涪陵地区农田径流水体中三氮含量及分布特征

本文在涪陵地区大面积和定点采集了农田径流水样品，测定了径流水体中的三氮含量。探讨了径流水体三氮随产流时间的变化，分析了干旱时间，水体流动等因素对三氮含量的影响。结果表明，干旱时间，径流水体流动对三氮含量有一定的影响。经统计分析，涪陵地区农田径流水体中的ＮＨ３－Ｎ，ＮＯ３＾－－Ｎ，ＮＯ２＾－－Ｎ和Ｔ－Ｎ含量分别为０．８４０，０．９７０，０．１０７和２．０７ｍｇ／ｌ。     

重金属离子对络合法（EDTA）测定Ca^2＋的干扰及其消除

用ＥＤＴＡ法测定Ｃａ＾２＋时，对Ｆｅ＾３＋，Ｃｕ＾２＋，Ｐｂ＾２＋，Ｍｎ＾２＋的干扰进行了试验，分别得出了最小干扰浓度，不同的干扰离子和浓度。采用不同的方法消除，效果良好。     

太湖流域上游典型水体中氮、磷动态变化特征研究

本研究在太湖流域上游的太湖与湖间的区域内，选择了25个监测点，对6种典型水体中TN、TP含量进行了为期1年的动态监测，分析了不同类型水体中氮、磷动态变化特征。其结果表明，畜禽养殖厂周围水体TN、TP含量在4～8月份相对较低；水产养殖场周围水体和居民区周围水体TN含量在1～6月份高于其他时间段，水产养殖场周围水体TP含较低的月份在5～8月，而居民区周围水体TP含量变化无明显规律；农田周围水体TN、TP含量较高的月份在12月至次年5月期间，最大值出现在3～4月；入湖河流与湖水TN含量变化趋势与农田周围水体基本一致，入湖河流TP含量在6～10月期间明显低于其他时间段，而湖水中TP含量变化则无明显规律。     

水体富营养化

水体富营养化是指氮、磷等植物营养物质含量过多所引起的水质污染现象。当过量营养进入湖泊、水库、河口、海湾等缓流水体后，水生生物特别是藻类将大量繁殖，使水中溶解氧含量急剧下降，以致影响到鱼类等的生存。在自然条件下，湖泊从贫营养湖→营养湖→沼泽→陆地的演变过程极为缓慢；人类的活动将大量工业废水和生活污水以及农田径流中的植物营养物质排入湖泊等水体后，将大大加速水体的富营养化进程。水体富营养化后，由于浮游生物大量繁殖，往往呈现蓝色、红色、棕色、乳白色等。这种现象在江河湖泊中称为水华，在海中则叫做赤潮。     

成都永丰乡南郊村蔬菜地Cu,Pb污染调查与评价

本文讨论了工业排放含Ｃｕ，Ｐｂ废水对永丰乡南效村蔬菜地的影响。结果表明：调查地土壤已遭较严重的Ｃｕ，Ｐｂ合污染。土地壤Ｃｕ含量为７７．５６－１６８２ｍｇ／ｋｇ，为对照点的１．６－３４倍，所采１６个土样中有１５个点的土壤Ｃｕ含量超过国家标准。土壤中Ｐｂ含量为４０．５－４１６ｍｇ／ｋｇ，为对照点的１．１－１１倍。生长于其上的蔬菜已不同程度的受到Ｃｕ，Ｐｂ的污染。     

成都市径流污染的概念性模型

概念性模型是根据城市径流形成过程及对水体影响变化的物理机理建立的一套数学模型，模型及参数均有明确的物理意义。本文用概念性模型求出了成都市街道地表物的累积量，降雨径流污染负荷量，并模拟了污染物对受纳水体的影响。     

环境小知识：什么是富营养化

富营养化指的是一种氮、磷等植物的营养物质含量过多所引起的水污染现象。当过量营养物质进入湖泊、水库、海湾等缓流水体后，水生生物特别是藻类将大量繁殖，使水中溶解氧含量急剧变化，以致影响到鱼类等的生存。在自然条件下湖泊会从贫营养湖过渡为富营养湖，进而演变为沼泽和陆地。不过这是一种极为缓陵的过程。但由于人类的活动，将大量工业废水和生活污水以及农田径流中的植物营养物质排入湖泊等水体后，     

湿法处理工业废渣热力学分析

根据冶金，煤炭及无机化工工业类废渣的物理化学性质，通过Ｍ＾ｎ＋ ｅ－Ｈ２Ｏ系和Ｍ＾ｎ＋ｅ－Ｆ＾－Ｈ２Ｏ系热力学平衡图，对废渣中硅，铝，铁及钙镁等主要矿物的溶出热力学行为进行了分析。     

会理污灌区重金属污染的调查,评价及防治对策

本文调查、评价了会理县锌矿污灌区内水、土、作物的重金属污染状况。调查结果表明：污灌区内土壤、作物重金属污染严重,尤以镉污染突出。作物中镉含量与距污染源距离呈负相关（ｒ＝－０．９９５）。镉在水稻植株各部位的分布,以根系含镉量最高,茎叶次之,谷粒最少。评价结果表明农灌水的污染程度不大,土壤中Ｃｄ、Ｚｎ、Ｐｂ污染是土壤污染的主要表现,水稻的污染较玉米更为严重。Ｃｄ已对人体健康构成潜在危害。本文还针对污染区的重金属污染提出了相应的防治措施     

稀土液体活力素及其生产工艺

稀土液体活力素的配比浓度为:Ｎ3～5,Ｆｅ0.4～07,Ｐ2Ｏ30.45～15,Ｚｎ0.3～05,Ｋ2Ｏ25～45,柠檬酸012～02,Ｍｎ1.6～23,络合剂03～055,糖份01～02,附着剂01～02,溶剂水余量,腐植酸钠005～010。其生产工艺过程包括原料预处理、计量混合、破碎、筛分、反应、冷却、过滤、包...     

Roofing as a source of nonpoint water pollution

Sixteen wooden structures with two roofs each were installed to study runoff quality for four commonly used roofing materials (wood shingle, composition shingle, painted aluminum, and galvanized iron) at Nacogdoches, Texas. Each roof, either facing NW or SE, was 1.22 m wide x 3.66 m long with a 25.8% roof slope. Thus, there were 32 alternatively arranged roofs, consisting of four roof types x two aspects x four replicates, in the study. Runoff from the roofs was collected through galvanized gutters, downspouts, and splitters. The roof runoff was compared to rainwater collected by a wet/dry acid rain collector for the concentrations of eight water quality variables, i.e. Cu(2+), Mn(2+), Pb(2+), Zn(2+), Mg(2+), Al(3+), EC and pH. Based on 31 storms collected between October 1997 and December 1998, the results showed: (1) concentrations of pH, Cu, and Zn in rainwater already exceed the EPA freshwater quality standards even without pollutant inputs from roofs, (2) Zn and Cu, the two most serious pollutants in roof runoff, exceeded the EPA national freshwater water quality standards in virtually 100% and more than 60% of the samples, respectively, (3) pH, EC, and Zn were the only three variables significantly affected by roofing materials, (4) differences in Zn concentrations were significant among all roof types and between all roof runoff and rainwater samples, (5) although there were no differences in Cu concentrations among all roof types and between roof runoff and rainwater, all means and medians of runoff and rainwater exceeded the national water quality standards, (6) water quality from wood shingles was the worst among the roof types studied, and (7) although SE is the most frequent and NW the least frequent direction for incoming storms, only EC, Mg, Mn, and Zn in wood shingle runoff from the SE were significantly higher than those from the NW; the two aspects affected no other elements in runoff from the other three roof types. Also, Zn concentrations from new wood-shingle roofs were significantly higher than those from aged roofs of a previous study. The study demonstrated that roofs could be a serious source of nonpoint water pollution. Since Zn is the most serious water pollutant and wood shingle is the worst of the four roof types, using less compounds and materials associated with Zn along with good care and maintenance of roofs are critical in reducing Zn pollution in roof runoff.     

Heavy metal content and distribution in surface sediments of the Seyhan River, Turkey

Chemical fractionation of seven heavy metals (Cd, Cr, Cu, Mn, Ni, Pb and Zn) was studied using a modified three-step sequential procedure to assess their impacts in the sediments of the Seyhan River, Turkey. Samples were collected from six representative stations in two campaigns in October 2009 and June 2010, which correspond to the wet and dry seasons, respectively. The total metal concentrations in the sediments demonstrated different distribution patterns at the various stations. Cadmium was the only metal that was below detection at all stations during both sampling periods. Metal fractionation showed that, except for Mn and Pb, the majority of metals were found in the residual fraction regardless of sampling time, indicating that these metals were strongly bound to the sediments. The potential mobility of the metals (non-residual fractions) is reflected in the following ranking: Pb > Mn > Zn > Cu > Ni > Cr in October 2009 and Mn > Pb > Zn > Cu > Ni > Cr in June 2010. The second highest proportion of metals was bound to organic matter/sulfides, originating primarily from anthropogenic activities. Non-residual metal fractions for all stations were highest in June 2010, which may be linked to higher organic matter concentrations in the sediment samples with 1.40% and 15.1% in October 2009 and June 2010, respectively. Potential sediment toxicity was evaluated using the Risk Assessment Code (RAC). Based on RAC classification, Cd and Cr pose no risk, Cu and Ni pose low risk, Pb and Zn were classified as medium risk metals, while the environmental risk from Mn was high. In addition, based on the sediment quality guidelines (SQG), the Seyhan River can be classified as a river with no, to moderate, toxicological risks, based on total metal concentrations.     

Changes in Extractable Metal Concentrations During Storage of Surface Water Samples Containing Sediments1

ABSTRACT: Changes in metal concentrations during storage of acidified water samples were studied. Water samples with high concentrations of suspended sediment were collected from the Fraser River, British Columbia. These samples were analyzed for “extractable” metals, which are defined to be the dissolved metals plus those metals extracted from suspended sediment by dilute mineral acid. Concentrations of extractable Cu, Fe, Pb, Zn, Ni, Co, Mn, and Cd were determined over time. Metal concentrations in these water samples were not stable and showed significant increases throughout the storage period. These results suggest that the extractable metal technique is inappropriate for the analysis of water samples containing suspended sediment.     

四川简阳东溪镇土壤环境六种元素含量评价

本文用随机布点法，采集了简阳东溪镇土壤样品29个，分析了土壤中Cd、Zn、Ni、Cu、Mn、Pb六种元素含量，用Shapiro-Wilk法和偏态系数检验了土壤中的元素含量分布类型，结果六种元素含量均为正态分布。根据元素含量类型分布，统计简阳东溪镇土壤中六种元素平均含量为：Cd0．295ppm、Zn62．5ppm、Ni27．49ppm、Cu23．25ppm、bin157．25ppm、Pb17．47ppm。     

不同酸消解方法在土壤重金属测定中的比较研究

分别用三种不同的酸消解方法进行土壤标准样品的前处理,用原子吸收分光光度法测定其中铜、铅、锌、镉、镍、锰、总铬元素的含量。结果表明,电热板/硝酸-过氧化氢-氢氟酸消解方法耗酸量少,消解时间短,适用于土壤中铜、铅、锌、镉、镍、锰元素的前处理,相对标准偏差为1.0%～5.0%;而使用电热板/硝酸-硫酸-氢氟酸方法针对土壤中总铬元素进行消解前处理,准确度更高,相对标准偏差为2.7%～5.1%。     

Surface runoff losses of copper and zinc in sandy soils

Increased anthropogenic inputs of Cu and Zn in soils have caused considerable concern relative to their effect on water contamination. Copper and Zn contents in surface soil directly influence the movement of Cu and Zn. However, minimal information is available on runoff losses of Cu and Zn in agricultural soils, and soil-extractable Cu and Zn in relation to runoff water quality. Field experiments were conducted in 2001 to study dissolved Cu and Zn losses in runoff in Florida sandy soils under commercial citrus and vegetable production and the relationship between soil-extractable Cu and Zn forms and dissolved Cu and Zn concentrations in runoff water. Five extraction methods were compared for extracting soil available Cu and Zn. Concentrations of dissolved Cu and Zn in runoff were measured and runoff discharge was monitored. Mean dissolved Cu in field runoff water was significantly correlated with the extractable Cu obtained only by 0.01 mol L(-1) CaCl2, Mehlich 1, or DTPA-TEA methods. Dissolved Zn in runoff water was only significantly correlated with extractable Zn by 0.01 mol L(-1) CaCl2. The highest correlations to dissolved Cu in runoff were obtained when soil-available Cu was extracted by 0.01 mol L(-1) CaCl2. The results indicate that 0.01 mol L(-1) CaCl2-extractable Cu and Zn are the best soil indexes for predicting readily released Cu and Zn in the sandy soils. Both runoff discharge and 0.01 mol L(-1) CaCl2-extractable Cu and Zn levels had significant influences on Cu and Zn loads in surface runoff.     

Multivariate analysis of trace metal levels in tannery effluents in relation to soil and water: a case study from Peshawar, Pakistan

Tannery effluents and relevant ground water and soil samples collected from various tanning industries of Peshawar were analyzed for Na, Ca, K, Mg, Fe, Mn, Cr, Co, Cd, Ni, Pb and Zn by the AAS method. The metal concentration data for the three media are reported in terms of basic statistical parameters, metal-to-metal correlations and linear regression analyses. Metal distributions in the three media were quite divergent and showed non-normal distributions with high standard deviation and skewness parameters. Sodium exhibited the highest mean levels of 1,277mg/L, 881mg/L and 12,912mg/kg in the effluent, ground water and soil samples, respectively. Among other metals, Cr concentrations were 410mg/L, 0.145mg/L, 100mg/kg and Ca, 278mg/L, 64.8mg/L, and 2,285mg/kg in the effluent, ground water and soil samples, respectively. Some significant correlations were observed between effluent and soils in terms of Na, Cr, Ni, Co and Pb. The ground water-soil interrelationship suggested that Na levels in the soil and ground water were significantly correlated with each other (r=0.486, P<0.01). Similarly, Cr in the soil is strongly correlated with Ca in ground water (r=0.486, P<0.01). These results were duly supported by the linear regression analysis of data. The source identification studies conducted using Principal Component Analysis (PCA) and Cluster Analysis (CA) evidenced that ground water and soil were being contaminated by the toxic metals emanating from the tannery effluents.     

Plant-available zinc and lead in mine spoils and soils at the mines of Spain, Iowa

To investigate the forms of Zn and Pb and their plant availability in mine spoil long after its abandonment, we studied seven sites in the Mines of Spain, near Dubuque, IA. Ores of Zn and Pb were mined from dolomitic limestone primarily during the 19th century, and there had been no subsequent remediation of metals-contaminated spoil. From both mine spoil and undisturbed areas, we collected root-zone soil samples as well as samples of the dominant ground-level, native plants, aniseroot [Osmorhiza longistylis (Torr.) DC.] and black snakeroot (Sanicular marilandica L.). We determined Zn and Pb concentrations in both the plant tissue and in the soil samples after strong-acid digestion, and we fractionated the solid-phase forms of Zn, Pb, and P in the soil samples by using sequential extraction. Concentrations of total Zn and Pb were 10- to 20-fold greater in the spoil than in the undisturbed soils. Plants growing in the mine spoil had Zn concentrations two to four times greater and Pb concentrations more than 26 times greater than did plants growing in the undisturbed soils. The highest concentrations of Zn and Pb were in the CBD-extractable and the residual fractions in both undisturbed and mine spoil samples. Although the mine spoil contained large amounts of P, Zn, and Pb were available for uptake by the two plant species in amounts proportional to Zn and Pb concentrations in the rooting zone.     

RUNOFF OF METALS FROM ALUM-TREATED HORSE MANURE AND MUNICIPAL SLUDGE1

ABSTRACT: Land application of organic soil amendments can increase runoff concentrations of metals such as Fe and Zn, metalbids such as B and As, and non-metals such as P and S that have the potential for causing adverse environmental impacts. Aluminum sulfate, or alum (Al₂(SO₄)3*(14H₂O), can reduce concentrations of some materials in runoff from sites treated with organic amendments. The objectives of this study were to (a) quantify concentrations of selected constituents (Al, As, B, Ca, Cd, Co, Fe, K, Mg, Mn, Mo, Na, P, Pb, 5, Se, Ti, and Zn) in runoff from plots treated with horse manure (mixed with stall bedding) and municipal sludge, (b) assess runoff quality effects of alum addition to those treatments, and (c) determine time variations in concentrations of the constituents. Horse manure and municipal sludge were applied to twelve 2.4 by 6.1 m fescue plots (six each for the manure and sludge). Alum was added to three of the manure-treated and three of the sludge-treated plots. Simulated rainfall (64 mm/h) was applied to the 12 treated plots and to three control (no treatment) plots. The first 0.5 h runoff was sampled and analyzed for the constituents described above. Addition of manure or sludge had no effect on runoff concentrations of the majority of constituents. In some cases (e.g., Al, As, Fe, Zn), however, concentrations were near or in excess of threshold values recommended for marine wildlife protection. Alum addition increased runoff of Al, Ca, K, and 5, due likely to its composition and by the addition of lime to counteract the acidity of alum. Concentration decreases of more than 50 percent were noted for P for the horse manure treatment. No alum effect was detected for P in runoff from the sludge-treated plots, possibly due to relatively stable P forms in the sludge. Runoff concentrations of Al, As, Fe, K, Mn, and P followed an approximately first-order decline with respect to time. Runoff concentrations of Ca and 5, however, peaked during the second runoff sample (four minutes following initiation of runoff), suggesting that differences in mobility and/or transport mechanisms exist among the materials investigated.     

Distribution of heavy metals in sediments of Igbede, Ojo and Ojora rivers of Lagos, Nigeria

The distribution of some heavy metals, namely Cd, Pb, Zn, Fe, Cu, Cr and Mn in epipellic sediments of Igbede, Ojo and Ojora rivers of Lagos was studied weekly in the early summer (November) of 2003. The levels of selected trace metals were determined using Atomic Absorption Spectrophotometer (UNICAM 969 AAS SOLAR). Trends in heavy metal burdens in the sediments revealed weekly variations in all the rivers assessed. Statistical analyses also showed different mean levels of trace metals in the aquatic environments, the distribution of which followed the sequence Fe > Zn > Mn > Pb > Cu > Cr > Cd, Fe > Zn > Cu > Mn > Pb > Cr > Cd and Fe > Zn > Mn > Cu > Cr > Pb > Cd in Igbede, Ojo and Ojora rivers respectively. Fe recorded the highest concentration levels (1,582.95 ± 96.57 μ g/g–1,910.34 ± 723.19 μ g/g) in all the sediments investigated while the Cd levels (0.06 ± 0.10 μ g/g–0.47 ± 0.36 μ g/g) were the lowest. Expectedly, trace metal concentrations in fine grain muddy sediments of the Igbede and Ojo coastline were much higher than those of Ojora which consist of coarse and sandy deposits covering the near shore area. Generally, the results obtained fell within tolerable limits stipulated by World Health Organization (WHO).