PHYTOPLANKTON IN THE FOX CHAIN OF LAKES1

ABSTRACT: As part of a comprehensive water quality investigation on the Fox Chain of Lakes during May to October 1975, water samples from the Chain and Cedar Lake (reference) at 25 locations were collected weekly or bi-weekly to determine the species and densities of algae. The results have been evaluated for algal composition, density, and succession for each location. Sixty-four algal species were recovered from 414 samples. The number of species per sampling location varied from 10 at Channel Lake and Lake Marie to 26 on Fox Lake (main) and Grass Lake. Blue green algae were predominant and occurred at 25 of the 25 sampling stations. They consisted mainly of Aphanizomenon flos-aquae. The only flagellate of importance was Ceratium hirundinella, and significant concentrations of this organism were limited to Channel Lake and Lake Catherine. The only green alga bloom was created by Ulothrix variabilis on the waters of Pistakee Lake. Diatoms were quite significant on the shallower water bodies. Algal densities ranged from about 25 to 14,000 cts/ml. The highest count occurred on Mineola Bay. Other high counts (>10,000 cts/ml) observed were waters taken from Channel Lake, Grass Lake, and Fox Lake (main). In Grass Lake, 60 percent of the collections had algal densities in excess of 2,000 cts/ml. Most of these were the diatom Cyclotella meneghiniana.     

URBAN INFLUENCE ON PHOSPHORUS AND SEDIMENT LOADING OF WEST POINT LAKE,GEORGIA1

ABSTRACT: West Point Lake is a 10,360 ha mainstream impoundment of the Chattahoochee River located 95 kilometers downstream of Atlanta, Georgia. Origins and magnitude of external total phosphorus (TP) and total suspended solids (TSS) loads from the West Point Lake basin were estimated over a one-year period. Partitioning the drainage basin allowed the sources of these loads to be determined. The upper subbasin area, from Franklin, Georgia, to the headwaters of the Chattahoochee River, contributed 96 percent of the discharge and 97 percent of the TP and TSS loads into West Point Lake. The lower subbasin area, from Franklin to West Point Lake dam, only contributed 3 percent of the TP and TSS loads. Ninety-one percent and 87 percent of the TP and TSS loads, respectively, from the upper subbasin originated from the Atlanta area. Point sources discharged 70 percent and 3 percent of the upper subbasin TP and TSS loads, respectively. A large portion (66 percent) of the TP from the upper subbasin was in the bioavailable form.     

DIGITAL SIMULATION OF THE EFFECT OF THERMAL DISCHARGE ON STREAM WATER QUALITY1

A modified transient version of the Streeter-Phelps model along with the energy balance equation is employed to analyze the effects of waste heat discharge from power plants on stream water quality. Analysis is also made to examine the effects of the upstream water quality and stream velocity on the downstream DO concentration level. The resulting coupled nonlinear hyperbolic partial differential equations representing the energy, BOD and DO concentrations are solved by the method of characteristics and simulated on a digital computer. Final numerical results indicate that the allowable quantity of thermal discharge does heavily depend on the upstream quality.     

WATER QUALITY MANAGEMENT OF SKUDAI RIVER1

ABSTRACT: Urban runoff as well as industrial and agricultural discharges have seriously affected the water quality of the Skudai River, Malaysia. A water quality model is developed for simulating BOD and oxygen relationship. The simulated values agree relatively well with survey data taken during low flow conditions. Survey and simulated values show that a pollution abatement program is needed to prevent further deterioration of the river from organic discharges. A systems approach, involving complete analysis of water quality models and environmental control procedures, considering various water use patterns, water quality criteria, and waste input, is essential for solution.     

MODELING FLOW IN THE EVERGLADES AGRICULTURAL AREA IRRIGATION/DRAINAGE CANAL NETWORK1

ABSTRACT: The south Florida ecosystem and Lake Okeechobee are important water resource areas that have degraded due to changes in hydroperiod, water supply, and water quality. Approximately 56 percent of the total phosphorus in water discharged from the Everglades Agricultural Area (EAA) is in particulate form. Currently, farm-level best management practices are being implemented in the effort to reduce total phosphorus and sediment in off-farm discharges. The objective of this work was to develop and calibrate a model describing water movement in primary EAA canals as a first step to development of a water quality (i.e., nutrient, sediment) model. The Netherlands-developed mechanistic flow and water quality model (DUFLOW) was adapted for the EAA. Flow, stage, geometry, canal network, and meteorological data, October 13, 1993, to February 13, 1994, were used to adapt and calibrate the DUFLOW model for EAA water level and flow in primary canals. Direct runoff discharge into the primary canals from farm-pump stations was used as runoff input for the model. The model results are comparable to an independently-calculated water balance for the EAA. The calibrated flow model will be the basis for the calibration of sediment and chemical transport in the future.     

NUTRIENT LOADING ASSESSMENT IN THE ILLINOIS RIVER USING A SYNTHETIC APPROACH1

ABSTRACT: A synthetic relationship is developed between nutrient concentrations and discharge rates at two river gauging sites in the Illinois River Basin. Analysis is performed on data collected by the U.S. Geological Survey (USGS) on nutrients in 1990 through 1997 and 1999 and on discharge rates in 1988 through 1997 and 1999. The Illinois River Basin is in western Arkansas and northeastern Oklahoma and is designated as an Oklahoma Scenic River. Consistently high nutrient concentrations in the river and receiving water bodies conflict with recreational water use, leading to intense stakeholder debate on how best to manage water quality. Results show that the majority of annual phosphorus (P) loading is transported by direct runoff, with high concentrations transported by high discharge rates and low concentrations by low discharge rates. A synthetic relationship is derived and used to generate daily phosphorus concentrations, laying the foundation for analysis of annual loading and evaluation of alternative management practices. Total nitrogen (N) concentration does not have as clear a relationship with discharge. Using a simple regression relationship, annual P loadings are estimated as having a root mean squared error (RMSE) of 39.8 t/yr and 31.9 t/yr and mean absolute percentage errors of 19 percent and 28 percent at Watts and Tahlequah, respectively. P is the limiting nutrient over the full range of discharges. Given that the majority of P is derived from Arkansas, management practices that control P would have the most benefit if applied on the Arkansas side of the border.     

COMPUTATION OF UNSTEADY FLOWS IN THE ALABAMA RIVER1

ABSTRACT: An application is described of the branch-network flow model, BRANCH, to the upper Alabama River system in central Alabama. The model is used to simulate one-dimensional unsteady flows and water surface elevations in approximately 60 river miles of the Alabama River system. Preliminary calibration was made using 72 hours of observed data. Simulated discharges are about 10 percent lower than observed discharges at higher discharge rates and computed flows lag observed flows by about 30 minutes.     

A QUARTER CENTURY OF INDUSTRIAL WATER USE AND A DECADE OF DISCHARGE CONTROLS1

This paper explores the trends in industrial water intake, discharge, recycling, and gross water use to see whether or not the 1972 Clean Water Act (CWA) has had an impact on industrial effluent discharge. Quinquennial Census data indicate that the levels of discharge, both generally and per unit of product, have been falling for as long as these data have been gathered. Trends in gross water use and recycling ratios suggest that during the 25 years of record production processes were gradually modified so that less total water was discharged and less was used per unit of output. Untreated discharge as a percent of all discharge fell fairly steadily across all industries until 1973 and continued to fall in 1978 in the major BOD-discharging industries. By 1978, 75 percent of the pulp and paper effluent and 40 percent of the food processing effluent was treated. The consistent increase in treated discharge in the pulp and paper mills, with their large component of BOD-related process discharge, was not matched by parallel trends in the steel, petroleum, and chemicals industries with their relatively smaller amounts (and percents) of process discharge. This suggests that the CWA may have been responsible in part for the change in the former. In the pulp and paper industry, there is further evidence that the CWA has influenced wastewater discharge. Although, for the century as a whole, pulp and paper mills discharged less water, and more discharge was treated, in 1978 than in 1973, these trends were especially dramatic among firms in the Northeast where controls were likely to have been most stringent. Finally, using the only direct evidence we have, it appears that the drop in discharge levels and the increasing amounts of treatment had a significant effect on the amount of BOD discharged to surface and ground water. In 1973 the pulp and paper mills in Wisconsin discharged an average of about 868,000 lbs/day; by 1982, despite increased levels of production, they discharged less than 10 percent of that. There is no doubt that industrial water use changed over the 25 years of record. Although the evidence is circumstantial, it appears that the CWA and the environmental ethic which spawned it played an important part in some aspects of the shifts.     

WATER QUALITY CONCERNS AND REGULATORY CONTROLS FOR NONSTORM WATER DISCHARGES TO STORM DRAINS1

ABSTRACT: Nonstorm water discharges to municipal separate storm sewer systems (MS4s) are notable for spatial and temporal variability in volume, pollutant type, pollutant concentration, and activity of origin. The objective of this paper was to determine whether current technical knowledge and existing U.S. policy support an improved regulatory approach. The proposed policy would use type of discharge as a regulatory basis, merging the concepts of allowability of de minimis discharges and type-based statewide consistent rules. Specific research objectives were to comprehensively identify discharge types, characterize their prevalence in California, analyze relevant local and regional regulatory guidelines, and systematically evaluate opinions of experts about potential water quality impacts. Results demonstrate nonstorm water discharges were widespread in at least one sector, industrial facilities subject to a state permit; one discharge for every four facilities was reported in 1995, even though the permit explicitly prohibits such discharges. Clear consensus exists for minimal water quality concern for some discharge types when considering both municipal guidelines and experts’ opinions. In particular, condensate from a wide range of equipment and discharges from fire fighting equipment testing were found to be of low concern. Discharge types with consensus high concern were largely limited to discharges prohibited under other regulations, such as wastewater and hazardous waste management controls. Some discharge types where no consensus was identified, such as landscape irrigation, nevertheless generated concern for water quality impacts and appear to be relatively widespread. Available information supports technical feasibility of the proposed policy because at least some discharge types show strong consensus for de minimis impacts among regulatory guidelines and opinions of technical experts.     

GROUND WATER SEEPAGE IN LAKE WASHINGTON AND THE UPPER ST. JOHNS RIVER BASIN,FLORIDA1

Direct ground water seepage measurements were made in Lake Washington, Florida, to determine the importance of seepage as a water and chloride source to the lake and upper St. Johns River. Over 200 seepage measurements were made in the lake and adjoining canals from July through December 1978. Results indicated that seepage into the shore areas of Lake Washington was an insignificant water source to the lake, representing 0.6 percent of the inputs, and was nearly balanced by ground water recharge in the midlake region. Drainage canals entering Lake Washington, however, exhibited high average seepage rates (17.7 L/m²-day), over eight times the lake average (2.01 L/M²-day). Discharge from the St. Johns River was the dominant factor in the water budget of Lake Washington and represented approximately 88 percent of the inputs during the study year. Although inputs from the drainage canals represented only 6.6 percent of the St. Johns River annual discharge, these canals represented 20.4 percent of the annual St. Johns River chloride loading and 62.1 percent of the river chloride loading during the five driest months of 1978. Evidence from this study indicates that rising levels of chloride in the river in recent years are largely attributable to ground water seepage in channelized areas, particularly in the headwaters. These chloride inputs assume greater importance during low water/low flow periods.     

STATISTICAL ANALYSIS OF DAILY WATER QUALITY DATA1

ABSTRACT. The stochastic nature of some water quality time series were examined. These time series include nine years of daily observations in: (1) the stream flow (Q), (2) the water temperature (T), (3) the dissolved oxygen (DO), and (4) the biochemical oxygen demand (BOD) of the Passaic River at Little Falls, New Jersey. It was found that the random component contributes more than 60 per cent of the variance in the BOD series, but only 30 per cent or less in the DO series. Autocorrelation analysis suggest that DO and BOD residual series have a persistence of about 30 days. Significant crosscorrelation between DO and temperature T was found when DO lags T for up to 30 days, which indicates that the critical DO probably lags the critical temperature. Also, spectral anlaysis shows multiple peaks in the BOD series, reflecting effects of storm runoff and other non-point source pollution on river water quality.     

EFFECTS OF INTERANNUAL VARIATION OF PRECIPITATION ON STREAM DISCHARGE FROM RHODE RIVER SUBWATERSHEDS1

ABSTRACT: The purpose of this study was to determine the relationships between precipitation at the seasonal and annual scale and water discharge per surface area for seven contiguous first - and second-order tributaries of the Rhode River, a small tidal tributary to Chesapeake Bay, Maryland, USA. The goal was to quantify the effects of a wide range of precipitation, representative of inter-annual variations in weather in this region. The discharges measured included both overland storm flows and groundwater, since the aquifers were perched on a clay aquiclude. Precipitation varied from 824 to 1684 mm/yr and area-weighted Rhode River watershed discharge varied from 130 to 669 mm/yr with an average of 332 mm/yr or 29.1 percent of average precipitation. Average annual dis. charges from three first-order watersheds were significantly lower per surface area and varied from 16.0 to 21.9 percent of precipitation. Winter season precipitation varied from 125 to 541 mm. Area-weighted Rhode River winter discharge varied from 26.3 to 230 mm with an average of 115 mm or 43.9 percent of average precipitation. Spring season precipitation varied from 124 to 510 mm and watershed discharge varied from 40.0 to 321 mm with an average of 138 mm or 46.9 percent of average precipitation. In the summer and fall seasons, watershed discharge averaged 40.6 and 40.9 mm or 13.5 and 14.3 percent of average precipitation, respectively. Except in winter, the proportion of precipitation discharged in the streams increased rapidly with increasing volume of precipitation. Stream order showed a higher correlation with volume of discharge than vegetative cover on the watershed.     

REGIONAL WATER QUALITY MANAGEMENT BY THE GENERALIZED REDUCED GRADIENT METHOD1

ABSTRACT: A river basin-wide water quality management system is considered. The river receives thermal as well as organic wastes. At-source treatment of these pollutants is imposed to control the basin-wide water quality. The related water quality standards are: the minimum DO concentration, the maximum allowable BOD concentration, the maximum allowable stream temperature, and the allowable rise in stream temperature. The general dynamic mathematical model representing water quality in streams and the thermal effects on BOD and DO concentrations is presented. The model is highly nonlinear in nature. The optimal management problem involving the model is solved by a recently developed nonlinear propgramming technique - the generalized reduced gradient (GRG) method. Comparison of results obtained by the GRG method vs. dynamic programming, and of results using a more realistic mathematical model vs. a simple model are presented. The analysis procedure can be applied to designing new and examining existing water quality programs, and to study the influence of alternate policies and constraints.     

WATER QUALITY AND SOURCE OF FRESHWATER DISCHARGE TO THE CALOOSAHATCHEE ESTUARY,FLORIDA1

ABSTRACT: The Caloosahatchee River has two major sources of freshwater one from its watershed and the other via an artificial connection to Lake Okeechobee. The contribution of each source to the freshwater discharge reaching the downstream estuary varies and either may dominate. Routine monitoring data were analyzed to determine the effects of total river discharge and source of discharge (river basin, lake) on water quality in the downstream estuary. Parameters examined were: color, total suspended solids, light attenuation, chlorophyll a, and total and dissolved inorganic nitrogen and phosphorus. In general, the concentrations of color, and total and dissolved inorganic nitrogen increased, and total suspended solids decreased, as total discharge increased. When the river basin was the major source, the concentrations of nutrients (excepting ammonia) and color in the estuary were relatively higher than when the lake was the major source. Light attenuation was greater when the river basin dominated freshwater discharge to the estuary. The analysis indicates that water quality in the downstream estuary changes as a function of both total discharge and source of discharge. Relative to discharge from the river basin, releases from Lake Okeechobee do not detectably increase concentrations of nutrients, color, or TSS in the estuary.     

Multiple pollutant discharge permit markets,a challenge for wastewater treatment plants

This study focuses on the challenge of using a multiple pollutant transferable discharge permit market for operating wastewater treatment plants. It uses an analytical case of Sefidrud River in Iran with two checkpoints. It shows that the operating limitations for simultaneous biochemical oxidation demand (BOD) and total nitrogen (TN) removal may convert the economically optimal waste load allocation (WLA) to a framework with lack of incentives. Therefore, water quality trading (WQT) may lose its economical advantages. In this case, a third parameter, such as dissolved oxygen is recommended as an index for assigning market interactions. In spite of economical and practical success, this approach made WLA become a more complicated and uncertain policy. It was totally concluded that using single parameter WQT is only recommended for areas with small agricultural activities or lakes. Otherwise, the integrated discharged permit and reclaimed water market is proposed instead for simultaneous BOD and TN management.     

EVALUATING THE INFLUENCE OF SOURCE BASINS ON DOWNSTREAM WATER QUALITY IN THE MISSISSIPPI RIVER1

ABSTRACT: Chemical variability in the Mississippi River during water years 1989 to 1998 was evaluated using stream discharge and water‐quality data in conjunction with the DAFLOW/BLTM hydraulic model. Model simulations were used to identify subbasin contributions of water and chemical constituents to the Mississippi River upstream from its confluence with the Ohio and the Mississippi River and at the Atchafalaya Diversion in Louisiana. Concentrations of dissolved solids, sodium, and sulfate at the Thebes site showed a general decreasing trend, and concentrations of silica and nitrate showed a general increasing trend as the percentage of discharge from the Mississippi River upstream from Grafton increased. Concentrations of most chemical constituents in the Mississippi River at the Atchafalaya Diversion exhibited a decreasing trend as the percentage of water from the Ohio River increased. Regression models were used to evaluate the importance of the source of water to the water chemistry in the Mississippi River at Thebes and the Atchafalaya Diversion. The addition of terms in regression equations to account for the percent of water from sub‐basins improved coefficients of determination for predicting chemical concentrations by as much as nine percent at the Thebes site and by as much as 48 percent at the Atchafalaya Diversion site. The addition of source‐water terms to regression equations increased the estimated annual loads of nitrate and silica delivered from the Mississippi River Basin to the Gulf of Mexico by as much as 14 and 13 percent, respectively.     

SPRINGFLOW EFFECTS ON CHEMICAL LOADS IN THE SNAKE RWER,SOUTH-CENTRAL IDAHO1

ABSTRACT: The 150-kilometer middle reach of the Snake River (middle Snake) in south-central Idaho receives large quantities of water from springs discharging along the north side of the river from the regional Snake River Plain aquifer. Water-quality samples collected from nine north-side springs in April 1994 indicated that springs in the upstream part of the reach had larger concentrations of dissolved solids, dissolved nitrate, total nitrogen, tritium, and heavy isotopes of hydrogen and oxygen than to springs in the downstream part of the reach. Because the spring chemistry varies in the reach, discharge from the springs resulted in a degradation in water quality in some parts of the middle Snake and improvements in water quality in other parts. Depending on the annual discharge in the Snake River, the contribution from the north-side springs represented 33 to 66 percent of the discharge, 32 to 57 percent of the dissolved solids, 26 to 50 percent of the total nitrogen, and 7 to 14 percent of the total phosphorus transported annually from the middle Snake. Synoptic sampling showed that the north-side springs contributed 84 percent of the discharge and 35, 40, and 10 percent of the dissolved solids, total nitrogen, and total phosphorus load, respectively, to the Snake River during the peak of the irrigation season in 1994.     

POLLUTANT LOADING CAPACITY FOR THE BLACK RWER,CHEHALIS RWER SYSTEM,WASHINGTON1

ABSTRACT: The Black River, a tributary of the Chehalis River in western Washington State, has a history of widespread low dissolved oxygen (DO), anoxia in some locations, and fish kills. As part of a Total Maximum Daily Load (TMDL) study, environmental data were collected during two summer dry seasons and simulations were conducted with the WASP5 model to assess the effect of biochemical oxygen demand ( BOD ), ammonia, and nutrient loads on DO in the Black River. DO levels were below the State water quality regulatory criterion of 8.0 mg/L in almost all locations during the study. The slow middle reach of the river showed stratified conditions, with anoxia in some of the deepest pools. Based on model simulations, DO was found to still fall below the 8.0 mg/L criterion in the entire mainstem under “natural” conditions, and eutrophication was identified as a potential problem in the middle reach. A TMDL was proposed for BOD and ammonia that would prevent significant degradation of DO in the Black River. To prevent eutrophic conditions in the Black River, a TMDL for total phosphorus was proposed that establishes a protective criterion of 0.05 mg/L for the middle river during the dry low-flow season.     

THE DILUTION/FLUSHING TECHNIQUE IN LAKE RESTORATION1

ABSTRACT: Dilution/flushing has been documented as an effective restoration technique to restore eutrophic Moses and Green Lakes in Washington State. The dilution water added to both lakes was low in nitrogen and phosphorus content relative to the lake or normal input water. Consequently, lake nutrient content dropped predictably. Dilution or flushing rates were about ten times normal during the spring-summer periods in Moses Lake and three times normal on an annual basis in Green Lake. Improvement in quality (nutrients, algae, and transparency) was on the order of 50 percent in Moses Lake and even greater in Green Lake. The facilities for supplying dilution water were largely in place for the cited lakes; thus, costs for water transport were minimal. Available facilities, and therefore, costs, for water transport would usually vary greatly, however. Achieving maximum benefit from the technique may be more limited by availability of low nutrient water rather than facilities costs. Quality improvement may occur from physical effects of algal cell washout and water column instability if only high nutrient water is available.     

TEMPORAL VARIABILITY OF WATER QUALITY IN THE ST. LUCIE ESTUARY,SOUTH FLORIDA1

ABSTRACT: Four years of monthly freshwater discharge and constituent concentration data from three tributaries were related to a concurrent series of data for three segments of the St. Lucie Estuary in South Florida using multiple regression and time-series analysis techniques. Water quality parameters examined were dissolved inorganic and total nitrogen and phosphorus, chlorophyll a, total suspended solids, turbidity, and color. On monthly time scales, a multiple regression, which included freshwater discharge, freshwater constituent concentration, and dilution with ocean water (salinity) as independent variables, explained 50 percent or less of the variability in estuarine constituents. No single independent variable explained more variation than another. By contrast, on seasonal (wet, dry) time scales, freshwater discharge explained the bulk of variation in estuarine water quality (up to 93 percent). On monthly time scales, variability in concentrations of nutrients and other constituents may be largely controlled by processes internal to the system. At seasonal time scales, freshwater discharge appears to drive variability in most estuarine water quality parameters examined. Results indicate that management of tributary input on a seasonal basis, with the expectation of achieving seasonal concentration goals in the estuary, would have a higher probability of success than managing on a monthly basis.