井下光谱多参数分析系统开发

本系统基于气体浓度光学分析方法理论朗伯-比尔(Lambert-Beer)定律、光谱气体检测技术开发,实现了对煤矿火灾与瓦斯灾害超前预警、灾害产生的有毒有害气体实时监测和煤矿环境气体爆炸危险性辨识,对于煤矿灾害防治、救灾过程中杜绝次生灾害,保障煤矿工人及救护队员的生命安全,促进煤矿安全生产具有重要意义。     

Stability of a Coal Waste Artificial Reef

The feasibility of using U.K. coal-fired power station waste materials for artificial reef production is being examined. in June, 1989, an experimental artificial reef was constructed in Poole Bay, off the central south coast of the U.K., using three different mixtures of pulverised fuel ash (PFA), flue gas desulphurisation (FGD) gypsum and slurry, stabilized with cement and formed into blocks. Fifty tonnes of 40 × 20 × 20 cm blocks were formed into eight conical reef units replicating three different PFA/gypsum mixtures and one concrete control. the reef structure is 10m below chart datum on a flat sandy sea-bed.

Combustion of coal concentrates the heavy metal content in the resultant ash. the purpose of stabilization of the ash as blocks is twofold: to immobilize heavy metals (or other components) and to provide hard substratum for the attachment of organisms. to examine the effectiveness of this stabilization and hence the environmental compatibility of the block materials, heavy metal (Cd, Cr, Cu, Pb, Mn, Ni, Zn) content of the blocks has been monitored routinely over two years, to determine leaching rates. Sectional profiles indicate partial replacement of calcium content by magnesium. Associated with this there has also been some redistribution of heavy metals. Only in the case of cadmium has there been a detectable loss from the surface of blocks. Chromium and manganese concentrations appear to have increased. the metal content of the reef epibiota (including ascidians, Ascidia mentula; hydroids, Halecium spp.; bryozoans, Bugula spp. and red algae) growing on the ash blocks has been compared to that of epibiota attached to the concrete controls and surrounding sea-bed. to date no evidence of excess bioaccumulation of metals has been detected.

The physical integrity of the ash reef blocks has been maintained. There is evidence that the blocks are increasing in compressive strength.

An indication of the fishery enhancement potential of the experimental structure is given by the presence of eight commercially fished species (crustaceans and molluscs) including lobsters (Homarus gammarus).     

焚烧飞灰重金属含量及浸出长期变化规律研究

通过对24个飞灰样品的重金属全量消解和高精度X射线荧光光谱法（HDXRF）快速检测结果进行线性回归分析,发现HDXRF法可较准确测定飞灰中Cu、Pb、Zn、Ni和Cd含量（线性回归决定系数R²³0.90）.采用HDXRF法对某焚烧厂飞灰重金属含量6个月快速检测及浸出毒性测定数据统计分析发现：飞灰重金属月均含量较稳定（变异系数CV<0.14）但日均含量波动较大（CV>2.54）;飞灰中Pb、Cu和Zn含量呈正相关（相关系数r>0.78）;金属浸出浓度受浸出液终点pH值影响显著,超标频率依次为Pb（68.9%）、Cd（66.1%）、Ni（24.0%）、Cu（14.2%）和Zn（1.6%）.短期飞灰金属含量和浸出毒性数据受焚烧工况,烟气处理工况和垃圾组分等多种因素共同影响,不具有代表性.为评估垃圾分类源头削减重金属效果,建议采用快速检测方法对焚烧飞灰重金属含量进行长期监测.     

Coupling mechanism of activated carbon mixed with dust for flue gas desulfurization and denitrification

To clarify the effect of coking dust, sintering dust and fly ash on the activity of activated carbon for various industrial flue gas desulfurization and denitrification, the coupling mechanism of the mixed activated carbon and dust was investigated to provide theoretical reference for the stable operation. The results show that coking dust had 34% desulfurization efficiency and 10% denitrification efficiency; correspondingly, sintering dust and fly ash had no obvious desulfurization and denitrification activities. For the mixture of activated carbon and dust, the coking dust reduced the desulfurization and denitrification efficiencies by blocking the pores of activated carbon, and its inhibiting effect on activated carbon was larger than its own desulfurization and denitrification activity. The sintering dust also reduced the desulfurization efficiency on the activated carbon while enhancing the denitrification efficiency. Fly ash blocked the pores of activated carbon and reduced its reaction activity. The reaction activity of coking dust mainly came from the surface functional groups, similar to that of activated carbon. The reaction activity of sintering dust mainly came from the oxidative property of Fe₂O₃, which oxidized NO to NO₂ and promoted the fast selectively catalytic reduction (SCR) of NO to form N₂. Sintering dust was activated by the joint action of activated carbon, and both had a coupling function. Sintering dust enhanced the adsorption and oxidation of NO, and activated carbon further promoted the reduction of NO_x by NH₃; thus, the denitrification efficiency increased by 5%-7% on the activated carbon.     

Fly-ash-induced oxidative stress and tolerance in Prosopis juliflora L. grown on different amended substrates

Field experiments were conducted to study the impact of metal accumulation on malondialdehyde (MDA), cysteine and non-protein thiol (NPSH) contents in the plants of Prosopis juliflora grown on the fly ash (FA) amended with soil, blue green algae (BGA) biofertilizer, farm yard manure, press mud and Rhizobium inoculation. The analysis of data revealed that the level of MDA, cysteine and NPSH was higher in the roots of the plant than leaves, which was found positively correlated with metal accumulation. An increase of 361.14, 64.25 and 305.62% in MDA, cysteine and NPSH contents, respectively was observed after 45 days in the roots of the plants grown in 100% FA as compared to 100% garden soil (GS). The level of MDA, cysteine and NPSH was found less in the plants grown on various amendments of FA showing ameliorating effect on the toxicity induced due to the accumulation of metals. The decrease in MDA, cysteine and NPSH contents was higher in Rhizobium-inoculated plants as compared to uninoculated plants grown on 100% FA. The results showed a high tolerance potential of the plant, which is further increased by inoculating the plant with FA-tolerant Rhizobium showing feasibility of using P. juliflora in environmental monitoring of FA landfills.     

煤中有害元素对环境和人体健康影响的评价参数

煤中有害元素对环境和人体健康影响的较为全面的评价体系一直未建立，环保部门也缺乏系统性评价参数对电厂等在煤煤过程中有害元素排向大气的释放量进行监测估算。本文在查阅大量资料（主要为外文）的基础上，认为评价煤中有害元素对环境和人体健康影响的参数应该包括以下方面的数据C、H、O、N、无机硫，有机硫，有害微量元素的含量，分布规律，赋存状态，迁移转化行为（在燃煤过程中），洁净能力，淋滤力，矿物质，有机化学特征，煤炭学特征，并对煤中有害元素的污染方法进行探讨，如果上述各参数的数据被全面提供，并据此数据作针对性的抑制措施，煤中有害元素对环境和人体健康危害影响必将降低到最小。     

中国能源的现状

研究中国能源的现状，其中主要包括能源储量和能源生产以煤为主；石油和天然气在能源构成中的比例低下；煤炭储量可观，但品质不高；能源生产增长迅速；能源短缺。尤其是清洁能源短缺，清洁能源危机将会长期存在。我国如此的能源现状已造成大气环境煤烟型严重污染。我国从石油输出国已变成石油进口国，我国半个多世纪以来实施的“能源自给政策”急需调整。采用洁净煤技术开发利用清洁能源，确保经济在持续迅速发展的同时，我国大气环境免遭污染，即经济发展和大气环境保护双赢。     

不同气氛下燃煤SO2的排放规律研究

在立式管状电加热炉上对合山高硫煤在不同的气氛、温度以及Ca／S比的条件下进行了动态燃烧实验，对收集的气体产物进行了红外光谱分析，并讨论了CO2浓度以及温度等因素对SO2释放的影响。结果表明：不同浓度的CO2气氛对煤燃烧过程中硫的释放以及石灰石的固硫效率有着不同的影响，在高于900℃以后，较之空气气氛下，无论是否存在钙基固硫剂，其它三种02／C02气氛下S02的排放量都比较低，且在不同C02浓度下，温度对S02的排放影响不一致。     

淮北煤中12种有害微量元素在煤及其灰中的分布特征

为了解有害微量元素在各煤层中的分布与变化规律,以及在煤燃烧后的煤灰中所发生的迁移与富集情况,采集了淮北煤田不同煤层、不同深度的15个煤样,采用中子活化法对其原煤及灰分中的12 种微量元素(Ag, As,Ba, Co, Cr, Cu, Mn, Mo, Sb, Th, U, V)进行了测试。结果显示:绝大部分有害微量元素的含量都处于n×10 6到n×10 5数量级范围内,不同煤层或同一煤层不同部位中微量元素的含量分布不同;与全国和华北煤中有害微量元素的(平均)含量相比,除Mn低于全国和华北的平均值外,As、Co、Mo、Sb、Th、U与之相近,而Ag、Ba、Cr、Cu、V高于全国和华北煤中的平均值;12种微量元素均在灰分中有所富集,而且富集能力序列为:Cu>Cr>Mn>Mo>Co>Ba>V>Th>As>U>Sb。     

CFB锅炉燃烧高硫石油焦的灰渣综合利用研究

循环流化床锅炉在燃烧含硫石油焦时,通过加入石灰石在燃烧的过程中以固态的形式脱硫,燃烧后将产生大量的灰渣,过去处理灰渣最通常的方式是作土地填埋。从灰渣的化学、物理特性试验研究出发,寻找循环流化床灰渣在建筑材料、农业应用和水泥添加剂方面的利用途径,研究了更加经济有效的灰渣处理方法。