Chemical and toxicologic assessment of organic contaminants in surface water using passive samplers

Passive sampling methodologies were used to conduct a chemical and toxicologic assessment of organic contaminants in the surface waters of three geographically distinct agricultural watersheds. A selection of current-use agrochemicals and persistent organic pollutants, including polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and organochlorine pesticides, were targeted using the polar organic chemical integrative sampler (POCIS) and the semipermeable membrane device passive samplers. In addition to the chemical analysis, the Microtox assay for acute toxicity and the yeast estrogen screen (YES) were conducted as potential assessment tools in combination with the passive samplers. During the spring of 2004, the passive samplers were deployed for 29 to 65 d at Leary Weber Ditch, IN; Morgan Creek, MD; and DR2 Drain, WA. Chemical analysis of the sampler extracts identified the agrochemicals predominantly used in those areas, including atrazine, simazine, acetochlor, and metolachlor. Other chemicals identified included deethylatrazine and deisopropylatrazine, trifluralin, fluoranthene, pyrene, cis- and trans-nonachlor, and pentachloroanisole. Screening using Microtox resulted in no acutely toxic samples. POCIS samples screened by the YES assay failed to elicit a positive estrogenic response.     

Passive Samplers for NOx Monitoring: A Critical Review

Nitrogen oxide is an important gaseous air pollutant. It plays a major role in atmospheric chemistry, particularly in the formation of secondary air pollutants such as ozone, peroxyacyl nitrate (PAN), nitrate aerosols, and contributes to environmental acidification. A comprehensive assessment of NO₂ levels in the atmosphere is required for developing effective strategies for control of air pollution and improvement of air quality. Consequently, spatial NO₂ monitoring has become an important aspect of air quality assessment. Present NO₂ monitoring networks are mostly confined to urban areas, having a limited number of monitoring sites. Wide spatial NO₂ monitoring in India is constrained because of the limited availability of the monitoring equipment, such as continuous chemiluminesence monitors, high volume and handy samplers, which are expensive and need to be imported. Moreover, they require elaborate infrastructure, scientific personnel, technical support and uninterrupted power supply. In an effort to overcome the above shortcomings, passive samplers have been successfully used for large scale monitoring of NO₂ in the ambient environment.In recent years, passive samplers have been gaining increasing attention because they are simple, lightweight and cheap devices, which operate without any power source. Passive samplers have been found to be efficient, cost effective and free from the need for elaborate calibration and maintenance. Hence, they are ideally suited for developing a wide spatial network for NO₂ monitoring. This paper presents a comprehensive review including, historical development and critical assessment of validation studies along with comparison of both badge and tube type passive samplers. An attempt has been also made to highlight advantages and limitations, as well as discussion on the factors affecting the efficiency of passive samplers under field conditions.     

Passive monitoring of nitrogen dioxide in urban air: a case study of Durban metropolis, South Africa

To devise and implement strategies to manage the quality of urban air, a metropolis needs air pollution data on which an air quality management plan can be formulated. Although air pollutants can come from several sources, many reports suggest that nitrogen dioxide from motor vehicle emissions is the major contributor to air pollution in cities. Since vehicles stop or move slowly through traffic intersections, concentrations of nitrogen dioxide (NO(2)) are expected to be relatively high at these sites. Inexpensive Ogawa passive samplers were placed at selected traffic intersections in the Durban Metropolis to trap the NO(2) which was then analysed by a sensitive laboratory-based method. The data obtained by this method was compared with data from sophisticated system comprising an active sampler cum on-line chemiluminescence detector. The sampling was done over a twelve month period to cover all seasons. Statistical analysis of the data showed that there was no significant difference between the means for the two methods. This study has established that an Ogawa passive sampler may be used as an economical and reliable collector for NO(2) in ambient air under varying climatic conditions. Further, the analysis method using a UV-Visible spectrophotometer was sensitive enough to detect NO(2) at the 10-20 ppb level. The cost of the method should be well within the budgets of most municipalities and it would motivate them to develop policies to alleviate traffic congestion.     

DETRITUS ABUNDANCE AND BENTHIC INVERTEBRATE CATCH IN ARTIFICIAL SUBSTRATE SAMPLES FROM MOUNTAIN STREAMS1

ABSTRACT: Artificial substrates were designed using rock filled polyethylene bags which were perforated with holes. The substrates trapped waterborne sediment and detritus which enhanced microhabitat complexity. Colonization was compared in side-by-side tests with multiple plate samplers in mountain streams ranging from second to seventh order. After 41 days the bag samples contained more sediment and detritus and more animals than did multiple plates. Plastic bags exceeded multiple plate samples by a factor of nearly 8 for individuals and 1.5 for taxa expressed as numbers/sampler. Although detritus amounts differed significantly between samplers, catch composition was similar in habitat preference and functional groups. Most taxa were “lotic erosional” or “lotic erosional-depositional” detritivores. The plastic bags better represented the streambed fauna judged by their greater similarity to dip net samples. Bag samplers had 4.5 × the colonization area of multiple plates, hence would be expected to support more species. Catch/m² of colonization area was not significantly different between samplers. Functionally the plastic bags act as detritus retention devices, offering a diverse, highly dynamic microhabitat for colonization. Results are interpretable in terms of research on microdistribution of stream benthos and the river continuum model. This study supports the conclusion that stream benthos abundance and diversity are related to the amount of detritus. Maximum diversity and numbers of individuals occurred in samples from third and fourth order streams. Grazers reached peak abundances in the same streams where the continuum model predicts P>R Shredders reached maximum abundances in third and fourth order streams where the riparian canopy was greatest. Predator abundance changed little with stream size. Although bag samples required more sorting time, the samplers are catch effective, inexpensive, and adaptable.     

Evaluation of a System to Automatically Sample Zooplankton From the Discharge of Dams1

ABSTRACT: Automatic plankton samplers installed at two dams on the Connecticut River Continuously monitored crustacean zooplankton from October 1977 through 1979 and allowed a significant reduction in man-hours involved in an extensive sampling program. Automatic samplers efficiently sampled most species and size classes of crustacean zooplankton in a similar, but not consistently identical manner as a commonly used towed-net plankton sampler. The smallest sized zooplankton were captured more efficiently than the largest. Mesh selection and sampler avoidance exerted different influences on automatic samplers and towed nets. Future use of the samplers and direct comparison of results to results obtained by other methods was supported.     

EFFECTS OF SPATIAL ORIENTATION OF MULTIPLE PLATE ARTIFICIAL SUBSTRATES ON INVERTEBRATE COLONIZATION1

ABSTRACT: Jumbo multiple plate samplers were suspended in a river at 0.3 and 1 m depth in one of three orientations: interplate spaces closed to downwelling light and open to flow, open to light and flow, or open to light and closed to flow. Mean numbers of colonizing taxa and individuals were not significantly different among orientations after eight weeks of submergence. All variables tested decreased significantly with depth. Mean number of taxa, number of individuals (1 m only), and insect diversity decreased between samplings at four and eight weeks for samplers that were closed to light and open to flow. All orientations, depths, and durations had one-half to two-thirds of the total taxa. Colonization was affected by location in the river and position on sampler suspension equipment. The results indicate lack of orientation effects on colonization or high variability that obscured such effects. The sampler suspension equipment possibly increased among-sampler variability by forming artificial snag habitats, and interplate light and flow conditions at different orientations may not have been sufficiently distinct to elicit different biological responses. Individual samplers provided diverse microhabitats regardless of orientation, but it would be prudent to include orientation among the variables considered in use of multiple plate samplers.     

A BASKET SAMPLING TECHNIQUE FOR QUANTIFYING RIVERINE MACROBENTHOS1

ABSTRACT: A colonization basket sampling technique for quantifying macroinvertebrates in rubble bottom rivers is described. Basket samplers were compared to collections made using the Surber square foot sampler. Procedure for processing samples is described. Macrobenthos were more accurately quantified by basket samplers because both surface and subsurface habitats were sampled, no organisms were lost when samplers were removed from the river, substrata and associated fauna were retained for analysis, and the samplers were used efficiently in both pool and riffle areas. At the end of the colonization period the basket samplers contained one-half cubic foot of river bottom and macroinvertebrates spatially arranged within.     

A STAGE-ACTIVATED TRIGGERING DEVICE FOR AUTOMATIC PUMPING SAMPLERS1

A device to trigger automatic pumping samplers at discrete stages on headwater streams in southeastern Oklahoma was developed. The magnetic switch column employs a sequence of magnetic reed switches wired in parallel and set at 0.03 m (0.10 ft) intervals. A magnetic float inside the column closes the reed switches, therby triggering the sampler as stage rises and falls. The columns were constructed from inexpensive, readily-available materials. Following installation and field calibration, the columns provided relaible and representative sampling during 12 storms, at three sites. The magnetic switch column may be used in a wide range of research and monitoring sites to improve water quality sampling.     

A Depth‐Proportional Intake Device for Automatic Water Samplers1

Abstract: This paper describes the construction and testing of a device for pumping water samplers that collects suspended sediment samples by moving the intake vertically to keep it at the same proportion of flow depth. The device uses a simple sprocket mechanism that can be mounted vertically on the downstream side of culverts and bridge pilings to protect against damage from floating debris during storms. Suspended sediment samples collected from an urban stream with the depth‐proportional device were compared with manual samples taken with a depth‐integrated sampler. Scatter in the relationship between pumped and manual samples (R² = 0.76) are probably explained by horizontal variability in concentrations, poor mixing associated with lateral sediment inputs from construction site erosion, the downstream orientation of the intake, and the failure of the concentration at 60% of the flow depth to match the average vertical concentration.     

A Sampler for Measuring Deposited Fine Sediments in Streams1

Turner, Andy W., Jeff J. Hillis, and Charles F. Rabeni, 2012. A Sampler for Measuring Deposited Fine Sediments in Streams. Journal of the American Water Resources Association (JAWRA) 48(2): 366‐378. DOI: 10.1111/j.1752‐1688.2011.00618.x Abstract: Improvements and standardization of methodologies to quickly and accurately quantify deposited sediment in streams will allow advances in our understanding of biological effects of sedimentation. Most methods used to evaluate streambed conditions as part of biological monitoring or assessment programs are selected for ease of use, but can be subjective, inappropriate, and often of unknown accuracy. We developed a portable, light‐weight device to quantify deposited unconsolidated sediment (particles <2 mm) in wadeable streams. This deposited sediment sampler is a hand‐held unit that circumscribes an area of the streambed and through suction creates a force that suspends unconsolidated materials into a collector. Laboratory evaluations determined the efficiency (percent of available deposited sediment recovered) of the sampler to collect different sizes and concentrations of deposited sediment under differing streambed conditions, which allowed appropriate correction factors to be applied to each of four categories of streambed particle size. Field trials comparing our sampler to other methods commonly used by many state and federal agencies showed high comparability. The sampler can be constructed in just a few hours from inexpensive, easily obtained materials.     

DESIGN CONSIDERATIONS FOR AMBIENT STREAM QUALITY MONITORING1

ABSTRACT: Existing ambient water quality monitoring programs have resulted in data which are often unsuitable for assessment of water quality trends. A primary concern in designing a stream quality monitoring network is the selection of a temporal sampling strategy. It is extremely important that data for trend assessment be collected uniformly in time. Greatly superior trend detection power results for such a strategy as compared to stratified sampling strategies. In general, it is desirable that sampling frequencies be at least monthly but not greater than biweekly; higher sampling frequencies usually result in little additional information. An upper limit on trend detectability exists such that for both five and ten year base periods it is often impossible to detect trends in time series where the ratio of the trend magnitude to time series standard deviation is less than about 0.5. For the same record lengths trends in records with trend to standard deviation ratios greater than about one can usually be detected with very high power when a uniform sampling strategy is followed.     

MODIFYING AUTOMATED PUMPING SAMPLERS FOR USE IN SMALL MOUNTAIN STREAMS1

ABSTRACT: Two modifications to automated pumping samplers improve discrete sampling during high flow events in small mountain streams. One modification entails mounting the intake nozzle on a bent, free-swinging metal rod supported in midstream. This allows sampling in midstream yet prevents the buildup of floatable organic debris that otherwise would cause the intake to fail. On the lower end of the rod, dynamic forces exerted by the stream keep the intake submerged over diverse flow conditions. The second modification consists of a magnetic switching device that automatically activates the pumping sampler at any preset stage on the rising limb of a storm hydrograph. The pumping sampler then remains on to collect one sample per hour which allows field crews sufficient time to change bottles before the sampler fills its 28-bottle capacity. This device improves the capability to sample frequently at fixed intervals, yet with minimal maintenance between runoff events. It also ensures sample collection during the rising limb of the hydrograph when flow and sediment concentrations are rapidly changing. Both modifications have improved data collection during periods of storm runoff.     

A DIGITAL CONTROLLER FOR DISCRETE STAGE ACTIVATION OF AUTOMATIC PUMPING SAMPLERS1

ABSTRACT: An electronic controller was developed to facilitate water sampling at discrete stage heights in perennial mountain streams of southeast Oklahoma. The controller operates in conjunction with an automatic pumping sampler and a magnetic, relay transducer. In response to changes in stage, the transducer generates an electrical pulse when relays are closed by a magnetic float. The controller monitors these relay closures and signals the sampler to pump a single sample at each desired water level during both rising and falling stages. After a sample is taken, additional switch closures at that stage axe ignored until the relay immediately above or below is closed. Inadvertent switch closures caused by turbulent stage fluctuations are not translated to the sampler thus eliminating duplicate or multiple samples at a given stage. Field testing has proven this device to be a reliable component with a range of applications for improving water quality sampling systems. The controller features battery operation, low power consumption, circuit simplicity and can be easily constructed for less than $100, including parts and labor.     

COMPARISON OF FOUR ARTIFICIAL SUBSTRATES AND THE PONAR GRAB FOR BENTHIC INVERTEBRATE COLLECTION1

ABSTRACT: Four different bottom-placed artificial substrates were compared with the Ponar grab for collecting benthic invertebrates. Artificial substrate samples of organisms were larger and more diverse than those of the grab. Barbeque Basket samplers caught the most taxa and individuals and Beak Trays caught the least. Chironomids and crustaceans were dominant in artificial substrate samples. Exposure habitat (left or right bank) determined taxa availability, whereas sampler design determined suitability for colonization by the taxa. Diversity for Beak Tray samples was lower than that for other artificial substrates but higher than for Ponar samples. The Barbeque Basket, Bull Basket, and Multiple Plate samples were taxonomically similar. Ponar samples were different, and Beak Trays were of intermediate similarity. As qualitative samplers, Barbeque Baskets were 63 percent efficient, followed by Bull Baskets (55 percent), Multiple Plates (48 percent), Beak Trays (38 percent), and Ponar Grabs (6–10 percent). Bull Baskets required the least and Beak Trays the most replicates to be within a preselected percentage error of the mean at the 95 percent probability level for numbers of taxa and individuals, and for diversity. Under conditions of the study, Bull Baskets ranked highest, followed by Barbeque Baskets and Multiple Plates, in selected performance criteria. Differences between grab and artificial substrate samples are explainable in terms of major riverine habitats and characteristics of the collection methods.     

WATER QUALITY SAMPLING SCHEMES FOR VARIABLE FLOW CANALS AT REMOTE SITES1

ABSTRACT: Growing interest in water quality has resulted in the development of monitoring networks and intensive sampling for various constituents. Common purposes are regulatory, source and sink understanding, and trend observations. Water quality monitoring involves monitoring system design; sampling site instrumentation; and sampling, analysis, quality control, and assurance. Sampling is a process to gather information with the least cost and least error. Various water quality sampling schemes have been applied for different sampling objectives and time frames. In this study, a flow proportional composite sampling scheme is applied to variable flow remote canals where the flow rate is not known a priori. In this scheme, historical weekly flow data are analyzed to develop high flow and low flow sampling trigger volumes for auto‐samplers. The median flow is used to estimate low flow sampling trigger volume and the five percent exceedence probability flow is used for high flow sampling trigger volume. A computer simulation of high resolution sampling is used to demonstrate the comparative bias in load estimation and operational cost among four sampling schemes. Weekly flow proportional composite auto‐sampling resulted in the least bias in load estimation with competitive operational cost compared to daily grab, weekly grab sampling and time proportional auto‐sampling.     

Can urban development be made environmentally sound?

By concentrating the urban developmental pattern, confining new buildings to areas where technical encroachments on nature have previously taken place, and by utilizing each building site efficiently, considerable advantages can be achieved where the overall goal is to preserve nature and maintain environments. These are the main conclusions from analyses of different alternatives for land use and developmental patterns in three Norwegian urban areas. However, there is relatively little popular support for urban policies in favour of more conservation of land and less use of automobiles. Politicians and bureaucrats are less negative than voters to such a change in urban policies.     

Global monitoring of wetlands--the value of ENVISAT ASAR Global mode

This paper elaborates on recent advances in the use of ScanSAR technologies for wetland-related research. Applications of active satellite radar systems include the monitoring of inundation dynamics as well as time series analyses of surface soil wetness. For management purposes many wetlands, especially those in dry regions, need to be monitored for short and long-term changes. Another application of these technologies is monitoring the impact of climate change in permafrost transition zones where peatlands form one of the major land cover types. Therefore, examples from boreal and subtropical environments are presented using the analysed ENVISAT ASAR Global mode (GM, 1 km resolution) data acquired in 2005 and 2006. In the case of the ENVISAT ASAR instrument, data availability of the rather coarse Global Mode depends on request priorities of other competing modes, but acquisition frequency may still be on average fortnightly to monthly depending on latitude. Peatland types covering varying permafrost regimes of the West Siberian Lowlands can be distinguished from each other and other land cover by multi-temporal analyses. Up to 75% of oligotrophic bogs can be identified in the seasonal permafrost zone in both years. The high seasonal and inter-annual dynamics of the subtropic Okavango Delta can also be captured by GM time series. Response to increased precipitation in 2006 differs from flood propagation patterns. In addition, relative soil moisture maps may provide a valuable data source in order to account for external hydrological factors of such complex wetland ecosystems.     

用β射线衰减法测定颗粒物的准确性和有效性验证

通过在线监测系统用β射线衰减法测定空气中颗粒物的工作原理、测试数据准确性和有效性。将参比采样器监测数据(重量法)与相应的自动采样器监测数据(β射线衰减法)进行不确定评估和平行性、线性回归分析验证。从而得出,在线监测系统用β射线衰减法测定空气中颗粒物时有较好的线性关系,监测数据准确、可靠,具有一定推广价值。同时,为提高环境监测能力、加强环境执法监管提供可靠依据。     

EVALUATION OF A DEPTH PROPORTIONAL INTAKE DEVICE FOR AUTOMATIC PUMPING SAMPLERS1

ABSTRACT: A depth proportional intake boom for portable pumping samplers was used to collect suspended sediment samples in two coastal streams for three winters. The boom pivots on the stream bed while a float on the downstream end allows debris to depress the boom and pass without becoming trapped. This equipment modifies point sampling by maintaining the intake nozzle at the same proportion of water depth regardless of stage. Data taken by pumping samplers with intakes mounted on the boom were compared with depth integrated hand samples. Pumped samples showed higher concentrations than depth integrated hand samples. Results suggested that cross-sectional sampling can give high precision with proper placement and calibration of a boom mounted intake.     

Climatic hazards warning process in Bangladesh: Experience of,and lessons from,the 1991 April cyclone

Science and technology cannot control entirely the causes of natural hazards. However, by using multifaceted programs to modify the physical and human use systems, the potential losses from disasters can effectively be minized. Predicting, identifying, monitoring, and forecasting extreme meteorological events are the preliminary actions towards mitigating the cyclone-loss potential of coastal inhabitants, but without the successful dissemination of forecasts and relevant information, and without appropriate responses by the potential victims, the loss potential would probably remain the same. This study examines the process through which warning of the impending disastrous cyclone of April 1991 was received by the local communities and disseminated throughout the coastal regions of Bangladesh. It is found that identification of the threatening condition due to atmospheric disturbance, monitoring of the hazard event, and dissemination of the cyclone warning were each very successful. However, due to a number of socioeconomic and cognitive factors, the reactions and responses of coastal inhabitants to the warning were in general passive, resulting in a colossal loss, both at the individual and national level. The study recommends that the hazard mitigation policies should be integrated with national economic development plans and programs. Specifically, it is suggested that, in order to attain its goals, the cyclone warning system should regard the aspects of human response to warnings as a constituent part and accommodate human dimensions in its operational design.