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1.
采用XAD-7树脂吸附富集自来和地面水中良量氯酚和对氯酚。后用氢焰气相色谱法测定。在溶液的pH小于6,流为10毫升/分以内,平均吸附效率达94%和92%。甲醇、丙酮和(1+1)丙酮+乙醚混和液均有96%以上的淋洗效率。  相似文献   

2.
GDX—502对水中微量混合一元酚的富集作用   总被引:3,自引:0,他引:3  
本文研究了GDX—502树脂对水中微量混合一元酚的富集作用,以及影响富集回收率的某些因素;对富集和洗脱机理也进行了初步探讨.实验结果表明,GDX—502是水中微量酚类化合物较好的富集剂,二氧六环是较好的洗脱剂。除2.4—二销基酚外,对8种一元酚的平均富集回收率为93.7%,平均洗脱率为96.5%。GDX—502对水中酚类的富集作用是以VanderWaals力和较氢键弱的π—键合作用力为基础的物理吸附,而二氧六环洗脱酚类的实质是氢键作用.  相似文献   

3.
聚乙烯吡咯烷酮修饰碳糊电极溶出伏安法测定水中硝基酚   总被引:7,自引:0,他引:7  
提出用聚乙烯吡咯烷酮(PVTr)修饰碳糊电极同时测定水中对硝酚和2,4-二硝基酚的方法。在0.1mol/LKcl的酚工液中开始路富集,然后在磷酸盐缓冲液介质中溶出,以微分脉冲伏安法测定,检测奶分别为0.50μg/L和1.80μg/L。讨论了测定的影响因素以及2种硝基酚在民极上的反应机理。测定了地面水中对硝基酚和2,4-二硝基酚的含量,回收率分别为90±6%和86±5%  相似文献   

4.
提出用聚乙烯毗咯烷酮(PVPr)修饰碳糊电极同时测定水中对硝基酸和2,4-二硝基酚的方法。在0.1mol/LKCl的酚试液中开路富集,然后在磷酸盐缓冲液介质中溶出.以微分脉冲伏安法恻定,检测限分别为0.50μg/L和1.80μg/L。讨论了测定的影响因素以及2种硝基酚在该修饰电极上的反应机理。测定了地面水中对硝基酸和2,4-二硝基酸的含量,回收率分别为90±6%和86±5%。  相似文献   

5.
对氨基偶氮苯盐酸盐(PABS)是生产染料的重要中间体。在PABS生产过程中,排放出高浓度(COD4万~8万mg/L)、高色度(4万~8万)、高毒性(含苯胺和对氨基偶氮苯)和高氯(Cl-4万~10万mg/L)的废水。利用中和沉淀—大孔吸附树脂吸附法进行了处理工艺的小试研究。结果表明,废水色度去除率达到999%,降到20以下;出水中基本不含对氨基偶氮苯(PAB);出水中苯胺的浓度降到3mg/L。GC/MS分析的结果表明,乙醇脱附液中苯胺是最主要的有机物,所以利用该工艺能实现苯胺的回收。  相似文献   

6.
新型生物吸附剂去除水中六价铬的研究   总被引:11,自引:0,他引:11  
陶颖  王竞  周集体 《上海环境科学》2000,19(12):572-574
以Pseudomonas sp.Gx4-1发酵培养得到的细菌胞外聚合物作吸附剂,研究其对水中重金属Cr(VI)的吸附,吸附剂对Cr(VI)吸附的最佳pH初值为0.5~2.0。Cr(VI)的吸附分三个阶段:5min达75%的快速吸附阶段;10~40min达表现一级反应动力学吸附阶段;50min以的趋于平衡,吸附过程符合Freundlich和Langmuir吸附等温方程。  相似文献   

7.
HPLC法测定废水中苯胺类化合物   总被引:3,自引:0,他引:3  
用乙醚为提取有机相,提取前先经碱化,提取后加酸使苯胺成盐,吹去乙醚,用HPLC法测定苯胺类化合物。方法适用于测定废水中苯胺类化合物。检出限:苯胺3.0ng,邻硝基苯胺0.5ng,对硝基苯胺1.0ng。线性范围:苯胺0.817-13.072μg/ml,邻硝基苯胺0.1464-2.3424μg/ml,对硝基苯胺0.253-4.048μg/ml。精密度(CV):苯胺2.38%,邻硝基苯胺1.09%,对硝  相似文献   

8.
长江水体氯化过程中强致突变物前驱物的筛选   总被引:8,自引:0,他引:8  
MX「3-氯-4-(二氯甲基)-5-羟基-2(5H)-呋喃酮」是饮用水液氯消毒中产生的一种具有强致突变性的副产物,利用一系列XAD吸附树脂和大孔离子交换树脂将长江水中的溶解态有机物分离为溶解态腐殖酸类,憎水弱酸类,憎水碱类,憎水中性物类,亲水酸类,亲水碱类6种组分,分别对不同组分的有机物进行氯化处理,用GC/MS选择离子峰面积法测定产物中的MX。  相似文献   

9.
在线树脂富集流动注射法测定水中痕量酚   总被引:3,自引:0,他引:3  
研究了用流动注射分析中的流体动力学注入技术与在线树脂富集相结合的方式,富集水中痕量苯酚,以4-氨基安替比林比色法测定的方法。结果表明,当进样频率为24个样品每小时时,方法的检出限为0.05mg/L,线性范围为0.05~7mg/L;对水中苯酚重复测定10次,相对标准偏差小于2%;回收率为99%~105%。  相似文献   

10.
水中痕量Cr(Ⅲ)和Cr(Ⅵ)交联壳聚糖吸附和DPCI光度法测定   总被引:14,自引:0,他引:14  
研究交联壳糖(CCTS)对Cr(Ⅵ)的吸附行为,建立了DPCI光度法测定水中痕量Cr(Ⅵ)和Cr(Ⅲ)的新方法,在100-200mlpH=3溶液中,CCTS对Cr(Ⅵ)的吸附率为97%,用2ml0.1mol.L^-1NaOH定量解吸Cr(Ⅵ)富集倍数达50-100倍,本法用于水中痕量Cr(Ⅵ)和Cr(Ⅲ)的测定,回收率90%-105%,变异系数1.2%-4.8%,检出限0.015μg.L^-1探讨  相似文献   

11.
The aim of the paper is to review critically the notion of autopoiesis as presented by Maturana and Varela. In particular, recognizing that there are difficulties in obtaining a complete and clear picture from the primary literature, an effort is made to present a coherent view--also based on many years of personal contact with Francisco Varela. The paper begins with a few historical notes to highlight the cultural background from which the notion of autopoiesis arose. The basic principles of autopoiesis as a theory of cellular life are then described, emphasizing also what autopoiesis is not: not an abstract theory, not a concept of artificial life, not a theory about the origin of life--but rather a pragmatic blueprint of life based on cellular life. It shown how this view leads to a conceptually clear definition of minimal life and to a logical link with related notions, such as self-organization, emergence, biological autonomy, auto-referentiality, and interactions with the environment. The perturbations brought about by the environment are seen as changes selected and triggered by the inner organization of the living. These selective coupling interactions impart meaning to the minimal life and are thus defined by Maturana and Varela with the arguable term of "cognition". This particular view on the mutual interactions between living organism and environment leads these authors to the notion of "enaction", and to the surprising view that autopoiesis and cognition are two complementary, and in a way equivalent, aspects of life. It is then shown how cognition, so defined, permits us to build a bridge between biology and cognitive science. Autopoiesis also allows one to conceive chemical models of minimal cellular life that can be implemented experimentally. The corresponding work on "chemical autopoiesis" is then reviewed. The surprising impact of autopoiesis in the social sciences ("social autopoiesis") is also briefly discussed. This review also comments on why the theory of autopoiesis had, and still has, a difficult time being accepted into the mainstream of life-science research. Finally, it is pointed out that the new interest in system biology and complexity theories may lead to a reappraisal of autopoiesis and related notions, as outlined also by other authors, such as Tibor Ganti and Stuart Kauffmann.  相似文献   

12.
公众环境意识与可持续发展关系初探   总被引:1,自引:0,他引:1  
目前,国内存在的各种环境问题,归根到底是由于发展战略的不同所致,人们开始重新去认识和评价传统发展战略的局限性,标志着人类文明即将步入一个被称之"环境文明"新的历史时代.历史文化传统和经济发展水平决定公众环境意识,公众的环境意识直接影响可持续发展战略的实施,如何增强,提出决策和建议,通过大力开展环境宣传教育,提高公众环境意识,可持续发展,实现可持续发展的战略.  相似文献   

13.
 A host invasion strategy hitherto unknown from other insect parasitoids was observed in the dipteran Acrocera orbicula (Fabricius) (Diptera: Acroceridae) parasitizing the wolf spider, Pardosa prativaga (L. Koch) (Araneida: Lycosidae). In laboratory experiments the free-living first instar acrocerid larvae attached themselves firmly to the spiders' integument by the mouthparts, cutting a tiny hole through the integument. No first instar larvae invaded the host. A week later the parasitoids molted, and a small, flexible, and glabrous second instar larva left each of the attached first instar exuviae and invaded the host through the attachment hole of the first instar larva. The novel host invasion pattern observed may reduce physical damage to the host in the initial phase of endoparasitism, enhancing parasitoid survival. Received: 14 April 1999 / Accepted in revised form: 2 July 1999  相似文献   

14.
"十一五"是我国经济社会发展的重要战略机遇期,也是环境保护工作极具挑战的时期.我们将以党的十六届五中全会精神为指针,以建设"绿色重庆"为目标,以"预防为主、综合治理,不欠新账、多还旧账,创新机制、强化监管,突出重点、分类指导,典型示范、带动全面"为基本原则,发展循环经济,解决突出问题,改善环境质量,建立工作机制,努力构建环境友好型社会.  相似文献   

15.
A hopper-predator community in an experimental rice field was observed weekly with regard to information content (H′), formation of a geometric series or the grade of orderly distribution of component taxa (R2), and clumping index (I). These community attributes changed with time in close association with one another, and attained the highest values around the heading time of the rice. Significant correlations were found between the density of prey and that of predators when a certain time-lag was assumed for the increase of predators.  相似文献   

16.
创建安静居住小区,是以营造安静和谐的宜居生活环境为目标,通过强化噪声监管、开展宣传教育等方式,改善城区声环境质量,提高居民环保意识,提高城市文明水平的一种有效方式.2009年以来,厦门市思明全区开展创建“安静居住小区”工作.目前,25个创建小区中共有24个通过验收达标.“安静居住小区”创建以来,小区居民对居住环境质量的满意率达到97%,小区噪声污染得到有效治理,居民的环保意识得到极大提高.  相似文献   

17.
18.
By increasing particle concentration and G value (root-mean-square velocity gradient) to enhance flocculation, a novel vertical-flow settler was designed to increase sedimentation effectiveness, and to simultaneously improve operational stabilization. Due to the gradual decrease in upward flow-rate of raw water, a floes blanket would form and suspend in the middle section of the settler, not at the bottom as in a conventional clarifier. Enough large floes, resulted from flocculation or fltration, would continuously settle out of the floes blanket, and simultaneously, the floes in raw water or those forming above the blanket would ceaselessly enter the floes blanket. As a result, the floes concentration in the blanket could keep a dynamic balance. The hydrodynamic shear in the blanket was improved by flow separation, which was induced by the abrupt change in flow channel. Due to the floes blanket and improved hydrodynamic shear, flocculation would be enhanced, which was helpful for removing fine particles in raw water. A comparative study showed that the novel vertical-flow settler had a much better performance in the removal of the particles in raw water than a conventional one, when they treated kaolin suspensions of different concentrations (500, 100 and 50 mg/L, respectively) coagulated by polyaluminum chloride(PAC1) at the up-flow rates of 1 and 2 mm/s, respectively.  相似文献   

19.
20.
During the last three of 20 years kept as a pet, a red knot (Calidris canutus) went through two complete 'circannual' cycles of body mass and plumage. With a record cycle length of 18 months, this individual shorebird provides evidence for an exceptionally strong circannual clock system. The absence of synchronisation to outdoor but visible periodic cues suggests that the constant, socially-induced, day-night environment was of overriding importance. So far, only for songbirds is there firm experimental evidence that annual cycles are orchestrated by an endogenous circannual clock system. In constant environments the circannual cycles of these passerines tend to have periods that are shorter, rather than longer, than a year.  相似文献   

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