Exposure to airborne organophosphates originating from hydraulic and turbine oils among aviation technicians and loaders

This study describes the potential for occupational exposure to organophosphates (OPs) originating from turbine and hydraulic oils, among ground personnel within the aviation industry. The OPs tri-n-butyl phosphate (TnBP), dibutyl phenyl phosphate (DBPP), triphenyl phosphate (TPP) and tricresyl phosphate (TCP) have been emphasized due to their use in such oils. Oil aerosol/vapor and total volatile organic compounds (tVOCs) in air were also determined. In total, 228 and 182 OPs and oil aerosol/vapor samples from technician and loader work tasks during work on 42 and 21 aircrafts, respectively, were collected in pairs. In general, the measured exposure levels were below the limit of quantification (LOQ) for 84%/98% (oil aerosol) and 82%/90% (TCP) of the samples collected during technician/loader work tasks. The air concentration ranges for all samples related to technician work were 相似文献   

How to foster agroecological innovations? A comparison of participatory design methods

Facing contemporary environmental crisis implies fostering agroecological innovations that take into account local ecological regulations and rely on multiple stakeholders' innovation capacities. This paper draws on two fields of literature that remain unconnected so far: participatory approaches and design sciences. It proposes an analysis grid to support a reflexive analysis of cases of implementation of three participatory design methods: ComMod (Companion Modelling for concerted management of natural resources), Forage Rummy (simulation-based board game for designing farming systems) and KCP (collective design workshops to foster innovation). This analysis highlights key features of the methods in view of agroecological innovation challenges, focusing on knowledge management and organisation for exploration.     

Short-term effect of fine particulate matter (PM<Subscript>2.5</Subscript>) and ozone on daily mortality in Lisbon,Portugal

Introduction  

Urban ambient air pollution exposures continue to be a global public health concern. Although air quality targets are often exceeded in Lisbon, the largest city in Portugal, there is currently no study that has assessed the quantitative impact of these pollutants on daily mortality.     

Thymol as an alternative to pesticides: persistence and effects of Apilife Var on the phototactic behavior of the honeybee Apis mellifera

Thymol is a natural substance increasingly used as an alternative to pesticides in the fight against the Varroa destructor mite. Despite the effectiveness of this phenolic monoterpene against Varroa, few articles have covered the negative or side effects of thymol on bees. In a previous study, we have found an impairment of phototaxis in honeybees following application of sublethal doses of thymol—lower or equal to 100 ng/bee—under laboratory conditions. The present work shows the same behavioral effects on bees from hives treated with Apilife Var®, a veterinary drug containing 74 % thymol, with a decrease in phototactic behavior observed 1 day after treatment. Thus, thymol causes disruption of bee phototactic behavior both under laboratory conditions as well as in beehives. The bee exposure dose in treated hives was quantified using gas chromatography coupled to mass spectrometry (GC–MS), giving a median value of 4.3 μg per body 24 h after treatment, with 11 ng in the brain. The thymol level in 20 organic waxes from hives treated with Apilife Var® was also measured and showed that it persists in waxes (around 10 mg/kg) 1 year after treatment. Thus, in the light of (1) behavioral data obtained under laboratory conditions and in beehives, (2) the persistence of thymol in waxes, and (3) the high load on bees, it would appear important to study the long-term effects of thymol in beehives.     

Report: New guidelines for characterization of municipal solid waste: the Portuguese case

This report proposes a new set of guidelines for the characterization of municipal solid waste. It is based on an analysis of reference methodologies, used internationally, and a case study of Valorsul (a company that handles recovery and treatment of solid waste in the North Lisbon Metropolitan Area). In particular, the suggested guidelines present a new definition of the waste to be analysed, change the sampling unit and establish statistical standards for the results obtained. In these new guidelines, the sampling level is the waste collection vehicle and contamination and moisture are taken into consideration. Finally, focus is on the quality of the resulting data, which is essential for comparability of data between countries. These new guidelines may also be applicable outside Portugal because the methodology includes, besides municipal mixed waste, separately collected fractions of municipal waste. They are a response to the need for information concerning Portugal (e.g. Eurostat or OECD inquiries) and follow European Union municipal solid waste management policies (e.g. packaging waste recovery and recycling targets and the reduction of biodegradable waste going to landfill).     

210Pb geochronology and trace metal fluxes (Cd, Cu and Pb) in the Gulf of Tehuantepec, South Pacific of Mexico

Distributions of Al, Cd, Cu, Fe, Li, Mn and Pb were analyzed in a sediment core collected in the Gulf of Tehuantepec, an important fisheries region located in the South Pacific of Mexico, where data on metal accumulation and accretion rates were previously almost nonexistent. Depth profiles of metal concentrations were converted to time-based profiles by using a 210Pb-derived vertical accretion rate, estimated to be 0.05 cm year(-1) on the average. Sediments were dated up to 8 cm depth, corresponding to a layer of ca. 140 years old. The historical changes of metal accumulation along the sediment core have shown a moderate enrichment of Cd, Cu and Pb concentrations at present, of about threefold the corresponding background concentrations. Chronological trace metal records showed that metal fluxes have increased over the last 20 years, reaching the maximum values at present of 2.5, 22.5 and 45.8 (microg cm(-2) year(-1)) for Cd, Pb and Cu, respectively. These increments in metal fluxes are likely influenced by the development of anthropogenic land-based activities since over this period of time oil production activities in the region have had a significant development.     

Social demand for multiple benefits provided by Aleppo pine forest management in Catalonia,Spain

This paper estimates the social demand for key benefits provided by Aleppo pine forests in Catalonia that can be enhanced by management. These so-called externalities are the side effects of forest management on citizens’ welfare and can be either positive or negative. The externalities addressed are: biodiversity (measured as the number of tree species), accessibility for practicing recreational activities, CO₂ sequestration and annual burned area by wildfires. By the use of a choice experiment, an economic valuation method, we estimate in a joint manner people’s preferences for these externalities and show that there is a social demand for their enhanced provision. Based on these estimates, we construct three hypothetical scenarios reflecting the range of likely outcomes of different management strategies and calculate the social demand for these scenarios. Results show that the highest gains in terms of social benefits are obtained under a scenario that minimizes the burned area (2044.23 €/ha year). Our estimates show that an increase in the investment in forest management is in line with the social demand for forest benefits and the social support that exists for a related cost increase for inhabitants.     

Cover Crops and Water Quality

Environmental Modeling & Assessment - This work deals with the regulation of water pollution caused by the use of nitrogen in agriculture. We investigate the policy instruments that should be...