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41.
Alba Pineda-Solano Lina Saenz-Noval Subramanya Nayak Simon Waldram Maria Papadaki M. Sam Mannan 《Process Safety and Environmental Protection》2012,90(5):404-410
Alkylpyridine N-oxides are important intermediates in the pharmaceutical and agrochemicals industries. The N-oxides are produced via the homogeneously catalyzed oxidation of the respective alkylpyridines using a 50% excess of hydrogen peroxide. The competitive hydrogen peroxide decomposition produces oxygen in the flammable environment of alkylpyridines and thus forms a key hazard for this reaction. In this work, the N-oxidation was performed under pressure in the temperature range of 110–125 °C with different catalyst concentrations. It was shown that temperature had an undisputable positive effect on the N-oxidation efficiency. The accurate measurement of the pressure rise due to decomposition was difficult. However, only 5% of the added H2O2 decomposed when stoichiometric quantities were employed, even in the temperature of 110 °C. The N-oxidation was very efficient, even when the lowest concentration of catalyst employed in this study was used. 相似文献
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Anabela Botelho Lina Lourenço-Gomes Lígia M. Costa Pinto Sara Sousa Marieta Valente 《Environment, Development and Sustainability》2018,20(1):145-162
Despite the often mentioned environmental benefits associated with transition from fossil fuels to renewable energy sources, their use for electricity production has non-negligible negative environmental impacts. The most commonly mentioned in surveys concern different types of landscape impacts, impacts on the fauna and flora, and noise. These impacts differ by size and location of plants, and by source of energy, rendering the policy decision complex. In addition, there are other welfare issues to take into consideration, as positive and negative environmental impacts are not evenly distributed among population groups. This paper proposes to compare the welfare impacts of renewable energy sources controlling for the type of renewable as well as the specific environmental impact by source. To this end, two discrete-choice experiments are designed and applied to a national sample of the Portuguese population. In one case, only individual negative impacts of renewables are used, and in another case, the negative impacts interact with a specific source. Results show the robustness of discrete-choice experiments as a method to estimate the welfare change induced by the impacts of renewable energy sources. Overall, respondents are willing to pay to reduce the environmental impacts, thus making compensation for local impacts feasible. Moreover, the estimations reveal that respondents are significantly sensitive to the detrimental environmental effects of specific renewable energy sources, being willing to pay more to use these sources of energy relative to others. 相似文献
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通过阿尔山市2005年大气中总悬浮微粒(TSP)的全年三个监测点的监测结果,结合采样时有关气象参数,着重对TSP与气象条件的关系做一下分析、研讨。 相似文献
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Lina Wang Xinran Zheng Svetlana Stevanovi Xin Wu Zhiyuan Xiang Mingzhou Yu Jing Liu 《环境科学学报(英文版)》2018,30(10):98-106
Cooking fume produced by oil and food at a high temperature releases large amount of fine particulate matter(PM) which have a potential hazard to human health. This chamber study investigated particle emission characteristics originated from using four types of oil(soybean oil, olive oil, peanut oil and lard) and different kinds of food materials(meat and vegetable). The corresponding emission factors(EFs) of number, mass, surface area and volume for particles were discussed. Temporal variation of size-fractionated particle concentration showed that olive oil produced the highest number PM concentration for the entire cooking process. Multiple path particle dosimetry(MPPD) model was performed to predict deposition in the human respiratory tract. Results showed that the pulmonary airway deposition fraction was the largest. It was also found that particles produced from olive oil led to the highest deposition. We strongly recommend minimizing the moisture content of ingredients before cooking and giving priority to the use of peanut oil instead of olive oil to reduce human exposure to PM. 相似文献
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测量了高平潮、低平潮及两潮位之间三个时段某高桩码头工作平台的振动情况,比较了不同潮位下振动的最大位移值.对测量数据进行了分析,发现海浪对结构振动的位移大小影响明显,得到了工作平台的前三阶自振频率.利用两点差法,根据码头平动记录求取了码头沿垂直轴向的码头扭转分量,经计算码头转角在10-7rad量级,码头扭转的转动中心按照... 相似文献