Residues of pharmaceutical products in recycled organic manure produced from sewage sludge and solid waste from livestock and relationship to their fermentation level

In recent years, sludge generated in sewage treatment plants (STPs) and solid waste from livestock being utilized is useful for circulation of nourishment in farmlands as recycled organic manure (ROM). In this study, we determined the residue levels and patterns of 12 pharmaceutical products generated by human activity in the ROMs produced from human waste sludge (HWS), sewage sludge (SS), cattle manure (CM), poultry manure (PM), swine manure (SM) and horse manure (HM).The kind and number of pharmaceutical products detected in ROMs were different. Fluoroquinolones (FQs) were detected at high levels in HWS and SS samples. In addition, the detection frequency and concentration levels of sulfonamides (SAs) in PM and SM were high. Moreover, high concentrations of chlortetracycline (CTC) were found in only SM. These differences reflect specific adherence adsorption of the pharmaceutical products to different livestock and humans. Moreover, it was found that the concentrations of pharmaceutical products and fermentation levels of ROMs had significant positive correlation (r = 0.41, p = 0.024).When the fermentation test of ROM was conducted in a rotary fermentor in a lab scale test, the residue levels of pharmaceutical products decreased effectively except carbamazepine (CBZ). The rates of decrease were in the case of tetracyclines (TCs): 85-92%, FQs: 81-100%, erythromycine: 67%, SAs: 79-95%, trimethoprim: 86% and CBZ: 37% by 30 d. Pharmaceutical products that can be decomposed by fermentation process at the lowest impact of residual antibiotic activities may therefore be considered as environmentally friendly medicines.     

Evaluation of violations in water quality standards in the monitoring network of São Francisco River basin,the third largest in Brazil

The São Francisco River is the largest river located entirely within Brazil, and water scarcity problems have been a major concern of Brazilian society and government. Water quality issues are also a concern and have worsened with the recent intensification of urbanization and industrialization. In this study, violations to water quality standards established by local legislation were calculated as a percentage for 26 selected parameters over a monitoring period of 14 years. The violation percentages were analyzed spatially using the Kruskal-Wallis test, followed by multiple comparison analysis. Temporal analysis was performed using the Mann-Kendall test and Spearman correlation. Some parameters could be identified as cause for concern due to high violation levels, such as the fecal coliform indicator (FCI) and phosphorus—both related to domestic and effluent disposal without treatment or with insufficient treatment—and color, turbidity, manganese, and total suspended solids—which can be affected by erosive processes of natural and anthropogenic causes. The study found that these violations are concentrated in the most urbanized and industrialized areas of the basin. Some metallic parameters, such as iron and arsenic violations, may be related to mining activities in the rich soil of the Iron Quadrangle area located within the Minas Gerais State. Trend analysis results indicated that most monitoring stations did not have significant modification (elevation or reduction) trends over time, which, together with the high violation percentages, might indicate the maintenance of a scenario of constant pressure upon water resources, in particular in those more urbanized areas.     

Detection of benzotriazole UV stabilizers in the blubber of marine mammals by gas chromatography-high resolution mass spectrometry (GC-HRMS)

Benzotriazole UV stabilizers (BUVSs), such as UV-328 and UV-327, were identified in the blubbers of finless porpoises (Neophocaena phocaenoides) collected from the Ariake Sea, western Japan, by gas chromatography-high resolution mass spectrometry (GC-HRMS). The mean concentrations and standard deviations of UV-328 and UV-327 in five blubber samples were 38 ± 28 ng g(-1) (lipid wt) and 19 ± 19 ng g(-1), respectively. The bioconcentration factor (BCF) of UV-327 between water and finless porpoises was estimated to be 33?300, which is approximately one order of magnitude higher than that found for small fish inhabiting the same regions. The BCF of UV-327 in finless porpoises was similar to that of persistent organochlorine pesticide, hexachlorocyclohexane (HCH: 37?000) in marine mammals from the western North Pacific Ocean. These results suggest that BUVSs appear to be persistent and bioaccumulative in the aquatic food chain. Further investigations on temporal trends, and regional and global monitoring of BUVSs are needed to understand their environmental profiles and potential risks to wildlife and human.     

Endocrine effects generated by photooxidation of coplanar biphenyls in water using titanium dioxide

The oxidative photodegradation behaviors of selected three coplanar polychlorinated biphenyls (PCBs), (CB77, CB81, and CB169) using titanium dioxide (TiO(2)) in water were investigated. The main purposes were to clarify the structural relation between the original PCBs and the intermediates derived by TiO(2) oxidation and to evaluate the estrogenic and thyroid hormonal activity in the treated three coplanar PCBs during the oxidative reactions. Approximately 90% of the three coplanar PCBs decomposed within 180 min. Intermediates from the decomposition of the three coplanar PCBs, such as some hydroxylated-PCBs (OH-PCBs), carboxylic intermediates, phenolic intermediates, and other intermediates produced by the cleavage of a benzene ring were identified and quantified. In the degradation pathways, the produced amounts of OH-PCBs increased within 60 min of irradiation time. The estrogenic activity and thyroid hormonal activity of the intermediates from the three coplanar PCBs in water at 0, 60, 120, 180 and 240 min of irradiation time were assessed by using a yeast two-hybrid assay system for human estrogen receptor alpha (hERalpha) and human thyroid hormone receptor alpha (hTRalpha). The maximal estrogenic activities were induced by the solutions of decomposed PCBs with irradiation time at 60-120 min similar and slightly lower than those after the irradiation time. We found that the solutions occuring during the irradiation times of 60-120 min contained several 4-OH-PCBs substituted with OH and Cl at para- and para'-positions having estrogenic activity. The thyroid hormonal activity was not detected in the decomposed three coplanar PCBs solutions.     

Norovirus GII.17 Associated with a Foodborne Acute Gastroenteritis Outbreak in Brazil, 2016

Foodborne transmission gastroenteritis (AGE) outbreak occurred during a celebration lunch in July, 2016, Brazil. All stool samples tested were positive for noroviruses (NoV) and phylogenetic analysis revealed that strains were genetically close to GII.17 Kawasaki_2014. These findings indicated circulation of NoV GII.17 Kawasaki_2014 in the Brazilian population, associated with AGE outbreak.     

Environmental impact assessment of sprayed-on asbestos in buildings

This study evaluated the environmental impacts of sprayed-on asbestos, which had been used as insulation material in buildings, from multiple perspectives, mainly at the disposal stage. The health risks from asbestos emission and energy consumption were estimated. Two disposal scenarios were assumed for the asbestos: melting for reduced-risk disposal and ordinary packaging/landfilling. We estimated the asbestos emission and health risk in the case of packaging/landfilling, assuming uncontrolled management of the landfill site. A difficulty with introducing health-risk concepts into life cycle assessment (LCA) is the pulse–flux problem, which is discussed in the light of these estimations. In order to solve this problem, we proposed a method using a conversion factor representing exposure-dose/emission, and showed that emission could be converted into health risk. We also estimated the energy consumption for melting asbestos in the disposal stage, which can decrease the health risk. If we consider the energy consumption for the life cycle of asbestos, only a little energy is required for melting, compared with the large amount of energy saved in the use stage owing to the insulating effect of the asbestos. The trade-off relationship between health risk and energy consumption for the disposal scenarios indicated the need for weighting methods to handle trade-offs such as this. Received: July 2, 1998 / Accepted: December 20, 1999     

A review of waste paper recycling networks focusing on quantitative methods and sustainability

Journal of Material Cycles and Waste Management - A discussion is currently under way in the literature on the sustainable benefits of recycling material, particularly paper, which has high global...     

Effects of work surface and task difficulty on neck–shoulder posture and trapezius activity during a simulated mouse task

Objectives. The purpose of this study is to evaluate the influence of the work surface and task difficulty on the head, upper back and upper arm postures and activity of the descending trapezius during a simulated mouse task. Methods. Healthy female university students (N?=?15) were evaluated. The work surface was positioned at elbow height (EH) and above elbow height (AEH) and the task difficulty was set at low (LD) and high (HD) levels. The postures were recorded by inclinometers. Trapezius activity was normalized by the maximum voluntary isometric contraction (MVIC). Results. Significantly higher head flexion was found at EH compared to the AEH condition, with an average difference of 2°–5° at the same difficulty level. The HD task significantly increased head (3°–6°) and upper back flexion (6°–7°) at the same table height. For upper arm elevation and trapezius activation, the AEH condition presented higher upper arm elevation (about 6°–8°) and trapezius activity (0.8–1.4% of MVIC), regardless of the difficulty level of the task. Conclusions. Head posture was influenced by the table height and task difficulty; the upper back posture by high difficulty; and upper arm posture and trapezius activity were only influenced by table height.