软锰矿烟气脱硫反应过程研究

研究了软锰矿浆体系中SO2和软锰矿的宏观动力学反应过程，考察了搅拌速度、温度、浓度、矿粉粒度、固体浓度等因素对反应速度的影响，应用了反应过程中粒径不断缩小的缩芯模型描述反应过程，计算出此反应的活化能。最终揭示了SO2与软锰矿反应的宏现动力学的数学模型，为工业装置的设计和操作提供了动力学理论依据，为本工艺的工业化应用打下了坚实的基础。     

软锰矿烟气脱硫资源化工艺研究

在喷射鼓泡反应器中，研究了工艺条件对软锰矿脱硫副产硫酸锰及稀酸两种工艺反应过程的影响。结果表明，在一定条件下，两工艺均能达到较高的脱硫率。搅拌转速是影响软锰矿脱硫反应体系选择性的重要因素。增大固液比，减小空塔气速和进口SO2浓度对提高脱硫率有利，提高搅拌转速起初有利于提高脱硫率，当增加到一定的值时，再增加转速对脱硫率几乎无影响。     

软锰矿烟气脱硫的研究进展

从脱硫机理、脱硫装置、影响因素等方面对软锰矿烟气脱硫(FGD)的研究进展进行了综述.深入剖析了已有研究工作的不足,展望了该方法的研究前景,为该方法的进一步研究和工业化提供参考.     

软锰矿与氧化亚铁硫杆菌吸收SO2过程中的影响因素

研究了低浓度软锰矿浆与氧化亚铁硫杆菌(Thiobacillus ferrooxidans,简称 T.f)联合吸收SO2过程中软锰矿浆浓度、T.f菌液量、O2体积分数、气体流量以及SO2进口浓度对硫酸根生成的影响.研究表明:在该体系中,生成的硫酸根浓度随着软锰矿浆浓度、T.f菌液量、O2体积分数以及气体流量的增加而增大;随着进口SO2浓度的增加,硫酸根的生成呈现先增加后减少的趋势.     

四川城口锰矿氧化矿石的利用与保护

城口锰矿发现于50年代末,大量地质工作始于1966年,1978年结束矿区初步勘探工作。经大量地质工作证实,该区为一大型沉积锰矿床;其中,地表浅部次生氧化矿石已于1977年被开发利用,加工生产的锰粉畅销省内外,收到了显著的经济和社会效益,对振兴该县经济起到了重要作用。城口锰矿地处四川东北边缘大巴山区,     

对铁碳处理硝基酚废水的研究

铁碳降解水中难降解有机污染物的影响因素、最佳工艺参数及处理效果;初步探讨了氧化降解污染物的作用机理;通过分析污染物降解的中间产物,提出了污染物降解的可能途径.探讨了pH、铁碳用量、温度以及锰矿物的粒径等对处理效果的影响,在最佳的工艺条件下,CODCr的去除率达到95%以上,TOC测定表明：大部分硝基酚被氧化降解为H2O和CO2.对硝基酚的降解途径主要是微电解将对硝基酚还原为对氨基酚,对氨基酚在酸性条件下被软锰矿氧化为H2O和CO2做探索性研究.     

锰矿产资源绿色开发及安全管理对策

分析并介绍了我国锰矿资源的分布及特点、开采现状、优质锰矿资源勘查潜力等战略储备,概述我国锰矿资源开采过程中引发的生态环境问题、资源利用问题,提出锰矿资源绿色开发的4个安全目标管理以及安全监管的对策,为锰矿产资源的持续开发奠定基础。     

碱性工业废水的治理技术

本文介绍了利用我国目前大量排放的印染、造纸等碱性工业废水进行中小型燃煤锅炉烟气脱硫的技术。该技术投资少、运行费用低,具有较好的经济效益     

低品位氧化锌矿的碱法浸出研究进展

随着世界对锌的需求量的增加,碱法浸出低品位氧化锌矿因其显著的优点（浸出率达90%以上、环境污染小等）而成为国内外研究的热点。本文主要介绍了低品位氧化锌矿氢氧化钠浸出体系的动力学和热力学过程,氨浸体系中氯铵、碳铵、硫氨浸出的国内外各研究单位的最近研究成果,并对碱浸过程中矿石活化、闪锌矿难溶解两类问题进行了讨论。     

脱硫工程招标书的技术经济评估

介绍了研究开发的脱硫工程招标书的技术经济评估体系,以及评估体系中的评估指标。     

Indian mineral resources — a short review

Though India's iron ore and manganese exports are a major source of foreign exchange, the continent lacks sufficient reserves of many important minerals, or has only recently exploited known reserves on an adequate scale. This article reviews India's mineral resources and points out trends in exploration and production.     

Brazil's mineral development: Potential and problems

Although Brazil is well endowed with natural resources, some of these are unexploited due to poor communications and political instability. The authors review present government policy and the situation with regard to oil and gas, iron ore, manganese and steel and other minerals, and conclude that Brazil has a bright economic future.     

碱锰型电解二氧化锰生产环境影响与环保措施

主要以某公司9000t/a碱锰型电解二氧化锰技改项目环境影响评价为例,结合验收监测数据,简要介绍碱锰型电解二氧化锰生产的环境影响与环保措施.该公司采用氧化锰矿和硫铁矿混合硫酸溶液浸出--电解的生产工艺生产碱锰型电解二氧化锰,生产过程中大气污染源主要有锅炉排放的烟气,化合、电解工序产生的硫酸雾;生产废水主要有锅炉除尘废水、漂洗水及炭黑生产废水;废渣主要是压滤锰渣.     

Study of inexpensive oxygen carriers for chemical looping combustion

Norwegian industrial tailings and by-products, as well as naturally occurring minerals and ores have been surveyed with the purpose of identifying candidate oxygen carrier materials for use in a chemical looping combustion process. Nine materials, based on manganese and/or iron oxide, were selected for an initial screening test; six were deemed promising and were hence investigated further. Thermogravimetric experiments were performed to investigate the oxygen capacity, the reaction kinetics and reversibility of the oxygen absorption reaction. A manganese ore with a reversible capacity of 4.9 wt% oxygen at 1000 °C was selected as the most promising for chemical looping combustion applications. This material was modified by addition of calcia to explore the possibility of enhancing the kinetic, catalytic and mechanical properties. The addition of excess calcium relative to manganese resulted in formation of calcium manganite and related phases. The oxygen capacity of the modified material was 4.5 wt% at 1000 °C, but it has potential advantages in terms of kinetics and chemical and mechanical stability relative to the pure ore.     

锰资源开发利用中存在的问题和对策——以秀山锰矿为例

针对秀山锰矿开采秩序混乱、效率偏低、矸石处理、电解锰渣堆存和生产废水、锰深加工路线不健全等特点,结合其他地区锰资源的开发利用情况,提出了秀山锰矿应扩大开采规模,规范管理,矸石用于充填安全柱,加高加固锰渣尾矿库,锰渣的资源化利用等措施；提取生产废水中的金属元素,减少废水产生量,废水达标处理和循环利用降低污染；依靠发展和扩大锰产业链,加大科技投入,促进秀山的可持续发展.     

锰尾矿资源循环利用分析与环境评价

通过分析我国锰资源分布及锰矿产业发展现状,预测未来10年我国锰尾矿排放量.通过分析评价重庆市秀山、城口锰尾矿对区域生态环境的影响,提出锰尾矿循环利用途径及可产生的效益,归纳出锰资源可持续发展的三点建议.     

Potential of Pacific Ocean Nodule, Crust, and Sulfide Mineral Deposits

This paper summarizes the main physical and economic features of manganese nodules, cobalt-rich manganese crusts and marine polymetallic sulfide deposits in the Pacific region. The most favourable areas for deposits of commerical interest are shown on a map of the Pacific. The gross metal sales values of hypothetical mines are compared to estimated size of world metal markets in the year 2000. It is suggested that a prudent policy for the major developed-country governments is to support research on those marine minerals that appear to have the potential to become a major source of minerals in the next century.     

The Environmental sustainability of mining in Australia: key mega-trends and looming constraints

At first ‘sustainable mining’ could be perceived as a paradox—minerals are widely held to be finite resources with rising consumption causing pressure on known resources. The true sustainability of mineral resources, however, is a much more complex picture and involves exploration, technology, economics, social and environmental issues, and advancing scientific knowledge—predicting future sustainability is therefore not a simple task. This paper presents the results from a landmark study on historical trends in Australian mining, including ore milled, ore grades, open cut versus underground mining, overburden/waste rock and economic resources. When complete data sets are compiled for specific metals, particular issues stand out with respect to sustainability—technological breakthroughs (e.g. flotation, carbon-in-pulp), new discoveries (e.g. uranium or U), price changes (e.g. Au, boom/bust cycles), social issues (e.g. strikes), etc. All of these issues are of prime importance in moving towards a semi-quantitative sustainability model of mineral resources and the mining industry. For the future, critical issues will continue to be declining ore grades (also ore quality and impurities), increased waste rock and associated liabilities, known economic resources, potential breakthrough technologies, and broader environmental constraints (e.g. carbon costs, water). For this latter area, many companies now report annually on sustainability performance—facilitating analysis of environmental sustainability with respect to production performance. By linking these two commonly disparate aspects—mining production and environmental/sustainability data—it becomes possible to better understand environmental sustainability and predict future constraints such as water requirements, greenhouse emissions, energy and reagent inputs, and the like. This paper will therefore present a range of fundamental data and issues which help towards quantifying the resource and environmental sustainability of mining—with critical implications for the mining industry and society as a whole.