The Effect of Hydroxyl Radical Generation on Free-Radical Activation of TMP Fibers

The purpose of this work was to study the mechanisms involved in free radical activation of thermal mechanical pulp (TMP) fibers with the ultimate goal of developing methods for bonding wood fiber without the use of traditional adhesives. The generation of hydroxyl radicals in a mediated Fenton system was studied using electron spin resonance (ESR) spin-trapping techniques and indirectly through chemiluminescence measurement. The activation of TMP fibers was also evaluated by ESR measurement of free phenoxy radical generation on solid fibers. The results indicate that low molecular weight chelators can improve Fenton reactions, thus in turn stimulating the free radical activation of TMP fibers. However, it was also shown that excessive and prolonged free radical treatment may cause the destruction of fiber phenoxy radicals. In conclusion, this study demonstrates the potential for application, but also the complexity of free radical chemistry in biological materials, especially with regard to the chelation of transition metals and the interaction between free radicals.     

Phosphorus and nitrogen in rainfall simulation runoff after fresh and composted beef cattle manure application

Fresh beef cattle (Bos taurus) manure has traditionally been applied to cropland in southern Alberta, but there has been an increase in application of composted manure to cropland in this region. However, the quality of runoff under fresh manure (FM) versus composted manure (CM) has not been investigated. Our objective was to compare runoff quality under increasing rates (0, 13, 42, 83 Mg ha(-1) dry wt.) of FM and CM applied for two consecutive years to a clay loam soil cropped to irrigated barley (Hordeum vulgare L.). We determined total phosphorus (TP), particulate phosphorus (PP), dissolved reactive phosphorus (DRP), total nitrogen (TN), NH4-N, and NO3-N concentrations and loads in runoff after one (1999) and two (2000) applications of FM and CM. We found significantly (P < or = 0.05) higher TP, DRP, and NH4-N concentrations, and higher DRP and TN loads under FM than CM after 2 yr of manure application. The TP loads were also higher under FM than CM at the 83 Mg ha(-1) rate in 2000, and DRP loads were higher for FM than CM at this high rate when averaged over both years. Application rate had a significant effect on TP and DRP concentrations in runoff. In addition, the slope values of the regressions between TP and DRP in runoff versus application rate were considerably higher for FM in 2000 than for FM in 1999, and CM in both 1999 and 2000. Significant positive relationships were found for TP and DRP in runoff versus soil Kelowna-extractable P and soil water-extractable P for FM and CM in 2000, indicating that interaction of runoff with the soil controlled the release of P. Total P and DRP were the variables most affected by the treatments. Overall, our study found that application of CM rather than FM to cropland may lower certain forms of P and N in surface runoff, but this is dependent on the interaction with year, application rate, or both.     

Empirical and theoretical evidence concerning the response of the earth's ice and snow cover to a global temperature increase

As a guide to the possible effects of a CO₂-induced warming on the cryosphere, we review the effects of three warm periods in the past, and out theoretical understanding of fluctuations in mountain glaciers, the Greenland and Antarctic ice sheets, ground ice, sea ice and seasonal snow cover. Between 1890 and 1940 A.D. the glaciated area in Switzerland was reduced by over 25%. In the Hypsithermal, at about 6000 BP, ground ice in Eurasia retreated northward by several hundred kilometres. In the interglacial Stage 5e, at about 120 000 BP, global sea-level rose by over 6 m. Fluctuations of mountain glaciers depend on mesoscale “weather” and on their mechanical response to it. Any melting of the Greenland ice sheet is likely to be slow in human terms. The West Antarctic ice sheet (its base below sea-level) is susceptible to an ungrounding, and such an event may have been the cause of the sea-level rise above. The East Antarctic ice sheet is susceptible to mechanical “surges”, which might be triggered by a warming at its margin. Both an ungrounding and a surge might occupy less than 100 yr, and are potetially the most important ice changes in human terms. Modelling studies suggest that a 5°C warming would remove the Arctic pack ice in summer, and this may be the most significant effect for further climatic change.     

Safety Recommendations — The engine that drives change

The National Transportation Safety Board (NTSB) considers the recommendations it makes to prevent accidents and improve the safety of the United States transportation system to be its most important product.In its 25-year history the NTSB has made almost 9,000 safety recommendations covering needed improvements in all the modes of transportation to more than 1,250 recipients. These recommendations are made to anyone the NTSB believes can make the change that is necessary to improve safety. Recommendations have been directed to federal, State and local government agencies, private transportation companies, labor unions, trade associations and others.Overall, more than 80 percent of the NTSB's safety recommendations have been accepted by the recipients and the changes called for have been implemented. This has had a very significant positive impact on the safety of the US transportation system. The NTSB is very proud of this record. The changes that have taken place as a result of the NTSB's recommendations have saved thousands of lives and prevented many accidents.How has the NTSB achieved such a good record? The basic foundation and most important reason for this achievement is the NTSB's independence. This independence lends the NTSB credibility. Recipients of the NTSB's recommendations are more willing to carefully and seriously consider taking the action recommended. The second essential reason for the NTSB's credibility is the highly competent, technical qualifications of its investigators and the thoroughness of its investigations and studies. The NTSB also is very careful and prudent in making its recommendations. Each proposed recommendation is carefully evaluated to make sure it is practical, feasible and capable of being implemented. The credibility of the NTSB has grown over the years, and along with that has come an increase in the acceptance rate of the recommendations.This paper will describe the NTSB's safety recommendation program, how it achieves improved safety, and its important elements, such as the Most Wanted Safety Recommendation Program and the Safety Recommendation Information System.     

Monitoring of iodinated X-ray contrast media in surface water

A monitoring programme was carried out in order to determine iodinated X-ray contrast media (ICM) in the River Danube and to investigate the raw water quality for drinking water production at Langenau waterworks. The study revealed that the maximum concentrations of ICM (over 500 ng l(-1) for diatrizoic acid and iopamidol) were found in 2h-composite samples taken from the downstream of the Ulm/Neu-Ulm metropolitan area. By means of a concentration profile over one month the highest ICM concentrations were observed on weekdays. The extended data evaluation with principal component analysis shows that the upstream and downstream samples had different pattern of variations in ICM concentration and also demonstrates a clear change in ICM composition by the discharge of municipal wastewater. In addition to load profiles of ICM, time-dependent plots of principal component 1 exhibited peaks, indicating a short-term discharge of ICM between the two sampling sites. In conclusion, a point source for ICM contamination between the sampling sites in Ulm upstream and Leipheim downstream seems to be the reasonable explanation for peak ICM concentrations. Due to the observed high variations of ICM concentrations in river, the evaluation of natural waters by means of a single analysis is not representative.     

Lattice-based methods for regression and density estimation on complicated multidimensional regions

Environmental and Ecological Statistics - This paper illustrates the use of diffusion kernels to estimate smooth density and regression functions defined on highly complex domains. We generalize...     

Climate change,food security,and livelihoods in sub-Saharan Africa

Sub-Saharan Africa is particularly vulnerable to climate change. Multiple biophysical, political, and socioeconomic stresses interact to increase the region’s susceptibility and constrain its adaptive capacity. Climate change is commonly recognized as a major issue likely to have negative consequences on food security and livelihoods in the region. This paper reviews three bodies of scholarship that have evolved somewhat separately, yet are inherently interconnected: climate change impacts, vulnerability and adaptation, food security, and sustainable livelihoods. The paper develops a conceptualization of the relationships among the three themes and shows how food security’s vulnerabilities are related to multiple stresses and adaptive capacities, reflecting access to assets. Food security represents one of several livelihood outcomes. The framework shows how several research paradigms relate to the issue of food security and climate change and provides a guide for empirical investigations. Recognizing these interconnections can help in the development of more effective policies and programs. The framework is applied here to synthesize findings from an array of studies in sub-Saharan Africa dealing with vulnerability to climate change, food security, and livelihoods.     

Modelling gas release event behaviour in hazardous waste tanks

Certain radioactive waste storage tanks at the United States Department of Energy Hanford facilities continuously generate gases as a result of radiolysis and chemical reactions. The congealed sludge in these tanks traps the gases beneath it and causes the level of the waste within the tanks to rise. The waste level continues to rise until the sludge loses its buoyancy and rolls over, changing places with fluid on top. During a rollover, the trapped gases are released, resulting in a sudden drop in the waste level. This is known as a gas release event (GRE). After a GRE, the waste re-congeals and gas again accumulates, leading to another GRE. We are interested in the time between consecutive GREs. Understanding the probabilistic behaviour of the time between consecutive GREs is important because the hydrogen and nitrous oxide gases released during a GRE are flammable and the ammonia that is released is a health risk. From a safety perspective, activity around such waste tanks should be halted when a GRE is imminent. With a credible probability model for the time between consecutive GREs, we can establish time windows in which waste tank research and maintenance activities can be safely performed. We discuss the application of non-linear time series models to this problem.