首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 15 毫秒
1.
We report for the first time the distribution and hazard potential of aerosol and metals resulting from joss paper burning. Burning joss paper and incense is a traditional custom in many Oriental countries. Large amounts of air pollutants, including particles, polycyclic aromatic hydrocarbons, toxic metals and other gaseous pollutants, are released into the environment during the burning stage. Many investigations have reported on the emission of pollutants from the incense burning. However, no work has been reported until now on the analysis of the released pollutants apart from polycyclic aromatic hydrocarbons. In this study, a micro-orifice uniform-deposit impactor and inductively coupled plasma optical emission spectrometry were, respectively, used to collect aerosols and characterize the toxic metals from joss paper burning. We studied two types of particulate matter (PM): PM2.5 that are particles with a diameter smaller than 2.5 μm and PM10 that are particles with a diameter smaller than 10 μm. PM2.5 are the most potentially toxic particles. Our results showed that PM2.5 are the major component of the pollutants and that the PM2.5 to PM10 ratio ranged from 62 to 99%. The metals Na, Ca, Mg, Al and K were the main species in the aerosol and in the bottom ash.  相似文献   

2.
Concentrations of total suspended particulate matter, particulate matter with aerodynamic diameter <2.5 μm (PM2.5), particulate matter <10 μm (PM10), and fallout dust were measured at the Iranian Gol-E-Gohar Mining and Industrial Facility. Samples were characterized in terms of mineralogy, morphology, and oxidative potential. Results show that indoor samples exceeded the 24-h PM2.5 and PM10 mass concentration limits (35 and 150 µg m?3, respectively) set by the US National Ambient Air Quality Standards. Calcite, magnetite, tremolite, pyrite, talc, and clay minerals such as kaolinite, vermiculite, and illite are the major phases of the iron ore PM. Accessory minerals are quartz, dolomite, hematite, actinolite, biotite, albite, nimite, laumontite, diopside, and muscovite. The scanning electron microscope structure of fibrous-elongated minerals revealed individual fibers in the range of 1.5 nm to 71.65 µm in length and 0.2 nm to 3.7 µm in diameter. The presence of minerals related to respiratory diseases, such as talc, crystalline silica, and needle-shaped minerals like amphibole asbestos (tremolite and actinolite), strongly suggests the need for detailed health-based studies in the region. The particulate samples show low to medium oxidative potential per unit of mass, in relation to an urban road side control, being more reactive with ascorbate than with glutathione or urate. However, the PM oxidative potential per volume of air is exceptionally high, confirming that the workers are exposed to a considerable oxidative environment. PM released by iron ore mining and processing activities should be considered a potential health risk to the mine workers and nearby employees, and strategies to combat the issue are suggested.  相似文献   

3.
An assessment of air quality of Belgrade, Serbia, was performed by determining the trace element content in airborne daily PM10 and PM2.5 samples collected from a central urban area. The ambient concentrations of Zn were the highest in PM2.5 (1,998.0 ng m−3). Multivariate receptor modelling (principal component analysis and cluster analysis) has been applied to determine the contribution of different sources of specific metallic components in airborne particles. The obtained results showed that vehicle traffic and fossil fuel combustion in stationary objects were the main sources of trace metals in Belgrade urban aerosols.  相似文献   

4.
Aerosol samples of particulate and chemical species for PM10 (particulate matter with aerodynamic diameters less than 10 μm) collected by Universal sampler were studied from June to August 1998 in the suburban area of central Taiwan. The ratios of PM2.5/PM2.5–10 displayed that the fine particles (particle size < 2.5 μm) are prevailing in the suburban site. Ion Chromatography was used to analyze for the water‐soluble ions: sulphate and nitrate in the Universal samples. Also, the collected samples were analyzed by atomic absorption spectrophotometry for the elemental analysis of Ca, Fe, Pb, Cu and Cr. The results indicated that the crustal elements (Ca and Fe) and resuspended matters were dominated in the coarse particulate mode while the anthropogenic elements (Cr, Pb, Cu) and sulphate components are mainly in the fine particle fraction. The results also showed that the sulphate and nitrate make the largest portion of the chemical species collected by Universal sampler (PMio). The concentrations of heavy metals in THU are generally high, owing to the higher motor vehicle and industrial density nearby. The degree of pollution from this source differs from day to day, depending on the motor vehicle density.  相似文献   

5.
The paucity of data on air pollution indices in Nigeria prompted us to commence a national screening exercise regarding particulate matter loads. Six potential megacities (Aba, Abuja, Lagos, Kano, Maiduguri, and Port-Harcourt) representing the six geographical zones in Nigeria were chosen for the study. Sampling was achieved using a ‘Gent’ stacked filter unit sampler capable of collecting fractions of particulate matter with sizes of <10-μm and <2.5-μm simultaneously. The mean values for PM10 are 550, 35, 87, 340, 246 and 130 μg m?3 while for PM2.5 the mean values are 100, 14, 25, 67, 20 and 30 μg m?3 respectively for Aba, Abuja, Lagos, Kano, Maiduguri, and Port-Harcourt. Except for Abuja, the daily PM10 mass loads exceeded the World Health Organization (WHO) guidelines daily limit where as the PM2.5 values were within the WHO guideline limit. Their correlation matrix result indicates that some PM2.5 fractions mass fractions were strongly correlated than the PM10 fractions probably due to their long range transport potentials. Further work is in progress to determine the elemental profiles of both particulate fractions collected.  相似文献   

6.
Exposure to airborne particulate matter results in the deposition of millions of particle in the lung; consequently, there is need for monitoring them particularly in indoor environments. Case study was conducted in three different microenvironments, i.e., urban, rural and roadside to examine the elemental bioavailability in fine particulate matter and its potential health risk. The samples were collected on polytetrafluoroethylene filter paper with the help of fine particulate sampler during August–September, 2012. The average mass concentration of PM2.5 was 71.23 µg m?3 (rural), 45.33 µg m?3 (urban) and 36.71 µg m?3 (roadside). Elements in PM2.5 were analyzed by inductively coupled plasma atomic emission spectroscopy. Percentage bioavailability was determined to know the amount of soluble fraction that is actually taken across the cell membrane through inhalation pathway. Cadmium and lead were found to have cancer risk in a risk evaluation using an Integrated Risk Information system.  相似文献   

7.
The increase in platinum (Pt) in the airborne particulate matter with size ≤2.5 µm (PM2.5) in urban environments may be interpreted as result of the abrasion and deterioration of automobile catalyst. Nowadays, about four million vehicles in Mexico City use catalytic converters, which means that their impact should be considered. In order to evaluate the contribution of Pt to environmental pollution of the metropolitan area of Mexico City (MAMC), airborne PM2.5 was collected at five different sites in the urban area (NW, NE, C, SW, SE) in 2011 during April (dry-warm season), August (rainy season) and December (dry-cold season). Analytical determinations were carried out using a ICP-MS with a collision cell and kinetic energy discrimination. The analytical and instrument performance was evaluated with standard road dust reference material (BCR-723). Median Pt concentration in the analyzed particulate was is 38.4 pg m?3 (minimal value 1 pg m?3 maximal value 79 pg m?3). Obtained Pt concentrations are higher than those reported for other urban areas. Spatial variation shows that SW had Pt concentration significantly higher than NW and C only. Seasonal variation shows that Pt median was higher in rainy season than in both dry seasons. A comparison of these results with previously reported data of PM10 from 1991 and 2003 in the same studied area shows a worrying increase in the concentration of Pt in the air environment of MAMC.  相似文献   

8.
The Eulerian Chemistry-Transport Model BelEUROS was used to calculate the concentrations of airborne PM10 and PM2.5 over Europe. Both primary as well as secondary particulate matter in the respirable size-range was taken into account. Especially PM2.5 aerosols are often formed in the atmosphere from gaseous precursor compounds. Comprehensive computer codes for the calculation of gas phase chemical reactions and thermodynamic equilibria between compounds in the gas-phase and the particulate phase had been implemented into the BelEUROS-model. Calculated concentrations of PM10 and PM2.5 are compared to observations, including both the spatial and daily, temporal distribution of particulate matter in Belgium for certain monitoring locations and periods. The concentrations of the secondary compounds ammonium, nitrate and sulfate have also been compared to observed values. BelEUROS was found to reproduce the observed concentrations rather well. The model was applied to assess the contribution of emissions derived from the sector agriculture in Flanders, the northern part of Belgium, to PM10- and PM2.5-concentrations. The results demonstrate the importance of ammonia emissions in the formation of secondary particulate matter. Hence, future European emission abatement policy should consider more the role of ammonia in the formation of secondary particles.  相似文献   

9.
Outdoor air pollution and fine particulate matter (PM) were recently classified as carcinogenic to humans by the International Agency for Research on Cancer. The exposure to airborne particulate matter also contributes to cardiovascular and respiratory diseases, which are major public health concerns. Up to now, no work has evaluated the ability of essential oils as an alternative medicine to relieve the adverse health effects caused by airborne particulate matter. Here, we investigated for the first time the effects of four essential oil components, trans-anethole, estragole, eugenol and isoeugenol, on the reduction in inflammation induced by particulate matter with an aerodynamic diameter below 2.5 μm (PM2.5), in human bronchial epithelial (BEAS-2B) and human liver carcinoma (HepG2) cell lines. Anethole is a flavor component of anise and fennel, estragole is occurring in basil, eugenol occurs in clove bud oil and isoeugenol occurs in ylang-ylang. Essential oil components were tested either as free or hydroxypropyl-β-cyclodextrin-encapsulated forms. Control experiments showed that particulate matter (PM2.5) induced inflammation by secretion of pro-inflammatory cytokines IL-6 and IL-8. Our results show that the addition of either free or encapsulated essential oil components to particulate matter exposed cells decreased up to 96 % the cytokine IL-6 level, and by up to 87 % the cytokine IL-8 level. Overall our findings evidence for the first time that natural essential oil components counteract the inflammatory effects of particulate matter and that encapsulation in cyclodextrins preserved their properties.  相似文献   

10.
Fine particulate matter (PM2.5) levels, carbon dioxide (CO2) levels and particle-number concentrations (PNC) were monitored in train carriages on seven routes of the mass transit railway in Hong Kong between March and May 2014, using real-time monitoring instruments. The 8-h average PM2.5 levels in carriages on the seven routes ranged from 24.1 to 49.8 µg/m3, higher than levels in Finland and similar to those in New York, and in most cases exceeding the standard set by the World Health Organisation (25 µg/m3). The CO2 concentration ranged from 714 to 1801 ppm on four of the routes, generally exceeding indoor air quality guidelines (1000 ppm over 8 h) and reaching levels as high as those in Beijing. PNC ranged from 1506 to 11,570 particles/cm3, lower than readings in Sydney and higher than readings in Taipei. Correlation analysis indicated that the number of passengers in a given carriage did not affect the PM2.5 concentration or PNC in the carriage. However, a significant positive correlation (p < 0.001, R 2 = 0.834) was observed between passenger numbers and CO2 levels, with each passenger contributing approximately 7.7–9.8 ppm of CO2. The real-time measurements of PM2.5 and PNC varied considerably, rising when carriage doors opened on arrival at a station and when passengers inside the carriage were more active. This suggests that air pollutants outside the train and passenger movements may contribute to PM2.5 levels and PNC. Assessment of the risk associated with PM2.5 exposure revealed that children are most severely affected by PM2.5 pollution, followed in order by juveniles, adults and the elderly. In addition, females were found to be more vulnerable to PM2.5 pollution than males (p < 0.001), and different subway lines were associated with different levels of risk.  相似文献   

11.
Many regions in China experience air pollution episodes because of the rapid urbanization and industrialization over the past decades. Here we analyzed the effect of emission controls implemented during the G-20 2016 Hangzhou summit on air quality. Emission controls included a forced closure of highly polluting industries, and limiting traffic and construction emissions in the cities and surroundings. Particles with aerodynamic diameter lower than 2.5 μm (PM2.5) and ozone (O3) were measured. We also simulated air quality using a forecast system consisting of the two-way coupled Weather Research and Forecast and Community Multi-scale Air Quality (WRF-CMAQ) model. Results show PM2.5 and ozone levels in Hangzhou during the G-20 Summit were considerably lower than previous to the G-20 Summit. The predicted concentrations of ozone were reduced by 25.4%, whereas the predicted concentrations of PM2.5 were reduced by 56%.  相似文献   

12.
The chemical characteristics of fine particulate matter (PM2.5) emitted from commercial cooking were explored in this study. Three typical commercial restaurants in Shanghai, i.e., a Shanghai-style one (SHS), a Sichuan-style one (SCS) and an Italian-style one (ITS), were selected to conduct PM2.5 sampling. Particulate organic matter (POM) was found to be the predominant contributor to cooking-related PM2.5 mass in all the tested restaurants, with a proportion of 69.1% to 77.1%. Specifically, 80 trace organic compounds were identified and quantified by gas chromatography/mass spectrometry (GC/MS), which accounted for 3.8%–6.5% of the total PM2.5 mass. Among the quantified organic compounds, unsaturated fatty acids had the highest concentration, followed by saturated fatty acids. Comparatively, the impacts of other kinds of organic compounds were much smaller. Oleic acid was the most abundant single species in both SCS and ITS. However, in the case of SHS, linoleic acid was the richest one. ITS produced a much larger mass fraction of most organic species in POM than the two Chinese cooking styles except for monosaccharide anhydrides and sterols. The results of this study could be utilized to explore the contribution of cooking emissions to PM2.5 pollution and to develop the emission inventory of PM2.5 from cooking, which could then help the policymakers design efficient treatment measures and control strategies on cooking emissions in the future.  相似文献   

13.
PM2.5 has become an important environmental issue in Taiwan during the past few years. Moreover, electricity increased significantly during the summertime and TTPP generated by coal burning base is the main electricity provider in central Taiwan. Therefore, summer season has become the main research target in this study. The ambient air concentrations of particulate matter PM2.5 and PM10 collected by using VAPS at a mixed characteristic sampling site were studied in central Taiwan. The results indicated that the average daytime PM2.5 and PM10 particulate concentrations were occurred in May and they were 44.75 and 57.77 µg/m3 in this study. The results also indicated that the average nighttime PM2.5 and PM10 particulate concentrations were occurred in June and they were 38.19 and 45.79 µg/m3 in this study. The average PM2.5/PM10 ratios were 0.7 for daytime, nighttime and 24-h sampling periods in the summer for this study. This value was ranked as the lowest ratios when compared to the other seasons in previous study. Noteworthy, the results further indicated that the metallic element Pb has the mean highest concentrations for 24-h, daytime and nighttime sampling periods when compared to those of the other metallic elements (Ni, Cu, Zn and Cd). The average mean highest metallic Pb concentrations in PM10 were 110.7, 203.0 and 207.2 ng/m3 for 24-h, daytime and nighttime sampling periods in this study. And there were 59.53, 105.2 and 106.6 ng/m3 for Pb in PM2.5 for 24-h, daytime and nighttime sampling periods, respectively. Moreover, the results further indicated that mean metallic element Pb concentrations on PM2.5 and PM10 were all higher than those of the other elements for 24 h, day and nighttime.  相似文献   

14.
Abstract

Airborne particulate matter PM2.5 was collected in an industrial, a low-density, and a high-density residential area of Lagos from December 2010 to November 2011, and elemental composition was determined by proton-induced X-ray emission. Across the months, mass concentrations ranged from 13 to 237?µg?m?3, exceeding the World Health Organization guideline value of 10?µg?m?3. Data on 24 elements were obtained, with maximum values during Harmattan season months; source identification and apportionment studies by positive matrix factorization suggested that petroleum oil combustion (70%) was the major source of PM2.5 and could pose a great hazard to Lagos receptors.  相似文献   

15.
In this work, the airborne particulate matter with an aerodynamic diameter less than 10 µm (PM10) was fractionated in a six-stage high-volume cascade impactor to identify particulate size distribution in Tehran atmosphere. The study was conducted at 15 sites located in the north, south, east, west, and central parts of Tehran in 2005. Air samples were analyzed for 16 polycyclic aromatic hydrocarbons (PAHs) by HPLC. The daily PM10 concentrations at the peak of traffic in roadside areas were found to be 106–560 µg m?3. The cumulated concentration sum of PAHs, based on 16 species, was found to have an average concentration of 380 ng m?3. Furthermore, it was found that more than 60% of PAHs belonged to the small particulate size range, having sizes of less than 0.49 µm, some containing benzo(ghi)perylene and indeno(123cd)pyrene (high molecular weight) with average concentrations of 8 and 6 ng m?3 and fluorene, phenanthrene, and fluoranthene (low molecular weight) with average concentrations of 14, 13, and 19 ng m?3, respectively. In addition, the results revealed that the lighter three- and four-ring PAH compounds were the most abundant pollutants in the air collected at all the sampling sites.  相似文献   

16.
Niu  Honghong  Wang  Baoqing  Liu  Bowei  Liu  Yuhong  Liu  Jianfeng  Wang  Zebei 《Environmental Fluid Mechanics》2018,18(4):829-847

To explore the effect of traffic emissions on air quality within street canyon, the wind flow and pollutant dispersion distribution in urban street canyons of different H/W, building gap and wind direction are studied and discussed by 3D computational fluid dynamics simulations. The largest PM2.5 concentrations are 46.4, 37.5, 28.4 µg/m3 when x = ? 88, ? 19.3, ? 19.3 m in 1.5 m above the ground level and the ratio of H/W is 1:1, 1:2 and 2:1, respectively. The flow around the top of the building and clearance flow between the buildings in street canyon influence by different H/W, which affected the diffusion of fine particulate matters. The largest PM2.5 concentrations are 88.1, 31.6 and 33.7 µg/m3 when x = 148.0, ? 92.3 and ? 186.7 m above the ground level of 1.5 m height and the building gap of 0, 20 and 40%, respectively. The air flows are cut by the clearance in the street canyons, and present the segmental characteristics. The largest PM2.5 concentrations are 10.6, 11.2 and 16.0 µg/m3 when x = 165.3 m, x = 58.0 and 1.5 m above the ground level of 1.5 m height and wind direction of the parallel to the street, perpendicular to the street and southwest, respectively. Modelled PM2.5 concentrations are basic agreement with measured PM2.5 concentrations for southwest wind direction. These results can help analyze the difussion of PM2.5 concentration in street canyons and urban planning.

  相似文献   

17.
Ambient PM2.5 samples were collected at four sites in Xiamen, including Gulangyu (GLY), Hongwen (HW), Huli (HL) and Jimei (JM) during January, April, July and October 2013. Local source samples were obtained from coal burning power plants, industries, motor vehicles, biomass burning, fugitive dust, and sea salt for the source apportionment studies. The highest value of PM2.5 mass concentration and species related to human activities (SO4 2–, NO3 , Pb, Ni, V, Cu, Cd, organic carbon (OC) and elemental carbon (EC)) were found in the ambient samples from HL, and the highest and lowest loadings of PM2.5 and its components occurred in winter and summer, respectively. The reconstructed mass balance indicated that ambient PM2.5 consisted of 24% OM (organic matter), 23% sulfate, 14% nitrate, 9% ammonium, 9% geological material, 6% sea salt, 5% EC and 10% others. For the source profiles, the dominant components were OC for coal burning, motor vehicle, biomass burning and sea salt; SO4 2– for industry; and crustal elements for fugitive dust. Source contributions were calculated using a chemical mass balance (CMB) model based on ambient PM2.5 concentrations and the source profiles. GLY was characterized by high contributions from secondary sulfate and cooking, while HL and JM were most strongly affected by motor vehicle emissions, and biomass burning and fugitive dust, respectively. The CMB results indicated that PM2.5 from Xiamen is composed of 27.4% secondary inorganic components, 20.8% motor vehicle emissions, 11.7% fugitive dust, 9.9% sea salt, 9.3% coal burning, 5.0% biomass burning, 3.1% industry and 6.8% others.
  相似文献   

18.
Movement rate, oxygen consumption, and respiratory tree ammonium concentration were measured in situ in the holothurians Pearsonothuria graeffei and Holothuria edulis in the Agan-an Marine Reserve, Sibulan, Philippines (9°20′30″N, 123°18′31″E). Measurements were made both day and night for both species during April–July 2005. P. graeffei had significantly higher movement rate during the day than at night (1.14 and 0.27 m h−1, respectively; three-way ANOVA, P < 0.05) while H. edulis had higher movement rate at night compared to the day (0.83 and 0.07 m h−1, respectively), spending the daylight hours sheltering under coral. More than 80% of H. edulis had movement rate of zero during the day. Oxygen consumption of P. graeffei was significantly higher during the day than at night (1.61 and 0.83 μmol O2 g−1 h−1, respectively; two-way ANCOVA, P < 0.05), but the reduction at night was not as pronounced as the reduction in movement. H. edulis had a 75% reduction in oxygen consumption during the day compared to night (0.51 and 1.96 μmol O2 g−1 h−1, respectively), matching this species’ reduced movement rates during the day. Ammonium concentration in water withdrawn from the respiratory trees of P. graeffei during the day (12.0 μM) was three times higher than in respiratory tree water sampled at night (4.3 μM) and 15 times higher than ambient seawater (0.8 μM; three-way ANOVA, P < 0.05). Ammonium concentration in the respiratory tree water of H. edulis was six times higher at night (14.6 μM) than during the day (2.2 μM) and 16 times higher than that of ambient seawater (0.9 μM). Even though H. edulis and P. graeffei are found within the same coral reef environment, they may affect different substrates and reef organisms due to their different habitats and distinct but opposite diel cycles.  相似文献   

19.
The objective of this study was to determine the black carbon concentration in Beijing in 2003. The aerosol properties were measured using an Aethalometer and a tapered element oscillating microbalance (TEOM) on the roof of the Physics Building of Peking University (39.99° N, 116.31° E) from July to August 2003 and from November 2003 to January 2004. The average black carbon (BC) concentrations in the summer and winter were 8.80 and 11.4 μg/m3, respectively. During winter, two different cyclone cut offs were installed at the inlet of an aethalometer. The BC mass concentration in TSP, PM10, and PM2.5 were obtained. The results indicated that in winter aerosol, 90% of BC exited in PM10 and 82.6% of BC exited in PM2.5. The BC in PM10 accounted for 5.11% of the PM10 mass.  相似文献   

20.
Trace metal concentrations were determined in particulate matter (PM10) in ambient air of four purposively selected residential areas in Ibadan, Nigeria namely Bodija market (BM), Ojo Park (OP), Oluyole Estate (OE) and University of Ibadan (UI). PM10 was determined in the morning (7–10 a.m.) and afternoon (2–5 p.m.) for 12 weeks in the dry season months of January–March using a volumetric sampler following standard procedures and levels compared with WHO guideline limits. Glass-fibre filter papers exposed to the particulate matter were digested using appropriate acid mixtures, and the digest analysed for trace metals including Ni, Cr, Mn, Zn, and Pb using ICPMS method and levels compared with WHO limits. Data was analysed using ANOVA and Pearson correlation test at 5 % level of significance. The highest mean PM10 concentrations 502.3 ± 39.9 μg/m3 were recorded in the afternoon period at BM, while the lowest concentration 220.6 ± 69.9 μg/m3 was observed in the morning hours at UI. There was a significant difference between the PM10 levels across the various locations (p < 0.05), and all the levels were higher than WHO limit of 50 μg/m3. The highest levels of Ni, Zn and Pb were recorded at BM, which also had the highest PM10 burden. The trend in Pb levels across the locations was BM > UI > OP > OE with the highest level 5.70 μg/m3 in BM nearly fourfolds WHO limits of 1.5 μg/m3. There was a significant correlation between PM10 and Ni (p < 0.05).Urban communities with increased human activities especially motor traffic recorded both higher levels of PM10 and toxic trace metals. There is need to carry out source apportionment to establish the origin of these trace metals in future studies.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号