共查询到19条相似文献,搜索用时 109 毫秒
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燃煤产生的SO2污染已成为世界各国环境污染的核心问题之一。目前控制燃煤排放SOx的方法,主要分为尾部烟气脱硫和炉内喷钙脱硫。烟气脱硫技术已较为成熟,但其昂贵的设备投资和运行费用极大地限制了它的广泛应用。而炉内喷钙脱硫技术则具有设备操作简单,占用空间小,投资少等优势。但它的主要缺陷是脱硫剂CaCO3的利用率低。因此,提高脱硫剂的利用率,是该技术能否得以广泛应用的关键。钙基脱硫剂改性方法炉内喷钙脱硫效果差的原因在于炉内燃烧脱硫剂的活性很低。因而,寻求一种提高钙基脱硫剂活性的方法,将会对炉内喷钙技术的发展起到很大的推… 相似文献
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为达到削减二氧化硫总量,通过探讨炉内喷钙法、半干法、氨法的优缺点比较,优选脱硫技术方案. 相似文献
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介绍了国内目前正在使用或即将使用的燃煤烟气脱硫技术的工艺特点、操作参数和适用范围。这些技术包括湿式石灰石(石灰)-石膏法、炉内喷钙后部烟气增湿脱硫法、海水洗涤法、除尘脱硫一体化技术等。 相似文献
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LIFAC脱硫新工艺 总被引:6,自引:0,他引:6
目前,烟气脱硫工艺很多,脱硫方法以燃烧前后分,可分为三大类,即炉前脱硫、炉内脱硫和炉后烟气脱硫.炉前脱硫是在煤入炉前将硫脱掉,如洗煤,磁脱硫等方法.这一类方法的脱硫率较低,目前在电力工业上应用的较少.炉后烟气脱硫方法也很多,常用的有湿法烟气脱硫和喷雾干燥法烟气脱硫.这两种方法适应于燃用中高硫煤的电厂,虽然脱硫效率较高,但工艺过程复杂,投资及运行费用较高,而且占用场地大,不易在现有火电厂改造采用.炉内喷钙脱硫是将石灰石粉用气体送入炉内,碳 相似文献
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介绍用于燃煤锅炉炉内喷钙脱硫的AG-2型固硫剂,及其在广州石油化工总厂脱硫示范工程中获得的技术指标和成本分析。 相似文献
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目前,世界上电站采用的脱硫工艺不下百余种,按脱硫工艺在生产中所处的部位不同可分为:燃烧前脱硫、燃烧中脱硫和燃烧后脱硫;按脱硫方法来分有湿法、半干法和干法。在这些工艺中,石灰石-石膏法的技术较为成熟,炉内喷钙、旋转喷雾等半干法也已达到工业应用水平。本文主要详细介绍TurboSonic烟气脱硫技术和美国Airpol公司的技术,供大家参考。 相似文献
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燃煤电厂烟气脱硫技术发展现状 总被引:3,自引:0,他引:3
综述近年来国内外应用及正在研究开发的脱硫工艺,包括国内应用的石灰石-石膏,海水,磷铵复肥,喷雾干燥,炉内喷钙,电子束烟气脱硫及国外的尿素,改进的石灰石-石膏,再生法脱除SO2和NOX等新方法,并对其中发生的化学反应,特点及存在的问题进行了较详细的分析。 相似文献
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铜基改性非碳基吸附剂汞脱除性能研究 总被引:2,自引:1,他引:1
对以CuCl2及CuBr2为活性物质,6种大比表面积非碳基载体制成的吸附剂在不同烟气条件下的汞吸附性能及价态分布进行了研究.在纯N2条件下以氧化铝、沸石、皂土为载体的吸附剂具有很高的汞脱除率.水蒸气会降低吸附剂的汞脱除率,SO2对非碳基吸附剂有抑制作用,对CuBr2改性吸附剂及以皂土为载体的吸附剂的影响尤为突出.NO的影响更多地取决于吸附剂载体的性质.HCl的加入对CuCl2改性吸附剂及以皂土为载体的吸附剂的汞脱除率有抑制效果.模拟真实烟气的作用是几种酸性气体的叠加.其中CuCl2改性氧化铝在所有烟气条件下均表现出较好的汞吸附性能及很高的汞氧化率. 相似文献
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Jitong Wang Huichao Chen Huanhuan Zhou Xiaojun Liu Wenming Qiao Donghui Long Licheng Ling 《环境科学学报(英文版)》2013,25(1):124-132
A high efficiency sorbent for CO2 capture was developed by loading polyethylenimine (PEI) on mesoporous carbons which possessed well-developed mesoporous structures and large pore volume. The physicochemical properties of the sorbent were characterized by N2 adsorption/desorption, scanning electron microscopy (SEM), thermal gravimetric analysis (TG) and Fourier transform infrared spectroscopy (FT-IR) techniques followed by testing for CO2 capture. Factors that affected the sorption capacity of the sorbent were studied. The sorbent exhibited extraordinary capture capacity with CO2 concentration ranging from 5% to 80%. The optimal PEI loading was determined to be 65 wt.% with a CO2 sorption capacity of 4.82 mmol-CO2 /g-sorbent in 15% CO2 /N2 at 75°C, owing to low mass-transfer resistance and a high utilization ratio of the amine compound (63%). Moisture had a promoting effect on the sorption separation of CO2 . In addition, the developed sorbent could be regenerated easily at 100°C, and it exhibited excellent regenerability and stability. These results indicate that this PEI-loaded mesoporous carbon sorbent should have a good potential for CO2 capture in the future. 相似文献
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The Kyoto Protocol calls for greenhouse gas emission reductions which could affect the use of coal for producing electricity. Carbon credits are being explored as a method for countries to meet their reduction commitments. Carbon dioxide removal in flue gas desulfurization (FGD) systems should be considered if and when the concept of carbon credits are implemented. This paper addresses the factors affecting sulfur dioxide removal, including the reaction of carbon dioxide, occurring during convective pass sorbent injection with high temperature filtration for a typical coal-fired power plant. Significant carbonation is found to occur, and the levels are found to depend on injection/filtration temperatures and the residence time on the filter. Ca/S stoichiometry during sorbent injection is found to affect not only the sorbent conversions in the convective pass sorbent injection stage but also the final sorbent conversions in the filtration stage. Even though high sorbent carbonation hinders the sorbent utilization for SO2 removal, slight alterations in CO2 concentration are found to have no significant effects on the SO2 removal of the process. 相似文献
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In order to reduce the impact of eutrophication caused by agricultural residues (i.e. excess nitrate) in aqueous solution, economic and effective anionic sorbents are required. In this article, we prepared anionic sorbent using wheat straw. Its structural characteristics and adsorption properties for nitrate removal from aqueous solution were investigated. The results indicate that the yield of the prepared anionic sorbent, the total exchange capacity, and the maximum adsorption capacity were 350%, 2.57 mEq/g, and 2.08 mmol/g, respectively. The Freundlich isotherm mode is more suitable than the Langmuir mode and the adsorption process accords with the first order reaction kinetic rate equation. When multiple anions (SO42-, H2PO4-, NO3-, and NO2-) were present, the isotherm mode of prepared anionic sorbent for nitrate was consistent with Freundlich mode; however, the capacity of nitrate adsorption was reduced by 50%. In alkaline solutions, about 90% of adsorbed nitrate ions could be desorbed from prepared anionic sorbent. The results of this study confirmed that the wheat straw anionic sorbent can be used as an excellent nitrate sorbent that removes nitrate from aqueous solutions. 相似文献
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钙基脱硫剂孔隙结构特性直接影响到脱硫效果及脱硫剂的利用率,对其空间网络特性的描述将有助于分析SO2的扩散及反应特性. 在石灰石分解动力学和烧结机理的基础上,结合固体分解的成核机理,运用Monte-Carlo 方法,建立了脱硫剂孔隙网络的动态生成模型,对钙基脱硫剂分解形成的孔隙结构进行了动态模拟,并对生成孔结构的分形特性进行研究.结果表明,运用动态生成模型,可以给出石灰石分解形成的CaO内部孔隙的微观空间结构,且模拟生成的孔隙网络的分形维数与实验测定值基本吻合. 相似文献