某金铜矿山含铜酸性废水处理研究

采用石灰调pH—铁屑置换—石灰沉淀处理工艺对废水进行试验，结果表明，采用该工艺处理含铜酸性矿山废水，不仅能使处理后的水满足排放标准，同时还能回收废水中的铜。     

含铜制药有机废水的处理研究

通过试验，采用将化学沉淀和生物处理相结合的工艺流程及方法处理含铜有机废水，经处理后的出水Cu^2 符合排放标准。     

印制板蚀刻液再生及铜回收技术与设备

由深圳市拓鑫环保设备有限公司开发的印制板蚀刻液再生及铜回收技术与设备,适用于印制板三废的治理。主要技术内容 一、基本原理利用含重金属溶液的选择性分离技术,对含铜废水中的铜进行选择性分离,使蚀刻废液得以再生循环利用的同时,获得高纯度的金属铜板。针对线路板生产蚀刻过程的特点,高效利用蚀刻废液中残留的有用成分,去除废液中影响蚀刻效果的成分,形成了分离铜、蚀刻液再生、电解铜、蚀刻液循环利用的技术方案,使因铜离子浓度过高而失去蚀刻功能的废液得以再生,同时获得高纯度铜板。对低含铜废水则是把其中的铜选择性分离,电解制成铜板,从而达到减少污染、回收资源的目的。     

浅析电镀含铜和含镍污泥的资源化回收工艺

电镀污泥中含有大量重金属，属于危险废物，但经恰当处理，对金属进行回收，可产生一定的经济效益和环境效益，其中的铜和镍最具有回收价值。本文简述了电镀含铜和含镍污泥的资源化回收工艺，并对其中的物料平衡和金属平衡作了分析。     

浅析PCB废水中络合态铜的处理方法

在PCB废水中,铜是主要的重金属污染物。Cu^2＋可通过加碱沉淀法完全沉淀下来,而废水中含有的络合态铜往往是造成出水总铜不能达标排放的重要因素。本文对络合态铜的各种处理方法如：化学沉淀法、氧化还原法、生物法等作了简要介绍和分析。     

重庆含铜废物利用行业技术准入研究

因缺失含铜废物利用技术准入规范,从业企业良莠不齐,制约了该行业的良性发展。通过分析重庆市含铜废物利用现状、存在问题,从含铜废物利用项目选址用地、建设规模、产品质量、技术工艺、设施建设、准入许可及环境管理等方面提出准入门槛规定,以期为含铜废物利用行业良性发展提供参考。     

二维与三维电解法处理含铜废水的试验研究

以含铜废水为处理对象,考察了二维电解法的电解电压、电解时间、pH值、极间距对铜去除率的影响。在此基础上为提高处理效率,两极间填充活性炭和玻璃珠形成三维电解,确定了三维电解的最佳运行条件是极间距4cm,pH值3～4,电解电压22 V,电解135min,铜离子的去除率为80.6%。     

硫酸亚铁法与硫化钠法处理络合铜废水的对比研究

通过硫酸亚铁（FeSO4）法和硫化钠（Na2S）法处理络合铜废水的对比实验研究，探讨了FeSO4和Na2S破络机理、两种药剂的授加量、pH值、絮凝剂（PAM）的加入量对铜去除率的影响，分析两种处理方法的优缺点，以期为线路板厂络合铜废水处理提供参考。     

谷壳碳能清除石油污水

石油天然气钻探过程中产生大量废水,其中石油污水是污染环境的主要有害成份。近年来,四川石油局各油气田在防治污染,保护环境过程中,普遍采用化学混凝沉降工艺处理钻井废水,取得了一定成效。但在废水含油较多的情况下,用该工     

水解酸化与生物接触氧化法的应用

本文介绍了生物接触氧化工艺对伞布印染废水在混入了少量的拉链厂生产废水以及毛线印染废水后的综合处理问题。在运行过程中，应根据实际情况选取合适的运行参数来解决运行中遇到的问题，以保证处理出水的顺利达标。     

Optimization of the electrocoagulation process for the removal of copper, lead and cadmium in natural waters and simulated wastewater

Chemical, electrochemical and flow variables were optimized to examine the effectiveness of the electrocoagulation process for the removal of copper, lead and cadmium. The electrochemical process, which uses electrodes of commercial laminate steel, was applied to simulated wastewater containing 12 mg dm(-3) of copper, 4 mg dm(-3) of lead and 4 mg dm(-3) of cadmium. The optimum conditions for the process were identified as pH=7, flow rate=6.3 cm(3) min(-1) and a current density between 31 and 54 A m(-2). When the electrode geometric area and time of electrolysis reached critical values, the copper removal reached a maximum value of 80%. A linear relationship was identified between the current density and the mass of generated sludge. In addition, a linear relationship was found between specific energy consumption and current density. The results of this investigation provide important data for the development of an industrial-scale electrolytic reactor.     

INPUTS OF COPPER‐BASED CROP PROTECTANTS TO COASTAL CREEKS FROM PASTICULTURE RUNOFF1

ABSTRACT: Inputs of copper‐based crop protectants from tomato fields grown under plastic mulch agriculture (plasticulture) to an estuarine creek were investigated. Copper was measured in runoff from diverse land‐uses including conventional agriculture, plasticulture, residences, and natural areas. Water column and sediment copper concentrations were measured in plasticulture and control (nonagriculture) watersheds. Copper concentrations in plasticulture‐impacted creeks exceeded background levels episodically. High concentrations occurred during or immediately after runoff‐producing rains. Concentrations of 263 μg/L total copper and 126 μg/L dissolved copper were measured in a tidal creek affected by plasticulture; concentrations exceeded the shellfish LC₅₀ values and the water quality criteria of 2.9 μg/L dissolved copper. Control watersheds indicated background water column levels of ≤ 4 μg/L dissolved copper with similar copper levels during periods with and without rain. The copper concentrations in tomato plasticulture field runoff itself contained up to 238 μg/L dissolved copper. Copper concentrations in runoff from other land‐uses were less than 5 μg/L dissolved copper. Creek sediment samples adjacent to a plasticulture field contained significantly higher copper concentrations than sediments taken from nonplasticulture watersheds.     

REVERSIBLE ADSORPTION OF AQUEOUS DIVALENT COPPER ION BY ESTUARINE SEDIMENTS1

Sediments were equilibrated with solutions containing divalent copper ion. A colorimetric method using the triethylenete-tramine complex of the metal ion was employed to measure changes in uptake of copper by the sediments. Studies were made with sediments from rivers in the British Isles which were in the proximity of areas which had been mined for metals for several hundred years. For comparison, similar studies were performed with a sample of sand and a soil with a high organic content. It was possible to follow the uptake of copper ion by the materials and estimate their abilities to adsorb copper ion. In particular, a strong correlation was observed between the organic content of the sediment and the total amount of copper adsorbed by the sample. Under the employed circumstances it was possible to demonstrate that the adsorption of the metal ion was reversible.     

扩展阴极型膜电解法处理含铜废水的数学模型

采用均匀设计法,研究离子膜扩展阴极电解法对低浓度含铜废水的处理效果,得到了反应条件与回收效果之间的线性模型,并比较了线性预测模型和BP网络的预测效果。结果表明,线性模型有较强的定性分析作用但预测能力不强,而BP网络具有很强的预测能力。两法结合,具有很强的理论和实践指导意义。模型预测结果和实验结果均表明,扩展阴极型膜电解法可带来很好的社会效益和经济效益。     

WATER USE AND WATER CONSERVATION BY THE COPPER MINING INDUSTRY1

ABSTRACT: This paper examines the use of water by copper mines for treating low grade ores. The froth flotation process for treating sulphide ore and the heap leaching process for treating oxide ore are described, and ways of reducing the amount of water used in these processes are discussed. Estimates of the costs reducing water consumption are given. Finally, the circumstances in which it would be desirable for a copper mine to reduce its level of water consumption are considered.     

再生铜行业环境管理问题的若干思考和建议

随着我国铜冶炼(原生铜和再生铜)行业对含铜二次资源需求量的增加,集废旧资源回收、拆解和分选、二次资源出售、铜再生利用于一体的产业链逐渐发展壮大起来。然而高能耗、高污染、低质量、低产出的特点在再生铜行业依然存在,环境监管政策和标准也不健全不完善。随着人们对美丽生态环境诉求的增加,必须加强有色金属行业的环境管理。本文对再生铜行业发展和环境管理做了一些思考,特别是对再生铜行业环境管理存在的问题进行了分析,并针对问题提出了几点政策性建议,以期为我国再生铜产业的环境友好发展和环境监管提供借鉴。     

EVALUATION OF COPPER ACCUMULATION IN PART OF THE CALIFORNIA AQUEDUCT1

ABSTRACT: Copper sulfate has been used extensively in the California Aqueduct to control phytoplankton and the alga Cladophora. Since 1969 more than 250,000 pounds of copper sulfate has been added to a part of the aqueduct. Although copper sulfate is effective in controlling algae, copper tends to accumulate in the system in which it is applied. Samples of water, biota including plants, clams, and snails, as well as sediment were analyzed for copper. Results of these analyses showed that copper concentrations in the water, with three exceptions, were less than 10 micrograms per litre. Samples of plant tissue showed a 198 percent increase in copper concentration in the treated reach of the aqueduct, and clam tissue showed a 68 percent increase. Snails in the treated reach had 77 percent more copper than in the untreated reach whereas copper concentrations in the sediment doubled. None of the concentrations found are considered to be harmful to the biota.