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1.
The distribution and sources of organochlorine pesticides (OCPs) in air and surface waters were monitored in Nairobi City using triolein-filled semipermeable membrane devices (SPMDs). The SPMDs were extracted by dialysis using n-hexane, followed by cleanup by adsorption chromatography on silica gel cartridges. Sample analysis was done by GC-ECD and confirmed by GC–MS. Separation of means was achieved by analysis of variance, followed by pair-wise comparison using the t-test (p≤ 0.05). The total OCPs ranged between 0.018 – 1.277 ng/m3 in the air and <LOD – 1391.000 ng/m3 in surface waters. Based on the results, the means of Industrial Area, Dandora and Kibera were not significantly different (p≤ 0.05), but were higher (p≤ 0.05) than those of City square and Ngong’ Forest. The results revealed non-significant (p≤ 0.05) contribution of long-range transport to OCP pollution in Nairobi City. This indicated possible presence of point sources of environmental OCPs in the city. The water-air fugacity ratios indicated that volatilization and deposition played an important role in the spatial distribution of OCPs in Nairobi City. This indicated that contaminated surface waters could be major sources of human exposure to OCPs, through volatilization. The incremental lifetime cancer risks (ILCR) determined from inhalation of atmospheric OCPs were 2.3745 × 10?13 – 1.6845 × 10?11 (adult) and 5.5404 × 10?13 – 3.9306 × 10?11 (child) in the order: Dandora > Kibera > Industrial Area > City Square > Ngong’ Forest. However, these were lower than the USEPA acceptable risks, 10?6 – 10?4. This study concluded that atmospheric OCPs did not pose significant cancer risks to the residents. 相似文献
2.
以铁基质生物载体为核心,将物理、生物和化学方法结合,对化粪池进行功能强化,实现黑水的原位深度处理.探究了溶解氧(DO)和碳氮比(C/N)等因素对黑水中污染物降解的影响,并在最佳运行参数下考察了氮素在系统中的转化机制.结果表明,当C/N为7.3~8.4时,好氧生物铁基质载体池DO为2.3~2.7mg/L时,系统氨氮(NH4+-N)、总氮(TN) 、COD和总磷(TP)的平均去除率分别可达90.74%、85.81%、92.65%和95.78%;当进水C/N降至3.3~4.2时,系统NH4+-N、TN、COD和TP的平均去除率仍可维持在81.16%、76.62%、93.87%和94.75%.铁基质生物载体内电解作用显著强化了化粪池内TN的脱除、COD的氧化和TP的固定.氮素转化机制分析表明,内电解与反硝化菌的耦合强化了反硝化作用,降低了反硝化过程对有机碳源的需求,强化了低C/N条件下TN、TP的脱除. 相似文献
3.
Effect of an industrial discharge on water quality and periphyton structure in a pampeam stream 总被引:1,自引:0,他引:1
Seasonal sampling was carried out at four sites on a pampeanstream that receives industrial effluent from two textile factories. To evaluate water quality, several physical and chemical parameters were examined and the periphyton growing oncattail (Typha latifolia L.) were analyzed.Water quality and periphyton structure differed significantlybetween sites upstream and downstream of the discharge. Differences in temperature and also in concentrations of phosphate, dissolved oxygen, and phaeopigment were detected. At the same time, changes in the dominant algae groups wereobserved. Downstream of the industrial discharge, the numberof Bacillariophyta decreased, while species of Cianophyta andEuglenophyta were more abundant. This abundance correlated withincreased phosphate and organic matter content and decreased oxygen concentration. Although this study did not detect a reduction in the number of species, similarity between stands decreased downstream of the industrial discharge. Changes incommunity structure were readily detected in this situation because the communities of the polluted and unpolluted zones were qualitatively different. Periphyton growing naturally on Typha latifolia is a useful indicator of the impact of waste waters on the biota and can also be used to evaluate water body recovery. 相似文献
4.
介绍对氨基二甲基苯胺光度法测定硫化物方法中如何降低空白值,提高硫化钠溶液的稳定度以及提高酸化吹气回收率的原理和方法. 相似文献
5.
Using environmental stressor information to predict the ecological status of Maryland non-tidal streams as measured by biological indicators 总被引:4,自引:0,他引:4
Vølstad JH Roth NE Mercurio G Southerland MT Strebel DE 《Environmental monitoring and assessment》2003,84(3):219-242
In Maryland, U.S., an interim framework has recentlybeen developed for using biologically based thresholds, or `biocriteria', to assess the health of nontidal streams statewide at watershed scales. The evaluation of impairment is based on indices of biological integrity from the Maryland Biological Stream Survey (MBSS). We applied logistic regression to quantify how the biotic integrity of streams at a local scale is affected by cumulative effects resulting from catchment land uses, point sources, and nearby transmission line rights-of-way. Indicators for land use were developed from the remote sensing National Land Cover Data and applied at different scales. We determined that the risk of local impairment in nontidal streams rapidly increases with increased urban land use in the catchment area. The average likelihood of failing biocriteria doubled with every 10% points increment in urban land, thus an increase in urban land use from 0 to 20% quadruples the risk of impairment. For the basins evaluated in this study, catchments with more than 40–50% urban land use had greater than 80% probability of failing biocriteria, on average. Inclusion of rights-of-way and point sources in the model did not significantly improve the fit for this data set, most likely because of their low numbers. The overall results indicate that our predictive modeling approach can help pinpoint stream ecosystems experiencing or vulnerable to degradation. 相似文献
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The curve of ion exchange ratio(%)-pH of the interactionbetween suspended particles with Cd(II) in the Yellow River wasstudied. The effects of lysine on this curve have been alsoinvestigated. The results showed that (1) Cadmium in Cd(OH)+ formin the suspended particles exchanges with the cations.The exchangeratio of Cd2+ is nearly at its greatest value in the range of pH(8.0-8.5) in natural aquatic system; (2) Ion exchange ratiodecreases as the concentration of Cd2+ raises from 8.9×10-6 mol/L to 2x8.9 x 10-6mol/L; (3) At the lysine concentration of 6.8x10-6 mol/L, it can promote the ion exchange ratio; (4) Adsorption of thesuspended particles to cadmium is weaker in seawater and Jin ShaRiver than in the Yellow River. 相似文献
9.
渤海江豚组织中钠,钙,锶,镁,磷,钾的研究 总被引:3,自引:0,他引:3
1990年,作者于辽东湾采集了10头江豚标本,分别测定了其骨骼、皮肤、肌肉、肝脏、肺、肾、心、胃、肠、胰、脾、肾上腺及生殖腺等13种组织中Ca、Sr、Mg、P、K、Na6种元素的含量,详细分析了骨骼及其他各组织中的Ca/Mg值、Ca/K值、Ca/P值、Ca/Na值和Ca/Sr×100值。结果表明,Ca、Sr、Mg、P,K在骨骼中累积率最高,钾在肌肉中具有高累积,Sr、Ca在肌肉中累积率最低;Mg累积率最低的组织是生殖腺,P累积率最低的组织是肠,而K在骨骼中,Na在肌肉中的累积率均高于其他组织。分析结果还显示,Ca/Mg值最高的是骨骼,最低为肌肉,Ca/P值最高的是骨骼,最低的是肌肉和胰脏,Ca/K值最高为骨骼,最低为脾Ca/Sr×100值最高为肺、最低为肠,而K/Na值最高为肌肉,最低为骨骼,在骨中Ca/P值大约为1,类同于猫和人类。 相似文献
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