江苏凹凸棒石粘土的开发利用

本文详细介绍了江苏凹凸棒石粘土的矿床特征、特殊性质和广泛用途。分析了凹凸棒石粘土的利用现状和开发前景，作者提出了进一步开发利用的若干建议。     

江苏凹凸棒石粘土的开发利用

本文详细介绍了江苏凹凸棒石粘土的矿床特征、特殊性质和广泛用途。分析了凹凸棒石粘土的利用现状和开发前景,作者提出了进一步开发利用的若干建议。     

凹凸棒石粘土资源化现状研究

凹凸棒石是一种具有层链状结构，含水富镁（铝）的硅盐粘土矿物。本文结合国内外相关资料，从应用角度分析了凹凸棒石粘土的理化特性，综述了国内凹凸棒石粘土的应用现状，并提出了加强对凹凸棒石研究应用的几点建议。     

利用改性凹凸棒石处理含油工业废水

利用改性后的凹凸棒石颗粒吸附剂进行含油工业废水处理实验。取样处理实验结果表明,改性粘土颗粒吸附剂的吸附量远大于活性炭,且处理效果好。在废水含油浓度72mg/L时,吸附剂可处理废水1.18m3/kg,停留时间约8min。用加热法对吸附饱和后的凹凸棒石颗粒可进行5次再生使用,且对油的吸附效率没有明显下降。清水淋沥实验表明,制备的改性凹凸棒石颗粒有很好的持油性,油释放率仅为2.05%。     

明光市女山火山地质遗迹资源特点及其可持续保护

介绍了明光市女山火山地质遗迹资源及其特点，指出保护中存在的问题：重视程度不够、宣传和研究力度不够、保护措施不到位等，提出了其可持续保护技术路线，即系统开展综合性地貌景观和地质遗迹的调查、划定保护区域和保护对象、加强科学研究工作、加强地质遗迹保护工程和基础设施建设以及多方筹集资金、适度开发旅游等。     

贵州省野生生物资源开发利用与保护

本文论述了贵州省的野生生物资源概况，揭示了资源开发利用存在的问题，并对资源的开发利用与保护提出了建议。     

贵州省能源资源评价

本文通过对能源资源的综合分析评价，揭示了贵州省能源资源的基本特点和开发利用的有利条件，并分别探讨了煤炭和水能资源的开发利用问题。     

曲阜市文化旅游资源及其开发利用

文化旅游资源是曲阜市的优势资源，文在分析其文化旅游资源特点和开发利用的区内外环境条件的基础上，提出了曲阜市文化旅游资源开发利用的基本战略。     

矿产资源的开发利用与环境保护

作者论述了人口、资源、环境三者之间的辩证关系，提出环境保护是矿产资源开发利用的前提，不能以牺牲环境为代价来开发利用矿产资源。以此为基点，作者概述了我国矿产资源开发利用对环境的影响，以及我国矿山环境保护工作的现状，提出了加强矿产资源开发利用中环境保护的五项建议。     

资源开发利用的环境经济学分析

资源开发利用产生的环境问题作为资源产业发展中的负产品，已成为资源产业能否可持续发展的关键。本文运用经济学理论，通过对资源开发利用地区环境容量和资源开发利用经济行为的分析，指出资源开发利用环境问题的实质是外部不经济性。为了实现在生态环境不被破坏的前提下资源开发利用经济效益最大化，需主动进行环境治理并取适当的经济手段。     

区域优势自然资源的评价——以河南省黄河两岸地区为例

本文试图从区域、自然资源本身和资源的外部条件出发,通过分析区域优势自然资源的概念,选择建立了衡量区域优势自然资源的6项标准体系,并以河南省黄河两岸地区为例,借助与高层次区域的比较研究,确定了该区域的优势自然资源是:铝土矿为第一优势资源,天然气为第二优势资源,以下资源次序为石油、煤、金矿、水泥灰岩、耐火粘土和水资源等。这为合理开发区域优势自然资源提供了重要科学依据.     

Conservation of building materials and the future of the built environment

Building uses a combination of materials resources ranging from clay to bronze. Some of these resources are widely available, but require substantial energy resources to process and distribute them as the volumes used are so great. Other resources, like copper, are in much smaller supply. The resources used in building need to be examined against the future resource limitations in their supply and the possibilities of recycling. The links between building and waste cycles will also be critical, as wastes from other processes can often be incorporated into the building process. Design for recycling has to be balanced against the advantages of design for longer life. Reversible cementitious processes could confer enormous advantages if the reversibility was safely controllable, but this represents a very formidable scientific problem. The advantages of composite materials need to be balanced against the difficulties of effective recycling, for example reinforced concrete. The building as an energy conservation device also needs more emphasis. The final section deals with the concept of the materials conservation city in a Utopian way. It is designed to stimulate constructive thinking about resource conservation and materials recycling.     

Pu在粉质粘土介质中的分配系数及其影响因素研究

本文以粉质粘土介质为研究对象，用批式法实验研究了Pu在砂土介质中的分配系数及其影响因素。研究结果表明：核素Pu在粉质粘土中的分配系数较大，反映该种地质介质对Pu具有较强的吸附阻滞性；另外，分配系数是一个随环境pH值、介质含水率及水中核素源项浓度而变化的量。     

Implications of cation exchange on clay release and colloid-facilitated transport in porous media

Column experiments were conducted to study chemical factors that influence the release of clay (kaolinite and quartz minerals) from saturated Ottawa sand of different sizes (710,360, and 240 microm). A relatively minor enhancement of clay release occurred when the pH was increased (5.8 to 10) or the ionic strength (IS) was decreased to deionized (DI) water. In contrast, clay release was dramatically enhanced when monovalent Na+ was exchanged for multivalent cations (e.g., Ca2+ and Mg2+) on the clay and sand and then the solution IS was reduced to DI water. This solution chemistry sequence decreased the adhesive force acting on the clay as a result of an increase in the magnitude of the clay and sand zeta potential with cation exchange, and expansion of the double layer thickness with a decrease in IS to DI water. The amount of clay release was directly dependent on the Na+ concentration of the exchanging solution and on the initial clay content of the sand (0.026-0.054% of the total mass). These results clearly demonstrated the importance of the order and magnitude of the solution chemistry sequence on clay release. Column results and scanning electron microscope (SEM) images also indicated that the clay was reversibly retained on the sand, despite predictions of irreversible interaction in the primary minimum. One plausible explanation is that adsorbed cations increased the separation distance between the clay-solid interfaces as a result of repulsive hydration forces. A cleaning procedure was subsequently developed to remove clay via cation exchange and IS reduction; SEM images demonstrated the effectiveness of this approach. The transport of Cu2+ was then shown to be dramatically enhanced by an order of magnitude in peak concentration by adsorption on clays that were released following cation exchange and IS reduction.     

Factors affecting the ratio of cation exchange capacity to clay content in lignite overburden

Unusually high cation exchange capacity (CEC) values relative to clay content are frequently reported for lignite overburden and minesoils. The CEC to percent clay ratio is commonly greater than one and would require that the average charge of the clay fraction be greater than 100 cmol(c) kg(-1). A comparison of methods for particle-size distribution suggests that the major reason lignite overburden samples have CEC to percent clay ratios greater than one is incomplete dispersion of aggregates of clay minerals or shale fragments. Preliminary investigations revealed the presence of shale fragments, smectite, and partially weathered mica in the silt fraction. Methods commonly used in soil textural analysis underestimated clay content by approximately 24%. The silt fraction may, therefore, provide a "hidden" source of CEC. Another important factor influencing the CEC to percent clay ratio was the presence of organic materials (lignite) in the samples. Lignite may make a significant contribution to CEC in overburden materials. In a study designed to estimate the pH-dependent charge of both the mineral and organic fractions, the CEC of overburden organic constituents was determined to be approximately 158 cmol(c) kg(-1) at pH 8.2. The high CEC to percent clay ratio in lignite overburden and minesoils may be resolved by adjusting methods for clay determination to optimize dispersion and by accounting for CEC due to organic materials. An alternative approach is to use existing methodology and use correction factors to account for incomplete dispersion of clay minerals and the charge contributions of organic materials.     

Woody plant roots fail to penetrate a clay-lined landfill: Managment implications

In many locations, regulatory agencies do not permit tree planting above landfills that are sealed with a capping clay, because roots might penetrate the clay barrier and expose landfill contents to leaching. We find, however, no empirical or theoretical basis for this restriction, and instead hypothesize that plant roots of any kind are incapable of penetrating the dense clays used to seal landfills. As a test, we excavated 30 trees and shrubs, of 12 species, growing over a clay-lined municipal sanitary landfill on Staten Island, New York. The landfill had been closed for seven years, and featured a very shallow (10 to 30-cm) soil layer over a 45-cm layer of compacted grey marl (Woodbury series) clay. The test plants had invaded naturally from nearby forests. All plants examined—including trees as tall as 6 m—had extremely shallow root plates, with deformed tap roots that grew entirely above and parallel to the clay layer. Only occasional stubby feeder roots were found in the top 1 cm of clay, and in clay cracks at depths to 6 cm, indicating that the primary impediment to root growth was physical, although both clay and the overlying soil were highly acidic. These results, if confirmed by experimental research should lead to increased options for the end use of many closed sanitary landfills.     

铀在土壤中的吸附动力学

以四川盆地红层丘陵区涪江河谷两岸广泛分布的第四系中更新统亚粘土为对象,用动态法测定了铀在该土壤中的平衡吸附量,为极低放废物的处置提供一些理论依据。研究了流速、土壤粒度及铀溶液初始浓度对土壤吸附铀的影响,并用常用的吸附动力学方程对实验数据进行了拟合。结果表明：土壤粒度小的平衡吸附量较大;流速越小、平衡吸附量越大;铀溶液的初始浓度越大,平衡吸附量越大;在用动力学方程拟合时,E lovich方程的拟合度最好;该土壤对铀的最大吸附率为61.1%,吸附性能较差。     

Can assessing for potential contribution of soil organic and inorganic components for butachlor sorption be improved?

Sorption of butachlor to various types of common soil components was investigated. Six pure minerals (montmorillonite [Mont], kaolinite [Kaol], Ca homoionic montmorillonite [Ca-Mont] and kaolinite [Ca-Kaol], amorphous hydrated Al and Fe oxides [AHOs-Al, AHOs-Fe]), four soil alkali-extractable pure humic acids (HAs), and the four corresponding HAs originated real unmodified and HO-treated soils were selected as the representative sorbents. Results showed that the HAs played a crucial role, and clay minerals (especially Mont) also showed an important effect in butachlor sorption. The AHOs may likely influence only in a mediator way by enhancing the availability of sorption domains of HAs. By removing 78% (on average) of the total organic carbon (TOC) from the soils with HO, the content ratio of clay to TOC (RCO) increased by an average of 367% and became >60. This change simultaneously decreased the sorption capacity of soils (40%, on average). Considering that the surface sorption domain on clay minerals may be highly exposed and more competitive after the partial removal of soil organic matter (SOM), this reaffirmed the potential contribution from clay minerals. It can thus be inferred that in the real soil where SOM and clay minerals are associated, the coating of clay minerals may have weakened the partition function of SOM or blocked some sorption domain within SOM, resulting in a decreased sorption of butachlor. Therefore, clay minerals, especially 2:1 type expanding minerals, may play a dual function vs. SOM content for the sorption of butachlor in soil.     

Management of old landfills by utilizing forest and energy industry waste flows

The lack of landfill capacity, forthcoming EU waste disposal and landfill management legislation and the use of non-renewable and energy intensive natural resources for the end-treatment of old landfills increase pressures to develop new landfill management methods. This paper considers a method for the end-management of old landfills in Finland, which is based on the utilization of forest and paper industry waste flows, wastes from paper recycling (de-inking) and wastes from forest industry energy production. Fibre clay wastes from paper mills, de-inking sludges from de-inking of recovered waste paper and incineration ash from forest industry power plants serve to substitute the use of natural clay for the building of landfill structures for closed landfills. Arguably, this method is preferable to existing practices of natural clay use for landfill building, because it (1) substitutes non-renewable natural clay, (2) consumes less energy and generates less CO2 emissions than the use of natural clay, and (3) eliminates considerable amounts of wastes from paper production, paper consumption and from forest industry energy production. Some difficulties in the application of the method are considered and the waste flow utilization is incorporated into a local forest industry recycling network.