A pilot-plant study for destruction of PCBs in contaminated soils using fluidized bed combustion technology

Destruction of polychlorinated biphenyls (PCBs) in contaminated soils and wastes using circulating fluidized bed combustion (CFBC) technology was studied using a pilot plant and simulated waste material. The results show that the technology is effective and particularly promising for treatment of PCB-containing materials like the toxic sludge from a large contaminated site. Destruction of the toxics in the gas phase appears to be very fast, and over 99.9999% destruction and removal efficiency can be achieved in the temperature range 875-880 degrees C. Heat transfer in the fluidized bed also appears adequate. Toxic residues in treated soil can be reduced to very low levels. Rate-controlling factors of the decontamination process are analyzed, and key issues for determination of the process conditions are discussed.     

Assessment of the greenhouse effect impact of technologies used for energy recovery from municipal waste: A case for England

Waste management activities contribute to global greenhouse gas emissions approximately by 4%. In particular the disposal of waste in landfills generates methane that has high global warming potential. Effective mitigation of greenhouse gas emissions is important and could provide environmental benefits and sustainable development, as well as reduce adverse impacts on public health. The European and UK waste policy force sustainable waste management and especially diversion from landfill, through reduction, reuse, recycling and composting, and recovery of value from waste. Energy from waste is a waste management option that could provide diversion from landfill and at the same time save a significant amount of greenhouse gas emissions, since it recovers energy from waste which usually replaces an equivalent amount of energy generated from fossil fuels. Energy from waste is a wide definition and includes technologies such as incineration of waste with energy recovery, or combustion of waste-derived fuels for energy production or advanced thermal treatment of waste with technologies such as gasification and pyrolysis, with energy recovery. The present study assessed the greenhouse gas emission impacts of three technologies that could be used for the treatment of Municipal Solid Waste in order to recover energy from it. These technologies are Mass Burn Incineration with energy recovery, Mechanical Biological Treatment via bio-drying and Mechanical Heat Treatment, which is a relatively new and uninvestigated method, compared to the other two. Mechanical Biological Treatment and Mechanical Heat Treatment can turn Municipal Solid Waste into Solid Recovered Fuel that could be combusted for energy production or replace other fuels in various industrial processes. The analysis showed that performance of these two technologies depends strongly on the final use of the produced fuel and they could produce GHG emissions savings only when there is end market for the fuel. On the other hand Mass Burn Incineration generates greenhouse gas emission savings when it recovers electricity and heat. Moreover the study found that the expected increase on the amount of Municipal Solid Waste treated for energy recovery in England by 2020 could save greenhouse gas emission, if certain Energy from Waste technologies would be applied, under certain conditions.     

Estimation of annual CH4 and N2O emissions from fluidised bed combustion: An advanced measurement-based method and its application to Finland

The aim of this study was to develop and apply an advanced, measurement based method for the estimation of annual CH₄ and N₂O emissions and thus gain improved understanding on the actual greenhouse gas (GHG) balances of combustion of fossil fuels, peat, biofuels and REF. CH₄ and N₂O emissions depend strongly on combustion conditions, and therefore the emission factors used in the calculation of annual emissions contain significant uncertainties. Fluidised bed combustion (FBC) has many good properties for combustion of different types of fuels and fuels of varying quality, e.g., biofuels and wastes. Therefore, it is currently increasing its market share. In this study, long term measurements (up to 50 days) were carried out at seven FBC boilers representing different size classes, loadings and fuel mixes. Both decreasing load and increasing share of coal in fuel mix increased N₂O emissions. Measurement results from different loading levels were combined with the common loading curves of similar plants in Finland to estimate annual emissions. Based on the results, recommendations for emission factors for the Finnish GHG emission inventory are given. The role of FBC as a potential technology for the utilisation of biofuels and wastes with future GHG reduction requirements is discussed.     

油田注汽锅炉烟气余热利用与低碳减排

通过对注汽锅炉烟气余热利用潜力的分析及开展余热利用方式对比分析,采用在注汽锅炉对流段上安装热管换热器,使高温烟气与助燃空气换热,利用换热器回收烟气余热。该技术的现场应用,实现了注汽锅炉燃料单耗降低和污染物排放量降低的目的,取得了良好的节能、减排效果。     

Environmental assessment of different management options for individual waste fractions by means of life-cycle assessment modelling

Several alternatives exist for handling of individual waste fractions, including recycling, incineration and landfilling. From an environmental point of view, the latter is commonly considered as the least desirable option. Many studies based on life-cycle assessment (LCA) highlight the environmental benefits offered by incineration and especially by recycling. However, the landfilling option is often approached unjustly in these studies, maybe disregarding the remarkable technological improvements that landfills have undergone in the last decades in many parts of the world.This study, by means of LCA-modelling, aims at comparing the environmental performance of three major management options (landfilling, recycling and incineration or composting) for a number of individual waste fractions. The landfilling option is here approached comprehensively, accounting for all technical and environmental factors involved, including energy generation from landfill gas and storage of biogenic carbon. Leachate and gas emissions associated to each individual waste fraction have been estimated by means of a mathematical modelling. This approach towards landfilling emissions allows for a more precise quantification of the landfill impacts when comparing management options for selected waste fractions.Results from the life-cycle impact assessment (LCIA) show that the environmental performance estimated for landfilling with energy recovery of the fractions “organics” and “recyclable paper” is comparable with composting (for “organics”) and incineration (for “recyclable paper”). This however requires high degree of control over gas and leachate emissions, high gas collection efficiency and extensive gas utilization at the landfill. For the other waste fractions, recycling and incineration are favourable, although specific emissions of a variety of toxic compounds (VOCs, PAHs, NO_x, heavy metals, etc.) may significantly worsen their environmental performance.     

Management of old landfills by utilizing forest and energy industry waste flows

The lack of landfill capacity, forthcoming EU waste disposal and landfill management legislation and the use of non-renewable and energy intensive natural resources for the end-treatment of old landfills increase pressures to develop new landfill management methods. This paper considers a method for the end-management of old landfills in Finland, which is based on the utilization of forest and paper industry waste flows, wastes from paper recycling (de-inking) and wastes from forest industry energy production. Fibre clay wastes from paper mills, de-inking sludges from de-inking of recovered waste paper and incineration ash from forest industry power plants serve to substitute the use of natural clay for the building of landfill structures for closed landfills. Arguably, this method is preferable to existing practices of natural clay use for landfill building, because it (1) substitutes non-renewable natural clay, (2) consumes less energy and generates less CO2 emissions than the use of natural clay, and (3) eliminates considerable amounts of wastes from paper production, paper consumption and from forest industry energy production. Some difficulties in the application of the method are considered and the waste flow utilization is incorporated into a local forest industry recycling network.     

Refrigeration waste heat utilization for drying applications: a review

ABSTRACT

Cold chain industry has a vast potential for waste heat recovery. It is a matter of importance for energy efficiency point of view, as global energy demand is increasing day by day. Ample amount of low-grade energy is either unutilized or underutilized. The heat rejected by a Heat pump or refrigeration system emerged as a promising solution for dehydration by utilizing low-grade waste heat despite higher investment. As compared to solar drying technology, heat pump drying evolved as a reliable method regarding better process control, energy efficiency, and quality of the product to be dried. Energy utilized through the refrigeration system’s waste/exhaust heat recovery in combination with or without renewable energy source enhances the overall efficiency of the system and also reduces the cost. This useful review investigated and compared the research findings of waste heat utilization through heat pump and from condenser of refrigeration system on laboratory, pilot as well as industrial scale for drying of various fruits, vegetables, and agro products. Various drying parameters like drying rate, moisture content, Specific Moisture Extraction Rate (SMER), Coefficient of Performance (COP), Exergy efficiency, and temperature as well as humidity conditions inside the drying chamber were also reviewed to promote the technological advancement of energy utilization by commercial cold storage waste heat recovery.     

Resource consumption of pharmaceutical waste solvent valorization alternatives

In this article, for the treatment of two specific pharmaceutical waste solvents the resource consumption of an on-site distillation process is evaluated and compared with an off-site incineration process. Both techniques are evaluated based on a thermodynamic quantitative method. The exergy approach and the cumulative exergy extracted from the natural environment (CEENE) are envisaged in order to evaluate the overall resource intake at different levels. Scenarios are constructed to make a fair comparison of both techniques. Two waste solvents, toluene (TOL) and dichloromethane (DCM), from the pharmaceutical industry which are frequently sent to distillation were evaluated. The functional unit for the comparison of both treatment alternatives is the treatment of 1 kg waste solvent + the incineration of W kg low calorific hazardous waste + the delivery of X kg “recovered” solvent + the production of Y MJ heat and Z MJ electricity. W, X, Y and Z depend on the waste solvent properties. In terms of resource requirements, distillation requires 17% (TOL) and 66% (DCM) less resources than incineration. It can be concluded that the waste solvent properties, the efficiency of the distillation process and the efficiency of the fresh solvent production process are of major importance on the resource consumption and the final choice between incineration and distillation. For a full environmental impact analysis of both treatment options, also the emissions should be taken into account. It also has to be stressed that in practice, only solvents go to incineration which cannot be distilled due to the type and degree of pollution/composition of the solvent. If distillation is not feasible, then such solvents are sent to incineration with energy recovery, according to the EU directive 2006/12/EG.     

Effects of planned expansion of waste incineration in the Swedish district heating systems

Recent targets for reduced amounts of waste to landfills in Sweden will result in a large increase in waste incineration with recovery of energy, used primarily for district heating. The aim of this study is to investigate what changes in the usage of other fuels and technologies for district heat production would be caused by this increase. A questionnaire was sent out to the largest district heating companies, and simulations in an energy systems model were carried out. The analysis shows that increased waste incineration reduces the demand for other fuels, especially biomass, for district heat production. The effects include reductions in operating hours as well as the avoidance or postponement of investments in new plants for district heat production. Increased waste incineration will also lead to a greater use of district heating in Sweden.     

Characterization of aromatic hydrocarbon formation from pyrolysis of polyethylene-polystyrene mixtures

Design and operating parameters, and cause and effect relationships among feedstocks and products in the pyrolysis of waste polymers are needed if this method of processing is to be used for energy recovery from waste plastics. The purpose of this study was to quantify the effect of various operating factors for the pyrolysis of common polymeric wastes. Experiments were performed using a conventional retort tube as a batch reactor. The operating factors considered were temperature and reaction time at constant heating rate. High density polyethylene (PE) and polystyrene (PS), the most common plastic waste in Korea, were used singly and in mixture.The pyrolysis time for maximum oil production from a PE-PS mixture was shorter than in the case of PE alone, showing an enhancement effect from the PS. The maximum gas production time from PE-PS mixtures was shorter than for PE alone at 500° C; above 600° C, this does not occur. Small aromatic compounds (which can be valuable) are produced at maximum with an 1:1 mixture of PE and PS at 600° C, showing the possibility of process control for the maximum recovery of desirable pyrolysis products. The maximum yield of toluene, xylene, styrene, and 1-propenyl benzene were 8.6, 8.9, 51.0 and 7.4 wt.% of feed for pyrolysis PS at 700° C, respectively. For naphthalene, it was at 700° C with 1:1 PE:PS (by wt.). The maximum recovery was 1.3 wt.%. Diels-Alder theory can explain the formation of aromatic compounds in the pyrolysis products. The yield of these secondary pyrolysis products can be controlled by reaction time, pyrolysis temperature and mixing ratio of plastic wastes in the pyrolysis feed.     

Environmental and economic analysis of management systems for biodegradable waste

The management system for solid and liquid organic waste affects the environment and surrounding technical systems in several ways. In order to decrease the environmental impact and resource use, biological waste treatment and alternative solutions for sewage treatment are often advocated. These alternatives include increased agricultural use of waste residuals. To analyse whether such proposed systems indicate improvements for the environment and its sustainability, systems analysis is a useful method. The changes in environmental impact and resource use is not only a result of changes in waste treatment methods, but also largely a result of changes in surrounding systems (energy and agriculture) caused by changes in waste management practices. In order to perform a systems analysis, a substance-flow simulation model, the organic waste research model (ORWARE), has been used. The results are evaluated by using methodology from life cycle assessment (LCA). An economic analysis was also performed on three of the studied scenarios. The management system for solid organic waste and sewage in the municipality of Uppsala, Sweden, was studied. Three scenarios for different treatments of solid waste were analysed: incineration with heat recovery, composting, and anaerobic digestion. These three scenarios included conventional sewage treatment. A fourth scenario reviewed was anaerobic digestion of solid waste, using urine-separating toilets and separate handling of the urine fraction. The results are only valid for the case study and under the assumptions made. In this case study anaerobic digestion result in the lowest environmental impact of all the solid waste management systems, but is costly. Economically, incineration with heat recovery is the cheapest way to treat solid waste. Composting gives environmental advantages compared to incineration methods, without significantly increased costs. Urine separation, which may be implemented together with any solid waste treatment, has great advantages, particularly in its low impact on the environment. However, there is a large increase in acidification.     

The potential contribution of sustainable waste management to energy use and greenhouse gas emission reduction in the Netherlands

Future limitations on the availability of selected resources stress the need for increased material efficiency. In addition, in a climate-constrained world the impact of resource use on greenhouse gas emissions should be minimized. Waste management is key to achieve sustainable resource management. Ways to use resources more efficiently include prevention of waste, reuse of products and materials, and recycling of materials, while incineration and anaerobic digestion may recover part of the embodied energy of materials. This study used iWaste, a simulation model, to investigate the extent to which savings in energy consumption and CO₂ emissions can be achieved in the Netherlands through recycling of waste streams versus waste incineration, and to assess the extent to which this potential is reflected in the LAP2 (currently initiated policy). Three waste streams (i.e. household waste, bulky household waste, and construction and demolition waste) and three scenarios compare current policy to scenarios that focus on high-quality recycling (Recycling+) or incineration with increased efficiency (Incineration+). The results show that aiming for more and high-quality recycling can result in emission reductions of 2.3 MtCO₂ annually in the Netherlands compared to the reference situation in 2008. The main contributors to this reduction potential are found in optimizing the recycling of plastics (PET, PE and PP), textiles, paper, and organic waste. A scenario assuming a higher energy conversion efficiency of the incinerator treating the residual waste stream, achieves an emission reduction equivalent to only one third (0.7 MtCO₂/year) of the reduction achieved in the Recycling+ scenario. Furthermore, the results of the study show that currently initiated policy only partially realizes the full potential identified. A focus on highest quality use of recovered materials is essential to realize the full potential energy and CO₂ emission reduction identified for the Netherlands. Detailed economic and technical analyses of high quality recycling are recommended to further evaluate viable integrated waste management policies.     

Conversion of leather wastes to useful products

The main objective of the present study is to investigate the production of useful materials from different kinds of leather waste. Three different types of tannery wastes (chromium- and vegetable-tanned shavings, and buffing dust) were pyrolyzed in a fixed bed reactor at temperatures of 450 and 600 °C under N₂ atmosphere. Gas, oil, ammonium carbonate and carboneous residue were obtained by pyrolysis. The effect of temperature and type of leather waste on product distribution of pyrolysis was investigated. Buffing dust gave the highest yield of oil (ca. 23%), while other wastes recorded yields of ca. 9%. Results of elemental analysis and column chromatography showed that pyrolysis oils could be used as fuel or chemical feedstock after re-treatment. The yields of carboneous residue (chars) were between 37.5% and 48.5% and their calorific value was between 4300 and 6000 kcal kg⁻¹, suitable for use as solid fuel. In addition, these chars were activated by CO₂ to obtain the activated carbon. The activated carbon having highest surface area (799.5 m² g⁻¹) was obtained from chromium-tanned shavings. Activated carbons prepared from chromium-tanned leather were presented as an adsorbant for the adsorption of dyes from aqueous solution.     

泰安市医疗废物的特性研究

通过实验分析了医疗废物的组成、灰分、水分、挥发分、固定碳和热值等特性参数,探讨其燃烧特性。研究表明,医疗废物具有高热值、高挥发分的特点,其热值远高于一般城市生活垃圾,而高挥发分的特点决定了其容易着火和稳定燃烧的特性。     

LCA: A decision support tool for environmental assessment of MSW management systems

Life cycle assessment (LCA) can be successfully applied to municipal solid waste (MSW) management systems to identify the overall environmental burdens and to assess the potential environmental impacts. In this study, two methods used for current MSW management in Phuket, a province of Thailand, landfilling (without energy recovery) and incineration (with energy recovery), are compared from both energy consumption and greenhouse gas emission points of view. The comparisons are based on a direct activity consideration and also a life cycle perspective. In both cases as well as for both parameters considered, incineration was found to be superior to landfilling. However, the performance of incineration was much better when a life cycle perspective was used. Also, landfilling reversed to be superior to incineration when methane recovery and electricity production were introduced. This study reveals that a complete picture of the environmental performance of MSW management systems is provided by using a life cycle perspective.     

Environmental and economic impact assessment of construction and demolition waste disposal using system dynamics

Construction and demolition wastes (CDW) have increasingly serious problems in environmental, social, and economic realms. There is no coherent framework for utilization of these wastes which are disposed both legally and illegally. This harms the environment, contributes to the increase of energy consumption, and depletes finite landfills resources. The aim of this paper is to evaluate the impacts of two alternatives for the management of CDW, recycling and disposing. The evaluation is carried out through developing a dynamic model with aid STELLA software by conducting the following steps: (1) quantifying the total cost incurred to mitigate the impacts of CDW landfills and uncollected waste on the environment and human health; (2) quantifying the total avoided emissions and saved energy by recycling waste; (3) estimating total external cost saved by recycling waste and; (4) providing a decision support tool that helps in re-thinking about waste disposal. The proposed evaluation methodology allows activating the stringent regulations that restrict waste disposal and developing incentives to encourage constructors to recycle their wastes. The research findings show that recycling CDW leads to significant reductions in emissions, energy use, global warming potential (GWP), and conserves landfills space when compared to disposal of wastes in landfills. Furthermore, the cost of mitigating the impact of disposal is extremely high. Therefore, it is necessary to recycle construction and demolition wastes.     

钻井废物综合治理技术的应用

针对急需解决的钻井废水、废气治理问题,以钻井作业大功率柴油机废气余热回收利用为出发点,研制了钻井废水废气综合治理设备。通过现场试验对钻井废水、废气治理效果及噪声影响的分析,试验结果表明,日处理钻井废水可达11～13m3/d,柴油机废气中污染物排放有一定程度的降低,柴油机高频噪声得到较明显降低,并有利于增加柴油机扭距。     

Emissions study of co-firing waste carpet in a rotary kiln

Post-consumer carpet represents a high volume, high energy content waste stream. As a fuel for co-firing in cement kilns, waste carpet, like waste tires, has potential advantages. Technological challenges to be addressed include assessing potential emissions, in particular NO emissions (from nylon fiber carpets), and optimizing the carpet feed system. This paper addresses the former. Results of pilot-scale rotary kiln experiments demonstrate the potential for using post-consumer waste carpet as a fuel in cement kilns. Continuous feeding of shredded carpet fiber and ground carpet backing, at rates of up to 30% of total energy input, resulted in combustion without transient puffs and with almost no increase in CO and other products of incomplete combustion as compared to kiln firing natural gas only. NO emissions increased with carpet waste co-firing due to the nitrogen content of nylon fiber. In these experiments with shredded fiber and finely ground backing, carpet nitrogen conversion to NO ranged from 3 to 8%. Conversion increased with enhanced mixing of the carpet material and air during combustion. Carpet preparation and feeding method are controlling factors in fuel N conversion.     

Alternative energy balances for Bulgaria to mitigate climate change

Alternative energy balances aimed to mitigate greenhouse gas (GHG) emissions are developed as alternatives to the baseline energy balance. The section of mitigation options is based on the results of the GHG emission inventory for the 1987–1992 period. The energy sector is the main contributor to the total CO₂ emissions of Bulgaria. Stationary combustion for heat and electricity production as well as direct end-use combustion amounts to 80% of the total emissions. The parts of the energy network that could have the biggest influence on GHG emission reduction are identified. The potential effects of the following mitigation measures are discussed: rehabilitation of the combustion facilities currently in operation; repowering to natural gas; reduction of losses in thermal and electrical transmission and distribution networks; penetration of new combustion technologies; tariff structure improvement; renewable sources for electricity and heat production; wasteheat utilization; and supply of households with natural gas to substitute for electricity in space heating and cooking. The total available and the achievable potentials are estimated and the implementation barriers are discussed.