EFFECTS OF TOPOGRAPHY AND SOIL PROPERTIES ON RECHARGE AT TWO SITES IN AN AGRICULTURAL FIELD1

ABSTRACT: Field experiments were conducted from 1992 to 1995 to estimate ground water recharge rates at two sites located within a 2.7‐hectare agricultural field. The field lies in a sand plain setting in central Minnesota and is cropped continuously in field corn. The sites are located at a topographically high (upland) site and a topographically low (lowland) site in an effort to quantify the effects of depression focusing of recharge. Three site‐specific methods were used to estimate recharge rates: well hydrograph analysis, chlorofluorocarbon age dating, and an unsaturated zone water balance. All three recharge methods indicated that recharge rates at the lowland site (annual average of all methods of 29 cm) exceeded those at the upland site (annual average of 18 cm). On an annual basis, estimates by the individual methods ranged from 12 to 44 percent of precipitation at the upland site and from 21 to 83 percent at the lowland site. The difference in recharge rates between the sites is primarily attributed to depression focusing of surface water runon at the lowland site. However, two other factors were also important: the presence of thin lamellae at the upland site, and coarser textured soils below a depth of 1.5 m at the lowland site.     

Upland Controls on the Hydrological Functioning of Riparian Zones in Glacial Till Valleys of the Midwest1

Abstract: Identifying relationships between landscape hydrogeological setting, riparian hydrological functioning and riparian zone sensitivity to climate and water quality changes is critical in order to best use riparian zones as best management practices in the future. In this study, we investigate water table dynamics, water flow path and the relative importance of precipitation, deep ground water (DG) and seep water as sources of water to a riparian zone in a deeply incised glacial till valley of the Midwest. Data indicate that water table fluctuations are strongly influenced by soil texture and to a lesser extent by upland sediment stratigraphy producing seeps near the slope bottom. The occurrence of till in the upland and at 1.7‐2 m in the riparian zone contributes to maintaining flow parallel to the ground surface at this site. Lateral ground‐water fluxes at this site with a steep topography in the upland (16%) and loam soil near the slope bottom are small (<10 l/d/m stream length) and intermittent. A shift in flow path from a lateral direction to a down valley direction is observed in the summer despite the steep concave topography and the occurrence of seeps at the slope bottom. Principal component and discriminant analysis indicate that riparian water is most similar to seep water throughout the year and that DG originating from imbedded sand and gravel layers in the lower till unit is not a major source of water to riparian zones in this setting. Water quality data and the dependence of the riparian zone for recharge on seep water suggest that sites in this setting may be highly sensitive to changes in precipitation and water quality in the upland in the future. A conceptual framework describing the hydrological functioning of riparian zones on this setting is presented to generalize the finding of this study.     

Artificial recharge of humic ground water

The purpose of this study was to investigate the efficiency of soil in removing natural organic matter from humic ground waters using artificial recharge. The study site, in western Denmark, was a 10,000 ml football field of which 2,000 m2 served as an infiltration field. The impact of the artificial recharge was studied by monitoring the water level and the quality of the underlying shallow aquifer. The humic ground water contained mainly humic adds with an organic carbon (OC) concentration of 100 to 200 mg C L(-1). A total of 5,000 mS of humic ground water were sprinkled onto the infiltration field at an average rate of 4.25 mm h(-1). This resulted in a rise in the water table of the shallow aquifer. The organic matter concentration of the water in the shallow aquifer, however, remained below 2.7 mg C L(-1). The organic matter concentration of the pore water in the unsaturated zone was measured at the end of the experiment. The organic matter concentration of the pore water decreased from 105 mg C L(-1) at 0.5 m to 20 mg C L(-1) at 2.5 m under the infiltration field indicating that the soil removed the organic matter from the humic ground water. From these results we conclude that artificial recharge is a possible method for humic ground water treatment.     

EFFECTS OF ARTIFICIAL RECHARGE ON GROUND WATER QUALITY AND AQUIFER STORAGE RECOVERY1

ABSTRACT: Ground water nitrate contamination and water level decline are common concern in Nebraska. Effects of artificial recharge on ground water quality and aquifer storage recovery (ASR) were studied with spreading basins constructed in the highly agricultural region of the Central Platte, Nebraska. A total of 1.10 million m³ of Platte River water recharged the aquifer through 5000 m² of the recharge basins during 1992, 1993, and 1994. This is equivalent to the quantity needed to completely displace the ground water beneath 34 ha of the local primary aquifer with 13 m thickness and 0.25 porosity. Successful NO₃-N remediation was documented beneath and downgradient of the recharge basins, where NO₃-N declined from 20 to 2 mg L^-1. Ground water atrazine concentrations at the site decreased from 2 to 0.2 mg L^-1 due to recharge. Both NO₃-N and atrazine contamination dramatically improved from concentrations exceeding the maximum contaminant levels to those of drinking water quality. The water table at the site rose rapidly in response to recharge during the early stage then leveled off as infiltration rates declined. At the end of the 1992 recharge season, the water table 12 m downgradient from the basins was elevated 1.36 m above the preproject level; however, at the end of the 1993 recharge season, any increase in the water table from artificial recharge was masked by extremely slow infiltration rates and heavy recharge from precipitation from the wettest growing season in over 100 years. The water table rose 1.37 m during the 1994 recharge season. Resultant ground water quality and ASR improvement from the artificial recharge were measured at 1000 m downgradient and 600 m upgradient from the recharge basins. Constant infiltration rates were not sustained in any of the three years, and rates always decreased with time presumably because of clogging. Scraping the basin floor increased infiltration rates. Using a pulsed recharge to create dry and wet cycles and maintaining low standing water heads in the basins appeared to reduce microbial growth, and therefore enhanced infiltration.     

Field-scale preferential transport of water and chloride tracer by depression-focused recharge

A tracer study was initiated in November 1993 to investigate depression-focused recharge and to monitor solute movement through the vadose zone into the shallow ground water in southeastern North Dakota. Granular potassium chloride (KCl) was surface-applied to two areas overlying subsurface drains and to one area instrumented with soil solution samplers, ground water monitoring wells, time domain reflectometry (TDR) probes, and temperature probes. One of the subsurface drain tracer plots was located on level ground while the other two sites were in small topographic depressions. Formation of ground water mounds beneath the depressions indicated that these areas are recharge sites. The applied Cl- tracer was found to move rapidly to the shallow ground water under the depressional areas after infiltration of spring snowmelt in 1994. Excessive rainfall events were also responsible for focused recharge and the rapid transport of the applied Cl- tracer. Water flow through partially frozen soil at the bottom of the depressions during thaw enhanced preferential movement of the tracer.     

SUBSURFACE RETURN FLOW AND GROUND WATER RECHARGE OF TERRACE FIELDS IN NORTHERN TAIWAN1

ABSTRACT: This study estimates subsurface return flow and effective ground water recharge in terraced fields in northern Taiwan. Specifically, a three dimensional model, FEMWATER, was applied to simulate percolation and lateral seepage in the terraced fields under various conditions. In the terraced paddy fields, percolation mainly moves vertically downward in the central area, while lateral seepage is mainly focused around the bund. Although the simulated lateral seepage rate through the bund exceeded the percolation rate in the central area of the paddy field, annual subsurface return flow at Pei‐Chi and Shin‐Men was 0.17 × 10⁶ m³ and 0.37 × 10⁶ m³, representing only 0.17 percent and 0.21 percent of the total irrigation water required for rice growth at Pei‐Chi and Shin‐Men, respectively. For upland fields, the effective ground water recharge rate during the second crop period (July to November) exceeded that during the first crop period (January to May) because of the wet season in the second crop period. Terraced paddy fields have the most efficient ground water recharge, with 21.2 to 23.4 percent of irrigation water recharging to ground water, whereas upland fields with a plow layer have the least efficient ground water recharge, with only 4.8 to 6.6 percent of irrigation water recharging to ground water. The simulation results clearly revealed that a substantial amount of irrigation water recharges to ground water in the terraced paddy, while only a small amount of subsurface return flow seeps from the upstream to the downstream terraced paddy. The amounts of subsurface flow and ground water recharge determined in the study are useful for the irrigation water planning and management and provide a scientific basis to reevaluate water resources management in the terrace region under irrigated rice.     

MODELING THE FOREST HYDROLOGY OF WETLAND-UPLAND ECOSYSTEMS IN FLORIDA1

ABSTRACT: Few hydrological models are applicable to pine flat-woods which are a mosaic of pine plantations and cypress swamps. Unique features of this system include ephemeral sheet flow, shallow dynamic ground water table, high rainfall and evapotranspiration, and high infiltration rates. A FLATWOODS model has been developed specifically for the cypress wetland-pine upland landscape by integrating a 2-D ground water model, a Variable-Source-Area (VAS)-based surface flow model, an evapotranspiration (ET) model, and an unsaturated water flow model. The FLATWOODS model utilizes a distributed approach by dividing the entire simulation domain into regular cells. It has the capability to continuously simulate the daily values of ground water table depth, ET, and soil moisture content distributions in a watershed. The model has been calibrated and validated with a 15-year runoff and a four-year ground water table data set from two different pine flat woods research watersheds in northern Florida. This model may be used for predicting hydrologic impacts of different forest management practices in the coastal regions.     

Pesticide fate and transport throughout unsaturated zones in five agricultural settings, USA

Pesticide transport through the unsaturated zone is a function of chemical and soil characteristics, application, and water recharge rate. The fate and transport of 82 pesticides and degradates were investigated at five different agricultural sites. Atrazine and metolachlor, as well as several of the degradates of atrazine, metolachlor, acetochlor, and alachlor, were frequently detected in soil water during the 2004 growing season, and degradates were generally more abundant than parent compounds. Metolachlor and atrazine were applied at a Nebraska site the same year as sampling, and focused recharge coupled with the short time since application resulted in their movement in the unsaturated zone 9 m below the surface. At other sites where the herbicides were applied 1 to 2 yr before sampling, only degradates were found in soil water. Transformations of herbicides were evident with depth and during the 4-mo sampling time and reflected the faster degradation of metolachlor oxanilic acid and persistence of metolachor ethanesulfonic acid. The fraction of metolachlor ethanesulfonic acid relative to metolachlor and metolachlor oxanilic acid increased from 0.3 to >0.9 at a site in Maryland where the unsaturated zone was 5 m deep and from 0.3 to 0.5 at the shallowest depth. The flux of pesticide degradates from the deepest sites to the shallow ground water was greatest (3.0-4.9 micromol m(-2) yr(-1)) where upland recharge or focused flow moved the most water through the unsaturated zone. Flux estimates based on estimated recharge rates and measured concentrations were in agreement with fluxes estimated using an unsaturated-zone computer model (LEACHM).     

USE OF SOIL MOISTURE PROBES TO ESTIMATE GROUND WATER RECHARGE AT AN OIL SPILL SITE1

Soil moisture data collected using an automated data logging system were used to estimate ground water recharge at a crude oil spill research site near Bemidji, Minnesota. Three different soil moisture probes were tested in the laboratory as well as the field conditions of limited power supply and extreme weather typical of northern Minnesota: a self‐contained reflectometer probe, and two time domain reflectometry (TDR) probes, 30 and 50 cm long. Recharge was estimated using an unsaturated zone water balance method. Recharge estimates for 1999 using the laboratory calibrations were 13 to 30 percent greater than estimates based on the factory calibrations. Recharge indicated by the self‐contained probes was 170 percent to 210 percent greater than the estimates for the TDR probes regardless of calibration method. Results indicate that the anomalously large recharge estimates for the self‐contained probes are not the result of inaccurate measurements of volumetric moisture content, but result from the presence of crude oil, or borehole leakage. Of the probes tested, the 50 cm long TDR probe yielded recharge estimates that compared most favorably to estimates based on a method utilizing water table fluctuations. Recharge rates for this probe represented 24 to 27 percent of 1999 precipitation. Recharge based on the 30 cm long horizontal TDR probes was 29 to 37 percent of 1999 precipitation. By comparison, recharge based on the water table fluctuation method represented about 29 percent of precipitation.     

A COMPARISON OF MODELS PREDICTING GROUND WATER LEVELS ON HILLSIDE SLOPES1

ABSTRACT: A comparative study of ground water level predictions on hillside slopes using two models is presented. The models are a simplified mass balance model that has components for evapotran-spiration, recharge, and drainage; and a two-dimensional finite difference model that employs kriging to estimate soil parameters and accounts for non-uniform thickness of the soil layer. These models are representative of a wide range of modeling capabilities and are used to illustrate the sensitivity of ground water level predictions to the sophistication of the modeling techniques. The drainage and recharge components of the two models are evaluated and the importance of unsaturated flow in recharge computations is underscored. Piezometric observations in a small drainage depression on the slope of Kennel Creek Valley in Tongass National Forest, Alaska, were used to evaluate the two models. The results show that, although the predictions differ from the field observations, the simple physically-based mass balance model predicts the ground water levels as well as the two-dimensional model. It is suggested that caution should be exercised in using complex models to validate simpler models.     

Effects of Groundwater-Flow Paths On Nitrate Concentrations Across Two Riparian Forest Corridors1

Speiran, Gary K., 2010. Effects of Groundwater-Flow Paths on Nitrate Concentrations Across Two Riparian Forest Corridors. Journal of the American Water Resources Association (JAWRA) 46(2):246-260. DOI: 10.1111/j.1752-1688.2010.00427.x Abstract: Groundwater levels, apparent age, and chemistry from field sites and groundwater-flow modeling of hypothetical aquifers collectively indicate that groundwater-flow paths contribute to differences in nitrate concentrations across riparian corridors. At sites in Virginia (one coastal and one Piedmont), lowland forested wetlands separate upland fields from nearby surface waters (an estuary and a stream). At the coastal site, nitrate concentrations near the water table decreased from more than 10 mg/l beneath fields to 2 mg/l beneath a riparian forest buffer because recharge through the buffer forced water with concentrations greater than 5 mg/l to flow deeper beneath the buffer. Diurnal changes in groundwater levels up to 0.25 meters at the coastal site reflect flow from the water table into unsaturated soil where roots remove water and nitrate dissolved in it. Decreases in aquifer thickness caused by declines in the water table and decreases in horizontal hydraulic gradients from the uplands to the wetlands indicate that more than 95% of the groundwater discharged to the wetlands. Such discharge through organic soil can reduce nitrate concentrations by denitrification. Model simulations are consistent with field results, showing downward flow approaching toe slopes and surface waters to which groundwater discharges. These effects show the importance of buffer placement over use of fixed-width, streamside buffers to control nitrate concentrations.     

SIMULATION OF INTEGRATED SURFACE WATER AND GROUND WATER SYSTEMS - MODEL FORMULATION1

ABSTRACT: The unique characteristics of the hydrogeologic system of south Florida (flat topography, sandy soils, high water table, and highly developed canal system) cause significant interactions between ground water and surface water systems. Interaction processes involve infiltration, evapotranspiration (ET), runoff, and exchange of flow (seepage) between streams and aquifers. These interaction processes cannot be accurately simulated by either a surface water model or a ground water model alone because surface water models generally oversimplify ground water movement and ground water models generally oversimplify surface water movement. Estimates of the many components of flow between surface water and ground water (such as recharge and ET) made by the two types of models are often inconsistent. The inconsistencies are the result of differences in the calibration components and the model structures, and can affect the confidence level of the model application. In order to improve model results, a framework for developing a model which integrates a surface water model and a ground water model is presented. Dade County, Florida, is used as an example in developing the concepts of the integrated model. The conceptual model is based on the need to evaluate water supply management options involving the conjunctive use of surface water and groundwater, as well as the evaluation of the impacts of proposed wellfields. The mathematical structure of the integrated model is based on the South Florida Water Management Model (SFWMM) (MacVicar et al., 1984) and A Modular Three-Dimensional Finite-Difference Groundwater Flow Model (MODFLOW) (McDonald and Harbaugh, 1988).     

STABLE ISOTOPE CHARACTERIZATION OF THE IMPACTS OF ARTIFICIAL GROUND WATER RECHARGE1

ABSTRACT: Stable isotopes of deuterium and oxygen-18 of surface and ground water, together with anion concentrations and hydraulic gradients, were used to interpret mixing and flow in ground water impacted by artificial recharge. The surface water fraction (SWF), the percentage of surface water in the aquifer impacted via recharge, was estimated at different locations and depths using measured deuterium/hydrogen (DIH) ratios during the 1992, 1993, and 1994 recharge seasons. Recharged surface water completely displaced the ground water beneath the recharge basins from the regional water table at 7.60 m to 12.16 m below the land surface. Mixing occurred beneath the recharge structures in the lower portions of the aquifer (>12.16 m). Approximately 12 m down-gradient from the recharge basin, the deeper zone (19.15 m depth) of the primary aquifer was displaced completely by recharged surface water within 193, 45, and 55 days in 1992, 1993, and 1994, respectively. At the end of the third recharge season, recharged surface water represented ～50 percent of the water in the deeper zone of the primary aquifer ～1000 m downgradient from the recharge basin. A classic asymmetrical distribution of recharged surface water resulted from the recharge induced horizontal and vertical hydraulic gradients. The distribution and breakthrough times of recharged surface water obtained with stable isotopes concurred with those of major anions and bromide in a tracer test conducted during the 1995 recharge season. This stable isotope procedure effectively quantified mixing between surface and ground water.     

EVAPOTRANSPIRATION CONCEPTUALIZATION IN THE HSPF‐MODFLOW INTEGRATED MODELS1

In 1988, the Florida Institute of Phosphate Research (FIPR) funded project to develop an advanced hydrologic model for shallow water table systems. The FIPR hydrologic model (FHM) was developed to provide an improved predictive capability of the interactions of surface water and ground water using its component models, HSPF and MODFLOW. The Integrated Surface and Ground Water (ISGW) model was developed from an early version of FHM and the two models were developed relatively independently in the late 1990s. Hydrologic processes including precipitation, interception, evapotranspiration, runoff, recharge, streamflow, and base flow are explicitly accounted for in both models. Considerable review of FHM and ISGW and their applications occurred through a series of projects. One model evolved, known as the Integrated Hydrological Model IHM. This model more appropriately describes hydrologic processes, including evapotranspiration fluxes within small distributed land‐based discretization. There is a significant departure of many IHM algorithms from FHM and ISGW, especially for soil water and evapotranspiration (ET). In this paper, the ET concepts in FHM, ISGW, and IHM will be presented. The paper also identifies the advantages and data costs of the improved methods. In FHM and IHM, ground water ET algorithms of the MODFLOW ET package replace those of HSPF (ISGW used a different model for ground water ET). However, IHM builds on an improved understanding and characterization of ET partitioning between surface storages, vadose zone storage, and saturated ground water storage. The IHM considers evaporative flux from surface sources, proximity of the water table to land surface, relative moisture condition of the unsaturated zone, thickness of the capillary zone, thickness of the root zone, and relative plant cover density. The improvements provide a smooth transition to satisfy ET demand between the vadose zone and deeper saturated ground water. While the IHM approach provides a more sound representation of the actual soil profile than FHM, and has shown promise at reproducing soil moisture and water table fluctuations as well as field measured ET rates, more rigorous testing is necessary to understand the robustness and/or limitations of this methodology.     

LANDSCAPE ATTRIBUTES AS CONTROLS ON GROITHD WATER NITRATE REMOVAL CAPACITY OF RIPARIAN ZONES1

ABSTRACT: Inherent site factors can generate substantial variation in the ground water nitrate removal capacity of riparian zones. This paper examines research in the glaciated Northeast to relate variability in ground water nitrate removal to site attributes depicted in readily available spatial databases, such as SSUIRGO. Linking site‐specific studies of riparian ground water nitrate removal to spatial data can help target high‐value riparian locations for restoration or protection and improve the modeling of watershed nitrogen flux. Site attributes, such as hydric soil status (soil wetness) and geomorphology, affect the interaction of nitrate‐enriched ground water with portions of the soil ecosystem possessing elevated biogeochemical transformation rates (i.e., biologically active zones). At our riparian sites, high ground water nitrate‐N removal rates were restricted to hydric soils. Geomorphology provided insights into ground water flowpaths. Riparian sites located on outwash and organic/alluvial deposits have high potential for nitrate‐enriched ground water to interact with biologically active zones. In till deposits, ground water nitrate removal capacity may be limited by the high occurrence of surface seeps that markedly reduce the time available for biological transformations to occur within the riparian zone. To fully realize the value of riparian zones for nitrate retention, landscape controls of riparian nitrate removal in different climatic and physiographic regions must be determined and translated into available spatial databases.     

Surface Water Seepage Effects on Shallow Ground‐Water Quality Along the Rio Grande in Northern New Mexico1

Abstract: Interactions between surface irrigation water, shallow ground water, and river water may have effects on water quality that are important for both drinking water supplies and the ecological function of rivers and floodplains. We investigated water quality in surface water and ground water, and how water quality is influenced by surface water inputs from an unlined irrigation system in the Alcalde Valley of the Rio Grande in northern New Mexico. From August 2005 to July 2006, we sampled ground water and surface water monthly and analyzed for concentrations of major cations and anions, specific conductance, pH, dissolved oxygen, and water levels. Results indicate that irrigation ditch seepage caused an increase in ground water levels and that the Rio Grande is a gaining stream in this region. Temporal and spatial differences were found in ion concentrations in shallow ground water as it flowed from under the ditch toward the river. Ground‐water ion concentrations were higher when the ditch was not flowing compared with periods during peak irrigation season when the ditch was flowing. Ditch inputs diluted ion concentrations in shallow ground water at well positions near the ditch. Specifically, lower ion concentrations were detected in ground water at well positions located near the ditch and river compared with well positions located in the middle of an agricultural field. Results from this project showed that ditch inputs influenced ion concentrations and were associated with ground‐water recharge. In arid region river valleys, careful consideration should be given to management scenarios that change seepage from irrigation systems, because in some situations reduced seepage could negatively affect ground‐water recharge and water quality.     

EVALUATION OF AN INDUCED INFILTRATION MODEL AS APPLIED TO GLACIAL AQUIFER SYSTEMS1

ABSTRACT: Numerical models were used to examine the limitations of the assumptions used in an analytical induced infiltration model. The assumptions tested included negligible streambed effects, negligible areal recharge, two-dimensional ground water flow, fully penetrating rivers and wells, and constant surface water stage. For situations that deviate from the underlying assumptions, the analytical model becomes a less reliable predictor of induced infiltration. The numerical experiments show that streambed effects cannot be neglected if the streambed conductivity is more than one order of magnitude lower than the aquifer hydraulic conductivity. Areal recharge cannot be neglected if the ground water basin receives more than 5 in/yr of areal recharge. Three-dimensional flow effects due to well partial penetration cannot be neglected if the ratio of horizontal hydraulic conductivity to vertical hydraulic conductivity (K_h/K_u) is greater than 10. Surface water elevation fluctuations can significantly influence the induced infiltration rate, depending on the degree of fluctuations and the ground water hydraulic gradient.     

FACTORS AFFECTING SPRING RUNOFF ON TWO FORESTED WATERSHEDS1

ABSTRACT Spring runoff from two forested watersheds in northern Minnesota is a function of annual snowfall, soil water recharge, and water supply rates. A drainage basin with a clay soil and a hardwood overstory had greater snowmelt and water supply rates than another drainage basin with a sandy soil and conifer overstory. The average soil water recharge rate for the clay soil was 28 percent less than for the sandy soil. The lower recharge rate of the clay soil resulted in spring runoff which averaged 40 percent of water supplied during the three year study while an average of two percent was produced on the sandy soil. Soil frost which affected soil water recharge varied between soil types and was influenced by amount of soil water storage and snow cover.     

HYDROLOGICAL EFFECTS OF AN UNCONTROLLED FLOWING WELL,RED RIVER VALLEY,NORTH DAKOTA,USA1

ABSTRACT: In areas of the Red River Valley that overlie permeable Paleozoic sediments, wetlands and salinization have developed where unregulated flowing wells discharge brackish water. Field data were collected to assess the fate of water and salt from a well 25 km northwest of Grand Forks. Drilled during the drought of the 1930s, discharge was used to replenish water in a small oxbow pond used by livestock. The unregulated well discharges about 56 m³/day, measured since 1993. This discharge exceeds ground water flow from the site, thereby forming a ground water mound with a maximum height of 1 m and a diameter of about 300 m. Most soil and underlying sediments near the well have a hydraulic conductivity of 0.3 m³/day. Flow net analysis suggests that less than 25 percent infiltrates, with the remaining water lost to surface flow and evapotranspiration (ET). Evapotranspiration and slow infiltration has led to increased salinization, with shallow soils exhibiting EC to 500 milliSiemens/m. The most pronounced soil salinization occurs along the margins of the oxbow pond and meander scars. Wetland vegetation with low diversity comprises three zones, with species associations similar to those of closed basin prairie potholes to the west.     

WATER QUALITY BENEATH URBAN RUNOFF WATER MANAGEMENT BASINS1

ABSTRACT: The chemical impact of urban runoff water on water quality beneath five retention/recharge basins was investigated as part of the US EPA's Nationwide Urban Runoff Program in Fresno, California. Soil water percolating through alluvium soils and the ground water at the top of the water table were sampled with ceramic/Teflon vacuum water extractors at depths up to 26 m during the two-year investigation. Inorganic and organic pollutants are present in the runoff water delivered to the basins. No significant contamination of percolating soil water or ground water underlying any of the five retention/recharge basins has occurred for constituents monitored in the study. The oldest basins was constructed in 1962. The concentration of selected trace elements in the ground water samples was similar to the levels reported in the regional ground water. None of the pesticides or other organic priority pollutants, for which water samples were analyzed, was s̊ detected except diazinon which was found in trace amounts (0.3 μg/L or less) in only three soil water samples. These results are important to the continued conservation of storm water and the development of a best management practice for storm-water management using retention/recharge basins in a semi-arid climate.