一种硫离子响应杀菌材料的制备及应用研究

目的制备硫离子响应杀菌材料,研究它在不同浓度铜离子条件下的封装效果,以及在不同浓度硫离子条件下的释放行为。方法选择埃洛石纳米管为载体并用透射电镜进行表征、采用真空负载的方式,将甲硝唑和苯骈三氮唑(BTA)分步填充到埃洛石纳米管内部,使用紫外分光光度法测试不同浓度铜离子对纳米管中甲硝唑的封堵效果,以及材料在不同浓度硫离子条件下的释放情况。结果实验中通过调整铜离子浓度发现,铜离子浓度越大对甲硝唑的封堵效果越好,当铜离子浓度达到160 mmol/L时,对甲硝唑的封堵效果最好。杀菌材料在外界硫离子达到0.1mmol/L后,甲硝唑的释放浓度迅速提高,进一步提高硫离子浓度,释放情况改变不明显。结论铜离子浓度达到160 mmol/L时,材料的封装效果是最好的。材料能够对硫离子实现响应释放,且对应的临界浓度为0.1 mmol/L。     

Modeling photocatalytic destruction of the organic contaminants in continuous stir flow reactor

Thin-film technique is becoming an industry standard for the preparation of TiO₂-based photocatalyst for organic destruction. The catalyst provides several advantages over the conventional powder TiO₂ in the treatment of wastewater and groundwater. In this study, a continuous stir flow reactor model is developed capable of describing the photocatalytic process. The model incorporates the following fundamental mechanisms: adsorption, diffusion, liquid-film transfer, UV attenuation, and photocatalytic reaction. All of the simulation results indicate that there exists a highly nonlinear relation between each of these parameters and the destruction rate. Various incident light intensities also are incorporated to simulate the energy efficiency. The simulations illustrate that the photocatalytic model can be used to elucidate the effect of process variables. It is also possible to “custom-design” a catalyst for the treatment of a particular waste stream.     

水解-好氧系统处理生活污水的特性研究

采用新型 Yakult填料和中心导流式曝气方式 ,设计制作了新型生活污水净化装置 ,试验表明 ,停留时间 16 h左右 ,CODCr去除率 >80 % ,BOD5去除率 >90 % ,SS去除率 >85 % ,NH3 - N去除率 >87% ,出水水质达到国家一级排放标准     

The effect of heating temperature of thin film transistor-liquid crystal display (TFT-LCD) optical waste glass as a partial substitute partial for clay in eco-brick

In order to fulfill the current WEEE directives, the traditional approach to manage thin film transistor-liquid crystal display (TFT-LCD) waste glass is inadequate. It is a serious opportunity to achieve resource conservation, reduction, stabilization and safety of management of TFT-LCD in the near future. To assist in achieving these goals, this study investigated the sintering characteristics and material properties of TFT-LCD waste glass, which can be pulverized and ground and subsequently blended with clay, at various substitution levels (0–40%) and finally fired from 800 °C to 1000 °C to make eco-brick. The brick thus produced was analyzed to determine variations in weight losses on ignition, 24-h absorption, bulk density, shrinkage, compressive strength and microstructure changes. The results for specific gravity, water adsorption, and compressive strength revealed that bricks made from mixtures containing TFT-LCD waste glass met the general requirements for bricks. The advantages of less water absorption, less weight loss on ignition, and a gain in compressive strength in the clay-TFT-LCD waste glass bricks should encourage the use of TFT-LCD waste glass as a brick additive.     

TiO2薄膜光催化效果的强化

采用溶胶-凝胶法制备TiO2溶胶,将其涂覆在普通钠钙玻璃上,以TiO2对甲基橙的光分解率探讨TiO2薄膜最佳光催化性能.结果表明,当PEG400的加入量为7%时,TiO2薄膜的光催化性能最强;用锐钛型TiO2粉末二次引发的溶胶提拉制成的薄膜对甲基橙的光催化分解效果有很大的提高;经滴加操作后薄膜的光催化性能有明显改善;各个影响因素最好的组合效果为滴加操作 锐钛型粉体引发 H2SO4超强酸化 La3 掺杂.     

铁蓝—活性炭生物膜法处理彩色胶片水洗废水的研究

定影漂白废话水用铁蓝法预处理，结果表明，以硫酸亚铁为沉淀剂，投加量为铁氰化物理论值的１．３倍，ＣＮ去除率为９８％，反应生成的普鲁士蓝纯度较高，可供综合利用，铁蓝法除ＣＮ后的出水与显影冲洗废水混合，再经生炭生物膜法处理，ＣＯＤｃｒ去除率为８０％；     

塑料薄膜用无滴消雾剂的研制

本文介绍了塑料薄膜用无滴消雾剂的配方、制备方法和使用情况。     

一种序批式生物膜反应器及其氧传递系数测定

介绍了一种序批式生物膜反应器 ,并求出了在给定的工艺条件下的氧传递系数。结果表明 :本反应器有较强的氧传递能力 ,能满足微生物的新陈代谢和降解有机污染物的需要     

渗水地膜与旱地农业

经过对地膜物料结构的深入研究，提出了单向渗水原理，设计并发明了渗水地膜。渗水地膜具有保温、调温、渗水、保水、微通气等多种功能，可使半干旱地区发生频率为７０％左右、年累计量为１００～１５０ｍｍ的小雨量资源得到开发利用。旱地试验表明：渗水地膜覆盖的粮食作物比常规地膜覆盖的增产１５７％～３８３％，比无覆盖的增产１倍以上。     

中国废旧农用塑料薄膜的回收与利用

介绍了中国废旧农用塑料薄膜回收利用的现状 ;重点阐述了中国废旧农膜再生造粒技术 ,从工艺、成本利益、再生粒料的应用市场等各方面对该技术进行了详细的介绍和剖析 ,在论述其优越性的同时 ,指出了再生造粒技术存在的问题 ,为研究人员今后的研究工作指明了方向 ;最后对废旧农膜再生造粒技术的应用前景进行了展望。