Enhanced biodegradation of azo dyes using an integrated elemental iron-activated sludge system: I. Evaluation of system performance.

The objective of this research is to evaluate an integrated system coupling zero-valent iron (Fe(0)) and aerobic biological oxidation for the treatment of azo dye wastewater. Zero-valent (elemental) iron can reduce the azo bond, cleaving dye molecules into products that are more amenable to aerobic biological treatment processes. Azo dye reduction products, including aniline and sulfanilic acid, were shown to be readily biodegradable at concentrations up to approximately 25 mg/L. Batch reduction and biodegradation data support the proposed integrated iron pretreatment and activated sludge process for the degradation of the azo dyes orange G and orange I. The integrated system was able to decolorize dye solutions and yield effluents with lower total organic carbon concentrations than control systems without iron pretreatment. The success of the bench-scale integrated system suggests that iron pretreatment may be a feasible approach to treat azo dye containing wastewaters.     

Polychlorinated dibenzo-p-dioxins (PCDDs) and furans (PCDFs) in urban air and deposition in the United Kingdom

Polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) have been monitored in air and deposition at four UK urban sites (London, Cardiff, Manchester and Stevenage) since the beginning of 1991; data from the first 2 years are presented here. Median Σ2,3,7,8-substituted PCDD/F concentrations in air were 3.2, 4.0, 3.5 and 2.6 pg/m³ respectively for London, Cardiff, Manchester and Stevenage. Median Σ2,3,7,8-substituted PCDD/F deposition fluxes were 1.5 ng/m²/day in London, 1.4 ng/m²/day in Cardiff and Manchester and 0.79 ng/m²/day in Stevenage. Seasonal variations in the PCDD/F concentrations were observed at all sites for both air and deposition, with concentrations/fluxes generally elevated during the winter.     

Polycyclic aromatic hydrocarbons in sediments and associated benthos in Lake Erie

Polycyclic aromatic hydrocarbons (PAH) were analyzed in surficial sediments and benthic organisms in southwestern Lake Erie near a large coal fired power plant. Sediment concentrations (530–770 ppb PAH) were relatively homogenous throughout most of the 150 km² area, although river and nearshore concentrations reached nearly 4 ppm. Oligochaete worms and chironomid midges were near equilibrium with local sediments except for enhanced concentrations in nearshore midges.     

Influence of soil hydrological pathways on stream aluminium chemistry at Llyn Brianne, mid-wales

Storm runoff in afforested catchments at Llyn Brianne is acidic and Al-bearing. At baseflows, stream water is well-buffered with low Al levels. This paper presents the results of a study into how hydrological pathways account for these variations in stream-water chemistry. The investigation was carried out in the LI1 catchment; a 0.4-ha subcatchment covered by stagnohumic gley soils was monitored between October 1988 and September 1989. An instrumented hill-slope was established to identify the hydrological pathways that control the hydrochemistry of storm runoff draining from the subcatchment. Perched watertables developed in the surface horizons of the soil during storm episodes and produced lateral flow above the impeding subsoil. This near-surface flow path was responsible for generating acid, Al-rich storm runoff. Some water drained vertically through the soil profile into the underlying slope drift; seepage from groundwater in the drift sustained baseflows. Buffering reactions in the groundwater zone reduced the acidity and Al levels of baseflows. These hydrochemical characteristics are likely to be representative of other areas of stagnohumic gley soils, which cover 19% of the LI1 catchment: these soils may therefore provide a substantial source of acid, Al-bearing storm runoff in LI1 and similar afforested catchments.     

USE AND MISUSE OF COMPLEX MODELS: EXAMPLES FROM WATER DEMAND MANAGEMENT1

ABSTRACT: The power of computers has increased in recent decades, and one might expect improved management to result because decisions can be made with understanding available only via models. However, there is potential for quite the opposite: poor decisions due to unrealistic model output generated by users without access to appropriate training in the use of models. We discuss and, by reference to water demand models (IWR-MAIN, MWD-MAIN), illustrate three areas in which unintended errors of judgment by untrained personnel may cause difficulty:

• * Attributes of management models; if output from any type of model has no measure of confidence, then results may be over- or undervalued
• * Input data; with complex models, problems here typically will be difficult to detect.
• * Calibration and history-matching (verification); if these steps or data are combined, then users should be less trustful of model output than otherwise.

Because all models have weaknesses and because there always is uncertainty about output from any model, we end with suggestions for coping with complex models. Monitoring programs play a central role in such efforts because they can identify discrepancies between model predictions and actual events and because they can ensure time is available to develop solutions for problems unanticipated in the modeling effort.     

Pollution and Genetic Structure of North American Populations of the Common Dandelion (Taraxacum Officinale)

Assessing the genetic structure of natural populations differentially impacted by anthropogenic contaminants can be a useful tool for evaluating the population genetic consequences of exposure to pollution. In this study, measures of genetic diversity at variable-number-tandem-repeat loci in six dandelion populations (3 urban and 3 rural) showed patterns that may have been influenced by exposure to environmental contaminants. Mean genetic similarity among individuals within a population was significantly and positively correlated with increasing levels of airborne particulate matter ( 10 m, PM₁₀) and soil concentrations of four metals (Cd, Fe, Ni and Pb). In addition, mean genetic similarity was always significantly higher at the urban sites compared to rural sites. There was a significant negative correlation between the number of genotypes at a site and increasing amounts of PM₁₀, concentrations of five soil metals (Cd, Cu, Fe, Ni and Pb), leaf tissue levels of Fe and a significant positive correlation between the extent of clonality at a site and levels of PM₁₀ and soil concentrations of five metals (Cd, Cu, Fe, Ni and Pb). Although, this study does not directly establish a causal link between the specific contaminants detected at the study sites and differences in genetic diversity, our data are consistent with the hypothesis that pollution-induced selection has contributed in some fashion to the lower genetic diversity found at the urban sites.     

Membrane-based wet electrostatic precipitation

Emissions of fine particulate matter, PM2.5, in both primary and secondary form, are difficult to capture in typical dry electrostatic precipitators (ESPs). Wet (or water-based) ESPs are well suited for collection of acid aerosols and fine particulates because of greater corona power and virtually no re-entrainment. However, field disruptions because of spraying (misting) of water, formation of dry spots (channeling), and collector surface corrosion limit the applicability of current wet ESPs in the control of secondary PM2.5. Researchers at Ohio University have patented novel membrane collection surfaces to address these problems. Water-based cleaning in membrane collectors made of corrosion-resistant fibers is facilitated by capillary action between the fibers, maintaining an even distribution of water. This paper presents collection efficiency results of lab-scale and pilot-scale testing at FirstEnergy's Bruce Mansfield Plant for the membrane-based wet ESP. The data indicate that a membrane wet ESP was more effective at collecting fine particulates, acid aerosols, and oxidized mercury than the metal-plate wet ESP, even with approximately 15% less collecting area.     

Estimating the aqueous solubility of aromatic hydrocarbons by high performance liquid chromatography

Empirical equations which correlate high performance liquid chromatography capacity factor (k′) to aromatic hydrocarbon aqueous solubility are developed. The correlations of k′ to octanol-water partition coefficients, and k′ to hydrocarbon surface area are also shown.     

Evaluation of the toxicity of substances to be assessed for biodegradability

The ability to distinguish between true non-biodegradability, and inhibition of biodegradability due to the toxic effects of the compound tested present problems. It results in possible false identification of substances as non-biodegradable.Six chemicals were evaluated in a variety of tests to assess their toxicity to aerobic sludge organisms. The tests employed were: BOD₅ and Closed Bottle inhibition tests, inhibition of respiration of activated sludge, growth inhibition of activated sludge, light emission from (MICROTOX test) and the repetitive die-away test (RDA). Results from these tests were compared with results obtained from a number of ready biodegradability tests using the compounds listed above at anticipated non-toxic and toxic concentrations.No test method evaluated consistently forecast toxicity due to the chemicals tested. The MICROTOX and nitrification inhibition tests were too sensitive. A combination of sludge respiration rate and/or growth tests seem most appropriate. To avoid toxicity to the sludge, biodegradability testing should be made at 10% of the EC₅₀ value. Compounds with an EC₅₀ value greater than 300 mg/l are unlikely to be toxic in ready biodegradability tests. Compounds with an EC₅₀ value of less than 20 mg/l may pose problems necessitating the use of the stringent closed bottle test, or the use of C¹⁴ labelled test materials. Compounds with an intermediate EC₅₀ that is between 20–300 mg/l, need to be evaluated at a range of concentrations in biodegradability tests, or may need to be evaluated carefully to define the precise no-effect level. Procedure recommendations to distinguish between the inhibition of biodegradability and inertness of the test substance are made.