Sequential UV-biological degradation of chlorophenols

The sequential UV-biological degradation of a mixture of 4-chlorophenol (CP), 2,4-dichlorophenol (DCP), 2,4,6-trichlorophenol (TCP), and pentachlorophenol (PCP) was first tested with each pollutant supplied at an initial concentration of 50 mg l(-1). Under these conditions, the chlorophenols were photodegraded in the following order of removal rate: PCP>TCP>DCP>CP with only CP and DCP remaining after 40 h of irradiation. The remaining CP (41 mg l(-1)) and DCP (13 mg l(-1)) were then completely removed by biological treatment with an activated sludge mixed culture. Biodegradation did not occur in similar tests conducted with a non-irradiated mixture due to the high microbial toxicity of the solution. UV treatment lead to a significant reduction of the phytotoxicity to Lipedium sativum but no further reduction of phytotoxicity was observed after biological treatment. Evidence was found that the pollutants were partially photodegraded into toxic and non-biodegradable products. When the pollutants were tested individually (initial concentration of 50 mg l(-1)), PCP, TCP, DCP, 4-CP were photodegraded according to first order kinetic model (r2>99) with half-lives of 2.2, 3.3, 5.7, and 54 h, respectively. The photoproducts were subsequently biodegraded. This study illustrates the potential of UV as pre-treatment for biological treatment in order to remove toxicity and enhance the biodegradability of organic contaminants. However, it also shows that UV treatment must be carefully optimized to avoid the formation of toxic and/or recalcitrant photoproducts and results from studies conducted on single contaminants cannot be extrapolated to mixtures.     

HYDROLOGICAL,METEOROLOGICAL, AND AGRICULTURAL RELATIONS IN NORTHERN IRAQ1

ABSTRACT: The northern regions of Iraq, an area comprised of mountains and undulating plains, has for centuries been the main granary for the country. Its agricultural production is largely dependent upon natural rainfall which ranges from about 300 to 1,000 mm/yr. Grain yields can be greatly improved by use of improved varieties and management practices. Equations are developed to show relationships between various hydrologic and meteorologic parameters with yields of wheat and barley. The amount of supplementary water needed to maximize grain yields is also shown.     

Long-Term Maintenance of Rapid Atrazine Degradation in Soils Inoculated with Atrazine Degraders

Two different microbial communities able to degrade atrazine (atz) were inoculated in four different soils. The most critical factor affecting the success of inoculation was the soil pH and its organic matter (OM) content. In two alkaline soils (pH > 7), some inoculations led immediately to a strong increase of the biodegradation rate. In a third slightly acidic soil (pH = 6.1), only one inoculum could enhance atz degradation. In a soil amended with organic matter and straw (pH = 5.7, OM = 16.5%), inoculation had only little effect on atz dissipation on the short as well as on the long-term. Nine months after the microflora inoculations, atz was added again and rapid biodegradation in all alkaline inoculated soils was recorded, indicating the long-term efficiency of inoculation. In these soils, the number of atz degraders was estimated at between 6.5 × 10³ and 1.5 × 10⁶ (g of soil)^-1, using the most probable number (MPN) method. Furthermore, the presence of the atz degraders was confirmed by the detection of the gene atzA in these soils. Denaturing gradient gel electrophoresis (DGGE) analysis of the 16S rDNA genes indicated that the inoculated bacterial communities had little effect on the patterns of the indigenous soil microflora.     

Freight transport and non-driving work duties as predictors of falling asleep at the wheel in urban areas of Crete

BACKGROUND: This study investigated the impact of subjective reports of drowsy driving and non-driving duties on the falling asleep responses and road crash involvement of professional drivers in Crete. An attempt was also made to elucidate other driving parameters, such as freight transportation, which could be potential predictors of risky driving, after controlling for lifestyle patterns. METHOD: A sample of 317 professional drivers was studied through personal interviews. The interview questionnaire included items about sleep and fatigue as contributing factors to falling asleep probability and crash risk. In addition, the drivers reported the type of freight they carried in their last trip, as well as practices such as smoking and alcohol consumption. RESULTS: The first logistic regression analysis showed that the most significant predictors of falling asleep at the wheel were transportation of fruits/vegetables and livestock, non-driving hours of work, insufficient hours of sleep, and smoking. The second logistic regression analysis revealed all the previous items as powerful factors of crash probability, including the transportation of express freight and freezer. IMPACT: The findings of the current study are discussed as they pertain to directions for future studies and for the development of fatigue countermeasures.     

Use of cement dust in the manufacture of vitrified sewer pipes

Waste by-pass cement dust was added in different percentages ranging from 2% to 10% to a standard mix for sewer pipes manufacture, as a substitute for expensive feldspar. It was found that a mix consisting of 45% kaolin, 36% ball clay, 9% grog and 10% by-pass dust and fired at a temperature of 1300 degrees C for 4 h yielded samples that meet the standards. It was possible to reach a water absorption of 4%, a modulus of rupture of 7.8 MPa and a resistance to acids and alkalis conforming with standard values. A test pipe was fabricated by vacuum extrusion using the suggested composition and was found to withstand a hydraulic pressure of 14 MPa for one minute without the appearance of any cracks.     

Element mobility during metasomatism of granitic rocks in the Saint-Chély d'Apcher area (Lozère,France)

This paper summarises the behaviour of major and trace elements during hydrothermal alteration processes in the Vareilles albite deposit, Saint-Chély d' Apcher area (Lozère, France). Sampling focused mainly on fine- to medium-grained two-mica granite facies surrounding albitite veins in two open pits. The primary chemical variability inherent in sampling parent rock and analytical uncertainties can seriously affect element mobility calculations. Here we present a simple model that allows to discriminate between magmatic and alteration effects and to make a proper evaluation of the chemical changes that have caused the alteration. For this reason, a range of unaltered granites and albitites were sampled to evaluate the degree of parent rock heterogeneity. Duplicate measurements were performed by epithermal neutron activation analysis (ENAA) to obtain a reliable mean concentration for trace elements and to evaluate results reproducibility. ENAA measurements are completed by analysis of major elements by inductively coupled plasma-mass spectrometry (ICP-MS). The enrichment or depletion of an element during alteration, relative to its concentration in fresh parent rock, can be calculated on the basis of the assumed immobility of some elements during the process. In this study, we have assumed Ta as immobile element on the basis for his inert behaviour. The distinct differences in chemical change between altered and unaltered granite suggest the need to consider alteration event as an important parameter in evaluating granitic rocks for nuclear waste disposal.     

Assessment of mammal reproduction for hunting sustainability through community‐based sampling of species in the wild

Wildlife subsistence hunting is a major source of protein for tropical rural populations and a prominent conservation issue. The intrinsic rate of natural increase. (r_max) of populations is a key reproductive parameter in the most used assessments of hunting sustainability. However, researchers face severe difficulties in obtaining reproductive data in the wild, so these assessments often rely on classic reproductive rates calculated mostly from studies of captive animals conducted 30 years ago. The result is a flaw in almost 50% of studies, which hampers management decision making. We conducted a 15‐year study in the Amazon in which we used reproductive data from the genitalia of 950 hunted female mammals. Genitalia were collected by local hunters. We examined tissue from these samples to estimate birthrates for wild populations of the 10 most hunted mammals. We compared our estimates with classic measures and considered the utility of the use of r_max in sustainability assessments. For woolly monkey (Lagothrix poeppigii) and tapir (Tapirus terrestris), wild birthrates were similar to those from captive populations, whereas birthrates for other ungulates and lowland‐paca (Cuniculus paca) were significantly lower than previous estimates. Conversely, for capuchin monkeys (Sapajus macrocephalus), agoutis (Dasyprocta sp.), and coatis (Nasua nasua), our calculated reproductive rates greatly exceeded often‐used values. Researchers could keep applying classic measures compatible with our estimates, but for other species previous estimates of r_max may not be appropriate. We suggest that data from local studies be used to set hunting quotas. Our maximum rates of population growth in the wild correlated with body weight, which suggests that our method is consistent and reliable. Integration of this method into community‐based wildlife management and the training of local hunters to record pregnancies in hunted animals could efficiently generate useful information of life histories of wild species and thus improve management of natural resources.     

Quinoa value chain,adoption, and market assessment in Morocco

Environmental Science and Pollution Research - Agriculture faces many challenges such as climate change, droughts, and salinity, which requires urgent interventions for fast adaptation and...     

Mass-transfer processes of chromium(VI) adsorption onto guava seeds

The chromium(VI) biosorption onto guava seeds, as an alternative method for Cr⁶⁺ removal from aqueous solutions, was investigated. The parameters affecting kinetics and equilibrium of Cr⁶⁺ adsorption onto guava seeds were studied. An external mass-transfer diffusion coefficient k and intra-particle diffusion coefficient k_i were determined to measure the rate-limiting step of adsorption. A single external mass-transfer diffusion model and intra-particle diffusion models were used. The effects of initial pH, sorbent mass, and initial Cr⁶⁺ concentrations on mass-transfer coefficients were investigated. The external mass-transfer coefficient has an average value of 7.2×10^-3 cm s^-1, while the intra-particle mass-transfer diffusion coefficient was 0.34 mg g^-1 min^-0.5. This indicates that external diffusion to the guava seeds surface and intra-particle diffusion are both involved in the sorption process. The isotherm equilibrium data were well fitted by the Langmuir and Freundlich models with an average correlation coefficient R²=0.98. The maximum removal of Cr⁶⁺ was obtained at pH 1 (about 100% for adsorbent dose of 15 g l^-1 and 25 mg l^-1 initial concentration of Cr⁶⁺). The results indicated that the guava seeds exhibit acceptable sorption capacity.