燃煤烟气中CO_2脱除方法的分析与探讨

作为主要的温室气体,CO2减排问题引起全球范围的广泛关注。阐述了燃煤烟气中CO2脱除的多种方法,分析比较了CO2的吸收法、吸附法、膜分离法等的特点及各自的优缺点,侧重介绍了有机胺和氨水脱除的技术进展,并介绍了氨水烟气脱碳的部分试验结果。     

欧盟国家燃煤电厂环保政策及技术路线分析

温室气体的排放控制作为全球性的环境问题受到了广泛关注。中国是火力发电的大国,其燃煤机组的温室气体排放总量巨大。《火电厂大气污染物排放标准》（GB 13223-2011）提高了我国燃煤电厂的烟气污染物排放的要求,对火电厂烟气处理的技术选择和投资都会产生重大影响。针对中国燃煤电厂环保面临的新形势,阐述了欧盟国家的环保政策重点,并对欧盟国家燃煤电厂污染物控制的相关标准进行了分析,同时简要介绍了欧盟国家燃煤电厂环保的主要技术路线,在一定程度上可作为中国燃煤电厂污染物控制的借鉴和参考。     

火电厂CO_2减排技术及成本探讨

介绍了我国火电厂CO2排放特点,阐述了火电厂CO2减排技术、成本及影响因素,分析了CO2减排对中国未来能源和经济的影响。指出最适合CO2捕集技术发展的电厂类型是超超临界燃煤电厂和IGCC电厂,CO2减排技术的研发重点是大幅度降低成本和效率损失。     

火电厂CO2捕集与封存技术探讨

火电厂CO2减排技术主要包括燃烧前处理、燃烧中减排及燃烧后捕集三类。介绍了IGCC、富氧燃烧、胺吸收法、生物法等CO2捕集与封存技术,分析其存在问题及应用前景。     

流化床O2/CO2燃烧技术和化学链燃烧技术

O2／CO2燃烧技术不仅能使分离收集CO2和处理SO2容易进行，还能减少NOx排放，是一种能够综合控制燃煤污染物排放的新型洁净燃烧技术。流化床O2／CO2燃烧技术将流化床和O2／CO2燃烧技术的优点结合起来，有可能取得更好的效果。化学链燃烧技术打破了自古以来的火焰燃烧概念，开拓了根除燃料型NOx生成、控制热力型NOx产生与回收CO2的新途径，是解决能源与环境问题的创新性突破口。介绍了流化床O2／CO2燃烧技术和流化床化学链燃烧技术的原理和研究现状，比较了它们之间的差别，展望了发展前景。     

水泥工业的废弃物利用与CO2排放控制探讨

水泥工业不仅通过能源利用排放CO2,而且还是工业生产工艺过程中CO2的最大非能源利用排放源.分析了水泥工业的发展现状及其能源消耗状况,计算了水泥工业的CO2排放总量和分途径CO2排放量,介绍了水泥工业的废弃物利用和控制水泥工业CO2排放方面的一些具体技术,提出了一些针对水泥工业的CO2排放控制措施和新型富氧燃烧技术应用于水泥工业的设想.     

控制CO2排放 实现人类可持续发展

科学研究表明：无论是煤炭、石油还是天然气，碳是所有化石燃料的重要组成部分。这些燃料在燃烧提供能源时均释放出温室气体CO2。联合国政府间气候变化专门委员会的研究表明，     

火电厂NOx污染排放控制方法探讨

NOx的排放控制是火电厂未来环境保护的重要任务。从控制燃烧过程中NOx的生成以及在燃烧后脱除烟气中NOx两个方面探讨了减少NOx排放的有效技术。     

钢铁企业制定温室气体排放监测计划的重点与难点

介绍了在钢铁企业温室气体排放工作中监测计划的重要性,研究了国内外温室气体排放政策对监测计划的要求,提出了钢铁企业制定温室气体排放监测计划的重点与难点。     

信息

控制CO2排放实现人类可持续发展科学研究表明:无论是煤炭、石油还是天然气,碳是所有化石燃料的重要组成部分。这些燃料在燃烧提供能源时均释放出温室气体CO2。联合国政府间气候变化专门委员会的研究表明,如果不采取积极的减排措施,到2100年,全球平均气温将上升1.8~4℃,恶劣天气更加频繁,人类可持续发展的目标将面临严峻的威胁。国电石嘴山第一发电有限公司2号炉烟气脱硫工程通过168h试运行2007年2月15日,由国电环境保护研究院总承包建设的国电石嘴山第一发电有限公司2号炉烟气脱硫工程顺利通过168h试运行。试运行结果表明:2号炉脱硫装置运…     

发展中国家（地区）风电装机规划及我国风电发展重点建议

在全球风电市场稳步发展的背景下,发展中国家（地区）的风电市场也都呈现快速发展的趋势,在各国风电发展持续升温的前提下,未来我国风电发展潜力巨大。列举了非洲、印度、拉丁美洲、东欧、中东等5个发展中国家（地区）未来风电发展规划情况,在总结这些国家或地区风电发展特点的基础上,对我国未来风电发展提出建议。     

国外光伏发电并入智能电网发展探讨

智能电网是未来电网发展的主要趋势。随着人们对环境保护的重视,如何将风能、太阳能等可再生能源大规模接入电网已经成为智能电网下一阶段的研究方向。介绍了国外光伏发电技术发展,概述了国外对光伏发电并入智能电网的最新研究,提出了光伏并网发电面临的问题以及相关建议,为我国未来光伏并网发电的实施提供参考。     

Mathematical modelling of particle mixing effect on the combustion of municipal solid wastes in a packed-bed furnace

Packed bed combustion is still the most common way to burn municipal solid wastes. In this paper, a dispersion model for particle mixing, mainly caused by the movement of the grate in a moving-burning bed, has been proposed and transport equations for the continuity, momentum, species, and energy conservation are described. Particle-mixing coefficients obtained from model tests range from 2.0x10(-6) to 3.0x10(-5)m2/s. A numerical solution is sought to simulate the combustion behaviour of a full-scale 12-tonne-per-h waste incineration furnace at different levels of bed mixing. It is found that an increase in mixing causes a slight delay in the bed ignition but greatly enhances the combustion processes during the main combustion period in the bed. A medium-level mixing produces a combustion profile that is positioned more at the central part of the combustion chamber, and any leftover combustible gases (mainly CO) enter directly into the most intensive turbulence area created by the opposing secondary-air jets and thus are consumed quickly. Generally, the specific arrangement of the impinging secondary-air jets dumps most of the non-uniformity in temperature and CO into the gas flow coming from the bed-top, while medium-level mixing results in the lowest CO emission at the furnace exit and the highest combustion efficiency in the bed.     

燃煤电厂除尘器的应用和选择研究

对目前我国燃煤电厂中使用较多的几种除尘器——电除尘器、袋式除尘器及电袋复合除尘器的原理、发展及应用进行了介绍和阐述,并结合几种除尘器的特点和国内外运行实例,就我国燃煤电厂除尘器的选择提出了建议。     

Hazardous waste incineration in context with carbon dioxide.

The Kyoto Protocol of 1997 demands an emission reduction of climate-affecting gases in various industrial sectors. In this context CO2 is one of the relevant gases and waste management is one of the relevant sectors. Referring to the situation in Europe, waste incineration is one of the major sources of CO2 in the waste management sector. The Kyoto Protocol, however, only covers CO2-emissions originating from fossil fuels, whereas the incineration of renewable materials, e.g. wood, is considered to be climate-neutral since it does not make any net contribution to the CO2 inventory of the atmosphere. Unlike the situation with municipal waste, there is little if any information on the CO2-emissions caused by the incineration of hazardous waste in specialized plants, and the renewable fraction in these materials. The present paper focuses on this gap of knowledge. Taking the full-scale hazardous waste incineration plant in Biebesheim, Germany, as an example, a carbon balance was set up for the whole-plant taking into account all other material flows. Afterwards the determination of the proportion of renewable materials in the hazardous waste incinerated by means of the radiocarbon method (14C) is reported. On the basis of the results, optimization potentials are discussed.     

Pyrolysis of municipal plastic wastes II: Influence of raw material composition under catalytic conditions

In this work, the results obtained in catalytic pyrolysis of three plastic waste streams which are the rejects of an industrial packing wastes sorting plant are presented. The samples have been pyrolysed in a 3.5 dm(3) reactor under semi-batch conditions at 440 °C for 30 min in nitrogen atmosphere. Commercial ZSM-5 zeolite has been used as catalyst in liquid phase contact. In every case, high HHV gases and liquids which can be useful as fuels or source of chemicals are obtained. A solid fraction composed of the inorganic material contained in the raw materials and some char formed in the pyrolysis process is also obtained. The zeolite has shown to be very effective to produce liquids with great aromatics content and C3-C4 fraction rich gases, even though the raw material was mainly composed of polyolefins. The characteristics of the pyrolysis products as well as the effect of the catalyst vary depending on the composition of the raw material. When paper rich samples are pyrolysed, ZSM-5 zeolite increases water production and reduces CO and CO(2) generation. If stepwise pyrolysis is applied to such sample, the aqueous liquid phase can be separated from the organic liquid fraction in a first low temperature step.     

Pyrolysis of municipal plastic wastes: Influence of raw material composition

The objective of this work is the study of pyrolysis as a feedstock recycling process, for valorizing the rejected streams that come from industrial plants, where packing and packaging wastes are classified and separated for their subsequent mechanical recycling. Four real samples collected from an industrial plant at four different times of the year, have been pyrolysed under nitrogen in a 3.5 dm³ autoclave at 500 °C for 30 min. Pyrolysis liquids are a complex mixture of organic compounds containing valuable chemicals as styrene, ethyl-benzene, toluene, etc. Pyrolysis solids are composed of the inorganic material contained in the raw materials, as well as of some char formed in the pyrolysis process, and pyrolysis gases are mainly composed of hydrocarbons together with some CO and CO₂, and have very high gross calorific values (GCV).It has been proved by the authors that the composition of the raw material (paper, film, and metals contents) plays a significant role in the characteristics of pyrolysis products. High paper content yields water in the pyrolysis liquids, and CO and CO₂ in the gases, high PE film content gives rise to high viscosity liquids, and high metals content yields more aromatics in the liquid products, which may be attributed to the metals catalytic effect.     

湿法脱硫装置SO2吸收系统增容改造方案探讨

国内越来越多火电厂石灰石—石膏湿法脱硫装置因燃煤硫分变化及其他原因需要进行增容改造。介绍了湿法烟气脱硫装置核心SO2吸收系统4种可行的增容改造方案,即塔外浆液箱方案、串联塔方案、并联塔方案、吸收塔重建方案,并对各方案的优缺点和适应性进行比较和论述,为同类烟气脱硫装置增容改造工程提供参考。     

Pyrolysis of tyres. Influence of the final temperature of the process on emissions and the calorific value of the products recovered

A study was made of the pyrolysis of tyre particles, with the aim of determining the possibilities of using the products resulting from the process as fuel. Three final temperatures were used, determined from thermogravimetric data. The design of the experiment was a horizontal oven containing a reactor into which particles of the original tyre were placed. After the process, a solid fraction (char) remained in the reactor, while the gases generated went through a set of scrubbers where most of the condensable fraction (oils) was retained. Finally, once free of this fraction, the gases were collected in glass ampoules. Solid and liquids fractions were subjected to thermogravimetric analyses in order to study their combustibility. The gas fraction was analysed by means of gas chromatography to establish the content of CO, CO2, H2 and hydrocarbons present in the samples (mainly components of gases produced in the pyrolysis process). A special study was made of the sulphur and chlorine content of all the fractions, as the presence of these elements could be problematic if the products are used as fuel. Tyre pyrolysis engenders a solid carbon residue that concentrates sulphur and chorine, with a relatively high calorific value, although not so high as that of the original tyre. The liquid fraction produced by the process has a high calorific value, which rises with the final temperature, up to 40 MJ/kg. The chlorine content of this fraction is negligible. Over 95% of the gas fraction, regardless of the final temperature, is composed of hydrocarbons of a low molecular weight and hydrogen, this fraction also appearing to be free of chlorine.