Design and off-design analyses of a pre-combustion CO2 capture process in a natural gas combined cycle power plant

In this study, a cycle designed for capturing the greenhouse gas CO₂ in a natural gas combined cycle power plant has been analyzed. The process is a pre-combustion CO₂ capture cycle utilizing reforming of natural gas and removal of the carbon in the fuel prior to combustion in the gas turbine. The power cycle consists of a H₂-fired gas turbine and a triple pressure steam cycle. Nitrogen is used as fuel diluent and steam is injected into the flame for additional NO_x control. The heat recovery steam generator includes pre-heating for the various process streams. The pre-combustion cycle consists of an air-blown auto-thermal reformer, water–gas shift reactors, an amine absorption system to separate out the CO₂, as well as a CO₂ compression block. Included in the thermodynamic analysis are design calculations, as well as steady-state off-design calculations. Even though the aim is to operate a plant, as the one in this study, at full load there is also a need to be able to operate at part load, meaning off-design analysis is important. A reference case which excludes the pre-combustion cycle and only consists of the power cycle without CO₂ capture was analyzed at both design and off-design conditions for comparison. A high degree of process integration is present in the cycle studied. This can be advantageous from an efficiency stand-point but the complexity of the plant increases. The part load calculations is one way of investigating how flexible the plant is to off-design conditions. In the analysis performed, part load behavior is rather good with efficiency reductions from base load operation comparable to the reference combined cycle plant.     

CO2 capture from combined cycles integrated with Molten Carbonate Fuel Cells

In this paper Molten Carbonate Fuel Cells (MCFCs) are considered for their potential application in carbon dioxide separation when integrated into natural gas fired combined cycles. The MCFC performs on the anode side an electrochemical oxidation of natural gas by means of CO₃^2? ions which, as far as carbon capture is concerned, results in a twofold advantage: the cell removes CO₂ fed at the cathode to promote carbonate ion transport across the electrolyte and any dilution of the oxidized products is avoided.The MCFC can be “retrofitted” into a combined cycle, giving the opportunity to remove most of the CO₂ contained in the gas turbine exhaust gases before they enter the heat recovery steam generator (HRSG), and allowing to exploit the heat recovery steam cycle in an efficient “hybrid” fuel cell + steam turbine configuration. The carbon dioxide can be easily recovered from the cell anode exhaust after combustion with pure oxygen (supplied by an air separation unit) of the residual fuel, cooling of the combustion products in the HRSG and water separation. The resulting power cycle has the potential to keep the overall cycle electrical efficiency approximately unchanged with respect to the original combined cycle, while separating 80% of the CO₂ otherwise vented and limiting the size of the fuel cell, which contributes to about 17% of the total power output so that most of the power capacity relies on conventional low cost turbo-machinery. The calculated specific energy for CO₂ avoided is about 4 times lower than average values for conventional post-combustion capture technology. A sensitivity analysis shows that positive results hold also changing significantly a number of MCFC and plant design parameters.     

Land use change and carbon exchange in the tropics: II. Estimates for the entire region

Determining the effect of tropical land use on the carbon dioxide (CO₂) content of the atmosphere requires: (a) estimates of the rates of land use change, (b) estimates of the difference between the carbon stored in forests and that stored in pastures and cultivated fields, and (c) a consideration of the fate of carbon stored in the cleared vegetation. The first article of this series analyzed land use in four tropical countries and estimated the carbon released to the atmosphere as a consequence of changes in land use. This article estimates the carbon released from the entire tropical region based on the two published studies of land use change for the tropics as a whole that distinguish between temporary and permanent land use: Seiler and Crutzen (1980) and Lanly (1982). We combine these estimates with two estimates of the difference in carbon storage between forests and fields derived from Whittaker and Likens (1975) and Brown and Lugo (1982), and the two scenarios of the fate of cleared vegetation, developed in the previous article, to produce several complete sets of data describing the necessary parameters to calculate carbon exchange. These data sets, entered into our model, produce a range of estimates of the annual release of carbon from tropical vegetation in 1980 of from 0.6 to 1.8 BMT/year, with the more likely range being 0.9–1.2 BMT/year. Our preliminary analysis suggests that the release from tropical soils due to land use change adds about an additional 0.3 BMT C/year, so that the total release is probably between 1.2 and 1.5 BMT C/year. Peng and others (1983) reported that new models of the oceanic carbon cycle can accommodate at least 1.2 BMT C/year in 1980 from forests and soils. Our results indicate that, given the uncertainties in the size of both the biotic release and oceanic uptake, the global carbon budget may be balanced if there is no significant release from nontropical ecosystems due to land use change and all mature ecosystems are in collective equilibrium with the atmosphere.     

Rubber tire life cycle assessment and the effect of reducing carbon footprint by replacing carbon black with graphene

This research utilizes real operating data from a tire plant operating in Central Taiwan to investigate the carbon footprint emissions (CO₂e) involved in producing the electric bicycle. The simulation results are based on the PAS 2050 standard using the SimaPro 7.3 software tool. Our results show the total carbon footprint emissions of 1.2-kg tire for the electric bicycle weighing 4.53-kg CO₂e, composed of 2.63-kg CO₂e from raw tire materials stage, 1.295-kg CO₂e from tire manufacturing stage, and 0.605-kg CO₂e from tire transport stage. An international certified organization, British Standard Institute (BSI), verified the accuracy of our results as 98.7%. We found that carbon emissions at the raw materials stage were higher than that for the other two stages – manufacturing and transportation. Carbon black was determined as the maximum source of carbon emissions at the raw material stage. To reduce the tire plant carbon emissions, this paper recommends using graphene to replace carbon black. Graphene has been reported by many researches to improve the properties of rubber products. From our simulation results, the carbon footprint emissions of 4.56-kg CO₂e of the origin tire plant uses 0.456-kg carbon black to produce 1.2-kg electric bicycle tires. This can be reduced to 4.29 (5.92%), 4.03 (11.62%), 3.75 (11.76%), and 3.49-kg CO₂e (23.46%) by using graphene to replace carbon black 25, 50, 75, and 100 wt% respectively. If we focus only on 0.456-kg carbon black producing 1.08-kg CO₂e, the reduced carbon footprint will be 0.812 (24.81%), 0.547 (49.35%), 0.28 (74.07%), and 0.0128-kg CO₂e (98.81%) by using graphene to replace carbon black 25, 50, 75, and 100 wt% respectively. From our analysis, graphene replacing carbon black can reduce carbon footprint. This has not been published previously and provides a direction for the tire plant to save carbon emissions.     

Implications of Land Use Changes on Carbon Dynamics and Sequestration—Evaluation from Forestry Datasets, India

Forests and soils are a major sink of carbon, and land use changes can affect the magnitude of above ground and below ground carbon stores and the net flux of carbon between the land and the atmosphere. Studies on methods for examining the future consequences of changes in patterns of land use change and carbon flux gains importance, as they provide different options for CO₂ mitigation strategies. In this study, a simulation approach combining Markov chain processes and carbon pools for forests and soils has been implemented to study the carbon flows over a period of time. Markov chains have been computed by converting the land use change and forestry data of India from 1997 to 1999 into a matrix of conditional probabilities reflecting the changes from one class at time t to another class time t+1. Results from Markov modeling suggested Indian forests as a potential sink for 0.94 Gt carbon, with an increase in dense forest area of about 75.93 Mha and decrease of about 3.4 Mha and 5.0 Mha in open and scrub forests, if similar land use changes that occurred during 1997–1999 would continue. The limiting probabilities suggested 34.27 percent as dense forest, 6.90 as open forest, 0.4 percent mangrove forest, 0.1 percent scrub and 58 percent as non-forest area. Although Indian forests are found to be a potential carbon sink, analysis of results from transition probabilities for different years till 2050 suggests that, the forests will continue to be a source of about 20.59 MtC to the atmosphere. The implications of these results in the context of increasing anthropogenic pressure on open and scrub forests and their contribution to carbon source from land use change and forestry sector are discussed. Some of the mitigation aspects to reduce greenhouse gas emissions from land use change and forestry sector in India are also reviewed in the study.     

The Application of the Ecological Footprint: A case of passenger transport in Merseyside

The release of carbon dioxide from the burning of fossil fuels is believed to be responsible for climate change. In the UK, road transport emits 22% of the total output of carbon dioxide. This study applies the ecological footprint to Merseyside to ascertain the global environmental impact of passenger transport (expressed in hectares). Results show that car travel has a footprint of 704 000 hectares, which is 87% of the total footprint. It is demonstrated in scenarios that Policy initiatives involving the Local Transport Plan will cause the footprint to increase. It is also shown that individual behaviour could be influenced when highlighting the impacts of different modes of transport along the same route. By using the ecological footprint in educational programmes, the effect can be shown of carbon emissions and land appropriation on the 'school run'; these issues could be promoted alongside others such as health, safety, congestion, global equity and fairness.     

A targeted social marketing approach for community pro-environmental behavioural change

Community-level initiatives will play a key role in meeting greenhouse gas reduction targets. This paper examines the experience gained in applying a targeted social marketing approach to foster local-scale community pro-environmental behavioural change in the City of York, UK. This involved determining the neighbourhood carbon footprint, identifying residents that had access to appropriate infrastructure and were receptive to green issues. Six community teams were recruited from the selected neighbourhoods and provided with information, advice and mentoring on how to reduce their carbon footprint over a six-month period. A statistically significant reduction in carbon emissions was achieved. Each participant achieved a mean reduction in their carbon footprint of 2.0 tonnes of CO₂e/year. The largest reductions were achieved in the areas of shopping and home energy. In addition, it helped to foster community spirit. Based on the experience gained from implementing this approach, a cost-effective model of community engagement is proposed.     

The Application of the Ecological Footprint: a case of passenger transport in Merseyside

The release of carbon dioxide from the burning of fossil fuels is believed to be responsible for climate change. In the UK, road transport emits 22% of the total output of carbon dioxide. This study applies the ecological footprint to Merseyside to ascertain the global environmental impact of passenger transport (expressed in hectares). Results show that car travel has a footprint of 704 000 hectares, which is 87% of the total footprint. It is demonstrated in scenarios that Policy initiatives involving the Local Transport Plan will cause the footprint to increase. It is also shown that individual behaviour could be influenced when highlighting the impacts of different modes of transport along the same route. By using the ecological footprint in educational programmes, the effect can be shown of carbon emissions and land appropriation on the 'school run'; these issues could be promoted alongside others such as health, safety, congestion, global equity and fairness.     

Land use change effects on forest carbon cycling throughout the southern United States

We modeled the effects of afforestation and deforestation on carbon cycling in forest floor and soil from 1900 to 2050 throughout 13 states in the southern United States. The model uses historical data on gross (two-way) transitions between forest, pasture, plowed agriculture, and urban lands along with equations describing changes in carbon over many decades for each type of land use change. Use of gross rather than net land use transition data is important because afforestation causes a gradual gain in carbon stocks for many decades, while deforestation causes a much more rapid loss in carbon stocks. In the South-Central region (Texas to Kentucky) land use changes caused a net emission of carbon before the 1980s, followed by a net sequestration of carbon subsequently. In the Southeast region (Florida to Virginia), there was net emission of carbon until the 1940s, again followed by net sequestration of carbon. These results could improve greenhouse gas inventories produced to meet reporting requirements under the United Nations Framework Convention on Climate Change. Specifically, from 1990 to 2004 for the entire 13-state study area, afforestation caused sequestration of 88 Tg C, and deforestation caused emission of 49 Tg C. However, the net effect of land use change on carbon stocks in soil and forest floor from 1990 to 2004 was about sixfold smaller than the net change in carbon stocks in trees on all forestland. Thus land use change effects and forest carbon cycling during this period are dominated by changes in tree carbon stocks.     

Pre-combustion CO2 capture from natural gas power plants,with ATR and MDEA processes

Among the various configurations of fossil fuel power plants with carbon capture, this paper focuses on pre-combustion techniques applied to natural gas combined cycles. With more detail, the plant configuration here addressed includes: (i) the steam reforming of natural gas, based on an air-blown autothermal process, following a recuperative pre-reforming treatment, (ii) the water gas shift producing CO₂ and H₂, (iii) the separation of CO₂ by means of a mixed physical–chemical absorption system using a MDEA solution, and (iv) a hydrogen fuelled combined cycle.Similar configurations have been studied quite extensively, being among the most attractive for full-scale realizations in a near-mid term future. This paper proposes a detailed thermodynamic study and optimization of the plant configuration, bringing to a reliable performance estimation based on today's best available technology as far as the various plant sections are concerned (gas and steam turbine, natural gas reforming process, CO₂ separation). The predicted LHV efficiency for the base configuration is about 50%. Being this value at the top of the range quoted in the open literature studies (35–50%), the paper includes a quite extensive sensitivity analysis, showing that more conservative assumptions may bring to significantly poorer performance, especially considering the pretty large number of operating parameters involved in the process.     

A qualitative reliability and operability analysis of an integrated reforming combined cycle plant with CO2 capture

Most of the current CO₂ capture technologies are associated with large energy penalties that reduce their economic viability. Efficiency has therefore become the most important issue when designing and selecting power plants with CO₂ capture. Other aspects, like reliability and operability, have been given less importance, if any at all, in the literature.This article deals with qualitative reliability and operability analyses of an integrated reforming combined cycle concept. The plant reforms natural gas into a syngas, the carbon is separated out as CO₂ after a water-gas shift section, and the hydrogen-rich fuel is used for a gas turbine. The qualitative reliability analysis in the article consists of a functional analysis followed by a failure mode, effects, and criticality analysis (FMECA). The operability analysis introduces the comparative complexity indicator (CCI) concept.Functional analysis and FMECA are important steps in a system reliability analysis, as they can serve as a platform and basis for further analysis. Also, the results from the FMECA can be interesting for determining how the failures propagate through the system and their effects on the operation of the process. The CCI is a helpful tool in choosing the level of integration and to investigate whether or not to include a certain process feature. Incorporating the analytical approach presented in the article during the design stage of a plant can be advantageous for the overall plant performance.     

Land use change and carbon exchange in the tropics: I. Detailed estimates for Costa Rica,Panama, Peru,and Bolivia

Our group, composed of modelers working in conjunction with tropical ecologists, 3 has produced a simulation model that quantifies the net carbon exchange between tropical vegetation and the atmosphere due to land use change. The model calculates this net exchange by combining estimates of land use change with several estimates of the carbon stored in tropical vegetation and general assumptions about the fate of cleared vegetation. In this report, we use estimates of land use and carbon storage organized into sixlife zone (sensu Holdridge) categories to calculate the exchange between the atmosphere and the vegetation of four tropical countries. Our analyses of these countries indicate that this life zone approach has several advantages because (a) the carbon content of vegetation varies significantly among life zones, (b) much of the land use change occurs in life zones of only moderate carbon storage, and (c) the fate of cleared vegetation varies among life zones. Our analyses also emphasize the importance of distinguishing between temporary and permanent land use change, as the recovery of vegetation on abandoned areas decreases the net release of carbon due to clearing. We include sensitivity analysis of those factors that we found to be important but are difficult to quantify at present.     

Coal energy conversion with carbon sequestration via combustion in supercritical saline aquifer water

The standard idea for deep saline aquifer sequestration is to separate carbon dioxide from a process stream, compress it, and inject it underground. However, since carbon dioxide is less dense than water, even at the high pressures found in aquifers, it is buoyant and will move towards the surface unless trapped by an impermeable seal. Also, significant energy expenditure is required to separate and compress carbon dioxide, even though neat carbon dioxide is not a desired product. These issues may be addressed by combining the idea of fast dissolution at the surface with supercritical water oxidation (SCWO). By burning coal at high pressure in supercritical water drawn from an aquifer, and then sequestering the entire pre-equilibrated effluent, all carbon from the fuel is captured, as well as all non-mineral coal combustion products including sulfur and metals.A possible block diagram of an SCWO-based electric power plant is proposed, including processes to handle salts from the aquifer brine and minerals from coal. The plant is thermodynamically modeled, using an indirectly fired combined cycle to convert energy from hot combustion products to work. This model estimates the overall thermal efficiency that can be achieved, and reveals unanticipated interactions within the plant that have significant effects on efficiency. The assumptions and results of the model highlight design challenges for an actual system.     

基于生命周期的产品碳足迹评价与核算分析

近年来,越来越多的企业对其产品进行碳足迹评价,评价方法主要采用产品碳足迹评价标准提供的碳计量方程,如GHG Protocol、ISO14064、PAS 2050、TS Q 0010等。在介绍相关评价标准的基础上,分析了产品碳足迹的评价步骤,最后利用河北盛华化工有限公司生产的PVC产品为例,给出了基于生命周期的B2B模式的产品碳足迹评价的案例。为企业及相关机构开展碳足迹评价提供借鉴作用。     

Long-term coal gasification-based power plants with near-zero emissions. Part A: Zecomix cycle

These two part papers analyse three plant configurations for high efficiency, near-zero emissions power generation from coal, suitable for long-term installations. In the first part the Zecomix cycle, a novel power plant based on various innovative processes, is presented. Zecomix plant is based on a coal hydrogasification process, using recycled steam and hydrogen as gasifying agents, to produce a CH₄ rich syngas. Methane is then converted to an H₂/H₂O based syngas and CO₂ is captured, by reacting in two carbonator reactors with CaO-based solid sorbent. CaCO₃ produced in carbonators is thermally regenerated in a calciner. The synthetic fuel is burned with oxygen in a semi-closed high temperature steam cycle, with a supercritical heat recovery.The paper presents a detailed analysis of the thermodynamic aspects of the process, with the scope of assessing its potential performance in terms of efficiency and emissions. Main operating parameters of the chemical island (e.g. hydrogasifier and calciner pressure, steam flow rates to carbonators, syngas recycle fraction) and of the power island (e.g. pressure ratio, turbine inlet temperature and reheat pressure) were varied in order to evaluate their effect on plant performance and to optimize the process. Critical issues are specifically discussed: the calcination process, the calcium oxide utilization in carbonators, the cooling requirement of the high temperature turbine, the presence of incondensable species in the steam cycle. An accurate performance estimation is therefore developed by considering advanced components, as an evolution of today's technology, excluding unproven devices whose feasibility cannot be anticipated.Depending on sorbent utilization, a net plant efficiency of 44–47% with a virtually complete carbon capture was obtained, a very interesting result with respect to other proposed coal-fired power plants with carbon capture. The high complexity of the chemical island and the importance of a good sorbent performance should be however taken into account for a fair comparison with other plant concepts. Further experimental investigations are mandatory to demonstrate the technical and economical feasibility of the Zecomix plant.     

Impact of closed-loop network configurations on carbon footprints: A case study in copiers

Growing concerns about the environment make a supply chains’ eco-footprint increasingly important, presuming that footprints are a more effective (policy) instrument than those currently in use. The eco-footprint comprises all kinds of environmental impact, but often is narrowed down to one aspect; e.g. the carbon footprint, material footprint, the water footprint, and so on. Although returns give rise to an additional goods flow from customers back to producers, it usually improves the eco-footprint due to the substitution effect. The reverse channel supplies high quality (recovered) products, components and materials to the forward channel thereby reducing the need for virgin sourcing and production. We refer to this as closed-loop recovery, as opposed to recovery for cascade markets which lacks substitution. To maximize substitution, the recovered items must re-enter the original supply chain. The feasibility of closed-loop recovery depends partly on the geographical proximity of forward and reverse facilities. We develop a decision framework for optimizing closed loop network configurations, i.e. the combined disposition and location–transport decision. We apply the framework to a single case study concerning one type of footprint (namely the carbon footprint) of a copier (closed-loop) supply chain. The main implication is that a regional network, with combined forward and reverse facilities per continent, proves most efficient and most robust in view of uncertain exogenous variables, but only when a full set of closed-loop options is available (including closed-loop recycling). As an embedded case, main contribution value of it lies in the discovery of a new phenomenon with generic implications; namely that not only the closed-loop supply chains footprint strongly depends on the substitution effect, but that in turn the feasibility of closed-loop recovery options depends heavily on the network design. From delineations of the study we derive issues for further research.     

Exergoeconomic and exergoenvironmental analyses of a combined cycle power plant with chemical looping technology

CO₂ capture and storage from energy conversion systems is one option for reducing power plant CO₂ emissions to the atmosphere and for limiting the impact of fossil-fuel use on climate change. Among existing technologies, chemical looping combustion (CLC), an oxy-fuel approach, appears to be one of the most promising techniques, providing straightforward CO₂ capture with low energy requirements.This paper provides an evaluation of CLC technology from an economic and environmental perspective by comparing it with to a reference plant, a combined cycle power plant that includes no CO₂ capture. Two exergy-based methods, the exergoeconomic and the exergoenvironmental analyses, are used to determine the economic and environmental impacts, respectively. The applied methods facilitate the iterative optimization of energy conversion systems and lead towards the improvement of the effectiveness of the overall plant while decreasing the cost and the environmental impact of the generated product. For the plant with CLC, a high increase in the cost of electricity is observed, while at the same time the environmental impact decreases.     

对燃油征税的区域能源环境影响研究:以中国为例

控制汽柴油消费对中国的能源安全和环境保护有着重要意义.燃油税和碳税是中国近期两种主要的已经或可能施加于燃油的税收政策.以自回归分布滞后模型为核心,本研究构建了一个燃油税和碳税的区域能源环境影响评估模型.利用模型估计了我国的燃油需求价格弹性,测算了燃油需求响应,计算了在相同CO2减排目标下,提高汽油消费税、提高柴油消费税、引入碳税三种政策情景下各省份预计产生的节能效应、减排效应和税收效益.研究结果显示,在相同的CO2减排目标下,第一,在不同情景下,各省份节能程度差异均有限,但节能数量均体现出区域匹配性,燃油消费越多的省份,节能数量一般越多,且提高汽油消费税的全国节能总量最大;第二,在引入碳税情景下,各省份CO2减排比例差异最小;第三,在全国层面,三种政策情景中空气污染物(PM2.5和NOx和SO2)减排数量均为提高汽油消费税>引入碳税>提高柴油消费税,但在提高柴油消费税情景下,有4/5的省份预计PM2.5排放减少程度超过14%.除此之外,提高汽油消费税的税收收益最大.     

Life cycle assessment of natural gas combined cycle power plant with post-combustion carbon capture,transport and storage

Hybrid life cycle assessment has been used to assess the environmental impacts of natural gas combined cycle (NGCC) electricity generation with carbon dioxide capture and storage (CCS). The CCS chain modeled in this study consists of carbon dioxide (CO₂) capture from flue gas using monoethanolamine (MEA), pipeline transport and storage in a saline aquifer.Results show that the sequestration of 90% CO₂ from the flue gas results in avoiding 70% of CO₂ emissions to the atmosphere per kWh and reduces global warming potential (GWP) by 64%. Calculation of other environmental impacts shows the trade-offs: an increase of 43% in acidification, 35% in eutrophication, and 120–170% in various toxicity impacts. Given the assumptions employed in this analysis, emissions of MEA and formaldehyde during capture process and generation of reclaimer wastes contributes to various toxicity potentials and cause many-fold increase in the on-site direct freshwater ecotoxicity and terrestrial ecotoxicity impacts. NO_x from fuel combustion is still the dominant contributor to most direct impacts, other than toxicity potentials and GWP. It is found that the direct emission of MEA contribute little to human toxicity (HT < 1%), however it makes 16% of terrestrial ecotoxicity impact. Hazardous reclaimer waste causes significant freshwater and marine ecotoxicity impacts. Most increases in impact are due to increased fuel requirements or increased investments and operating inputs.The reductions in GWP range from 58% to 68% for the worst-case to best-case CCS system. Acidification, eutrophication and toxicity potentials show an even large range of variation in the sensitivity analysis. Decreases in energy use and solvent degradation will significantly reduce the impact in all categories.     

Grassland Plant Composition Alters Vehicular Disturbance Effects in Kansas,USA

Many “natural” areas are exposed to military or recreational off-road vehicles. The interactive effects of different types of vehicular disturbance on vegetation have rarely been examined, and it has been proposed that some vegetation types are less susceptible to vehicular disturbance than others. At Fort Riley, Kansas, we experimentally tested how different plant community types changed after disturbance from an M1A1 Abrams tank driven at different speeds and turning angles during different seasons. The greatest vegetation change was observed because of driving in the spring in wet soils and the interaction of turning while driving fast (vegetation change was measured with Bray-Curtis dissimilarity). We found that less vegetation change occurred in communities with high amounts of native prairie vegetation than in communities with high amounts of introduced C₃ grasses, which is the first experimental evidence we are aware of that suggests plant communities dominated by introduced C₃ grasses changed more because of vehicular disturbance than communities dominated by native prairie grasses. We also found that vegetation changed linearly with vehicular disturbance intensity, suggesting that at least initially there was no catastrophic shift in vegetation beyond a certain disturbance intensity threshold. Overall, the intensity of vehicular disturbance appeared to play the greatest role in vegetation change, but the plant community type also played a strong role and this should be considered in land use planning. The reasons for greater vegetation change in introduced C₃ grass dominated areas deserve further study.