Vegetation succession and impacts of biointrusion on covers used to limit acid mine drainage

A cover with capillary barrier effects (CCBE) was constructed in 1998 on the abandoned Lorraine mine tailings impoundment to limit the generation of acid mine drainage. The Ministry of Natural Resources and Fauna of Quebec (MRNF) is responsible for the site and for all restoration works on it, including CCBE construction. The CCBE is made up of three layers: a 0.3-m layer of sand used as a support and capillary break layer; a moisture-retaining layer with a thickness of 0.5 m (this layer is constructed of a nonplastic silt); and a 0.3-m sand and gravel layer on top. The main objective of the CCBE is to maintain one (or more) of the layers at a high degree of water saturation to impede oxygen migration and acid generation. Vegetation succession on the Lorraine CCBE results in an improvement in soil conditions, leading to the installation of deep-rooted species, which could represent a risk to CCBE long-term performance. Hence, the characterization of vegetation succession is an important aspect of the monitoring strategy for the Lorraine CCBE. Species occurrence was documented, and depth of tree roots was measured by excavation on a regular basis. Eight functional groups of plants were identified; herbaceous plants were the most abundant ecological plant groups. Tree ring counts confirmed that tree colonization started the year of CCBE construction (1999). Of the 11 tree species identified, the most abundant were poplar (Populus spp.), paper birch (Betula payrifera Marsh.), black spruce (Picea mariana Mill.), and willow (Salix spp.). Significant differences in occurrence related to environmental conditions were observed for most functional groups. Root excavation showed that tree roots exceeded the depth of the protective layer and started to reach the moisture-retaining layer; in 2008, root average depth was 0.4 m and the maximal root depth was 1.7 m.     

EVAPOTRANSPIRATION CONCEPTUALIZATION IN THE HSPF‐MODFLOW INTEGRATED MODELS1

In 1988, the Florida Institute of Phosphate Research (FIPR) funded project to develop an advanced hydrologic model for shallow water table systems. The FIPR hydrologic model (FHM) was developed to provide an improved predictive capability of the interactions of surface water and ground water using its component models, HSPF and MODFLOW. The Integrated Surface and Ground Water (ISGW) model was developed from an early version of FHM and the two models were developed relatively independently in the late 1990s. Hydrologic processes including precipitation, interception, evapotranspiration, runoff, recharge, streamflow, and base flow are explicitly accounted for in both models. Considerable review of FHM and ISGW and their applications occurred through a series of projects. One model evolved, known as the Integrated Hydrological Model IHM. This model more appropriately describes hydrologic processes, including evapotranspiration fluxes within small distributed land‐based discretization. There is a significant departure of many IHM algorithms from FHM and ISGW, especially for soil water and evapotranspiration (ET). In this paper, the ET concepts in FHM, ISGW, and IHM will be presented. The paper also identifies the advantages and data costs of the improved methods. In FHM and IHM, ground water ET algorithms of the MODFLOW ET package replace those of HSPF (ISGW used a different model for ground water ET). However, IHM builds on an improved understanding and characterization of ET partitioning between surface storages, vadose zone storage, and saturated ground water storage. The IHM considers evaporative flux from surface sources, proximity of the water table to land surface, relative moisture condition of the unsaturated zone, thickness of the capillary zone, thickness of the root zone, and relative plant cover density. The improvements provide a smooth transition to satisfy ET demand between the vadose zone and deeper saturated ground water. While the IHM approach provides a more sound representation of the actual soil profile than FHM, and has shown promise at reproducing soil moisture and water table fluctuations as well as field measured ET rates, more rigorous testing is necessary to understand the robustness and/or limitations of this methodology.     

Field water balance of landfill final covers

Landfill covers are critical to waste containment, yet field performance of specific cover designs has not been well documented and seldom been compared in side-by-side testing. A study was conducted to assess the ability of landfill final covers to control percolation into underlying waste. Conventional covers employing resistive barriers as well as alternative covers relying on water-storage principles were monitored in large (10 x 20 m), instrumented drainage lysimeters over a range of climates at 11 field sites in the United States. Surface runoff was a small fraction of the water balance (0-10%, 4% on average) and was nearly insensitive to the cover slope, cover design, or climate. Lateral drainage from internal drainage layers was also a small fraction of the water balance (0-5.0%, 2.0% on average). Average percolation rates for the conventional covers with composite barriers (geomembrane over fine soil) typically were less than 12 mm/yr (1.4% of precipitation) at humid locations and 1.5 mm/yr (0.4% of precipitation) at arid, semiarid, and subhumid locations. Average percolation rates for conventional covers with soil barriers in humid climates were between 52 and 195 mm/yr (6-17% of precipitation), probably due to preferential flow through defects in the soil barrier. Average percolation rates for alternative covers ranged between 33 and 160 mm/yr (6 and 18% of precipitation) in humid climates and generally less than 2.2 mm/yr (0.4% of precipitation) in arid, semiarid, and subhumid climates. One-half (five) of the alternative covers in arid, semiarid, and subhumid climates transmitted less than 0.1 mm of percolation, but two transmitted much more percolation (26.8 and 52 mm) than anticipated during design. The data collected support conclusions from other studies that detailed, site-specific design procedures are very important for successful performance of alternative landfill covers.     

Vegetation Cover and Long-Term Conservation of Radioactive Waste Packages: The Case Study of the CSM Waste Disposal Facility (Manche District,France)

The CSM is the first French waste disposal facility for radioactive waste. Waste material is buried several meters deep and protected by a multi-layer cover, and equipped with a drainage system. On the surface, the plant cover is a grassland vegetation type. A scientific assessment has been carried out by the Géophen laboratory, University of Caen, in order to better characterize the plant cover (ecological groups and associated soils) and to observe its medium and long term evolution. Field assessments made on 10 plots were complemented by laboratory analyses carried out over a period of 1 year. The results indicate scenarios and alternative solutions which could arise, in order to passively ensure the long-term safety of the waste disposal system. Several proposals for a blanket solution are currently being studied and discussed, under the auspices of international research institutions in order to determine the most appropriate materials for the storage conditions. One proposal is an increased thickness of these materials associated with a geotechnical barrier since it is well adapted to the forest plants which are likely to colonize the site. The current experiments that are carried out will allow to select the best option and could provide feedback for other waste disposal facility sites already being operated in France (CSFMA waste disposal facility, Aube district) or in other countries.     

Landscape Hydrogeology and its Influence on Patterns of Groundwater Flux and Nitrate Removal Efficiency in Riparian Buffers

This study uses data from 46 riparian sites to examine the influence of landscape hydrogeology on patterns of groundwater flux and the buffer width required for effective nitrate removal in humid temperate agricultural regions. There is a considerable imbalance in the research focus on different hydrogeologic settings. More than 40% of the buffers are located in landscapes with surficial sand aquifers, whereas few buffers have been studied in glacial till and weathered bedrock landscapes which cover large areas. Annual groundwater fluxes for 29 of these sites ranged from <20 L/m/day for buffers on flat sand plains and uplands with fine‐textured deposits to 50‐1,200 L/m/day for many sites with upland sand aquifers. Despite a similar range of water fluxes, buffers in gently to moderately sloping landscapes with <4 m depths of sand sediments reached a 90% removal efficiency within 30‐60 m while sites with >4 m depths required a 150‐200 m width. The width for 90% efficiency in buffers with loamy sand and sandy loam sediments also increased from 10‐20 m with <4 m sediment depths to 50‐100 m for >4 m depths. Limited data for buffers with fine‐textured sediments suggest that 90% of the nitrate flux was often depleted in a 10‐20 m width. Groundwater flux did not have a significant relationship with nitrate removal percent per meter buffer width because of the variation in efficiency that occurred in buffers with similar fluxes in different hydrogeologic settings.     

Support of sustainable management of nitrogen contamination due to septic systems using numerical modeling methods

Nitrogen contamination is a serious concern to sustainable environmental management, and one important source of nitrogen contaminant is due to wastewater treatment using onsite sewage treatment and disposal systems (OSTDS, a.k.a., septic systems). This paper presents a study in which numerical modeling is used to support sustainable decision-making and management of nitrogen contamination by utilizing a recently developed GIS-based software, VZMOD, a Vadose Zone MODel for simulating nitrogen transformation and transport in vadose zone between drainfield of septic systems and water table. VZMOD is based on a physical model of unsaturated flow and nitrogen transformation and transport, and the model is solved numerically using the finite element methods. This is the major difference between VZMOD and other GIS-based software of nitrogen modeling. Using GIS techniques, VZMOD considers spatial variability of a number of hydrogeologic parameters such as hydraulic conductivity and porosity. A unique feature of VZMOD is that VZMOD addresses spatial variability of water table by using VZMOD together with ArcNLET, an ArcGIS-based software developed to simulate groundwater flow and nitrate load from septic systems to surface water bodies. VZMOD is designed to execute in different modes to be compatible with different levels of data availability in various management projects of nitrogen contamination. This paper presents an application of VZMOD at a neighborhood with hundreds of septic systems and heterogeneous hydraulic conductivity, porosity, and water table depth. The modeling results indicate that using septic systems at the considered neighborhood is unsustainable and more management means are necessary.     

Passive flux meter measurement of water and nutrient flux in saturated porous media: bench-scale laboratory tests

The passive nutrient flux meter (PNFM) is introduced for simultaneous measurement of both water and nutrient flux through saturated porous media. The PNFM comprises a porous sorbent pre-equilibrated with a suite of alcohol tracers, which have different partitioning coefficients. Water flux was estimated based on the loss of loaded resident tracers during deployment, while nutrient flux was quantified based on the nutrient solute mass captured on the sorbent. An anionic resin, Lewatit 6328 A, was used as a permeable sorbent and phosphate (PO4(3-)) was the nutrient studied. The phosphate sorption capacity of the resin was measured in batch equilibration tests as 56 mg PO4(3-) g(-1), which was determined to be adequate capacity to retain PO4(3-) loads intercepted over typical PNFM deployment periods in most natural systems. The PNFM design was validated with bench-scale laboratory tests for a range of 9.8 to 28.3 cm d(-1) Darcy velocities and 6 to 43 h deployment durations. Nutrient and water fluxes measured by the PNFM averaged within 6 and 12% of the applied values, respectively, indicating that the PNFM shows promise as a tool for simultaneous measurement of water and nutrient fluxes.     

Transport and reaction processes affecting the attenuation of landfill gas in cover soils

Methane and trace organic gases produced in landfill waste are partly oxidized in the top 40 cm of landfill cover soils under aerobic conditions. The balance between the oxidation of landfill gases and the ingress of atmospheric oxygen into the soil cover determines the attenuation of emissions of methane, chlorofluorocarbons, and hydrochlorofluorocarbons to the atmosphere. This study was conducted to investigate the effect of oxidation reactions on the overall gas transport regime and to evaluate the contributions of various gas transport processes on methane attenuation in landfill cover soils. For this purpose, a reactive transport model that includes advection and the Dusty Gas Model for simulation of multicomponent gas diffusion was used. The simulations are constrained by data from a series of counter-gradient laboratory experiments. Diffusion typically accounts for over 99% of methane emission to the atmosphere. Oxygen supply into the soil column is driven exclusively by diffusion, whereas advection outward offsets part of the diffusive contribution. In the reaction zone, methane consumption reduces the pressure gradient, further decreasing the significance of advection near the top of the column. Simulations suggest that production of water or accumulation of exopolymeric substances due to microbially mediated methane oxidation can significantly reduce diffusive fluxes. Assuming a constant rate of methane production within a landfill, reduction of the diffusive transport properties, primarily due to exopolymeric substance production, may result in reduced methane attenuation due to limited O(2) -ingress.     

SIMULATION OF REGIONAL GROUND WATER FLOW IN BEDROCK,SOUTHWESTERN NEW YORK-NORTHWESTERN PENNSYLVANIA1

ABSTRACT: This paper presents the results of steady-state three-dimensional computer simulations to determine the hydrogeologic setting of formation water in the hydrocarbon producing formations of southwestern New York and northwestern Pennsylvania. Recharge areas for the regional ground water flow systems in the study area are the Valley Heads Moraine and Allegheny uplands; discharge areas are Lakes Erie and Ontario to the north and the northern margin of the Appalachian basin to the south. Simulated ground water flow in all model layers moves north from the ground water divide on the Valley Heads Moraine towards Lake Erie at a rate from 10^?-⁶ to 10^?-³ ft/day. South of the divide intermediate-scale and local-scale flow systems occur in the upper 4000 feet of the stratigraphic section and the directions of ground water flow diverge towards major rivers and other topographically low areas.     

Investigation of titanium liquid/gas diffusion layers in proton exchange membrane electrolyzer cells

In a proton exchange membrane electrolyzer cell (PEMEC), liquid/gas diffusion layer (LGDL) is expected to transport electrons, heat, and reactants/products to and from the catalyst layer with minimum voltage, current, thermal, interfacial, and fluidic losses. In addition, carbon materials, which are typically used in PEM fuel cells (PEMFCs), are unsuitable in PEMECs due to the high ohmic potential and highly oxidative environment of the oxygen electrode. In this study, a set of titanium gas diffusion layers with different thicknesses and porosities are designed and examined coupled with the development of a robust titanium bipolar plate. It has been found that the performance of electrolyzer improves along with a decrease in thickness or porosity of the anode LGDL of titanium woven meshes. The ohmic resistance of anode LGDL and contact resistance between anode LGDL and the anode catalyst play dominant roles in electrolyzer performance, and better performance can be obtained by reducing ohmic resistance. Thin titanium LGDLs with straight-through pores and optimal pore morphologies are recommended for the future developments of low-cost LGDLs with minimum ohmic/transport losses.     

Nutrient processing capacity of a constructed wetland in western Ireland

In Ireland, constructed wetland systems are increasingly being used to perform tertiary treatment on municipal waste effluent from small towns and villages located in areas whose receiving waters are deemed sensitive. The bedrock formation in the west of Ireland is primarily karst limestone and where the overburden-soil cover is very shallow, such waters are highly sensitive to pollution sources, as little or no natural attenuation and/or treatment will occur. Constructed wetland technology has been seen to offer a relatively low-cost alternative to the more conventional tertiary treatment technologies, particularly when dealing with low population numbers in small rural communities. This paper examines the waste treatment performance, in terms of nutrient (P and N) reduction, of a recently constructed surface-flow wetland system at Williamstown, County Galway, Ireland. Performance evaluation is based on more than two years of water quality and hydrological monitoring data. The N and P mass balances for the wetland indicate that the average percentage reduction over the two-year study period is 51% for total N and 13% for total P. The primary treatment process in the wetland system for suspended solids (between 84 and 90% reduction), biological oxygen demand (BOD) (on average, 49% reduction), N, and P is the physical settlement of the particulates. However, the formation of algal bloom during the growing season reduces the efficiency of the total P removal.     

DEVELOPMENT OF A WATER SUPPLY PROTECTION MODEL IN A GIS1

ABSTRACT: As part of a larger model to identify lands suitable for acquisition, a water supply protection model was developed using the Southwest Florida Water Management District's GIS. Several hydrologic and hydrogeologic data layers were overlaid to develop maps showing ground-water supply suitability, protection areas for surface-water supply, protection areas for major public supply wells, susceptibility to ground-water contamination, and recharge to the Floridan aquifer. These intermediate layers were combined into a final map to prioritize protection areas for water supply.     

UNSATURATED FLOW THROUGH SOLID WASTE LANDFILLS: MODEL AND SENSITIVITY ANALYSIS1

ABSTRACT: The movement of precipitation water infiltrating through the material (refuse) of solid waste landfills is examined via numerical solution of the equations of continuity, and motion (Darcy's Law). The solution of the equations is obtained by a fully implicit, finite-difference scheme. Both unsaturated and saturated surface conditions are considered, making the scheme suitable for real-time simulation of net precipitation and moisture redistribution events. A sensitivity analysis showed that for unsaturated surface conditions the solution is primarily affected by hydraulic conductivity and capillary diffusivity, and is relatively independent of the space and time steps. In addition, the precipitation averaging process is shown to be critical in the correct computation of moisture transport during the time period where the transition from unsaturated to saturated conditions occurs. The model presented herein is suitable for analysis of water movement through landfills, and the design of bottom collection systems.     

Multiple-year water balance of soil covers in a semiarid setting

Surface covers are used to isolate contaminants in hazardous and low-level radioactive sites for time frames ranging from hundreds of years to millennia or more. In the absence of data for such durations, the long-term performance of surface barriers can only be represented with short-term tests or inferred from analogs and modeling. This paper provides evidence of field performance of soil covers for periods up to 17 yr. The results of lysimeter studies from a semiarid site in Washington State show that a cover design known as the Hanford Barrier, which consists of 1.5 m of silt loam above a sand-gravel capillary break, can nearly eliminate drainage. The results were similar if plants were present or not, demonstrating the robustness of the design. Furthermore, reducing the silt loam thickness to 1.0 m (as might occur via erosion), with or without plants, did not lead to drainage. When irrigated to mimic 3x average precipitation conditions, the vegetated Hanford Barrier continued to prevent drainage. Overall, the results showed no loss in performance during the 17 yr of testing. Only when plants were eliminated completely from the 3x precipitation test did drainage occur (rates ranged from 6 to 16 mm yr(-1)). In a separate test, replacing the top 0.2 m of silt loam with dune sand and reducing the plant cover did not lead immediately to the onset of drainage, but soil matric heads within the silt loam noticeably increased. This observation suggests that dune sand migration onto a surface cover has the potential to reduce a cover's ability to minimize deep drainage.     

Nitrogen fluxes through unsaturated zones in five agricultural settings across the United States

The main physical and chemical controls on nitrogen (N) fluxes between the root zone and the water table were determined for agricultural sites in California, Indiana, Maryland, Nebraska, and Washington from 2004 to 2005. Sites included irrigated and nonirrigated fields; soil textures ranging from clay to sand; crops including corn, soybeans, almonds, and pasture; and unsaturated zone thicknesses ranging from 1 to 22 m. Chemical analyses of water from lysimeters and shallow wells indicate that advective transport of nitrate is the dominant process affecting the flux of N below the root zone. Vertical profiles of (i) nitrogen species, (ii) stable isotopes of nitrogen and oxygen, and (iii) oxygen, N, and argon in unsaturated zone air and correlations between N and other agricultural chemicals indicate that reactions do not greatly affect N concentrations between the root zone and the capillary fringe. As a result, physical factors, such as N application rate, water inputs, and evapotranspiration, control the differences in concentrations among the sites. Concentrations of N in shallow lysimeters exhibit seasonal variation, whereas concentrations in lysimeters deeper than a few meters are relatively stable. Based on concentration and recharge estimates, fluxes of N through the deep unsaturated zone range from 7 to 99 kg ha(-1) yr(-1). Vertical fluxes of N in ground water are lower due to spatial and historical changes in N inputs. High N fluxes are associated with coarse sediments and high N application rates.     

Revegetation Strategies for Bauxite Refinery Residue: A Case Study of Alcan Gove in Northern Territory, Australia

Alumina extraction from bauxite ore with strong alkali produces waste bauxite refinery residue consisting of residue sand and red mud. The amount and composition of refinery residue depend on the purity of the bauxite ore and extraction conditions, and differs between refineries. The refinery residue is usually stored in engineered disposal areas that eventually have to be revegetated. This is challenging because of the alkaline and sodic nature of the residue. At Alcan Gove’s bauxite refinery in Gove, Northern Territory, Australia, research into revegetation of bauxite residue has been conducted since the mid-1970s. In this review, we discuss approaches taken by Alcan Gove to achieve revegetation outcomes (soil capping of refinery residue) on wet-slurry disposal areas. Problems encountered in the past include poor drainage and water logging during the wet season, and salt scalding and capillary rise during the dry season. The amount of available water in the soil capping is the most important determinant of vegetation survival in the seasonally dry climate. Vegetation cover was found to prevent deterioration of the soil cover by minimising capillary rise of alkalinity from the refinery residue. The sodicity and alkalinity of the residue in old impoundments has diminished slightly over the 25 years since it was deposited. However, development of a blocky structure in red mud, presumably due to desiccation, allows root penetration, thereby supplying additional water to salt and alkali-tolerant plant species. This has led to the establishment of an ecosystem that approaches a native woodland.     

A Stochastic Modeling Approach to Address Hydrogeologic Uncertainties in Modeling Wellhead Protection Boundaries in Karst Aquifers1

Abstract: Development of any numerical ground‐water model is dependent on hydrogeologic data describing the subsurface. These data are obtained from geologic core analyses, stratigraphic analyses, aquifer performance tests, and geophysical studies. But typically in remote areas, these types of data are very sparse and site‐specific in terms of the aerial extent of the resource to be modeled. Uncertainties exist as to how well the available data from a few locations defines a heterogeneous surficial aquifer such as the Biscayne Aquifer in Miami‐Dade County, Florida. This is particularly the case when an exceptionally conductive horizontal flow zone is detected at one site due to specialized testing that was not historically conducted at the other at sites that provided data for the model. Not adequately accounting for the potential effect of the high flow zone in the aquifer within a ground‐water numerical model, even though the zone may be of very limited thickness, might underpredict the well field protection capture boundaries. Applied Stochastic ground‐water modeling in determining well field protection zones is steadily becoming important in addressing the uncertainty of the hydrogeologic subsurface parameters, specifically in karstic heterogeneous aquifers. This is particularly important in addressing the uncertainty of a 60‐day travel time capture zone in the Northwest Well Field, Miami‐Dade County, where a predominantly high flow zone controls much of the flow in the production wells. A stochastic ground‐water modeling application along with combination of pilot points and regularization technique is presented to further consolidate the uncertainty of the subsurface.     

WATER QUALITY ANALYSIS OF THE HALIFAX RIVER,FLORIDA1

ABSTRACT: An application of the receiving water block of the EPA Storm Water management Model (SWMM) is presented to quantify water quality impacts and evaluated control alternatives for a 208 areawide waste water management plan in Volusia Country, Florida. The water quality impact analyses were conducted for dry-and wet-weather conditions to simulate dissolved oxygen (DO), chlorides, total nitrogen (TN), and total phosphorus (TP) in the Halifax Rivers, Florida, a 40-kilometer-long tidal estuary located on the Atlantic coast of Florida near Daytona Beach. Dry-weather analysis was performed using conventional 7-day, 10-year low flow conditions to determine a set of unit transfer coefficients which estimate the pollutant concentration transferred to any point in the estuary from a constant unit discharge of pollutants at the existing waste water treatment plant outfall locations. Wet-weather analysis was performed by continuous simulation of a typical three-month summer wet season in Florida. Three-month cumulative duration curves of DO, TN and TP concentrations were constructed to estimate the relative value of controlling urban runoff of waste water treatment plant effluent on the Halifax River. The three-month continuous simulation indicated that the greatest change in DO, TN, and TP duration curves is possible by abatement of waste water treatment plant pollution.     

RAPID WATER TABLE RESPONSES TO RAINFALL IN A NORTHERN PEATLAND ECOSYSTEM1

ABSTRACT: Two types of rapid water table responses to rain were observed in a northern Michigan peatland. The first, called the Lisse effect, occurred during rains of high intensity when the infiltrating water acted as a tightly closing lid that forced the water table to rise to the level required to compensate for the pressure increase. The second, called the Wieringermeer effect, was a rapid rise of the water table to the surface due to the conversion of capillary to phreatic water and was always followed by an equally rapid decline after cessation of the rainfall. We simulated these phenomena in the laboratory and estimated the critical parameters that determine their occurrence. The recognition of the importance of the capillary fringe is essential in evaluating the role of wetlands in flood control and in wastewater treatment.