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大孔径聚砜超滤膜的研究 总被引:5,自引:0,他引:5
作者用向铸膜液中加水的方法对制备大孔膜进行了研究。选择适宜的聚砜浓度和水含量,可以制得截留分子量为15万的聚砜超滤膜。该膜对丙种球蛋白的截留率>95%,纯水透水速度可达70-80ml/cm^2·h(0.1MPa)。 相似文献
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将氯甲基化聚砜(CMPS)超滤膜浸泡于三甲胺水溶液中制得季铵化聚砜(QMPS)超滤膜。本文就一些反应条件对季铵化聚砜超滤膜性能的影响进行了探讨,同时对季铵化聚砜超滤膜和氯甲基化聚砜超滤膜的形态结构作了对比,并研究了它们的亲水性能和电性能等方面的差异。 相似文献
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膜材料本身的性质是决定膜性能的主要因素,对于荷电超滤膜,荷电性和荷电程度对膜性能有较大的影响,本文研究了含氯量对氯甲基化聚砜超滤膜性能的影响,就有关制膜条件对膜的物理性能和电性能的影响也进行了研究。 相似文献
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研究了溶液化学特性(包括pH值,离子强度和给溶液浓度)对谷氨酸 在疏水性聚砜膜上吸附行为的影响。结果表明:谷氨酸菌在聚砜膜上的吸附符合静电作用机理;菌体在等电点时发生絮凝,是影响吸附量的重要原因;pH值愈高,谷氨酸菌的吸附量愈小;离子强度降低相同电荷物质之间的静电排斥,增加吸附,同时也降低相反物质电荷之间的静电吸附,从而降低吸附;谷氨酸菌浓度愈大,平衡吸附量也愈大。 相似文献
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Anti-fouling ultrafiltration membrane prepared from polysulfone-graft-methyl
acrylate copolymers by UV-induced grafting method 总被引:1,自引:0,他引:1
HUA Helin LI N WU Linlin ZHONG Hui WU Guangxi YUAN Zonghuan LIN Xiangwei TANG Lianyi 《环境科学学报(英文版)》2008,20(5):565-570
Membrane fouling is one of the most important challenges faced in membrane ultrafiltration operations. The copolymers of polysulfone-graft-methyl acrylate were synthesized by homogeneous photo-initiated graft copolymerization. The variables affecting the degree of grafting, such as the time of UV(Ultraviolet-visible)irradiation and the concentrations of the methyl acrylate and photoinitiator, were investigated. The graft copolymer membranes were prepared by the phase inversion method. The chemical and morphological changes were characterized by attenuated total reflection-Fourier transform infrared spectroscopy(ATR/FT-IR), scanning electron microscopy, and water contact angles measurements. Results revealed that methyl acrylate groups were present on the membranes and the graft degree of methyl acrylate had remarkable effect on the performance of membranes. Pure water contact allgle on the membrane surface decreases with the increase of methyl acrylate graftdegree. which indicated that the hydrophilicity of graft copolymer membranes Was improved. The permeation fluxes of pure water and bovine serum albumin solution were measured to evaluate the antifouling property of graft copolymer membranes, the results of which have shown an enhancement of antifouling property for graft copoly mermembranes. 相似文献
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SHEN Ying-jie WU Guang-xi XU Shu-guang ZHONG Hui ZHANG Shao-lai ZHANG Xue-zhu ZHAO Xian-hong WU Tong ZHANG Wei-jun 《环境科学学报(英文版)》2005,17(3):465-468
Using the inner-surface of polysulfone hollow fiber ultrafiltration membranes as grafted layer, the method of gas-initiation and liquid-polymerization has been studied, which aimed to adjust the diameter of the pores in the membranes. The degree of polymerization varied with the changes of the parameters, such as irradiation time, monomer concentration, temperature and time of polymerization and so on. The results indicated that using benzophenone(BP) which is in a gaseous condition as photo-initiator, acrylamide as graft monomer, the polyacrylamide chain was grafted on the surface of membranes. After the surface membrane being modified, the water flux and retention altered, and thus it can be seen that the diameter of the pores in the membrane was altered. These experiments contribute to finding a new way to produce the hollow fiber membrane with the small pore size and are extraordinarily worth developing and studying. 相似文献
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