Comparison of PM2.5 and PM10 in A Suburban Area in Korea During April, 2003

Airborne particulate matter (PM) concentrations were measured in Iksan, a suburban area in South Korea during April, 2003. PM_2.5 (particles with an aerodynamic diameter less than 2.5 μm) and PM₁₀ (particles with an aerodynamic diameter less than 10 μm) samples were collected, and the chemical characteristics of particles were examined for diurnal patterns, yellow dust/rainfall influences, and scavenging effects. Average concentrations of PM_2.5 and PM₁₀ mass measured were 37.3 ± 16.2 μg m⁻³ and 60.8 ± 29.5 μg m⁻³, respectively. The sum of ionic chemical species concentrations for PM_2.5 and PM₁₀ was 16.9 ± 7.3 and 23.1 ± 10.1 μg/m³, respectively. A significant reduction in PM mass concentrations during rainfall days was observed for coarse mode (PM_{2.5 − 10}) particles, but less reduction was found for fine (PM_2.5) mass concentration. SO₄ ²⁻, NH₄ ⁺, and K⁺ predominated in fine particulate mode, NO₃ ⁻ and Cl⁻ predominated in fine particle mode and coarse particle mode, but Na⁺, Mg²⁺, and Ca²⁺ mostly existed in coarse mode. The high concentration of ammonium due to local emissions and long-range transport neutralized sulfate and nitrate to ammonium sulfate and ammonium nitrate, which were major forms of airborne PM in Iksan. Average mass concentrations of PM₁₀ in daytime and at night were 57.6 and 70.0 μg m⁻³, and those of PM_2.5 were 35.4 and 42.5 μg m⁻³, respectively. NO₃ ⁻ and Cl⁻ in both PM_2.5 and PM₁₀ were about double at night than in the daytime, while the rest of the chemical species were equal or a little higher at night than in the daytime. The results suggest the formation of ammonium nitrate and chloride when high ammonia concentration and low air temperature are allowed. Backward air trajectory analyses showed that air masses arriving at the site during yellow dust period were transported from arid Chinese regions, which resulted in high concentrations of airborne PM mass concentrations. In the meantime, air mass trajectories during a rainfall period were mostly from the Pacific Ocean or the East China Sea, along with a relatively low PM concentration.     

Characterization of Indoor and Outdoor Aerosols in a Suburban Area of Prague

The mass, ionic and elemental size distributions of particulate matter (PM) measured indoors and outdoors in an apartment situated in a north–westward suburb of Prague are presented. The PM samples were collected by two Berner type low pressure impactors separating particles into 10 size fractions from 26 nm to 10 μm and were further analyzed by ion chromatography (IC) and proton induced X-ray emission (PIXE). Temperature, pressure and relative humidity were measured both indoors and outdoors parallel to PM sampling. The indoor and outdoor PM dynamics were recorded by two scanning mobility particle sizers (SMPS) and an aerodynamic particle sizer (APS). Finally, the ventilation rate was determined by a radon technique. Ion chromatography showed that the major inorganic components of the fine particle mode are sulfate, nitrate, and ammonium with very low indoor nitrate concentration. Crustal elements (Al, Si, Ca, Ti, Mn, and Fe) were associated with the coarse aerosol mode. The presence of people increased the mass concentration of coarse particles, whereas cooking, smoking, and burning of incense and candles contributed predominantly to the fine particle mode. Smoking and the burning of incense also increased the concentration of potassium, bromine and chlorine content in fine particles.     

PM10, O3, CO Concentrations and Elemental Analysis of Airborne Particles in a School Building

Measurements of indoor and outdoor PM10, as well as indoor O₃ and CO concentrations were conducted and are presented here. These measurements were carried out at an institute building, located in a suburban industrial area in Greece. Both indoor and outdoor PM10 samples were also collected and their elemental composition was identified by ED-XRF analysis. Twenty seven major, minor and trace elements were identified. The measurements took place generally in different periods of institute operation, from June 2004 to February 2005. The indoor PM10 concentrations which were measured during the normal operation period of the institute were found to be many times higher than the respective outdoor PM10 concentrations of the same periods. On the contrary, the indoor PM10 concentrations which were measured during the holiday period were found to be lower than their corresponding outdoor values. Indoor O₃ and CO concentrations were found to be in low level. Indoor PM10 concentrations were found to be in a relative good correlation with O₃ (r = 0.45) and in high correlation (r = 0.98) with CO concentrations. On average, total elements concentrations were much higher indoors relative to outdoors. Based on above findings we attempted to determine the pollution sources of the indoor environment and to investigate some parameters or chemical processes that affect indoor pollutants’ levels.     

Air Quality Management in Izmir Region of Turkey as Required by Clean Air Plans

As a first step to work out an abatement plan against air pollution, a local emission inventory with 1 hr temporal and 1 km spatial resolution in the city of Izmir and its surroundings was prepared. The study area consisted of a 200 × 170 km² rectangle having the city of Izmir at the centre. The studied pollutants were total particulate matter (PM), sulfur oxides (SO_x), nitrogen oxides (NO_x), volatile organic compounds (VOC) and carbon monoxide (CO). Emissions of these pollutants were determined by estimation methods making use of suitable emission factors. Emission sources were evaluated in three categories; point, area and line sources. For year 2000 total emissions in the study area on an average day were estimated as 173 tons PM, 299 tons SOx, 136 tons NOx, 68 tons VOC and 320 tons CO. At the second part of the study, calculated emissions were transformed into air quality predictions in the area by using the Industrial Source Complex – Short Term (ISCST3) dispersion model. Model results were tested with monitoring data from urban air quality stations obtained during the year 2000. Results of the past, present and future air quality estimates in the region were discussed. In order to do so, future scenarios including various control technology applications were formulated and tested to see their effect on the future air quality.     

PM<Subscript>10</Subscript> and Ultrafine Particles Counts In-Vehicle and On-Road in the Athens Area

This work presents the first results of a study concerning on-road and in-vehicle exposure to particulate matter in the area of Athens. PM₁₀ concentration measurements were conducted by TSI DustTrak, while driving along routes with different characteristics of traffic density, during September 2003–March 2004. Concurrent measurements of the ultrafine particles (UFPs) number concentration were also conducted, by condensation particle counter during part of the days. Pedestrian exposure to PM₁₀ and UFPs was also studied through stationary measurements on the kerbside of selected roads on November 2003 and February 2004. A major avenue, a heavy-trafficked road across a children hospital and two central roads, one in a residential and one in a commercial area were selected for measurement. The results indicate that every day commuters are exposed to significant concentration levels. Higher exposures were observed in heavy-trafficked areas and during rush hours. Mean PM₁₀ in-vehicle and on-road concentrations ranged from 30–320 μg/m³ and 70–285 μg/m³, respectively. The ultrafine particles number concentrations were in the range of 5.0 × 10⁴–17.3 × 10⁴ particles/cm³ in-vehicle and 3.1 × 10⁴–7.3 × 10⁴ particles/cm³ on the kerbside of a central residential road. Both PM₁₀ and UFPs concentrations presented repeated short-term peak exposures. The results clearly point out the importance of the road microenvironment (in-vehicle and on kerbside) for population exposure in urban areas.     

沸腾炉大气污染物的生成与排放特征分析

以20台沸腾炉(功率小于等于60 MW)的燃料特性分析数据和大气污染物的排放实测数据为基础,利用统计分析方法,研究了燃烧过程中排放的颗粒物(PM)、SO_2和NO_x初始排放浓度的影响因素,分析了沸腾炉PM、SO_2和NO_x排放现状,探讨了我国中小型沸腾炉PM、SO_2和NO_x排放管理控制的潜力和可行性.实验结果表明:在锅炉运行负荷大于等于80%的条件下,中小型沸腾炉PM的初始排放浓度基本上不受锅炉出力、过量空气系数和燃煤灰分含量的影响;燃煤的硫含量越高,SO_2初始排放浓度越高;过量空气系数越大,燃煤挥发分越低,NO_x初始排放浓度越高.     

Air Quality in Major Portuguese Urban Agglomerations

This paper presents some recent research work that has beendeveloped for the major Portuguese agglomerations. Threemain topics are developed: the methodology used in Portugalto limit agglomerations (as they are defined by theEuropean Air Quality Framework Directive 96/62/EC), thepreliminary assessment of the air quality levels in themost densely populated agglomerations over the last fiveyears and their influence on the air quality levels acrossthe country (a requirement by Directive 96/62/EC), and theuse of an air quality index to raise public awareness aboutair quality levels. It is concluded that particulate matteris the critical pollutant in Portuguese populated urbanareas. In Lisbon and Oporto, based in 1999 data, in allmonitoring stations, the daily average limit value of 50g m^-3 for particulate matter (PM₁₀) isexceeded more times during a year period then allowed byDirective 99/30/EC. In the same areas, nitrogen dioxideconcentrations are above the annual limit value of 40g m^-3 for the protection of human health set byDirective 99/30/EC, and influence pollution concentrationswithin a few tens of kilometres surrounding the urbanareas.     

Characteristics of air pollution in Beijing during sand-dust storm periods

In the Beijing area, March and April have the highest frequency of sand-dust weather. Floating dust, blowing sand, and dust storms, primarily from Mongolia, account for 71%, 20%, and 9% of sand-dust weather, respectively. Ambient air monitoring and analysis of recent meteorological data from Beijing sand-dust storm periods revealed that PM₁₀ mass concentrations during dust storm events remained at 1500 μg m⁻³, which is five to ten times higher than during non-dust storm periods, for fourteen hours on both April 6 and 25, 2000. During the same period, the concentrations in urban areas were comparable to those in suburban areas, while the concentrations of gaseous pollutants, such as SO₂, NO _x , NO₂, and O₃, remained at low levels, owing to strong winds. Furthermore, during sand-dust storm periods, aerosols were created that consisted not only of many coarse particles, but also of a large quantity of fine particles. The PM_2.5 concentration was approximately 230 μg m⁻³, accounting for 28% of the total PM₁₀ mass concentration. Crustal elements accounted for 60–70% of the chemical composition of PM_2.5, and sulfate and nitrate for much less, unlike the chemical composition of PM_2.5 on pollution days, which was primarily composed of sulfates, nitrates, and organic material. Although the very large particle specific surface area provided by dust storms would normally be conducive to heterogeneous reactions, the conversion rate from SO₂ to SO₄ ²⁻ was very low, because the relative humidity, less than 30%, was not high enough.     

Aerosol Number Concentrations during Kosa Events on Suburban Hills in Japan

Measurements of aerosol size-separated number concentrations were performed in March 2001 on the Tama Hills of Japan, located near regions of heavy industry. The concentrations of particles larger than 1.0 μ m in diameter dramatically increased during the Kosa phenomena on 6–8 and 18–24 March. The number concentrations of coarse particles (> 3.0 μm) showed distinct diurnal variations, especially during the Kosa events. Fine particles smaller than 0.5 μm increased when the relative humidity was high and the wind speed was low. On the other hand, the coarse particles concentrations were well correlated with wind speed and temperature. The dry deposition velocity of the coarse particles at the forest canopy was estimated from the nighttime decrease in the number concentrations.     

Indoor Air Quality Assessment of Elementary Schools in Curitiba, Brazil

The promotion of good indoor air quality in schools is of particular public concern for two main reasons: (1) school-age children spend at least 30% of their time inside classrooms and (2) indoor air quality in urban areas is substantially influenced by the outdoor pollutants, exposing tenants to potentially toxic substances. Two schools in Curitiba, Brazil, were selected to characterize the gaseous compounds indoor and outdoor of the classrooms. The concentrations of benzene, toluene, ethylbenzene, and the isomers xylenes (BTEX); NO₂; SO₂; O₃; acetic acid (HAc); and formic acid (HFor) were assessed using passive diffusion tubes. BTEX were analyzed by gas chromatography–ion trap mass spectrometry and other collected gasses by ion chromatography. The concentration of NO₂ varied between 9.5 and 23?µg m^?3, whereas SO₂ showed an interval from 0.1 to 4.8?µg m^?3. Within the schools, BTEX concentrations were predominant. Formic and acetic acids inside the classrooms revealed intermediate concentrations of 1.5?µg m^?3 and 1.2?µg m^?3, respectively.     

Observations of Dust-Storms in China, Mongolia and Associated Dust Falls in Korea in Spring 2003

A joint monitoring of dust-storms that occurred in East Asia from March until May 2003 has been carried. Our discussions include dust-storm observations in the source areas of China and Mongolia, and measurements with satellites and ground monitors in central Korea. Differences were found in the definition and measurement of dust-storms. Over the source area of Mongolia there were 6 dusty days in March, 18 days in April, and 10 dusty days in May. In Inner Mongolia of northern China there were 4 dust-storms with 14 dusty days observed over the three months. In central Korea, a sink area, there were 4 cases of weak dust-storm and 17 dusty days in the spring of 2003. The highest PM10 value was 607 μgm⁻³ and PM 2.3 was 149 μgm⁻³, respectively. These observations identify the growing need for further universal observation practices and dust-storm reporting in future. Observations indicated that snow covered the central part of the Gobi Desert, near the boundary of China and Mongolia, from December until mid-March. This is in contrast to other years when the Gobi was relatively wet, producing unfavourable conditions for the formation of intense dust-storms. In addition, the very strong winds associated with intense cyclones and anticyclones were not apparent and the systems shifted northward during the spring. As a result, the frequency and intensity of observed dust-storms in 2003 in this region were very low. This confirms that there is variability in the frequency of dust-storm formation due to the current process of desertification and climate change.     

Sources and Variability of Indoor and Outdoor Gaseous Aerosol Precursors (O3, NOx and VOCs)

Measurements of indoor and outdoor aerosol concentrations and their gaseous precursors (O₃, NO and NO₂) as well as volatile organic compounds (VOCs) concentrations were performed at two houses in the Oslo metropolitan area. The variability of the concentration of gaseous compounds was studied in respect to their sources in the indoor and outdoor environments. Domestic heating during the winter and photochemical production during the summer were the main sources for outdoor NOx and O₃. In the indoor environment infiltration of outdoor air, candle burning, smoking and indoor chemical reactions were the main sources affecting their concentrations. The concentrations of VOCs outdoors were enhanced during the summer due to biogenic emissions whereas in the indoor environment their values were affected mostly by emissions from materials used during the recent refurbishing of the houses (>0.4 mg/m³).     

Indoor Aerosol Modeling: Basic Principles and Practical Applications

The type and amount of indoor air pollutants affects the comfort and quality of indoor environments. Therefore, indoor air quality is an important issue with different social, economic, and health aspects because people in developing countries spend most of their time indoors being exposed to different kinds of indoor pollutants. The indoor air quality can be assessed empirically by measuring the pollutant concentrations or can be predicted by means of mathematical models. An indoor aerosol model describes the dynamic behavior of indoor air pollutants. The basic concept of indoor air models is the mass-balance-conservation where several factors that govern the indoor particle concentrations can be described. These factors may include direct emissions from indoor sources, outdoor aerosol particles penetrating indoors as a result of the ventilation and filtration processes, deposition onto indoor surfaces, and removal from indoor air by means of ventilation. Here we present principles of indoor aerosol models and we also give examples of different kind of models.     

Effects of Nitrogen Supply on the Sensitivity to O3 of Growth and Photosynthesis of Japanese Beech (Fagus crenata) Seedlings

To obtain basic information for evaluating critical levels of O₃ under different nitrogen loads for protecting Japanese beech forests, two-year-old seedlings of Fagus crenata Blume were grown in potted andisol supplied with N as NH₄NO₃ solution at 0, 20 or 50 kg ha⁻¹ year⁻¹ and exposed to charcoal-filtered air or O₃ at 1.0, 1.5 and 2.0 times the ambient concentration from 16 April to 22 September 2004. The O₃ induced significant reductions in the whole-plant dry mass, net photosynthetic rate at 380 μmol mol⁻¹ CO₂ (A ₃₈₀), carboxylation efficiency (CE) and concentrations of ribulose-1,5-bisphosphate carboxylase/oxygenase (Rubisco) and total soluble protein (TSP) in the leaves. The concentrations of Rubisco and TSP were negatively correlated with the concentration of leaf acidic amino acid, suggesting that O₃ enhanced the degradation of protein such as Rubisco. The N supply to the soil did not significantly change the whole-plant dry mass and A ₃₈₀, whereas it significantly increased the CE and concentrations of Rubisco and total amino acid. No significant interactive effects of O₃ and N supply to the soil were detected on the growth, photosynthetic parameters and concentrations of protein and amino acid in the leaves. In conclusion, N supply to the soil at ≤50 kg ha⁻¹ year⁻¹ does not significantly change the sensitivity to O₃ of growth and net photosynthesis of Fagus crenata seedlings.     

Conceptual Site Model Development and Phased Remedy Implementation to Achieve Vapor Screening Goals at a Former Dry Cleaner

Tetrachloroethene (PCE) releases at a former dry cleaner resulted in impacts to soil and shallow groundwater beneath and adjacent to the building. Subsurface impacts led to vapor intrusion with PCE concentrations between 900 and 1,200 micrograms per cubic meter (μg/m³) in indoor air. The migration pathways of impacted soil vapor were evaluated through implementation of a helium tracer test and vapor sampling of an exterior concrete block wall. Results confirmed that the concrete block wall acted as a conduit for vapor intrusion into the building. A combination of remediation efforts focused on mass reduction in the source area as well as mitigation efforts to inhibit vapor migration into the building. Excavation of soils beneath the floor slab and installation of a spray‐applied vapor barrier resulted in PCE concentrations in indoor air decreasing by over 97.9 percent. Operation of an active ventilation system installed under the floor slab and groundwater remediation via injections of nano‐scale zero valent iron (nZVI) further reduced PCE concentrations in indoor air by over 99.8 percent compared to baseline conditions. While significant reductions of PCE concentrations in groundwater were observed within two months after injection, maximum reductions to PCE concentrations in indoor air were not observed for an additional 12 months. © 2014 Wiley Periodicals, Inc.     

Sediment–Water Interactions in an Eroded and Heavy Metal Contaminated Peatland Catchment,Southern Pennines,UK

Atmospherically deposited lead in the upper layer of the heavily eroded peatlands of the Peak District, southern Pennines, UK, reaches concentrations in excess of 1,000 mg kg⁻¹. Erosion of the upper peat layer in this region is releasing lead, associated with eroded peat particles, into the fluvial system. Understanding the process mechanisms that control dissolved lead concentrations in contaminated peatland streams is vital for understanding lead cycling and transport in peatland streams. Many headwater streams of the southern Pennines recharge drinking water reservoirs. Measurements in the Upper North Grain (UNG) study catchment show that mean sediment-associated and dissolved lead concentrations are 102 ± 39.4 mg kg⁻¹ and 5.73 ± 2.16 μg l⁻¹, respectively. Experimental evidence demonstrates that lead can desorb from suspended sediments, composed of contaminated peat, into stream waters. In-stream processing could therefore account for the elevated dissolved lead concentrations in the fluvial system of UNG.     

Characterization and determination of the odorous charge in the indoor air of a waste treatment facility through the evaluation of volatile organic compounds (VOCs) using TD–GC/MS

Municipal solid waste treatment facilities are generally faced with odorous nuisance problems. Characterizing and determining the odorous charge of indoor air through odour units (OU) is an advantageous approach to evaluate indoor air quality and discomfort. The assessment of the OU can be done through the determination of volatile organic compounds (VOCs) concentrations and the knowledge of their odour thresholds. The evaluation of the presented methodology was done in a mechanical–biological waste treatment plant with a processing capacity of 245.000 tons year^?1 of municipal residues. The sampling was carried out in five indoor selected locations of the plant (Platform of Rotating Biostabilizers, Shipping warehouse, Composting tunnels, Digest centrifugals, and Humid pre-treatment) during the month of July 2011. VOC and volatile sulphur compounds (VSCs) were sampled using multi-sorbent bed (Carbotrap, Carbopack X, Carboxen 569) and Tenax TA tubes, respectively, with SKC AirCheck 2000 pumps. The analysis was performed by automatic thermal desorption (ATD) coupled with a capillary gas chromatography (GC)/mass spectrometry detector (MSD). One hundred and thirty chemical compounds were determined qualitatively in all the studied points (mainly alkanes, aromatic hydrocarbons, alcohols, aldehydes, esters, and terpenes), from which 86 were quantified due to their odorous characteristics as well as their potentiality of having negative health effects. The application of the present methodology in a municipal solid waste treatment facility has proven to be useful in order to determine which type of VOC contribute substantially to the indoor air odorous charge, and thus it can be a helpful method to prevent the generation of these compounds during the treatment process, as well as to find a solution in order to suppress them.     

The Spatial and Temporal Variation of Measured Urban PM10 and PM2.5 in the Helsinki Metropolitan Area

We have studied particulate matter (PM) concentrations,PM₁₀ and PM_2.5, measured in an urban air qualitymonitoring network in the Helsinki Metropolitan Area during1997–1999. The data includes PM₁₀ concentrationsmeasured at five locations (two urban traffic, one suburbantraffic, one urban background and one regional backgroundsite) and PM_2.5 concentrations measured at twolocations (urban traffic and urban background sites). Theconcentrations of PM₁₀ show a clear diurnal variation,as well as a spatial variation within the area. Bycontrast, both the spatial and temporal variation of thePM_2.5 concentrations was moderate. We have analysedthe evolution of urban PM concentrations in terms of therelevant meteorological parameters in the course of oneselected peak pollution episode during 21–31 March, 1998.The meteorological variables considered included wind speedand direction, ambient temperature, precipitation, relativehumidity, atmospheric pressure at the ground level,atmospheric stability and mixing height. The elevated PMconcentrations during the 1998 March episode were clearlyrelated to conditions of high atmospheric pressure,relatively low ambient temperatures and low wind speeds inpredominantly stable atmospheric conditions. The resultsprovide indirect evidence indicating that the PM₁₀concentrations originate mainly from local vehiculartraffic (direct emissions and resuspension), while thePM_2.5 concentrations are mostly of regionally andlong-range transported origin.     

Characterization of air emissions and residual ash from open burning of electronic wastes during simulated rudimentary recycling operations

Air emissions and residual ash samples were collected and analyzed during experiments of open, uncontrolled combustion of electronic waste (e-waste), simulating practices associated with rudimentary e-waste recycling operations. Circuit boards and insulated wires were handled separately to simulate processes associated with metal recovery. The average emissions of polychlorinated dibenzodioxins and dibenzofurans (PCDD/PCDFs) were 92 ng toxic equivalency (TEQ)/kg [n = 2, relative standard deviation (RSD) = 98%] and 11 900 ng TEQ/kg (n = 3, RSD = 50%) of the initial mass of the circuit boards and insulated wire, respectively. The value for the insulated wire is about 100 times higher than that for backyard barrel burning of domestic waste. The emission concentrations of polybrominated dibenzodioxins and dibenzofurans (PBDD/PBDFs) from the combustion of circuit boards were 100 times higher than for their polychlorinated counterparts. Particulate matter (PM) sampling of the fly ash emissions indicated PM emission factors of approximately 15 and 17 g/kg of the initial mass for the circuit boards and insulated wire, respectively. Fly ash samples from both types of e-waste contained considerable amounts of several metallic elements and halogens; lead concentrations were more than 200 times the United States regulatory limits for municipal waste combustors and 20 times those for secondary lead smelters. Leaching tests of the residual bottom ash showed that lead concentrations exceeded U.S. Environmental Protection Agency landfill limits, designating this ash as a hazardous waste.     

Distribution of organophosphoric acid triesters between water and sediment at a sea-based solid waste disposal site

Organophosphoric acid triester (OPE) concentration levels in water and bottom sediment at the Osaka North Port Sea-Based Solid Waste Disposal Site were investigated, and the behavior of OPEs in the water environment of the waste disposal site was examined. The more highly water-soluble OPEs were frequently detected in raw water. Of the OPEs detected, TCEP and TCPP showed very high concentrations (1.0–90 μg/l), followed by TEP (0.3–10 μg/l) > TBXP (0.8–6.3 μg/l) > TDCPP (0.6–6.2 μg/l) > TBP (0.2–1.5 μg/l) > TPP (<0.1 μg/l). Most OPEs detected in water were eluted from the disposal waste to the water phase immediately and behaved as dissolved forms with no distribution in suspended solids (SS). On the other hand, the less water-soluble OPEs, such as TCP or TEHP, were detected in bottom sediment but hardly at all in water samples. All OPEs were detected at the waste disposal site, within which their concentration levels were uniform. It appeared that the less water-soluble OPEs were present as SS-associated forms and behaved in line with the floating surface sludge at the bottom. Received: July 6, 1998 / Accepted: February 25, 1999