Pharmaceuticals and personal care products (PPCPs) have been regarded as an emerging problem in the surface water environment in the past few decades. In China, although related studies were initiated several years ago, an increasing number of studies on this topic have been conducted in recent years. These studies have expanded knowledge of their occurrence, behavior and associated risk in the surface water environment in China. This review compiles the most recent literature related to the studies of PPCPs in the surface water environment in China. It includes PPCP occurrence in surface water and sediments, their geographical distribution, and outcomes of the associated risk assessment. It shows that antibiotics have received much more attention in both surface water and sediments than other PPCPs. Compared to other countries; most antibiotics in the collected sediments in China showed higher contamination levels. Many more study areas have been covered in recent years; however, attention has been given to only specific areas. Environmental risk assessment based on risk quotients indicated that sulfamethoxazole presents the most significant environmental risk to relevant aquatic organisms; followed by ofloxacin, ciprofloxacin, enrofloxacin, 17α-ethynylestradiol, ibuprofen and diclofenac. Despite limited research on the environmental risk assessment of PPCPs in sediments, higher risks posed by PPCPs in the sediments rather than surface water were identified highlighting the need for further risk assessment of PPCPs in sediment samples.
Six wastewater treatment plants （WWTPs） were investigated to evaluate the occurrence and removal of N-nitrosodimethylamine （NDMA）, NDMA formation potential （FP） and four specific NDMA precursors, dimethylamine （DMA）, trimethylamine （TMA）, dimethyl- formamide （DMFA） and dimethylaminobenzene （DMAB）. DMA and tertiary amines with DMA functional group commonly existed in municipal wastewater. Chemically enhanced primary process （CEPP） had no effect on removal of either NDMA or NDMA FP. In WWTPs with secondary treatment processes, considerable variability was observed in the removal of NDMA （19%-85%） and NDMA FP （16%-76%）, moreover, there was no definite relationship between the removal of NDMA and NDMA FP. DMA was well removed in all the six surveyed WWTPs; its removal efficiency was greater than 97%. For the removal of tertiary amines, biologic treatment processes with nitrification and denitrification had better removal efficiency than conventional activated sludge process. The best removal efficiencies for TMA, DMFA and DMAB were 95%, 68% and 72%, respectively. CEPP could remove 73% of TMA, 23% of DMFA and 36% of DMAB. After UV disinfection, only 17% of NDMA was removed due to low dosage of UV was applied in WWTP. Although chlorination could reduce NDMA precursors, NDMA concentration was actually increased after chlorination. 相似文献
In order to assess the intake of lead and cadmium by consumers of home grown vegetables in urban areas, replicated experimental plots of uniform size, comprising summer and winter crops, were established in 94 gardens and allotments in nine towns and cities in England.The geometric mean lead and cadmium concentrations for the soils (n = 94) were 217 g g–1 (ranging from 27 to 1,676 g g–1) and 0.53 g g–1 (<0.2–5.9 g g–1), respectively. Compared with agricultural soils, the garden and allotment soils contained elevated levels of lead but not cadmium.Lead concentrations in the vegetables ranged from <0.25 g g–1 to 16.7 g g–1 dry weight and cadmium concentrations ranged from <0.025 g g–1 to 10.4 g g–1 dry weight. Lead concentrations were higher than reported background levels, although <1% exceeded the statutory limit for saleable food in the UK (1 g g–1 fresh weight). Cadmium concentrations were generally similar to background levels. 相似文献
Since analysis of both soil and plants are useful to assess contamination of a geographic area, concentrations of five representative metals: copper (Cu), zinc (Zn), cadmium (Cd), lead (Pb), and iron (Fe) in soil and associated plants were measured by atomic absorption spectroscopy. Samples were collected from four different Egyptian regions (El-mehala El-kobra, Kafr El-Sheikh, Kafr El-zayat, and Al-fayoum) during spring and summer 2010. Concentrations of the selected metals in agricultural soils were significantly different among locations and seasons. Concentrations of Cd and Fe in soils at the four locations exceeded the maximum allowable concentrations for Cd (8 mg/kg, dry mass (dm)) and Fe (1000 mg/kg, dm). Accumulation was different for clover and cotton. Clover blossoms grown in soil from Kafr El-zayat contained the greatest concentrations of Cu, Zn, Pb, and Fe. Cotton flowers from El-mehala El-kobra accumulated the highest levels of Cd. Concentrations of Cd and Pb in both clover and cotton flowers from the four locations exceeded maximum allowable concentrations (3 mg/kg, dm) for both Cd and Pb. Using such agricultural soils for cultivation of edible crops for consumption may result in chronic hazards to human health. 相似文献
The food and agriculture sector controls the economic growth of a developing country. The food industries have practices of growing crops, raising livestock and sea foods, food processing and packaging, regulating production and distribution with quality and safety. The process control and monitoring quality are crucial steps. Here we review nanosensors and nanobiosensors as alternative of classical quantification methods. Nanoscale dimensions of metal nanoparticles, metal nanoclusters, metal oxide nanoparticles, metal and carbon quantum dots, graphene, carbon nanotubes, and nanocomposites expand the sensitivity by signal amplification and integrate several novel transduction principles such as enhanced electrochemical, optical, Raman, enhanced catalytic activity, and superparamagnetic properties into the nanosensors. The electrochemical nanosensors, optical nanosensors, electronic nose and electronic tongue, nanobarcode technology, and wireless nanosensors have revolutionized the sensing in food and agriculture sectors with multiplex and real-time sensing capabilities. Despite previous success stories of the remunerative health sector, the approaches are transferred subsequently to food and agriculture sector; with potential application in detection of food contaminants such as preservatives, antibiotics, heavy metal ions, toxins, microbial load, and pathogens along with the rapid monitoring of temperature, traceability, humidity, gas, and aroma of the food stuff. 相似文献
Sequential extraction has been used as a suitable method for fractionation of chemical forms of trace elements and study of
their plant availability. Surface soils were sampled from Guilan and Hamadan provinces in north and northwest of Iran with
temperate and semiarid climates. The chemical forms of Pb in the Pb(NO3)2-treated (400 μg Pb g−1) soils have been studied in solid state incubation (FC) at 27°C in sterile and unsterile conditions. After 20 min and 3600 h
a sequential extraction scheme was also used to fractionate Pb of incubated samples into soluble-exchangeable (Sol-Exch),
carbonates associated (ACar), organic matter associated (AOM), Mn oxide associated (AMnOx), Fe oxide associated (AFeOx), and
residual (Res) forms. Temperate soil samples had higher clay content, cation exchange capacity (CEC), dichromate oxidable
organic carbon (OC), total Kjeldahl-nitrogen (TN), biological activity, amorphous and crystalline Fe and Al, but semiarid
soil samples had higher sand content, pH, equivalent calcium carbonate (ECC), available P and K. Soil lead fractionation revealed
that in both groups of soils Pb largely changed to exchangeable, carbonates associated and organic associated forms after
20 min. The chemical forms of Pb differed widely among soils after 3600-h incubation. The conversion rate of Pb from more
available forms to less available forms was higher in temperate soils with higher Fe–Mn oxides and OM contents compared to
semiarid soils. In temperate soils after 3600-h incubation, greater content of Pb was observed in Res (68%), AOM (14%), ACar
(7%), and AMnOx (5%) fractions. However, in semiarid soils greater content of Pb was observed in Res (61%), ACar (16%), Sol-Exch
(8%), and AOM (8%) fractions. The sum of AMnOx and AFeOx chemical forms for Pb in semiarid soils compared to temperate soils
was lower. It was only 7% against 9% in temperate soils. Soil microorganisms in unsterile soils had significant effect on
AOM, AFeOx and Res fractions of Pb. They not only increased AOM and AFeOx fractions of Pb in soils but also decreased Res
fraction of Pb significantly. 相似文献
The seasonal variations of Cd, Pb, and Cu in the water, sediments, and freshwater fish (Hypophthalmichthys molitrix, Cirrhinus molitorella, and Oreochromis mossambicus) of four lakes in Hanoi, Vietnam, were investigated. Samples for analysis were taken four times from April 2010 to March 2011. The levels in water were lower than the Vietnamese standards, except for Pb, but they were all much higher than the Canadian standards for protection of aquatic life; in the sediments, they were higher than world average levels. Bioaccumulation of the three metals in fish was site-dependent and species-dependent, but correlations of their levels in fish to those in water and sediments were weak. Levels of Pb in fish exceeded those of the UK and the WHO standards, and the recommended values of Vietnam for human consumption. Overall, the results show that the lakes are polluted with these metals, and consumption of high quantities of fish from them may be problematic. The outcome of this research helps to establish background data for future monitoring. 相似文献
