Optimal resource management control for CO2 emission and reduction of the greenhouse effect

In recent years, the world has witnessed an ever-growing concern towards global warming caused by greenhouse gases, such as carbon dioxide (CO₂). In order to reduce the emissions of CO₂ without limiting economic growth, substantial investments should target the development of clean technology and the expansion of forested areas. Considering the limited availability of resources, investments must be used in the most effective way. The present work proposes a method to efficiently manage these resources by applying the optimal control theory to a new mathematical model that describes the dynamics of the atmospheric CO₂. The contributions of this work are twofold: (1) present a model that describes the dynamic relation of CO₂ emission with investment in reforestation and clean technology and (2) present a method to efficiently manage the available resources by casting an optimal control problem. The mathematical model uses ordinary differential equations to relate the production of CO₂ with forest area and Gross Domestic Product (GDP). The model parameters are adjusted to fit the actual published data. Given an appropriate performance index, the optimal solution is found by numerically solving the Two-Point Boundary Value Problem (TPBVP) that arises from the application of Pontriagyn's Maximum Principle. The sensitivity of the obtained numerical solution is evaluated with respect to the uncertainties in the model parameters. The main objective of this work is to provide a quantitative tool for the efficient allocation of resources to reduce the greenhouse effect caused CO₂ emissions.     

An optimized policy for the reduction of CO2 emission in the Brazilian Legal Amazon

The Brazilian government has already acknowledged the importance of investing in the development and application of technologies to reduce or prevent CO₂ emissions resulting from human activities in the Legal Brazilian Amazon (BA). The BA corresponds to a total area of 5 × 10⁶ km² from which 4 × 10⁶ km² was originally covered by the rain forest. One way to interfere with the net balance of greenhouse gases (GHG) emissions is to increase the forest area to sequester CO₂ from the atmosphere. The single most important cause of depletion of the rain forest is cattle ranching. In this work, we present an effective policy to reduce the net balance of CO₂ emissions using optimal control theory to obtain a compromising partition of investments in reforestation and promotion of clear technology to achieve a CO₂ emission target for 2020. The simulation indicates that a CO₂ emission target for 2020 of 376 million tonnes requires an estimated forest area by 2020 of 3,708,000 km², demanding a reforestation of 454,037 km². Even though the regional economic growth can foster the necessary political environment for the commitment with optimal emission targets, the reduction of 38.9% of carbon emissions until 2020 proposed by Brazilian government seems too ambitious.     

Emissionen und Minderungspotential von HFKW, FKW und SF6 in Deutschland

The greenhouse gases subject to emission reduction commitments under the UN Climate Convention include the fluorinated compounds sulphur hexafluoride (SF₆), perfluorocarbons (PFCs) and hydrofluorocarbons (HFCs). The present study projects the emissions of these gases in Germany over the 1995–2010 period, with and without additional emission abatement efforts In the business-as-usual scenario, total emissions of the three fluorinated gases rise over the 1995–2010 period from 11,1 to 27.4 million tonnes CO₂ equivalent. This rise is attributable to 72% to HFCs, used above all for refrigeration and stationary air-conditioning, for mobile air-conditioning, for blowing extruded polystyrene (XPS) foam and for one-component polyurethane (PU) foam. Soundproof glazing is the largest SF₆ emission sector. Most PFC emissions come from semiconductor manufacturing and aluminium smelting. The reduction scenario does not achieve a stabilisation of fluorinated gas emissions either. The rate of growth is only slowed, with 11.1 million tonnes CO₂ equivalent in 1995 growing to 14.9 million in 2010. The measures proposed to attenuate emissions growth are: mandatory equipment maintenance in refrigeration and stationary air-conditioning, refrigerant substitution of HFCs by CO₂ in mobile air-conditioning, partial HFC substitution by CO₂ in XPS foam blowing, 95% HFC substitution by flammable hydrocarbons in one-component PU foam. Complete SF₆ phase-out is considered to be feasible in soundproof glazing. The PFC emissions of the semiconductor industry can be cut by 85% by new chamber cleaning technologies.     

29 % N2O emission reduction from a modelled low-greenhouse gas cropping system during 2009–2011

Atmospheric concentration of nitrous oxide (N₂O), a greenhouse gas (GHG), is rising largely due to agriculture. At the plot scale, N₂O emissions from crops are known to be controlled by local agricultural practices such as fertilisation, tillage and residue management. However, knowledge of greenhouse gas emissions at the scale of the cropping system is scarce, notably because N₂O monitoring is time consuming. Strategies to reduce impact of farming on climate should therefore be sought at the cropping system level. Agro-ecosystem models are simple alternative means to estimate N₂O emissions. Here, we combined ecosystem modelling and field measurements to assess the effect of agronomic management on N₂O emissions. The model was tested with series of daily to monthly N₂O emission data. It was then used to evaluate the N₂O abatement potential of a low-emission system designed to halve greenhouse gas emissions in comparison with a system with high productivity and environmental performance. We found a 29 % N₂O abatement potential for the low-emission system compared with the high-productivity system. Among N₂O abatement options, reduction in mineral fertiliser inputs was the most effective.     

Integrierte Treibhausgasbewertung der Prozessketten von Erdgas und industriellem Biomethan in Deutschland

Background The use of natural gas has increased in the last years. In the future, its import supply and transport structure will diversify (longer distances, higher share of LNG (liquefied natural gas), new pipelines). Thus the process chain and GHG emissions of the production, processing, transport and distribution might change. Simultaneously, the injection of bio methane into the natural gas grid is becoming more important. Although its combustion is regarded as climate neutral, during the production processes of bio methane GHG emissions are caused. The GHG emissions occurring during the process chain of energy fuels are relevant for the discussion on climate policy and decision making processes. They are becoming even more important, considering the new Fuel Quality Directive of the EU (Dec. 2008), which aims at controlling emissions of the fuel process chains. Aim In the context of the aspects outlined above the aim is to determine the future development of gas supply for Germany and the resulting changes in GHG emissions of the whole process chain of natural gas and bio methane. With the help of two gas consumption scenarios and an LCA of bio methane, the amount of future emissions and emission paths until 2030 can be assessed and used to guide decision processes in energy policy. Results and discussion The process chain of bio methane and its future technical development are outlined and the related emissions calculated. The analysis is based on an accompanying research study on the injection of bio methane to the German gas grid. Two types of biogas plants have been considered whereof the “optimised technology” is assumed to dominate the future market. This is the one which widely exploits the potential of process optimisation of the current “state of the art” plant. The specific GHG emissions of the process chain can thus be nearly halved from currently 27.8?t CO₂-eq./TJ to 14.8?t CO₂-eq./TJ in 2030. GHG emissions of the natural gas process chain have been analysed in detail in a previous article. Significant modifications and a decrease of specific emissions is possible, depending on the level of investment in the modernisation of the gas infrastructure and the process improvements. These mitigation options might neutralise the emission increase resulting from longer distances and energy intensive processes. In the last section two scenarios (low and high consumption) illustrate the possible development of the German gas supply until 2030, given an overall share of 8–12?% of bio methane. Considering the dynamic emission factors calculated in the former sections, the overall gas emissions and average specific emissions of German gas supply can be given. The current emissions of 215.4 million t CO₂-eq. are reduced by 25?% in the low-consumption scenario (162 million t CO₂-eq.), where consumption is reduced by 17?%. Assuming a consumption which is increased by 17?% in 2030, emissions are around 7?% higher (230.9 million t CO₂-eq.) than today. Conclusions Gaseous fuels will still play a significant role for the German energy supply in the next two decades. The GHG emissions mainly depend on the amount of gas used. Thus, energy efficiency will be a key issue in the climate and energy related policy discussion. A higher share of bio methane and high investments in mitigation and best available technologies can significantly reduce the emissions of the process chain. The combustion of bio methane is climate neutral compared to 56?t CO₂/TJ caused by the direct combustion of natural gas (or 111?t CO₂/TJ emitted by lignite). The advantage of gaseous energy carriers with the lowest levels of GHG emissions compared to other fossil fuels still remains. This holds true for fossil natural gas alone as well as for the expected future blend with bio-methane.     

Efficient air pollution abatement for regions in China

This paper computes the efficient air pollution abatement ratios of 30 regions in China during the period 1996–2002. Three air emissions (SO₂, soot and dust) are considered. Data envelopment analysis (DEA) with a single output (real GDP) and five inputs (labour, real capital stock, SO₂, dust and soot emissions) is used to compute the target emissions of each region for each year. The efficient abatement ratios of each region in each year are then obtained by dividing the target emission by the actual emission of an air pollutant. Our major findings are: 1. The eastern area is the most efficient region with respect to SO₂, soot and dust emissions in every year during the research period. 2. The eastern, central and western areas have the lowest, medium and highest 1996–2002 average target abatement ratios of SO₂ (22.09%, 42.23% and 57.58%), soot (26.19%, 56.34% and 66.37%) and dust (15.20%, 29.09% and 40.59%), respectively. 3. These results are consistent with the Environmental Kuznets Curve (EKC) theory, whereby a more developed area will use environmental goods more efficiently than a less developed area. 4. Compared to dust emission, the average target abatement ratios for SO₂ and soot emissions (as direct outcomes of burning coal) are relatively much higher for all three areas.     

Technological influences and abatement strategies for industrial sulphur dioxide in China

Industrial SO₂ is the most important air pollutant in China. This paper outlines the technological impacts on industrial SO₂ emissions in China in terms of: amount, intensity, structure of energy consumption and structure of energy-intensive industries. It shows that industrial SO₂ emissions have linear growth alongside increases in energy consumption, particularly the rise in coal consumption. The contribution of technological factors to decreases in the intensity of energy consumption is 25%, while the structural factor is 75%. The power industry accounts for 52.6% of total industrial SO₂. Optimisation of the structure of energy consumption can reduce SO₂ emissions by 1.98 million tonnes per year. We propose the following technological strategies for industrial SO₂ abatement: adjustment of the system and structure of thermal power generating units, acceleration of flue gas desulphurisation projects, transformation of industrial structures, development of eco-industries and a reduction in energy consumption per unit product. In addition, an effective way to abate industrial SO₂ emissions is to promote governance strategies to stricly enforce SO₂ emission standards, conduct emission trading, and formulate incentives for encouraging cleaner production and clean energy development.     

Effect of biochar addition on short-term N<Subscript>2</Subscript>O and CO<Subscript>2</Subscript> emissions during repeated drying and wetting of an anthropogenic alluvial soil

Agricultural soils are an important source of greenhouse gases (GHG). Biochar application to such soils has the potential of mitigating global anthropogenic GHG emissions. Under irrigation, the topsoils in arid regions experience repeated drying and wetting during the crop growing season. Biochar incorporation into these soils would change the soil microbial environment and hence affect GHG emissions. Little information, however, is available regarding the effect of biochar addition on carbon dioxide (CO₂) and nitrous oxide (N₂O) emissions from agricultural soils undergoing repeated drying and wetting. Here, we report the results of a 49-day aerobic incubation experiment, incorporating biochar into an anthropogenic alluvial soil in an arid region of Xinjiang Province, China, and measuring CO₂ and N₂O emissions. Under both drying–wetting and constantly moist conditions, biochar amendment significantly increased cumulative CO₂ emission. At the same time, there was a significant reduction (up to ~20 %) in cumulative N₂O emission, indicating that the addition of biochar to irrigated agricultural soils may effectively slow down global warming in arid regions of China.     

The dynamic causal links between CO2 emissions from transport,real GDP,energy use and international tourism

This study examines the dynamic causality relationship between international tourism and carbon dioxide (CO₂) emissions from transport, real gross domestic product and energy use. The vector error correction model and Granger causality test approach have been used to investigate these relationships for the top ten international tourism destinations spanning the period 1995–2013. Results reveal a unidirectional causality running from CO₂ emissions to economic growth without feedback; a bidirectional causality between economic growth and energy use; a bidirectional causality between international tourism and economic growth; and a bidirectional causality between international tourism and energy use. They also suggest that energy use and international tourism both contribute to the decrease of emissions level coming from transport sector, while economic growth leads to the increase of CO₂ emissions. This study can be used in policy recommendations by encouraging countries to use clean energy and to stimulate tourism sector for combating global warming.     

Embodied energy and emergy evaluation of a typical biodiesel production chain in China

Biodiesel from non-grain feedstock has been considered as one of the proper substitutes for fossil fuels associated with a series of activities emerging in China in order to meet the resource shortage and develop the energy crops. This paper presents an ecological accounting framework based on embodied energy, emergy, and CO₂ emission for the whole production chain of biodiesel made from Jatropha curcas L. (JCL) oil. The energy and materials invested in and CO₂ emission from the whole process, including cropping, transportation, extraction, and production, are accounted and calculated. Also, E_mCO₂, the ratio of real CO₂ released to the emergy-based sustainability indicator per joule biodiesel, is proposed in this paper to present a new goal function for low-carbon system optimization. Finally, the results are compared with those of the bioethanol (wheat) production in Henan Province, China, and bioethanol (corn) production in Italy in view of the indices of embodied energy, emergy and CO₂ emissions and E_mCO₂.     

Modeling a sustainable Saudi Arabian economy: the real issues

This paper develops a macroeconomic framework for creating a competitive and sustainable Saudi Arabian economy, taking into account the interrelationships among social, environmental, and economic factors. The objective of the research is to build a model that will allow for evaluating the effects of a wide range of emissions abatement policies on economic growth and development. The research methodology is grounded in econometric modeling of the Saudi economy over the period 1980–2010. The estimated parameters of the model were used to project long-term gross domestic product (GDP) growth paths based on three environmental degradation abatement scenarios. The results suggest that the sustainability of economic growth in Saudi Arabia critically depends on aggressive emissions-reduction policies since policy scenarios corresponding to higher pollution cuts yielded higher, sustained long-term GDP. The results also broadly reject the Environmental Kuznets Curve (EKC) hypothesis, implying that a turning point in the relationship between CO₂ emissions and per capita GDP is yet to be attained.     

Ökologische Optimierungspotenziale der energetischen Nutzung von Palmöl

Aim and Background The use of palm oil for bioenergy has become increasingly important for Europe in the last years because of its favourable proportion of yield to area under cultivation. Thus, palm oil presents a low-priced alternative to other energy sources, e.?g. rapeseed oil. Currently, however, palm oil gets a bad press due to new studies about the negative environmental consequences of cultivation practices. Due to the high demand for palm oil, land is becoming scarce. This results in the clearing of primary forests and consequently in the loss of biodiversity and in an increase of greenhouse gas emissions. To reduce the latter, not only the process of oil palm cultivation has to be optimised but also the practice of establishing new plantations by clearing natural forests has to be questioned. The aim of this article is to disclose potentials for greenhouse gas reductions in existing as well as in newly-planned oil palm plantations. Results and Discussion For existing oil palm plantations, two main fields for possible optimisation can be identified: one is improving the plantation management, the other is increasing the efficiency of the utilisation of waste products such as fibres and husks or oil mill effluents. For newly-planned oil palm plantations alternative land use scenarios have to be considered. The results show a big potential for optimisation. Thus, the greenhouse gas balance improves slightly if plantations are run more efficiently. If the waste products are used to generate energy, there are significantly positive effects on the greenhouse gas balance, especially through the reduction of methane emissions. By running a plantation in a professional best-practice way, 4.8 t of greenhouse gases can be saved annually per hectare cultivation area, expressed as CO₂ equivalents. If newly-planned oil palm plantations are established on fallow land, greenhouse gas emissions can be further reduced by an additional 4.8 t of CO₂ equivalents per hectare and year. From an economic perspective, this may be more costly than clearing primary forest but it is advantageous for both the greenhouse gas balance and the biodiversity of the concerned areas. All in all, exploiting the whole potential for optimisation could result in the saving of 10.2 t CO₂ equivalents per hectare and year more than it is the case in the existing mode of cultivation. Conclusions and Perspectives Due to the high demand of palm oil by the world market, cultivation areas for oil palms are becoming increasingly scarce. Thus, it is vital to exploit the full potential of oil palm cultivation in an environmentally and economically sustainable way. The management of plantations has to be optimised and a generally valid waste management system must be implemented in existing and future plantations. New plantations should preferably be established on fallow land, not by the clearing of primary forests. It is essential for a sustainable palm oil production to tap the full potential for optimisation. This, however, is currently not happening due to the high start-up investments. It is thus recommended to introduce an internationally valid certification system which may provide an incentive for more sustainable and effective production methods.     

Ancillary benefits of reduced air pollution in the US from moderate greenhouse gas mitigation policies in the electricity sector

Actions to slow atmospheric accumulation of greenhouse gases also would reduce conventional air pollutants yielding “ancillary” benefits that tend to accrue locally and in the near-term. Using a detailed electricity model linked to an integrated assessment framework to value changes in human health, we find a tax of $25 per metric ton of carbon emissions would yield NO_x-related health benefits of about $8 per metric ton of carbon reduced in the year 2010 (1997 dollars). Additional savings of $4–$7 accrue from reduced investment in NO_x and SO₂ abatement in order to comply with emission caps. Total ancillary benefits of a $25 carbon tax are $12–$14, which appear to justify the costs of a $25 tax, although marginal benefits are less than marginal costs. At a tax of $75, greater total benefits are achieved but the value per ton of carbon reductions remains roughly constant at about $12.     

Economic and environmental performance of electricity production in Finland: A multicriteria assessment framework

Meeting environmental, economic, and societal targets in energy policy is complex and requires a multicriteria assessment framework capable of exploring trade-offs among alternative energy options. In this study, we integrated economic analysis and biophysical accounting methods to investigate the performance of electricity production in Finland at plant and national level. Economic and environmental costs of electricity generation technologies were assessed by evaluating economic features (direct monetary production cost), direct and indirect use of fossil fuels (GER cost), environmental impact (CO₂ emissions), and global environmental support (emergy cost). Three scenarios for Finland's energy future in 2025 and 2050 were also drawn and compared with the reference year 2008. Accounting for an emission permit of 25 €/t CO₂, the production costs calculated for CHP, gas, coal, and peat power plants resulted in 42, 67, 68, and 74 €/MWh, respectively. For wind and nuclear power a production cost of 63 and 35 €/MWh were calculated. The sensitivity analysis confirmed wind power's competitiveness when the price of emission permits overcomes 20 €/t CO₂. Hydro, wind, and nuclear power were characterized by a minor dependence on fossil fuels, showing a GER cost of 0.04, 0.13, and 0.26 J/J_e, and a value of direct and indirect CO₂ emissions of 0.01, 0.04, and 0.07 t CO₂/MWh. Instead, peat, coal, gas, and CHP plants showed a GER cost of 4.18, 4.00, 2.78, and 2.33 J/J_e. At national level, a major economic and environmental load was given by CHP and nuclear power while hydro power showed a minor load in spite of its large production. The scenario analysis raised technological and environmental concerns due to the massive increase of nuclear power and wood biomass exploitation. In conclusion, we addressed the need to further develop an energy policy for Finland's energy future based on a diversified energy mix oriented to the sustainable exploitation of local, renewable, and environmentally friendly energy sources.     

Bewertung der Umwelteffizienz moderner Autoantriebe – auf dem Weg vom Diesel-Pkw-Boom zu Elektroautos

Motorized traffic is among the biggest CO₂-emitting sources and is additionally dominating NO_x emission. Engine technology shifts are approaching, while automobiles developed in Germany and Europe are exported worldwide together with the European emission thresholds for cars. The Diesel car boom induced by EU commission, national EU governments and car industry is accordingly analyzed for sustainability and its effects on environment. German CO₂ emission reduction numbers by motorized traffic, as claimed by the government, are questioned. Radiative forcing by soot (black carbon) Diesel car emissions is added on the CO₂ emissions by fuel combustion. Diesel cars without particle filters are found to cause an atmospheric warming. Modelled and measured NO_x emission data are assessed to mismatch considerably. In spite of an ambitious national NO_x reduction plan there is excess NO_x emission by the German and European Diesel car boom. In this context environmental sustainability of battery electric vehicles (BEV) is investigated. Direct (by car) und indirect (by power plant) emissions (CO₂, NO_x, PM₁₀, SO₂) of cars with internal combustion engines (ICE) and BEVs, respectively, are calculated and compared. CO₂-ecoanalysis revealed advantages for BEVs even operated with current German electricity mix based on around 15?% renewable sources.     

Decomposition analysis of energy-related carbon dioxide emissions in the iron and steel industry in China

This work aims to identify the main factors influencing the energy-related carbon dioxide (CO₂) emissions from the iron and steel industry in China during the period of 1995–2007. The logarithmic mean divisia index (LMDI) technique was applied with period-wise analysis and time-series analysis. Changes in energyrelated CO₂ emissions were decomposed into four factors: emission factor effect, energy structure effect, energy consumption effect, and the steel production effect. The results show that steel production is the major factor responsible for the rise in CO₂ emissions during the sampling period; on the other hand the energy consumption is the largest contributor to the decrease in CO₂ emissions. To a lesser extent, the emission factor and energy structure effects have both negative and positive contributions to CO₂ emissions, respectively. Policy implications are provided regarding the reduction of CO₂ emissions from the iron and steel industry in China, such as controlling the overgrowth of steel production, improving energy-saving technologies, and introducing low-carbon energy sources into the iron and steel industry.     

High CO<Subscript>2</Subscript> adsorption by amino-modified bio-spherical cellulose nanofibres aerogels

Climate change has become increasingly serious due to the greenhouse effect. It is therefore necessary to control the content of greenhouse gases such as carbon dioxide in the atmosphere, using, for instance, CO₂-adsorbing materials. Here, we synthesized ultra-lightweight and spherical cellulose nanofibres aerogels by a suspension titration method using an efficient amination process. These functional materials with high porosity, higher than 96.54%, and three-dimensional network structure, were prepared by freeze-drying spherical cellulose nanofibres hydrogel. Their maximum CO₂ adsorption capacity reaches 1.78 mmol/g, and they show excellent regeneration, of more than 10 cycles. This synthesis of bioaerogels represents a new method for the preparation of bio-CO₂ adsorbents.     

Greenhouse effect of clusterization of CO2 and CH4 with atmospheric moisture

Carbon dioxide and methane are major compounds involved in global warming. The process of CO₂ and CH₄ molecules absorption by water clusters was investigated by the molecular dynamics method. The frequency spectra of dielectric permittivity for systems consisting of (H₂O) _n , (CO₂) _i (H₂O)₁₀ and (CH₄) _i (H₂O)₁₀ clusters mixed in various proportions were determined. The IR radiation absorption spectra of these systems were calculated and compared. Also, the radiating power of these systems was established. The capture of greenhouse gases’ molecules by ultra disperse water media reduces the ability of the media to absorb the Earth’s radiation, i.e., it reduces the greenhouse effect.     

Efficient adsorption of carbon dioxide and methane on activated carbon prepared from glycerol with potassium acetate

In the context of global warming and the energy crisis, emissions to the atmosphere of greenhouse gases such as carbon dioxide (CO₂) and methane (CH₄) should be reduced, and biomethane from landfill biogas should be recycled. For this, there is a need for affordable technologies to capture carbon dioxide, such as adsorption of biogas on activated carbon produced from industrial wastes. Here we converted glycerol, a largely available by-product from biodiesel production, into activated carbon with the first use of potassium acetate as an activating agent. We studied adsorption of CO₂ and CH₄ on activated carbon. The results show that activated carbon adsorb CO₂ up to 20% activated carbon weight at 250 kPa, and 9% at atmospheric pressure. This is explained by high specific surface areas up to 1115 m²g⁻¹. Moreover, selectivity values up to 10.6 are observed for the separation of CO₂/CH₄. We also found that the equivalent CO₂ emissions from activated carbon synthesis are easily neutralized by their use, even in a small biogas production unit.