Mechanical separation-oriented characterization of electronic scrap

The ever-increasing amount of electronic scrap and the steadily-decreasing contents of the precious metals used in electronics, as well as the ever-growing environmental awareness, challenges such conventional precious-metal-oriented recycling techniques as pyrometallurgy. Separation and beneficiation of various materials encountered in electronic scrap might provide a correct solution ahead. In this context, mechanical separation-oriented characterization of electronic scrap was conducted in an attempt to evaluate the amenability of mechanical separation processes. Liberation degrees of various metals from the non-metals, which are crucial for mechanical separation, were analyzed by means of a grain counting approach. It is found that the metallic particles below 2 mm achieve almost complete liberation. Particle shapes were also quantified through an image processing system. The results obtained show that the shapes of the particles, as a result of shredding, turn out to be heterogeneous, thereby complicating mechanical separation processes. In addition, separability of various materials was ascertained by a sink–float analysis. It has been shown that density-based separation techniques shall be viable in separating metals from plastics, light plastics (ABS, PS and PVC, etc.) from glass fiber reinforced resins and aluminum from heavy metals. Specifically, a high quality copper concentrate can be expected by density-based separation techniques. Moreover, FT-IR spectra of plastics pieces from the light fractions after the sink–float testing show that PC scrap primarily contains ABS, PS and PVC plastics with the density range of +1.0–1.5 g/cm³, whereas PCB scrap mainly contains glass fiber reinforced epoxy resins plastics with the density range of +1.5–2.0 g/cm³.     

Long-term global availability of steel scrap

Primary steelmaking involves CO₂-intensive processes, but the expansion of secondary steel production is limited by the global availability of steel scrap. The present work examines global scrap consumption in the past (1870–2012) and future scrap availability (2013–2050) based on the historical trend. The results reveal that (i) historically, the consumption of old scrap has been insufficient compared with the amounts of discarded steel, and (ii) based on historical scrap consumption, the future availability of scrap will not be sufficient to satisfy the two assumed cases of steel demand. Primary steelmaking is expected to remain the dominant process, at least up until 2050. Under the reference-demand case of 2.19 billion tons in crude steel production by 2050, the total production of pig iron and direct reduced iron could reach 1.35 billion tons. Consumption of old scrap could reach 0.76 billion tons. Because the availability of scrap will be limited in the context of the global total, it is important to research and develop innovative low-carbon technologies for primary steelmaking and to explore their economic viability if we are to aim for achieving large reductions in CO₂ emissions from the iron and steel industry.     

我国废有色金属拆解利用再生产业发展现状

阐述了我国废金属拆解利用产业发展现状及存在的主要问题,提出了应对废金属拆解再生产业加强政府引导、加强回收体系建设、研发推广先进技术和改善税收政策等对策建议。     

Metals recycling in the United States

Twenty-two metals for which secondary recovery is important, in terms of quantity and/or value, were compared and ranked for rate and efficiency of recycling, and availability of recycled metal. In general, their recycling rates trended upward over the period 1970–1993. Iron, aluminum, copper, gold, platinum, and lead accounted for most of the value of all secondary metal produced, while iron and steel dominated in terms of quantity produced and exported. The factors most influential on recycling rates are profitability, public support, organization of infrastructure, sortability, legislative support, and scrap purity. The share of supply accounted for by secondary metals is expected to surpass that of primary metals sometime in the next decade.     

Copper recycling and scrap availability

According to existing estimates, available old copper scrap has more than tripled over the past 40 years. Secondary production (that is, copper produced from recycling old scrap), however, has only doubled. Indeed, over the past 10 years, while copper consumption and primary production have continued to expand briskly, while available old scrap has increased by over 35%, secondary production has actually stagnated.For a world concerned with sustainable development and the quality of the earth's environment, this performance is disappointing and in need of explanation. Other things being equal, one would expect the amount of recycling to increase with the availability of scrap, as many econometric models of the world copper market developed over the past several decades explicitly assume.The key to understanding sluggish growth in secondary production, this paper argues, is distinguishing carefully between (1) the flow of old scrap that arrives each year from products reaching the end of their useful lives during the year and (2) the available stock of old scrap that was not recycled during earlier years presumably because it was too costly to do so. Using an econometric model, the paper shows that old scrap stocks, which have contributed most of the increase in available old copper scrap over the years, have a very modest impact on secondary production. Old scrap flows have a much greater effect, but they account for only about 4% of the available old scrap for any given year.     

Price and volatility transmission between primary and scrap metal markets

The relationship between primary and scrap prices has been hypothesized for the most part as unidirectional, characterized by spillovers from primary to scrap prices. The purpose of this study is to evaluate empirically the dynamic interactions between primary and scrap metal prices through multivariate time series methods. In addition, the study expands the investigation at the level of volatility transmission, which has not been previously examined. The metal prices utilized are for copper, lead, and zinc for the period 1984–2001. The paper demonstrates differing long run and short run links. Scrap prices do not improve the long run interpretation of primary prices, but information flows from the scrap to the primary markets exist in the short run. Additionally, the copper and lead markets exhibit bidirectional information flows in terms of volatility transmission. The analysis provides valuable insight into the interactions of the primary and scrap metal sectors which can be used to improve forecasting and planning.     

Incorporation of neural network analysis into a technique for automatically sorting lightweight metal scrap generated by ELV shredder facilities

In an attempt to improve the technique of automatic sorting of lightweight metal scrap by sensing apparent density and three-dimensional shape, realized by the combination of a three-dimensional (3D) imaging camera and a meter to weigh a moving object on a conveyor belt, neural network analysis was integrated into the scrap identification algorithm, and its effect on the sorting accuracy of this technique was examined using approximately 1750 pieces of scrap sampled at three different end-of-life vehicle (ELV) shredder facilities. As a result, the newly developed algorithm, in which an unknown fragment is identified by passing through two discriminant analyses and one neural network analysis, was demonstrated to greatly decrease the time required for data analysis to prepare the identification algorithm without reducing the sorting accuracy. The average sorting accuracy for a mixture of three types of lightweight metal fragments was found to be 85%, based on the fact that the fist-sized fragments of cast aluminum, wrought aluminum, and magnesium sampled at the three ELV shredder facilities had similar apparent densities and 3D shapes. It was also suggested that still higher sorting performance is possible by repeating the procedure of modifying the database and re-learning of the neural network in the identification algorithm.     

Historical evolution of anthropogenic aluminum stocks and flows in Italy

Dynamic stocks and flows analysis was applied to the anthropogenic aluminum cycle in Italy in order to detect and quantify metal flows and in-use stocks over the years 1947–2009. The model utilized a top-down approach, including data for production, consumption, loss, and trade flows of aluminum. Seven end-use markets were considered, namely buildings and construction, transportation, consumer durables, machinery and equipment, electrical engineering, containers and packaging, and miscellaneous appliance types. The results of this dynamic stocks and flows analysis model quantified the contemporary anthropogenic reservoirs (or in-use stocks) of aluminum at about 320 kg per capita, mainly embedded within the transportation and building and construction sectors. Cumulative in-use stock represents approximately 11 years of supply at current usage rates (about 20 Mt versus 1.7 Mt/year), implying significant potential for recycling in the future as this stock comes out of use. Flow analysis revealed that Italy imports mainly unwrought aluminum and exports final products, while the main material losses occur during alumina refining and collection of old scrap: specifically, containers and packaging have the highest old scrap generation rate, but for the lowest recovery rate (50%). Increasing support to collection of scrap and initiatives oriented to aluminum recovery specifically would allow Italy to increase its reliance on domestic material, and may also allow a decline of the country import-dependence on primary sources. The dynamic stocks and flows model created here provides a quantitative historical record of the aluminum required by Italian society during important periods of development and provides guidance for future decision-making around the use of domestic secondary resources.     

Environmental consequences of recycling aluminum old scrap in a global market

Nowadays, aluminum scrap is traded globally. This has increased the need to analyze the flows of aluminum scrap, as well as to determine the environmental consequences from aluminum recycling. The objective of this work is to determine the greenhouse gases (GHG) emissions of the old scrap collected and sorted for recycling, considering the market interactions. The study focused on Spain as a representative country for Europe. We integrate material flow analysis (MFA) with consequential life cycle assessment (CLCA) in order to determine the most likely destination for the old scrap and the most likely corresponding process affected. Based on this analysis, it is possible to project some scenarios and to quantify the GHG emissions (generated and avoided) associated with old scrap recycling within a global market. From the MFA results, we projected that the Spanish demand for aluminum products will be met mainly with an increase in primary aluminum imports, and the excess of old scrap not used in Spain will be exported in future years, mainly to Asia. Depending on the scenario and on the marginal source of primary aluminum considered, the GHG emission estimates varied between −18,140 kg of CO₂ eq. t⁻¹ and −8427 of CO₂ eq. t⁻¹ of old scrap collected. More GHG emissions are avoided with an increase in export flows, but the export of old scrap should be considered as the loss of a key resource, and in the long term, it will also affect the semifinished products industry. Mapping the flows of raw materials and waste, as well as quantifying the GHG impacts derived from recycling, has become an essential prerequisite to consistent development from a linear toward a circular economy (CE).     

Dynamic material flow analysis of zinc resources in China

Zinc is one of the most widely applied nonferrous metals in China. Study on the applications and recurrent situation of zinc resources is of great strategic importance for the sustainable development of China's economy. In this paper, a dynamic material flow analysis (MFA) method has been adopted to analyze quantificationally zinc resources in China, as well as to analyze and predict the quantity of zinc product scrap and their recycling situation. The weighted average method was applied to calculate average lifetimes of six major zinc products in China. The average lifetimes of battery, zinc oxide, zinc die-casting alloys, zinc material products, galvanized zinc and brass are 0.17, 5.3, 11.1, 12, 21 and 30 years, respectively. Assuming the lifetime of zinc product group obeys the Weibull distribution and the consumption of zinc products varies linearly with time, the future consumption and scrap generation of zinc products will increase continuously. It is expected that they would increase from 49% to 76% during 2004–2020, respectively. Assuming the recycling rate remains unchanged with time, the zinc old scrap index, both the theoretical and actual values, would continue increasing in China. The values are expected to reach 0.402 and 0.076 by 2020, respectively. Therefore, the regeneration resource of depreciated zinc is actually insufficient in China. According to the scenario analysis, the actual value of old scrap indexes is positively correlated with the recycling rate of zinc products. Because galvanized products are the largest consumption area of zinc products in China, the influence of their recycling rate on old scrap index is obviously larger than other zinc products. Through the analysis, this paper suggests that the increase of the recycling rate of zinc products could not only improve to a certain degree China's relative shortage of zinc resources, but greatly relive the supply pressure of zinc in the world.     

废旧铝、铁片粉煤灰复合混凝剂的制备及在废水处理中的应用

我国粉煤灰和铝、铁片固体废物产量日益增多,危害越来越严重。在高温加热、搅拌条件下,用强酸浸渍粉煤灰和易拉罐碎片,使粉煤灰和废旧铝、铁片资源化,制得废旧铝、铁片粉煤灰复合混凝剂,并用所制得的废旧铝、铁片粉煤灰复合混凝剂处理屠宰废水。在一定条件下,经混凝试验处理后的屠宰废水pH值在7左右,COD去除率为92．0％,SS去除率为98．7％,浊度去除率为98．4％,色度去除率为96．6％。结果表明,粉煤灰和废旧铝、铁片资源化和在废水处理中的应用具有可行性。     

Challenges and political solutions for steel recycling in China

The circular economy is an essential component of China's sustainable development. To promote the recycling of end-of-life products, the government has adopted various policies. Steel scrap is an important resource for steelmaking. Yet, the Chinese iron and steel industry uses less scrap to produce new steel compared to other large steelmaking countries. This article examines the reasons, why steel recycling is still relatively weak in China and what measures the government takes to improve the situation. We found that limited availability of scrap, high scrap prices, inadequate steelmaking capacities, industry fragmentation and unclear responsibilities for manufacturers are the main obstacles for steel recycling in China. The government is trying to improve steel recycling through tax incentives, import facilitation, support for supply, industry reorganization, and recycling parks, but with modest results.     

电子废弃物再生利用产业化的问题与对策研究

分析了目前我国电子废弃物再生利用产业化过程中存在的主要问题,提出了相关的对策和措施,并结合电子废弃物的特点提出了电子废弃物处理路线的设想。     

A study of the relationship between regional ferrous scrap prices in the USA, 1958–2004

This paper discusses univariate and mulitvariate methods used to deal with seasonal data with special emphasis on periodic models. These models are examined within the context of three regional U.S. ferrous scrap prices. All these variables can be described as being periodically integrated. The periodic models identified will be of use in assessing the future profitability of electric arc steel making. These scrap prices are shown to be periodically cointegrated in three of the four quarters with rapid speeds of adjustment to these long run equilibria. The cointegration relations have implications for the location of minimills.     

Quantification of Chinese steel cycle flow: Historical status and future options

China is the largest steel producer and consumer around the world. Quantifying the Chinese steel flow from cradle to grave can assist this industry to fully understand its historical status and future options on production route transformation, capacity planning, scrap availability, resource and energy consumption. With the help of the systematic methods combined dynamic MFA (material flow analysis) with scenario analysis, the Chinese steel cycle during the first half of the 21st century was quantified and several thought-provoking conclusions were draw. In the past decade, lots of pig iron or molten iron was fed into EAF (electric arc furnace) and the scrap usage of EAF fluctuated slightly. Thus, the real scrap-EAF route share is much lower than the EAF production share. On the other hand, we reconfirmed that the scrap supply in China will rise significantly in the future. Meanwhile, the secondary production route share will grow sharply and exceed primary production share before or after 2050 depending on our options. The scrap recycling rate and construction's lifetime play a vital role in this trend. In the end, an intensive discussion on production capacities’ adjustment and energy and resource consumption was conducted and relative policy suggestions were given. It is worth noting that scrap usage is crucial to future energy saving and emissions reduction of Chinese steel sector and its energy consumption might peak as early as 2015.     

Environment-friendly technology for recovering nonferrous metals from e-waste: Eddy current separation

The current generation pattern of e-waste consisted of dead electronic and electrical equipments poses one of the world's greatest pollution problem due to the lack of appropriate recovery technology. Crude recovery methods of resource materials (aluminum, zinc, copper, lead, gold) from e-waste caused serious pollution in China in the past years. Thus, environment-friendly technologies have been the pressing demand in e-waste recovering. Eddy current separation (ECS) was advised as the preferable technology for recovering nonferrous metals from e-waste. However, just a few reports focused on the application of ECS in e-waste recovering. This paper introduced the information about ECS including the models of eddy current force and movement behavior of nonferrous metallic particle in the separation process. Meanwhile, the developing process of eddy current separator was summarized. New industrial applications of ECS in e-waste (waste toner cartridges and refrigerator cabinets) recovering were also presented. Finally, for improving separation rate of ECS in industrial application of e-waste recovering, some suggestions were proposed related to crushing process, separator design, and separator operation. The aim of this paper is to demonstrate the effectiveness of ECS technology as practical and available tool for recovering non-ferrous metals from e-waste which is now being ignored.     

Tracking effective measures for closed-loop recycling of automobile steel in China

Closed-loop recycling of steel in automobiles is particularly difficult because of the low tolerance for impurities and the use of composites of various types of steel products. Technologies that reduce impurities or increase impurity tolerance must be developed and introduced to the steel recycling system at the appropriate time. This study evaluated the feasibility of closed-loop recycling in the automobile industry in China. Material pinch analysis combined with dynamic modeling of the life cycle of steel sheets used in the manufacture of automobiles was employed to estimate the amount of steel sheet scrap available for closed-loop recycling and the amount of copper contamination in the scrap. The results indicate that by 2050, more than half of the old steel sheet scrap generated annually will have to be down-cycled because of its high copper contamination. However, scenario analyses of three types of technologies for mitigating the problem of copper contamination showed the potential for increasing the amount of old scrap used in closed-loop recycling. In particular, improving copper tolerance in the steel production process could be effective both now and in 2050.     

Elemental analysis of lightweight metal scraps recovered by an automatic sorting technique combining a weight meter and a laser 3D shape-detection system

To verify the effectiveness of a new automatic sorting technique that combines a weight meter and a laser 3D shape-detection system, elemental analysis of lightweight metal scraps generated in end-of-life vehicle (ELV) shredder facilities was conducted using a handheld XRF analyzer. According to their 3D shape and chemical composition, aluminum scraps were classified into cast alloy (Alc) and wrought alloy (Alw) fragments, and magnesium scraps were classified into irregularly shaped and rod-like fragments. The average chemical composition of a group of fragments was estimated before and after the separation test using the developed automatic sorting technique. The results show that the production of wrought aluminum alloy from the mixture of Alc and Alw fragments is not realistic because the contents of some alloying elements greatly exceed the standard values, although these alloying elements greatly decrease after the Alc fragments are separated out. For the magnesium scraps, after the rod-like magnesium fragments originating from the steering column were separated from the irregularly shaped fragments, the average chemical compositions of the rod-like products and the irregularly shaped products clearly approached the standard compositions of AM60B and AZ91D alloys, respectively. Thus, it was confirmed that the developed automatic sorting technique contributes to recycling of lightweight metal scrap in the automobile industry.     

乌昌地区废旧轮胎回收利用现状调查及分析

选取新疆经济发展最快的乌昌地区为靶区,以现场调查资料为基础,根据国内外废旧轮胎回收利用发展变化特点,对该区域的废旧轮胎现状进行了统计分析,并对乌昌地区废旧轮胎的产生量进行了预测。通过对乌昌地区废旧轮胎回收市场特点的调查研究,指出了乌昌地区废旧轮胎回收市场目前存在的问题,提出了相应的建议和措施。     

Manufacture of strand board made from construction scrap wood

The objective of this research was to evaluate the physical and mechanical properties of strand board made from construction scrap wood. The strand board was manufactured using Sugi (Cryptomeria japonica D. Don) and Douglas-fir (Pseudotsuga japonica) strands selected from construction scrap wood. The strands were oriented, and three-layer (face/core/face) strand board of three types was produced: one in which the strands of the face layer were oriented at a right angle to those of the core layer (R board), another in which the strands of the face layer were oriented parallel to those of the core layer (P board), and a third in which the strands of both layers were oriented at random (Ra board). The physical and mechanical properties of the boards were evaluated based on Japanese Industrial Standard (JIS). The main results obtained are as follows: the bending strength of the strand board with a density larger than 0.55 g/cm³ exceeded the standard value of type 18 particleboard of JIS A 5908. The bending strength of the strand board was affected by board density, strand orientation and resin content, and became larger with increased density as well as resin content. That of the parallel specimen of P board was the largest among the specimen-orientations and types. The internal bond strength of the strand board with a density larger than 0.55 g/cm³ exceeded the standard value of type 18 particleboard and type 24-10 particleboard of JIS A 5908. The internal bond strength was markedly affected by the resin content of the core layer, and became larger with increased density. The thickness swelling of the strand board decreased with increased resin content, and become larger with increased density.