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排序方式: 共有467条查询结果,搜索用时 578 毫秒
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Xin Xing Na Li Jie Cheng Yonggang Sun Zhongshen Zhang Xin Zhang Zhengping Hao 《环境科学学报(英文版)》2020,32(10):55-63
In this work, a series of Cu-ZSM-5 catalysts with different SiO2/Al2O3 ratios (25, 50, 100 and 200) were synthesized and investigated in n-butylamine catalytic degradation. The n-butylamine can be completely catalytic degradation at 350°C over all Cu-ZSM-5 catalysts. Moreover, Cu-ZSM-5 (25) exhibited the highest selectivity to N2, exceeding 90% at 350°C. These samples were investigated in detail by several characterizations to illuminate the dependence of the catalytic performance on redox properties, Cu species, and acidity. The characterization results proved that the redox properties and chemisorption oxygen primarily affect n-butylamine conversion. N2 selectivity was impacted by the Brønsted acidity and the isolated Cu2+ species. Meanwhile, the surface acid sites over Cu-ZSM-5 catalysts could influence the formation of Cu species. Furthermore, in situ diffuse reflectance infrared Fourier transform spectra was adopted to explore the reaction mechanism. The Cu-ZSM-5 catalysts are the most prospective catalysts for nitrogen-containing volatile organic compounds removal, and the results in this study could provide new insights into catalysts design for VOC catalytic oxidation. 相似文献
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Water quality indices (WQIs) have been developed to assess the suitability of water for a variety of uses. These indices reflect the status of water quality in lakes, streams, rivers, and reservoirs. The concept of WQIs is based on a comparison of the concentration of contaminants with the respective environmental standards. The number, frequency, and magnitude by which the environmental standards for specific variables are not met in a given time period are reflected in WQIs. Further, the water quality trend analysis predicts the behavior of the water quality parameters and overall water quality in the time domain. In this paper, the concept of WQI was applied to three selected watersheds of Atlantic region: the Mersey River, the Point Wolfe River, and the Dunk River sites. To have robust study, two different water quality indices are used: Canadian Water Quality Index (CWQI), and British Columbia Water Quality Index (BWQI). The complete study was conducted in two steps. The first step was to organize and process the data into a format compatible with WQI analysis. After processing the input data, the WQI was calculated. The second step outlined in the paper discusses detailed trend analysis using linear and quadratic models for all the three sites. As per the 25 years trend analysis, overall water quality for agriculture use observed an improving trend at all the three sites studied. Water quality for raw water used for drinking (prior to treatment) and aquatic uses has shown improving trend at Point Wolfe River. It is further observed that pH, SO4, and NO3 concentrations are improving at Dunk River, Mersey River, and Point Wolfe River sites. To ascertain the reliability and significance of the trend analysis, a detailed error analysis and parametric significance tests were also conducted It was observed that for most of the sites and water uses quadratic trend models were a better fit than the linear models. 相似文献
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城市人居环境的可持续发展体系是一个由人口、社会、资源、环境与经济5个子系统构成的开放巨系统。通过提出综合衡量系统“协调性”和“发展水平”的“协调发展度”模型,研究人居环境复合系统内5个子系统之间协调发展度情况。并运用灰色预测理论构建GM(1,N)动态模型,预测未来几年各子系统之间协调发展的状况。 相似文献
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通过试验筛选出对炼油污泥处理效果好的复配絮凝剂。试验和现场应用结果表明:使用有机高分子絮凝剂(PAM)分别和无机高分子絮凝剂(PAC)复配处理炼油污泥比单独使用任何一种絮凝剂的处理效果更好,复配絮凝剂具有适应性广、投加量少、浮渣少等优点,处理后的污水可以达到排放标准。 相似文献
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A new approach applying fuzzy mathematic theorems, including the Primary Matrix Element Theorem and the Fisher Classification Method, was established to solve the optimization problem of atmospheric environmental sampling sites. According to its basis, an application in the optimization of sampling sites in the atmospheric environmental monitoring was discussed. The method was proven to be suitable and effective. The results were admitted and applied by the Environmental Protection Bureau (EPB) of many cities of China. A set of computer software of this approach was also comuletelv comniled and used. 相似文献
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钢绞线逐根张拉下锚墩基床沉陷所致锚索预应力损失问题 总被引:1,自引:0,他引:1
在预应力锚索锚墩下部地基岩土的基床系数较低情况下,采用钢绞线逐根张拉来施加预应力会导致较大的预应力损失以及各钢绞线较显著的预应力不均。基于锚墩基床岩土体的弹性压缩模型,理论探讨了钢绞线逐根对称循环张拉下的锚索预应力损失,及钢绞线的预应力均匀性问题。分析表明,基床系数越低,逐根张拉下的锚索预应力损失越大,且其所含各钢绞线预应力的均匀性越差;而同样荷载和基床系数下,锚索所含钢绞线根数越多, 逐根张拉后的预应力损失和不均匀性也越大。但采用分级循环张拉、正序张拉及调整、锚墩下部一定扩散角填石等工序及措施有助于减轻预应力损失和解决不均匀性问题。 相似文献
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