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1.
为了探讨修复微污染河水的潜流湿地中植物对污染物去除效果的影响及其生长变化,在野外条件下构建2座分别栽种菖蒲和空心菜的水平潜流人工湿地,并以未栽种植物的湿地作空白。分析了湿地中污染物的去除效果,考察了湿地中植物的生物量、根系活力和氮磷含量的变化。植物湿地中污染物净化效果优于空白湿地,菖蒲和空心菜湿地对氨氮(NH+4-N)、总氮(TN)、总磷(TP)和高锰酸盐指数(CODMn)的平均去除率分别为61.1%和57.5%,31.5%和39.7%,24.7%和25.5%,20.4%和20.7%。实验结果表明,湿地中菖蒲的根系鲜重是空心菜的4.2倍,但其根系活力低于空心菜。2种植物均可在湿地中正常生长,但受湿地中营养盐浓度的限制性影响,移栽后的植物组织氮磷含量与移栽前相比下降了11.8%~20.3%。植物在净化微污染河水的潜流人工湿地中对N、P的去除起重要作用。  相似文献   

2.
While phytoextraction tools are increasingly applied to remediation of contaminated soils, strategies are needed to optimize plant uptake by improving soil conditions. Mineral nutrition affects plant growth and metal absorption and subsequently the accumulation of heavy metal through hyper-accumulator plants. Microcosm experiments were conducted in greenhouse to examine the effect of different phosphorus (P) sources on zinc (Zn) phytoextraction by Sedum alfredii in aged Zn-contaminated paddy soil. The Zn accumulation, soil pH, microbial biomass and enzyme activity, available Zn changes. and Zn phytoremediation efficiency in soil after plant harvest were determined. Upon addition of P, Zn uptake of S. alfredii significantly increased. Mehlich-3 extractable or the fractions of exchangeable and carbonate-bound soil Zn were significantly increased at higher P applications. Soil pH significantly decreased with increasing P application rates. Soil microbial biomass in the P-treated soils was significantly higher (P?<?0.05) than those in the control. Shoot Zn concentration was positively correlated with Mehlich-3 extractable P (P?<?0.0001) or exchangeable/carbonate-bound Zn (P?<?0.001), but negatively related to soil pH (P?<?0.0001). These results indicate that application of P fertilizers has the potential to enhance Zn mobility and uptake by hyperaccumulating plant S. alfredii, thus increasing phytoremediation efficiency of Zn-contaminated soils.  相似文献   

3.
巢湖入湖河流沉积物中有机磷的形态分级研究   总被引:2,自引:0,他引:2  
为识别巢湖流域污染物的特征、来源及其沉积物有机磷各形态分布与富营养化的关系,测定了7条巢湖入湖河流沉积物中有机磷各形态的含量,分析不同污染类型入湖河流沉积物中有机磷各形态分布的差异及与其他因素间的相关性。研究发现,不同污染类型入湖河流沉积物中水土保持控制型河流沉积物中有机磷各组分的相对含量顺序为残渣态Po >富里酸-Po >HCl-Po >胡敏酸-Po >NaHCO3-Po,平均的相对比例为7.5:3.1:1.9:1.5:1.0,而城市污染控制型和面源污染控制型河流沉积物中有机磷各组分的相对含量顺序恰好相同,面源污染控制型河流沉积物Po各形态含量低于城市污染控制型和水土保持控制型河流。中活性Po和OM、TP、Pi、Po、TN、NaHCO3-Pi、NaOH-Pi呈正相关,非活性Po与Po、NaOH-Pi呈显著正相关关系,反映了中活性Po很容易转化为生物可利用磷和非活性Po,且非活性Po仍然具有潜在的生物活性。  相似文献   

4.
Sulfate-reducing microorganisms (SRM) have been thought to play a key role in mercury (Hg) methylation in anoxic environments. The current study examined the linkage between SRM abundance and diversity and contents of methylmercury (MeHg) in paddy soils collected from a historical Hg mining area in China. Soil profile samples were collected from four sites over a distance gradient downstream the Hg mining operation. Results showed that MeHg content in the soil of each site significantly decreased with the extending distance away from Hg mine. Soil MeHg content was correlated positively with abundance of SRM and the contents of organic matter (OM), NH4 +, SO4 2?, and Hg. The abundances of SRM based on dissimilatory (bi) sulfite reductase (dsrAB) gene at 0–40 cm depths were higher than those at 40–80 cm depth at all sites. The SRM community composition varied in the soils of different sampling sites following terminal restriction fragment length polymorphism (T-RFLP) and phylogenetic analyses, which appeared to be correlated with contents of MeHg, OM, NH4 +, and SO4 2? through canonical correspondence analysis. The dominant groups of SRM in the soils examined belonged to Deltaproteobacteria and some unknown SRM clusters that could have potential for Hg methylation. These results advance our understanding of the relationship between SRM and methylmercury concentration in paddy soil.  相似文献   

5.
The remediation of copper-contaminated soils by aided phytostabilisation in 16 field plots at a wood preservation site was investigated. The mobility and bioavailability of four potentially toxic trace elements (PTTE), i.e., Cu, Zn, Cr, and As, were investigated in these soils 4 years after the incorporation of compost (OM, 5 % w/w) and dolomite limestone (DL, 0.2 % w/w), singly and in combination (OMDL), and the transplantation of mycorrhizal poplar and willows. Topsoil samples were collected in all field plots and potted in the laboratory. Total PTTE concentrations were determined in soil pore water (SPW) collected by Rhizon soil moisture samplers. Soil exposure intensity was assessed by Chelex100-DGT (diffusive gradient in thin films) probes. The PTTE phytoavailability was characterized by growing dwarf beans on potted soils and analyzing their foliar PTTE concentrations. OM and DL, singly and in combination (OMDL), were effective to decrease foliar Cu, Cr, Zn, and As concentrations of beans, the lowest values being numerically for the OM plants. The soil treatments did not reduce the Cu and Zn mineral masses of the bean primary leaves, but those of Cr and As decreased for the OM and DL plants. The Cu concentration in SPW was increased in the OM soil and remained unchanged in the DL and OMDL soils. The available Cu measured by DGT used to assess the soil exposure intensity correlated with the foliar Cu concentration. The Zn concentrations in SPW were reduced in the DL soil. All amendments increased As in the SPW. Based on DGT data, Cu availability was reduced in both OM and OMDL soils, while DL was the most effective to decrease soil Zn availability.  相似文献   

6.
Field trials contribute practical information towards the development of phytoremediation strategies that cannot be provided by laboratory tests. We conducted field experiments utilizing the Cd hyperaccumulator plant Solanum nigrum L., on farmland contaminated with 1.91 mg kg−1 Cd in the soil. Our study showed that S. nigrum has a relatively high biomass. Planting density had a significant effect on the plant biomass and thus on overall Cd accumulation. For double harvesting, an optimal cutting position influenced the amount of Cd extracted from soils. Double cropping was found to significantly increase the amount of Cd extracted by S. nigrum. Fertilizing had no significant effect on plant biomass or on the Cd remediation of the soil over the short-term period. Our study indicates that S. nigrum can accumulate Cd from soils where the concentrations are relatively low, and thus has application for use in decontamination of slightly to moderately Cd-contaminated soil.  相似文献   

7.
The impacts of the fungicides azoxystrobin, tebuconazole and chlorothalonil on microbial properties were investigated in soils with identical mineralogical composition, but possessing contrasting microbial populations and organic matter contents arising from different management histories. Degradation of all pesticides was fastest in the high OM/biomass soil, with tebuconazole the most persistent compound, and chlorothalonil the most readily degraded. Pesticide sorption distribution coefficient (K(d)) did not differ significantly between the soils. Chlorothalonil had the highest K(d) (97.3) but K(d) for azoxystrobin and tebuconazole were similar (13.9 and 12.4, respectively). None of the fungicides affected microbial biomass in either soil. However, all fungicides significantly reduced dehydrogenase activity to varying extents in the low OM/biomass soil, but not in the high OM/biomass soil. The mineralization of subsequent applications of herbicides, which represents a narrow niche soil process was generally reduced in both soils by azoxystrobin and chlorothalonil. 16S rRNA-PCR denaturing gradient gel electrophoresis (DGGE) indicated that none of the fungicides affected bacterial community structure. 18S rRNA PCR-DGGE analysis revealed that a small number of eukaryote bands were absent in certain fungicide treatments, with each band being specific to a single fungicide-soil combination. Sequencing indicated these represented protozoa and fungi. Impacts on the specific eukaryote DGGE bands showed no relationship to the extent to which pesticides impacted dehydrogenase or catabolism of herbicides.  相似文献   

8.
Nutrient load into the ocean can be retained during the process of plant uptake and sedimentation in marshes along the bay zone. Seasonal variations of biomass and nutrient concentration in three dominated plant assemblages and associated sediments were monitored in this study area to determine effects of salt marsh on nutrient retention. Results showed that plant aboveground biomass displayed a unimodal curve with nutrient concentration generally decreased from spring to winter. Belowground biomass was relatively low during the rapid growth period with nutrient concentration tending to decrease and then increase during this period. Plant total nitrogen (TN) pools are higher than total phosphorus (TP) pools, and both pools showed significant seasonal variations. Water purification coefficients (WPC) of nutrients by plant assimilation were 34.4/17.3, 19.3/24.0, and 5.14/6.04 t/(m2 year) (TN/TP) for Phragmites australis, Spartina alterniflora, and Scirpus mariqueter, respectively. Overall, these results suggest that higher annual plant biomass and nutrient assimilation contribute to greater nutrient retention capacity and accumulation in sediments, thereby enabling reduced eutrophication in transitional waters.  相似文献   

9.
This study investigates biomass, density, photosynthetic activity, and accumulation of nitrogen (N) and phosphorus (P) in three wetland plants (Canna indica, Typha augustifolia, and Phragmites austrail) in response to the introduction of the earthworm Eisenia fetida into a constructed wetland. The removal efficiency of N and P in constructed wetlands were also investigated. Results showed that the photosynthetic rate (P n), transpiration rate (T r), and stomatal conductance (S cond) of C. indica and P. austrail were (p?<?0.05) significantly higher when earthworms were present. The addition of E. fetida increased the N uptake value by above-ground of C. indica, T. augustifolia, and P. australis by 185, 216, and 108 %, respectively; and its P uptake value increased by 300, 355, and 211 %, respectively. Earthworms could enhance photosynthetic activity, density, and biomass of wetland plants in constructed wetland, resulting in the higher N and P uptake. The addition of E. fetida into constructed wetland increased the removal efficiency of TN and TP by 10 and 7 %, respectively. The addition of earthworms into vertical flow constructed wetland increased the removal efficiency of TN and TP, which was related to higher photosynthetic activity and N and P uptake. The addition of earthworms into vertical flow constructed wetland and plant harvests could be the significantly sustainable N and P removal strategy.  相似文献   

10.
Severe eutrophication of surface water has been a major problem of increasing environmental concern worldwide. In the present study, economic plant annual ryegrass (Lolium multiflorum) was grown in floating mats as an economic plant-based treatment system to evaluate its potential after ion implantation for removing nutrients in simulated eutrophic water. The specific weight growth rate of L. multiflorum with ion implantation was significantly greater than that of the control, and the peroxidase, nitrate reductase, and acid phosphatase activities of the irradiated L. multiflorum were found to be greater than those plants without ion implantation. Higher total nitrogen (TN) and total phosphorus (TP) removal efficiencies were obtained for the L. multiflorum irradiated with 25 keV 5.2?×?1016 N+ ions/cm2 and 30 keV 4.16?×?1016 N+ ions/cm2, respectively (p?L. multiflorum itself was directly responsible for 39–49 and 47–58 % of the overall N and P removal in the experiment, respectively. The research results suggested that ion implantation could become a promising approach for increasing phytoremediation efficiency of nutrients from eutrophic water by L. multiflorum.  相似文献   

11.
某矿区土壤和地下水重金属污染调查与评价   总被引:3,自引:0,他引:3  
为了解湘南某矿区土壤和地下水重金属污染状况,对该矿区东河流域附近重金属污染源进行了调查,同时,对地下水和土壤样品进行了采样分析,结果表明:(1)该矿区东河流域附近的主要污染源有18个,其中有色金属选厂、尾矿库、采矿场和冶炼厂是排放重金属较多的污染源;(2)20个采样点中土壤重金属Pb、Cd、Zn、As和Hg大部分超过国家土壤环境质量标准(GB15618-1995),综合污染指数P综〉1,该矿区主要的重金属污染元素为Cd、As和Hg,且土壤中Cd、Zn和As的含量两两之间存在着极显著的正线性相关关系;(3)重金属元素在土壤中的纵向迁移不明显,该矿区附近20个采样点的地下水并未受到污染,综合污染指数P综〈1。20个采样点地下水Pb、Cd、Zn、As、Hg浓度均能达到地下水质量标准(GB/T14848.9)中的Ⅲ类标准。  相似文献   

12.
The endophytic bacterium isolated from Scirpus triqueter was proved to be an oil-degraded bacterium. A pot experiment was conducted to investigate the removal ratio of diesel under the combined effect of oil-degraded microorganism (Pseudomonas sp. J4AJ) and S. triqueter. The effect of diesel on plant growth parameters, soil enzymes and microbial community was assessed after 60 days. The results showed that the soils which were planted with S. triqueter and inoculated with J4AJ displayed the highest removal ratio (54.51?±?0.15 %) after 60-day experiment. However, the removal ratio of J4AJ-treated soils was 38.97?±?0.55 %. Diesel was toxic to S. triqueter, as evidenced by growth inhibition during the experimental period. However, the plant height and stem biomass in the soils inoculated with J4AJ significantly increased. The combined effect of S. triqueter and J4AJ improved the enzyme activities of the catalase and dehydrogenase in the contaminated soil. The diversity index in soils under the effect of S. triqueter combined with J4AJ was lower than that of the other soil samples. The principal analysis of phospholipid fatty acid signatures revealed that the combined effect of S. triqueter and J4AJ increased the differences of soil microbial community structure with the other treatments.  相似文献   

13.
Abstract

The adsorption, desorption, and mobility of permethrin in six tropical soils was determined under laboratory and greenhouse conditions. The six soils were selected from vegetable growing areas in Malaysia. Soil organic matter (OM) was positively correlated (r 2 = 0.97) with the adsorption of permethrin. The two soils, namely, Teringkap 1 and Lating series with the highest OM (3.2 and 2.9%) released 32.5 and 30.8% of the adsorbed permethrin after four consecutive repetitions of the desorption process, respectively, compared to approximately 75.4% of the Gunung Berinchang soil with the lowest OM (1.0%) under the same conditions. The mobility of permethrin down the soil column was inversely correlated to the organic matter content of the soil. Permethrin residue penetrated only to the 10–15 cm zone in the Teringkap 1 soil with 3.2% OM but penetrated to a depth of more than 20 cm in the other soils. The Berinchang series soil with the lowest OM (1.0%) yielded leachate with 14.8% permethrin, the highest level in leachates from all the soils tested. Therefore, the possibility for permethrin to contaminate underground water may be greater in the presence of low organic matter content, which subsequently allows a higher percentage of permethrin to move downwards through the soil column.  相似文献   

14.
Brian L. Worobey 《Chemosphere》1984,13(10):1103-1111
Three soils of varying organic matter (OM) concentrations (0, 1.7 and 57%) were treated with 3,3′4,4′-tetrachlorazobenzene (TCAB) at the 25 ppm level. Germinated soybeans(Glycinemax (L.) Merr.) were planted in the treated soils, along with controls, and grown for 12 days. The shoots, roots and soil were air-dried and analyzed for TCAB and 3,3′,4,4′-tetrachloroazoxybenzene (TCAOB). TCAB appears to translocate from the treated soil into the plant shoots and roots. Residue levels varied with the percentage organic matter of each soil; levels as high as 58.4 ppm were identified in roots of soybeans grown in 1.7% OM soil and 0.620 ppm in the shoots from 0% OM soil. TCAOB was identified in soil and root extracts with the highest levels in soybean roots grown in 0% OM soil, 0.317 ppm. Residues of TCAB and TCAOB decreased in soil and root and shoot tissues as percentage OM increased. Bound residues of TCAB were released from roots grown in 0% OM soil by refluxing with boron trifluoride methanol (BF3CH3OH).  相似文献   

15.
Yu XY  Mu CL  Gu C  Liu C  Liu XJ 《Chemosphere》2011,85(8):1284-1289
Pyrolysis of vegetative biomass into biochar and application of the more stable form of carbon to soil have been shown to be effective in reducing the emission of greenhouse gases, improving soil fertility, and sequestering soil contaminants. However, there is still lack of information about the impact of biochar amendment in agricultural soils on the sorption and environmental fate of pesticides. In this study, we investigated the sorption and dissipation of a neonicotinoid insecticide acetamiprid in three typical Chinese agricultural soils, which were amended by a red gum wood (Eucalyptus spp.) derived biochar. Our results showed that the amendment of biochar (0.5% (w/w)) to the soils could significantly increase the sorption of acetamiprid, but the magnitudes of enhancement were varied. Contributions of 0.5% newly-added biochar to the overall sorption of acetamiprid were 52.3%, 27.4% and 11.6% for red soil, paddy soil and black soil, respectively. The dissipation of acetamiprid in soils amended with biochar was retarded compared to that in soils without biochar amendment. Similar to the sorption experiment, in soil with higher content of organic matter, the retardation of biochar on the dissipation of acetamiprid was lower than that with lower content of organic matter. The different effects of biochar in agricultural soils may attribute to the interaction of soil components with biochar, which would block the pore or compete for binding site of biochar. Aging effect of biochar application in agricultural soils and field experiments need to be further investigated.  相似文献   

16.
The aim of this study was to develop techniques to evaluate soil phosphorus (P) sorption capacity (PSC) and determine critical soil P levels to predict P loss potential for calcareous soils. Seventy-five soils mostly from Northern China were analyzed for soil P using four extraction methods (water, Pw; carbonate, POls; ammonium oxalate, Pox; and Mehlich 3, PM3) as well as PSC derived from single-point (PSC150) and multipoint sorption (S t) isotherms. Strong correlation was found between PSC150 and S t (r 2=0.89, p<0.001). The sum of αCaM3 and βMgM3 as an index of PSC (PSC(CaM3 + MgM3)) was most closely related to the maximum amount of P sorbed (S max) as given by the sum of S t and soil initial P setting α=0.039 and β=0.462 (r 2=0.80, p<0.001). The degree of P saturation (DPS) was thereafter calculated from PSC(CaM3 + MgM3) (DPS(CaM3 + MgM3)), to which Olsen P (POls) was significantly correlated (r 2=0.82, p<0.001). In a split-line regression from Pw against DPS(CaM3 + MgM3) (r 2=0.87, p<0.05), a change point was identified at 28.1% DPS(CaM3 + MgM3), which was equivalent to 49.2 mg kg?1 POls and corresponded to a Pw concentration of 8.8 mg kg?1. After the change point, a sharp increase in Pw was observed. Our results reveal a new approach to approximating DPS from CaM3 and MgM3 for calcareous soils without the need to generate a S max. We conclude that in the absence of an environmental soil test criteria for P, the DPS(CaM3 + MgM3) and POls could be used to predict P loss potential from calcareous soils.  相似文献   

17.
Nag SK  Kookana R  Smith L  Krull E  Macdonald LM  Gill G 《Chemosphere》2011,84(11):1572-1577
We evaluated wheat straw biochar produced at 450 °C for its ability to influence bioavailability and persistence of two commonly used herbicides (atrazine and trifluralin) with different modes of action (photosynthesis versus root tip mitosis inhibitors) in two contrasting soils. The biochar was added to soils at 0%, 0.5% and 1.0% (w/w) and the herbicides were applied to those soil-biochar mixes at nil, half, full, two times, and four times, the recommended dosage (H4). Annual ryegrass (Lolium rigidum) was grown in biochar amended soils for 1 month. Biochar had a positive impact on ryegrass survival rate and above-ground biomass at most of the application rates, and particularly at H4. Within any given biochar treatment, increasing herbicide application decreased the survival rate and fresh weight of above-ground biomass. Biomass production across the biochar treatment gradient significantly differed (< 0.01) and was more pronounced in the case of atrazine than trifluralin. For example, the dose-response analysis showed that in the presence of 1% biochar in soil, the value of GR50 (i.e. the dose required to reduce weed biomass by 50%) for atrazine increased by 3.5 times, whereas it increased only by a factor of 1.6 in the case of trifluralin. The combination of the chemical properties and the mode of action governed the extent of biochar-induced reduction in bioavailability of herbicides. The greater biomass of ryegrass in the soil containing the highest biochar (despite having the highest herbicide residues) demonstrates decreased bioavailability of the chemicals caused by the wheat straw biochar. This work clearly demonstrates decreased efficacy of herbicides in biochar amended soils. The role played by herbicide chemistry and mode of action will have major implications in choosing the appropriate application rates for biochar amended soils.  相似文献   

18.
Yan X  Zhang M  Liao X  Tu S 《Chemosphere》2012,88(2):240-244
Increasing availability of soil arsenic is of significance for accelerating phytoremediation efficiency of As-polluted sites. The effects of seven amendments, i.e., citrate, oxalate, EDTA, sodium polyacrylate (SPA), phosphate rock (PR), single superphosphate (SSP), and compost on fractionation and phytoavailability of soil As were investigated in lab culture experiment. The results showed that the addition of PR, SPA, EDTA or compost to soils significantly increased the concentration of NaHCO3-extractable As over a 120 d incubation period compared with the control (amendment-free) soil. Then, the four amendments were selected to add to As-contaminated soil growing Pteris vittata. It was concluded that As accumulation by the fern increased significantly under the treatments of PR and SPA by 25% and 31%, respectively. For As fractionation in soil, SPA increased Fe-As significantly by 51% and PR increased Ca-As significantly by 18%, while both the two amendments reduced occluded-As by 16% and 19%, respectively. Adding PR and SPA in soil increased the activities of urease and neutral phosphatase resulting from the improvement the fertility and physical structure of the soil, which benefits plant growth and As absorption of P. vittata. The results of the research revealed that both PR and SPA were effective amendments for improving phytoremediation of As-contaminated sites by P. vittata.  相似文献   

19.
Two lead (Pb)-resistant endophytic bacteria were isolated from rape roots grown in heavy metal-contaminated soils and characterized. A pot experiment was conducted for investigating the capability of the two isolates to promote the growth and Pb uptake of rape from Pb-amended soil. The two isolates were identified as Pseudomonas fluorescens G10 and Microbacterium sp. G16 based on the 16S rDNA gene sequence analysis. Strains G10 and G16 exhibited different multiple heavy metal and antibiotic resistance characteristics and increased water-soluble Pb in solution and in Pb-added soil. Root elongation assays demonstrated increases in root elongation of inoculated rape seedlings compared to the control plants. Strain G16 produced indole acetic acid, siderophores and 1-aminocyclopropane-1-carboxylate deaminase. Increases in biomass production and total Pb uptake in the bacteria-inoculated plants were obtained compared to the control. The two strains could colonize the root interior and rhizosphere soil of rape after root inoculation.  相似文献   

20.
The soils at a depleted copper mine in Touro (Galicia, Spain) are chemically degraded. In order to determine the effect of amendments and vegetation on the chemical characteristics of a mine soil and on the plant uptake of metals, a greenhouse experiment was carried out for 3 months. A settling pond soil was amended with different percentages of a compost and biochar mixture and vegetated with Brassica juncea L. The results showed that the untreated settling pond soil was polluted by Cu. Amendments and planting mustards decreased the pseudototal concentration of this metal, reduced the extreme soil acidity and increased the soil concentrations of C and TN. Both treatments also decreased the CaCl2-extractable Co, Cu and Ni concentrations. However, the amendments increased the pseudototal concentration of Zn in the soil, provided by the compost that was used. The results also showed that mustards extracted Ni efficiently from soils, suggesting that B. juncea L. is a good phytoextractor of Ni in mine soils.  相似文献   

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