lead was detected only in samples collected in the vicinity of roads; the MAC (maximum admitted concentration) for surface waters is exceeded for nickel and chromium in samples collected in April and respectively in April and November; zinc concentrations were usually above the MAC; molybdenum concentration was above the set reference value, especially for samples collected in April and November. Possible explanations are given for the presence of the investigated microelements along the river.     

An assessment of heavy metals loading in River Benue in the Makurdi Metropolitan Area in Central Nigeria

River Benue, the second largest river in Nigeria, serves as the major source of municipal water supplies for towns and villages along its course. Water samples from the river were collected at ten stations in the Makurdi metropolitan area (7°44^′ N, 8°32^′ E) in Benue State, Central Nigeria, for 12 months and analyzed for their heavy metals concentration, along with other water-quality parameters such as turbidity, pH, total dissolved solids and total solids. The results revealed that the mean concentrations of heavy metals in the river was in the following ascending order, Cd < Cu < Zn < Mn < Pb < Cr < Fe. The levels of most of the parameters determined, with the exception of Cd, Cr and Pb were, generally, within acceptable limits for drinking water. From the present study, it is concluded that the River Benue is only moderately contaminated with regard to heavy metals, in the Makurdi metropolitan area.     

基于鱼类生物完整性指数的上海苏州河水生态系统健康评价

苏州河横贯上海中心城区，曾是都市污染河流。为从生态学角度揭示苏州河的污染程度，笔者采用鱼类生物完整性指数（F-IBI）评价了苏州河水生态系统的健康状况。分别于2019年6月4—23日（夏季）和9月14—26日（秋季），租用专业渔船在苏州河13个断面采集样本，共采集到10 102尾鱼类，隶属于8目15科37属45种。以大莲湖为参照点，通过判别分析和关联度筛选，从5大类29个初选指标中筛选出10个指标，构建了苏州河F-IBI评价指标体系。分析结果表明：夏季干流上游的5个断面状况为"极好"或"好"，支流3个断面为"好"或"一般"，而干流下游的5个断面则为"差"或"极差"。秋季干流上游5个断面和支流3个断面与夏季的健康状况相似，下游断面则有所改善，仅武宁路桥为"极差"，其余均为"一般"或"差"。研究显示苏州河上游干流的水生态系统已基本恢复，而上游支流和下游干流还未建立健康稳定的水生态系统。建议苏州河环境综合整治第四期工程要更加注重治理岸上的污染源，同步实施干支流水系的污染治理，定期开展城区段淤泥清理，实施岸线的生态化改造。     

Information theoretic perspective on coastal water-quality monitoring and management near an offshore industrial park

A semi-continuous water-quality monitoring system was installed in Yunlin Offshore Industrial Park (YOIP), the largest industrial park in Taiwan, in 2007 to provide real-time water-quality information such as pH, water depth, dissolved oxygen, temperature, turbidity, conductivity, and chlorophyll. To interpret the large quantities of high-frequency data generated by this system, information theory was applied for data analysis and extraction of useful information for further coastal water-quality management. Information theory is a branch of applied mathematics that involves the quantification of information. Shannon entropy is a key measure of information that was calculated in this study to reveal the inherent uncertainty of water-quality information. The applicability of Shannon entropy for signaling possible coastal pollution events in the YOIP was explored and results showed that it provides new insight into the inherent uncertainty or randomness of the original data. Specially, when Shannon entropy was high, multiple instable readings were observed for turbidity and salinity. This indicates that Shannon entropy may be a useful new tool for exploratory data analysis. It can be used as a supplementary indicator along with the original environmental data to signify some episodes of water-quality degradation.     

四川省毛河流域污染综合治理方案探讨

分析了四川省毛河流域各类污染源分布状况及水质现状,采用一维稳态单组分水质模型、多宾斯-坎普稳态模型,引入水文数据、水质监测数据、环境统计数据、社会统计公报数据,以Excel作为数据平台,对毛河水环境进行了动态模拟,反演出主要污染物降解系数。总结了毛河水环境目前存在的问题,并模拟计算了2种污染综合治理方案实施后对毛河水质的影响,确定了毛河流域水污染综合治理的重点以及制约因子。     

渭河干流(宝鸡段)表层沉积物Cu、Zn、Pb污染特征与评价

对渭河干流（宝鸡段）表层沉积物中重金属Cu、Zn、Pb含量进行了调查，用潜在生态危害系数法对其污染水平进行了评价，并与松花江（吉林市段）、淮河（江苏段）、长江（下游）、苏州河、珠江（广州段）5条河流表层沉积物中Cu、Zn、Pb的含量做了对比研究。结果表明，3种重金属元素平均含量均超出相应的土壤背景值，出现了一定程度上的富集；生态危害系数均〈40，属轻微生态危害。重金属含量水平在国内诸河中处于中间位置。