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111.
Akira Ohki Tsunenori Nakajima Kentaro Hayashi Haruna Taniguchi Kousei Haraguchi Hirokazu Takanashi 《毒物与环境化学》2016,98(7):778-786
Mt. Sakurajima is a volcanic island in Japan, and a big city, Kagoshima, is quite close to the active volcano. Samples of volcanic ash fall erupted from Mt. Sakurajima were collected at several locations in Kagoshima City and analyzed for Hg and other elements, including major (Mg, Al, Ca, and Fe) and trace elements (V, Cr, Mn, Co, Ni, Zn, As, and Pb). The concentrations of Hg varied from 6.3 to 124 ng g?1, with the amounts of ash varying from 13 to 1230 g m?2 month?1. The Hg concentrations tended to be higher when the monthly amounts of ash fall were lower; other elements did not show such a tendency. 相似文献
112.
Akira Mori Gordon M. Burghardt Alan H. Savitzky Kathleen A. Roberts Deborah A. Hutchinson Richard C. Goris 《Chemoecology》2012,22(3):187-198
Of the various chemical defensive adaptations of vertebrates, nuchal glands are among the most unusual. First described in a Japanese natricine snake, Rhabdophis tigrinus, in 1935, these organs are embedded under the skin of the neck region as a series of paired glands that have neither lumina nor ducts. The major chemical components of the glandular fluid are bufadienolides, which are cardiotonic steroids also found in the skin secretion of toads. Here we review early studies of nuchal glands and briefly introduce our recent findings on the sequestration of bufadienolides from consumed toads and the maternal provisioning of those sequestered compounds. We summarize behavioral studies associated with the antipredator function of the nuchal glands, which have been conducted during our more than decade-long collaboration. Results of preliminary analyses on the possible costs of toad-eating and on the ultrastructure of the nuchal glands are also presented. Finally, we discuss the evolutionary origin of the nuchal glands and suggest future directions designed to understand the biological importance of these novel vertebrate organs, which have evolved in a limited number of snake species. 相似文献
113.
Mst. Shamsun Nahar Jing Zhang Akira Ueda Fujishiro Yoshihisa 《Environmental geochemistry and health》2014,36(6):1079-1094
The present study evaluated water supply geochemistry in Dhaka City, Bangladesh, to provide detailed trace level (subppb) water quality data that include major ions, low dissolved oxygen (DO) and toxic trace metals for sustainable development. Dhaka Groundwater, which almost uniformly meets the World Health Organization guideline, has become the preferred source. Due to groundwater depletion and an ever-increasing need to meet water demands by city residents, Dhaka water supply and sewerage authority has initiated the treatment of river water, despite the fact that very little is known about the geochemical structure, and trace metal content in the Dhaka water supply. Major ion composition of water samples was determined, and the results used to generate Stiff diagrams. The diagrams served to visually compare water from different sources based on units of mass/volume. Hydrochemical facies analysis showed supply ground and surface waters are comprised predominately of Ca–Na–Mg–HCO3 and Ca–Na–Mg–HCO3–Cl types. Spatial distribution of ions, and Na/Cl and Na/SiO2 molar ratio indicated that silicate weathering is the dominant geochemical process. Chemical data revealed that toxic Cr metal mobilization is associated with chemical hazards from the leather industry. The vulnerability of deep wells to contamination by As is governed by the geometry of induced groundwater flow paths and the geochemical conditions encountered between the shallow and deep regions of the aquifer. Quantifying total arsenic (As) and As from interlocking geochemical cycles (Fe, Mn) may assist in interpreting As dynamics in Dhaka well water. The surface source water was hypoxic to anoxic low DO associated with very high concentrations of biological oxygen demands, and electrical conductivity compared to industrial and non-industrial urban processes and standard activity guidelines. The results of this study should be applied to future research focused on the potential to improve water quality in urban and surrounding areas. 相似文献
114.
Pentachlorophenol (PCP) in contaminated soil was removed by treatment with aqueous solutions of iron(III)-porphyrin complexes as catalysts and potassium monopersulfate (KHSO5) as the oxygen donor. The contaminated soils were artificially prepared by spiking PCP to the kaolin and ando soils. Three types of iron(III)-porphyrin complexes, tetra(?p-sulfophenyl) porphineiron(III) (Fe(III)-TPPS), tetra(N-methyl-4-pyridil)porphineiron(III) (Fe(III)-TMPyP) and heme, were examined, and Fe(III)-TPPS was found to be the most effective for removing PCP. Although the sequential addition of KHSO5 was examined, in an attempt to improve the efficiency of PCP removal, it was not effective. In a preliminary test of various aqueous solutions, the addition of humic acid (HA), with a lower degree of humification, led to a significant enhancement in PCP removal. When HA was added to the soil system, the percentages of PCP removal were increased by up to 10% compared to the absence of HA. Therefore, the addition of HA to the catalytic system was useful in enhancing PCP removal from contaminated soil. 相似文献
115.
In this study, polychlorinated biphenyls (PCBs) were decomposed by low‐temperature heat treatment with metallic catalyst, and with metallic catalyst and a hydrogen source. Of the catalysts used, iron (Fe) was the most active catalyst for the decomposition of PCBs, and the decomposition was due to dechlorination. The addition of hydrogen sources accelerated the decomposition of PCBs in the presence of catalyst. Surface analysis of the catalyst using X‐ray photoelectron spectroscopy (XPS) suggested that the emitted chlorine was presumed to form metal chloride. The reactions of each homolog can be expressed by a successive first‐order reaction model. This means that a substituted chlorine is successively detached during this reaction. The overall decomposition rate in this reaction system was controlled by that of the lower chlorinated homologs. The decomposition rates with Fe and NaBH4 for the lower chlorinated homologs were about 10 times as fast as the rates with only Fe. 相似文献
116.
The objectives of this research are to propose a new impact response corridor for the ISO legform impactor and to determine the biofidelity of the current legform impactor with rigid leg and thigh developed by the Transport Research Laboratory (TRL). The latest data obtained from Post Mortem Human Subject (PMHS) knee impact tests were analyzed in connection with the proposal, and biofidelity legform impact tests were conducted using the current rigid legform impactor. New normalized biofidelic corridors of impact force corresponding to adult male 50th percentile (AM50) are proposed. The impact test results indicate the current rigid legform impactor does not have sufficient human knee biofidelity. The present results suggest that human tolerance can not be used directly for the injury reference value of the legform impactor. A conversion method is needed to interpret the data measured by current legform impactors as the injury reference value. 相似文献
117.
Structural changes of polyamideamine–epichlorohydrin (PAE) in solution during storage at 4 °C and pH 4.2–4.5 for up to 8.9 years were studied by 1H- and 13C-NMR analyses, colloidal titration and others. NMR signals due to 3-hydroxy-azetidinium groups of PAE decreased during storage, and correspondingly 2, 3-dihydroxypropyl groups were formed by the ring opening. The content of 3-hydroxy-azetidinium groups in PAE determined by 1H-NMR were similar to that determined by the colloidal titration, although the former was higher than the latter. About 50% of the 3-hydroxy-azetidinium groups present in the fresh PAE were lost during storage for 8.9 years. Furthermore, 13C-NMR analysis revealed that significant depolymerization of polyamideamine chains occurred by hydrolysis of the amide linkages during storage. Rough evaluation of number average degree of polymerization (DPn) of the amideamine repeating unit showed that the DPn decreased from 12 to 2 during storage for 8.9 years. 相似文献
118.
Oxygen Permeability and Biodegradability of Polyuronic Acids Prepared from Polysaccharides by TEMPO-Mediated Oxidation 总被引:2,自引:0,他引:2
Yumiko?Kato Jun-ichi?Kaminaga Rukichi?Matsuo Akira?IsogaiEmail author 《Journal of Polymers and the Environment》2005,13(3):261-266
Polyuronic acids, i.e., amylouronic acid, cellouronic acid and chitouronic acid, were prepared from starch, cellulose and chitin, respectively, by the 2,2,6,6-tetramethylpiperidine-1-oxy radical (TEMPO)-mediated oxidation, and their gas-barrier properties and biodegradability were studied in consideration to use the polyuronic acids as flexible packaging films or coating materials. Cellouronic acid and amylouronic acid had excellent oxygen-barrier properties similar to that of poly(vinyl alcohol) (PVA), while chitouronic acid did not. The regular chemical structures of the former two polyuronic acids with no bulky substituents or adducts may have brought about such high oxygen-barrier levels. An oxidized product prepared form fine microcrystalline cellulose by the TEMPO-mediated oxidation was not completely dissolved in water, but became a paste. However, this paste also formed sufficiently smooth films by coating, and had good gas-barrier property. All polyuronic acids prepared were biodegradable; cellouronic acid and chitouronic acid had high degrees of biodegradability, while amylouronic acid had quite low value. These various characteristics are significant for end use of these new polyuronic acids as gas-barrier materials for biodegradable packaging. 相似文献
119.
To evaluate the quantities of 137Cs from past nuclear tests being transported to and deposited in Japan by naturally-occurring phenomena, the authors developed long-range transport models for 137Cs considering Asian dust. The simulation using these models backed the observed recent increase of 137Cs deposition along the coast of the Sea of Japan in early spring. For the sake of public safety, it is vital to ascertain whether an increase of radioactive deposition is caused by natural phenomena or a nuclear accident. The observations in recent years have suggested that dust and soil containing 137Cs is transported from the regions around Inner Mongolia to Japan by the wind. In this paper, using observation data from the early spring of 2002 and 2006, the authors have found good agreement between the simulations and the measurements. The simulations reproduced the entrainment of 137Cs and subsequent transport to Japan caused by strong winds associated with low pressure areas around the Inner Mongolian grasslands. The most likely cause of high-level 137Cs deposition over northern Japan during March 2002 was 137Cs associated with particles transported at low-altitude (1 km) and subjected to precipitation on the 22nd to 24th. 相似文献
120.
Environmental Economics and Policy Studies - Assuming that consumption goods are differentiated in terms of environmental friendliness in a mixed duopolistic market, we present an analysis of... 相似文献